CN103269594A - Synergistic herbicidal composition containing penoxsulam and benfuresate - Google Patents
Synergistic herbicidal composition containing penoxsulam and benfuresate Download PDFInfo
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- CN103269594A CN103269594A CN2011800618390A CN201180061839A CN103269594A CN 103269594 A CN103269594 A CN 103269594A CN 2011800618390 A CN2011800618390 A CN 2011800618390A CN 201180061839 A CN201180061839 A CN 201180061839A CN 103269594 A CN103269594 A CN 103269594A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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Abstract
An herbicidal composition containing (a) penoxsulam and (b) benfuresate provides synergistic control of selected weeds. The synergistic mixture of the present invention can be used on acetolactate synthase inhibitor tolerant crops. The synergistic composition of the present invention can, further, be used in conjunction with 2,4-D, glyphosate, glufosinate, dicamba or imidazolinones on 2,4-D tolerant, glyphosate-tolerant, glufosinate-tolerant, dicamba-tolerant or imidazolinone-tolerant crops.
Description
Crop protected to make it be problem of incessant recurrence in the agricultural away from the weeds that suppress plant growth and other vegetation.In order to help to address this problem, the researcher in synthetic chemistry field has produced number of chemical product and the chemicals of the described unnecessary growth of effective control.The chemical herbicide of many types discloses in the literature, and the number of chemical weed killer herbicide has been used for commercial use.
In some cases, prove that more effective when ratio is used separately during weeding active component combined administration, this is called " synergy ".As Herbicide Handbook of the Weed Science Society of America, Eighth Edition, 2002, p.462 described in, " ' synergy ' is two or more factor interactions, thereby the effect in when combination is greater than the prediction effect of the response when using separately based on each factor ".The present invention is based on such discovery: the known benfuresate that has the weeding effect separately (benfuresate) and penoxsuam (penoxsulam) demonstrate synergistic effect when Combination application.
Summary of the invention
The present invention relates to the Synergistic herbicidal mixture, it comprises (a) penoxsuam of herbicidally effective amount and (b) benfuresate.Described composition also can contain agriculture acceptable assistant or carrier.
The invention still further relates to control and do not expect the method for the growth of vegetation, particularly in paddy.
Penoxsuam is the (common name of 2-(2,2-difluoroethoxy)-N-(5,8-dimethoxy-[1,2,4] triazols [1,5-c] pyrimidine-2-base)-6-(trifluoromethyl) benzsulfamide.Its activity of weeding is described in The Pesticide Manual, and Fifteenth Edition is in 2009.Barnyard grass grass and multiple broad-leaved nutgrass flatsedge and aquatic weed in the penoxsuam control paddy.
Benfuresate is ethyl sulfonic acid 2,3-dihydro-3, the common name of 3-dimethyl-benzofuran-5-base ester.Its activity of weeding is described in The Pesticide Manual, and Fifteenth Edition is in 2009.Benfuresate control dogstail and broad leaved weed.
Term weed killer herbicide used in this application is represented kill plants, control plant or is otherwise changed the active component of plant growth unfriendly.Herbicidally effective amount or vegetation control amount are the amounts that causes unfavorable change effect and comprise the active component of effects such as deviating from nature is grown, kills, regulates, dewatered, delay.Term " plant (plant) " and " vegetation (vegetation) " are intended to comprise seeds germinated (germinant seed), incipient seedling (emerging seedling), the plant (plants emerging from vegetative propagules) that germinates from vegetative propagule and the vegetation (established vegetation) that has grown up to.
When Synergistic mixtures was applied directly to plant or plant location at any vegetative stage or in plantation or before emerging, the compound exhibits of described Synergistic mixtures went out activity of weeding.Granularity, environmental condition, the particular compound that adopts, the concrete auxiliary agent that adopts and carrier when using, soil types of the administration parameters of vegetative stage, dilution of plant species to be prevented and treated, plant and spray droplet size (spray drop size), solid constituent etc. depended in viewed effect, and the amount of the chemicals that adopts.Known in the art is can adjust these and other factor, to promote non-selective or the selective herbicidal effect.Generally speaking, preferably with present composition postemergence application to the immature relatively vegetation of not expecting, thereby realize maximum control to weeds.
In composition of the present invention, benfuresate is 6:1 to 95:1 with the active component that plays the Synergistic herbicidal effect of penoxsuam than (wt:wt) scope, and preferred range is 8:1 to 40:1.
The rate of application of cooperative compositions depends on the particular type of the weeds that will prevent and treat, degree, the opportunity of using and the method for needs control.Generally speaking, the rate of application of the present composition based on the total amount of the active component in the composition can for 300 gram active component/hectares (gai/ha) to 1000gai/ha.Preferred rate of application is 415gai/ha to 645gai/ha.In particularly preferred embodiment of the present invention, the rate of application of benfuresate is that the rate of application of 400gai/ha to 600gai/ha and penoxsuam is 15gai/ha to 45gai/ha.
The component of Synergistic mixtures of the present invention can be used separately or use as the part of multicomponent weeding system.
Synergistic mixtures of the present invention can use to prevent and treat the more vegetation of not expecting of wide variety with one or more other weed killer herbicides.When using with other weed killer herbicide, the present composition can be prepared with other one or more weed killer herbicides, in container, mix (tank mix) with other one or more weed killer herbicides or successively use with other one or more weed killer herbicides.Can comprise with some weed killer herbicides that cooperative compositions of the present invention is used: 2,4-drips (2,4-D), 2 first, 4 chlorine (2,4-MCPA), Acetochlor (acetochlor), acifluorfen (acifluorfen), aclonifen (aclonifen), alachlor (alachlor), amidosulfuron (amidosulfuron), aminocyclopyrachlor, chlorine Fampridine acid (aminopyralid), aminotriazole(ATA) (aminotriazole), ammonium thiocyanate (ammoniumthiocyanate), anilofos (anilifos), azimsulfuron (azimsulfuron), benfuresate (benfuresate), bensulfuron-methyl (bensulfuron-methyl), bentazone (bentazone), benthiocarb (benthiocarb), benzobicylon (benzobicyclon), benzofenap (benzofenap), bifenox (bifenox), two careless ethers (bispyribac-sodium), bromacil (bromacil), bromobutide (bromobutide), Brominal (bromoxynil), butachlor (butachlor), butafenacil (butafenacil), butralin (butralin), cafenstrole (cafenstrole), carbetamide (carbetamide), azoles humulone (carfentrazone-ethyl), chlorflurenol (chlorflurenol), chlorimuronethyl (chlorimuron), chlorpropham (chlorpropham), cinosulfuron (cinosulfuron), clethodim (clethodim), clodinafop-propargyl (clodinafop-propargyl) clomazone (clomazone), clomeprop (clomeprop), clopyralid (clopyralid), cloransulammethyl (cloransulam-methyl), cumyluron (cumyluron), AC322140 (cyclosulfamuron), cycloxydim (cycloxydim), cyhalofop-butyl (cyhalofop-butyl), daimuron (daimuron), dicamba (dicamba), dichlobenil (dichlobenil), smart 2,4-drips propionic acid (dichlorprop-P), diclosulam (diclosulam), diflufenican (diflufenican), diflufenzopyr (diflufenzopyr), dimepiperate (dimepiperate), dimethametryn (dimethametryn), dimethenamid (dimethenamid), dimethenamid-P (dimethenamid-P), diquat (diquat), dithiopyr (dithiopyr), diuron (diuron), EK2612, EPTC (EPTC), esprocarb (esprocarb), ethoxy sulphur swells (ethoxysulfuron), ethobenzanid (etobenzanid) oxazole diclofop-methyl (fenoxaprop) oxazole diclofop-methyl ethyl ester (fenoxaprop-ethyl) oxazole diclofop-methyl ethyl ester+Shuan Ben oxazole acetoacetic esters (isoxidifen-ethyl), fentrazamide (fentrazamide), flazasulfuron (flazasulfuron), florasulam (florasulam), fluazifop (fluazifop), efficient fluazifop (fluazifop-P-butyl), fluorine pyrrole sulphur swells (flucetosulfuron), flufenacet (flufenacet), flufenpyrethyl (flufenpyr-ethyl), Flumetsulam (flumetsulam), Flumiclorac pentyl (flumiclorac-pentyl), flumioxazin (flumioxazin), fluometuron (fluometuron), flupyrsulfuron-methyl-sodium (flupyrsulfuron), fluroxypyr (fluroxypyr), fomesafen (fomesafen), formamido group Sulfometuron Methyl (foramsulfuron), fumiclorac, grass ammonium phosphine (glufosinate), grass ammonium phosphine (glufosinate-ammonium), smart careless ammonium phosphine (glufosinate-P), glyphosate (glyphosate), halosulfuronmethyl (halosulfuron), haloxyfop-P-methyl (haloxyfop-methyl), fluazifop-butyl-R (haloxyfop-R), miaow oxalic acid (imazamethabenz), methoxy imazethapyr (imazamox), AC 263222 (imazapic), imidazoles nicotinic acid (imazapyr), imazaquin (imazaquin), imazethapyr (imazethapyr), imazosulfuron (imazosulfuron), indanofan (indanofan), iodine sulphur swells (iodosulfuron), ioxynil (ioxynil), Chinese mugwort is divided carbazones (ipfencarbazone), isoproturon (isoproturon) Yi Evil acyl grass amine (isoxaben) isoxazole humulone (isoxaflutole), lactofen (lactofen), 2 first, 4 chlorine (MCPA), 2 first, 4 chlorine esters and amine (MCPAester﹠amp; Amine), Thistrol (MCPB), mecopropP (mecoprop-P), mefenacet (mefenacet), methyl two sulphurs swell (mesosulfuron), nitre sulphur humulone (mesotrione) oxazole acyl grass amine (metamifop), isopropyl methoxalamine (metolachlor), metosulam (metosulam), metsulfuron-methyl (metsulfuron), molinate (molinate), monosulfmeturon (monosulfuron), monosodium methanearsonate (MSMA), napropamide (napropamide), nicosulfuron (nicosulfuron), norflurazon (norflurazon), OK-9701, phonetic aniline sulphur swells (orthosulfamuron), oryzalin (oryzalin) Bing Que Evil humulone (oxadiargyl) Evil humulone (oxadiazon) oxazine humulone (oxaziclomefone), Oxyfluorfen (oxyfluorfen), paraquat (paraquat), pendimethalin (pendimethalin) Huan Wu Evil humulone (pentoxazone), pethoxamid (pethoxamid), picloram (picloram), fluorine pyrrole acyl grass amine (picolinafen), piperophos (piperophos), the third careless amine (pretilachlor), primisulfuronmethyl (primisulfuron), clefoxidim (profoxydim), propachlor (propachlor), Stam F-34 (propanil), propisochlor (propisochlor), propyzamide (propyzamide), prosulfocarb (prosulfocarb), prosulfuron (prosulfuron), pyraclonil (pyraclonil), pyrrole grass ether (pyraflufen-ethyl), pyrazogyl, pyrazolate (pyrazolynate), pyrazosulfuron (pyrazosulfuron-ethyl), pyrazoxyfen (pyrazoxyfen), pyribenzoxim (pyribenzoxim), pyributicarb (pyributicarb), pyriftalid (pyriftalid), KIH 6127 (pyriminobac-methyl), pyrimisulfan, pyridine sulphur grass amine (pyroxsulam), dichloro quinolinic acid (quinclorac), quinoclamine (quinoclamine), Quizalotop-ethyl (quizalofop-ethyl-P), S-3252, saflufenacil, sethoxydim (sethoxydim), Simanex (simazine), symetryne (simetryn), SL-0401, SL-0402, smart isopropyl methoxalamine (S-metolachlor), sulphur humulone (sulcotrione), sulfentrazone (sulfentrazone), sulphosate (sulfosate), tefuryltrione, tembotrione, terbacil (terbacil), P DimethenamidP (thenylchlor), thrizopyr (thiazopyr), benthiocarb (thiobencarb), trichlopyr (triclopyr), trichlopyr-ester and amine (triclopyr-estersandamine), trefanocide (trifluralin), anti-ester (trinexapac-ethyl) and tritosulfuron (tritosulfuron).
Synergistic mixtures of the present invention can be used on the crop of anti-inhibitor of acetolactate synthetase.Further, cooperative compositions of the present invention can be with 2,4-drips, glyphosate, careless ammonium phosphine, dicamba or imidazolone type (imidazolinones) are used in anti-2 together, 4-drip (2,4-D-tolerant), on the crop of glyphosate tolerant (glyphosate-tolerant), anti-careless ammonium phosphine (glufosinate-tolerant), anti-dicamba (dicamba-tolerant) or anti-imidazolone type (imidazolinone-tolerant).
Usually preferably cooperative compositions of the present invention and following combinations of herbicides are used, the crop for the treatment of disposal when described weed killer herbicide uses with used rate of application has selectivity, and has replenished the weeds spectrum by these compound controls.Usually no matter further preferably use cooperative compositions of the present invention and other complementary weed killer herbicide simultaneously, be as combination preparation or as mixture in the container.
Cooperative compositions of the present invention generally can be used in combination to strengthen their selectivity, described herbicide-safener such as benoxacor (benoxacor) with known herbicide-safener; benthiocarb (benthiocarb); brassin lactones (brassinolide); cloquitocet_mexyl (cloquintocet (mexyl)); cyometrinil (cyometrinil); cyprosulfamate; daimuron (daimuron); dichlormide (dichlormid); dicyclonon; dietholate; dimepiperate (dimepiperate); disulfoton (disulfoton); fenchlorazole-ethyl (fenchlorazole-ethyl); fenclorim (fenclorim); separate careless amine (flurazole); fluxofenim (fluxofenim) Xie Cao oxazole (furilazole); super quick albumen (Harpinproteins) Shuan Ben oxazole acetoacetic ester (isoxadifen-ethyl); mefenpyrdiethyl (mefenpyr-diethyl); mephenate; MG191; MON4660; naphthalene acid anhydride (NA); oxabetrinil (oxabetrinil); R29148 and N-phenyl sulfonyl benzamide.
In practice, preferably in the mixture of the weeding component that contains herbicidally effective amount and at least a agriculture acceptable assistant or carrier, use cooperative compositions of the present invention.Proper auxiliary agent or carrier should not have phytotoxicity to valuable crop, and used concentration is in order to carry out the selectivity control of weeds when having crop when particularly using composition, and not should with weeding component or other composition components generation chemical reaction.These mixtures can be designed as and directly are applied to weeds or their location, or can be concentrate (concentrate) or the preparation that dilutes with other carrier and auxiliary agent before using usually.They can be solids, for example pulvis, granule, water dispersible granule or wettable pulvis, or liquid, for example missible oil (emulsifiable concentrate), solution, emulsion or suspension.
The suitable agricultural agent and the carrier that can be used for preparing Herbicidal mixture of the present invention are well known to a person skilled in the art.In these auxiliary agents some include but not limited to crop oil concentrate (mineral oil (85%)+emulsifier (15%)); Nonyl phenol ethoxylate; Benzyl cocoa alkyl-dimethyl based quaternary ammonium salt; The blend of petroleum hydrocarbon, Arrcostab, organic acid and anion surfactant; C
9-C
11APG; The phosphated alcohol ethoxylate; Natural primary alconol (C
12-C
16) ethoxylate; Di sec-butylphenol EO-PO block copolymer; Polysiloxanes-methyl blocking; Nonyl phenol ethoxylate+urea ammonium nitrate; The seed oil that methylates of emulsification; Tridecanol (synthesizing) ethoxylate (8EO); Beef tallow amine ethoxylate (15EO) and PEG (400) dioleate-99.
Adoptable liquid-carrier comprises water and organic solvent.Normally used organic solvent includes but not limited to petroleum distillate or hydro carbons, for example mineral oil, arsol, paraffin wet goods; Vegetable oil, for example soybean oil, rapeseed oil, olive oil, castor oil, sunflower oil, cocoa butter, corn oil, cottonseed oil, linseed oil, palm oil, peanut oil, safflower oil, sesame oil, tung oil etc.; The ester of above-mentioned vegetable oil; The ester of monohydric alcohol, dihydroxylic alcohols, trihydroxylic alcohol or other lower polyol (containing 4-6 hydroxyl), for example stearic acid 2-ethylhexyl, n butyl oleate, isopropyl myristate, Rikemal PO 200, succinic acid dioctyl ester, adipic acid dibutyl ester, phthalic acid dioctyl ester etc.; The ester of monocarboxylic acid, dicarboxylic acids and polybasic carboxylic acid etc.Concrete organic solvent comprises toluene, dimethylbenzene, naphtha, crop oil, acetone, methyl ethyl ketone, cyclohexanone, trichloro-ethylene, tetrachloro-ethylene, ethyl acetate, pentyl acetate, butyl acetate, propylene glycol monomethyl ether, diglycol monotertiary methyl ether, methyl alcohol, ethanol, isopropyl alcohol, amylalcohol, ethylene glycol, propane diols, glycerine, N-methylpyrrolidin-2-ketone, N, N-dimethyl alkylamide, dimethyl sulfoxide (DMSO), liquid fertilizer etc.Water normally dilutes the selected carrier of concentrate.
Suitable solid carrier comprises talcum, pyrophyllite, silica, atlapulgite, kaolin, diatomite (kieselguhr), chalk, diatomite (diatomaceous earth), lime, calcium carbonate, bentonite, bleaching earth, cotton seed hull, wheat flour, soybean meal, float stone, wood powder, walnut parting, lignin etc.
Usually expectation is incorporated into one or more surfactants in the present composition.Described surfactant is advantageously utilised in solid and the fluid composition, and especially those are designed to the solid and the fluid composition that dilute with carrier before using.Surfactant can be anionic property, cationic or nonionic and can be used as emulsifier, wetting agent, suspending agent or be used for other purpose with regard to character.In formulation art surfactant commonly used and that also can be used for preparation of the present invention especially referring to " McCutcheon ' s Detergents and Emulsifiers Annual; " MC Publishing Corp., Ridgewood, New Jersey, 1998and in " Encyclopedia of Surfactants, " Vol.I-III, Chemical Publishing Co., New York, 1980-81.Common surfactant comprises alkyl sulfate, for example lauryl sulfate diethanol ammonium; Alkylaryl sulfonates, for example calcium dodecyl benzene sulfonate; Alkylphenol-oxyalkylene adduction product, for example nonyl phenol-C
18Ethoxylate; Alcohol-oxyalkylene adduction product, for example tridecanol-C
16Ethoxylate; Soap class, for example odium stearate; Fluhyzon-sulfonate, for example nekal; Dialkyl sulfosuccinates, for example two (2-ethylhexyl) sodium sulfosuccinate; Sorbitol ester, for example oleic acid sorbitol ester; Quaternary ammonium, for example lauryl trimethyl ammonium chloride; Fatty acid polyethylene glycol ester, for example stearic acid macrogol ester; The block copolymer of oxirane and expoxy propane; The salt of monoalkyl phosphoric acid esters and the salt of dialkyl phosphate; Vegetable oil, for example soybean oil, rapeseed oil, olive oil, castor oil, sunflower oil, cocoa butter, corn oil, cottonseed oil, linseed oil, palm oil, peanut oil, safflower oil, sesame oil, tung oil etc.; Ester with above-mentioned vegetable oil.
Other auxiliary agent commonly used in Pestcidal compositions comprises compatilizer, defoamer, screening agent, neutralizer, buffer, corrosion inhibiter, dyestuff, aromatic, spreading agent, penetrant, sticker, dispersant, thickener, freezing point depressing agent, antimicrobial etc.Described composition also can contain other compatible components, for example other weed killer herbicide, plant growth regulator, fungicide, agrochemical, and can be with liquid fertilizer or for example preparation such as ammonium nitrate, urea of solid granular fertilizer carrier.
The concentration of the active component in the cooperative compositions of the present invention is generally 0.001 to 98 weight %.Normally used concentration is 0.01 to 90 weight %.In the composition that is designed to the use of concentrate form, described active component exists with the concentration of 5 to 98 weight % usually, is preferably 10 to 90 weight %.Usually before using with inert carrier for example water dilute described composition.Usually be applied to the on-site diluted composition of weeds or weeds and contain the active component of 0.0001 to 1 weight % substantially, and preferably contain 0.001 to 0.05 weight %.
Can execute the cloth device, by other conventional means well known by persons skilled in the art the present composition is applied to weeds or their location by being added into the irrigation water neutralization by using conventional ground or aerial duster, sprayer and particle.
Following examples explanation the present invention.
Embodiment
Embodiment
Estimate the postemergence herbicide activity of mixture under field condition
Method
In Japan, under field condition, carry out these tests.The test site is arranged in the paddy of commercial plantation.Utilize fertilising, sow and keep used standard agricultural operation and cultivate described paddy, thereby guarantee that described crop and weeds well grow.Utilize the research on standard method to carry out described test.The test site is between 2-4 rice (m) (wide) * 2-4m (length).Use all handled things (treatment) with the complete block design of randomization, each is handled and repeats 3 times.Described test site has the weed control that nature exists.Described weeds spectrum include but not limited to barnyard grass grass (Echinochloa crus-galli) (ECHCG), firefly Lin (Scirpus juncoides) (SCPJU), Monochoria vaginalis (Monochoria vaginalis) (MOOVP), spend more water amaranth (Ammannia multiflora) (AMMMU), wild water chestnut (Eleocharis kuroguwai) (ELOKU), Procumbent Falsepimpernel (Lindernia procumbens) (LIDPY) and Herba Cyperi Glomerati (Cyperus serotinus) (CYPSE).
Handled thing is made of mixture in the container that is applied in the formulation product in the water.Use by carrying out all in the manual water with directly being sprayed onto the rice field.
Estimate
After using, in the different interval phase ignorant grading is carried out in treated place and contrast place.Grading based on the range estimation control of weeds percentage (%), wherein 0 corresponding to free of losses and 100 corresponding to killing fully.
Collect all test datas and use various statistical methods to analyze.
The Colby equation is used for the herbicide effect (Colby that definite described mixture expection has, S.R.Calculation of the synergistic and antagonistic response of herbicide combinations.Weeds1967,15,20-22).
Following equation is used for calculating the expection activity of the mixture that contains two kinds of active components A and B:
Estimated value=A+B-(AxB/100)
A=is observed effectiveness when the concentration of active components A is identical with its concentration of using in described mixture;
B=is observed effectiveness when the concentration of active component B is identical with its concentration of using in described mixture.
The result is summarised in table 1 in 3.
30 day the collaborative control of weeds-field experiment #1 of table 1. after using penoxsuam+benfuresate
AMMMU-spends more the water amaranth
ECHCG-barnyard grass grass
The MOOVP-Monochoria vaginalis
Gramsai/ha-restrains active component/hectare
Ob-control percentage measured value
Ex-is by the control percentage of Colby equation budget
30 day collaborative control of weeds-field experiment #1 and the #2. of table 2. after using penoxsuam+benfuresate
The CYPSE-Herba Cyperi Glomerati
The wild water chestnut of ELOKU-
SCPJU-firefly Lin
Gramsai/ha-restrains active component/hectare
Ob-control percentage measured value
Ex-is by the control percentage of Colby equation budget
27 day the collaborative control of weeds-field experiment #3. of table 3. after using penoxsuam+benfuresate
The LIDPY-Procumbent Falsepimpernel
SCPJU-firefly Lin
Gramsai/ha-restrains active component/hectare
Ob-control percentage measured value
Ex-is by the control percentage of Colby equation budget
Claims (5)
1. Herbicidal mixture, it comprises (a) penoxsuam of herbicidally effective amount and (b) benfuresate.
2. the mixture of claim 1, wherein in active component (ai), the weight ratio of benfuresate and penoxsuam is 6:1 to 95:1.
3. Herbicidal combinations, it comprises Herbicidal mixture and agriculture acceptable assistant or the carrier of the claim 1 of herbicidally effective amount.
4. the method for vegetation is not expected in control, and described method comprises makes described vegetation or its location contact with the Herbicidal mixture of the claim 1 of herbicidally effective amount.
5. the method for not expecting vegetation in the control paddy, described method comprises makes described vegetation or its location contact with the Herbicidal mixture of the claim 1 of herbicidally effective amount.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061425300P | 2010-12-21 | 2010-12-21 | |
| US61/425,300 | 2010-12-21 | ||
| PCT/US2011/065960 WO2012087998A1 (en) | 2010-12-21 | 2011-12-20 | Synergistic herbicidal composition containing penoxsulam and benfuresate |
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| Publication Number | Publication Date |
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| CN103269594A true CN103269594A (en) | 2013-08-28 |
| CN103269594B CN103269594B (en) | 2017-03-01 |
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| JP (1) | JP5841613B2 (en) |
| KR (1) | KR20130132933A (en) |
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| WO (1) | WO2012087998A1 (en) |
Citations (3)
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|---|---|---|---|---|
| CN101128115A (en) * | 2005-02-11 | 2008-02-20 | 美国陶氏益农公司 | Penoxsulam as a turfgrass, vineyard and orchard floor herbicide |
| CN101530105A (en) * | 2009-04-21 | 2009-09-16 | 北京颖泰嘉和科技股份有限公司 | Herbicide composition containing sulfonylurea, pyridine and penoxsulam and use thereof |
| US20100279864A1 (en) * | 2009-05-01 | 2010-11-04 | Dow Agrosciences Llc | Safening penoxsulam herbicide injury in water-seeded, direct-seeded and transplanted paddy rice |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL190282B1 (en) * | 1996-09-24 | 2005-11-30 | Dow Agrosciences Llc | N-([1,2,4]triazole-azinyl)benzene and pyridinsulphonamide compounds, containing compound herbicides, derivatives of pyridine-3-sulphonyl chloride and derivatives of 2-amino [1.2.4] triazole [1.5-c] pyrimidine |
| JP2001233718A (en) * | 2000-02-22 | 2001-08-28 | Dow Chem Japan Ltd | Herbicide composition |
| US20060154823A1 (en) * | 2003-03-13 | 2006-07-13 | Basf Aktiengesellschaft | Synergistically acting herbicidal mixtures |
| JP2009084245A (en) * | 2007-10-02 | 2009-04-23 | Ishihara Sangyo Kaisha Ltd | Herbicide composition |
| JP2010280578A (en) * | 2009-06-02 | 2010-12-16 | Nissan Chem Ind Ltd | Solid agrochemical composition containing release-controlled granule |
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- 2011-12-20 WO PCT/US2011/065960 patent/WO2012087998A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101128115A (en) * | 2005-02-11 | 2008-02-20 | 美国陶氏益农公司 | Penoxsulam as a turfgrass, vineyard and orchard floor herbicide |
| CN101530105A (en) * | 2009-04-21 | 2009-09-16 | 北京颖泰嘉和科技股份有限公司 | Herbicide composition containing sulfonylurea, pyridine and penoxsulam and use thereof |
| US20100279864A1 (en) * | 2009-05-01 | 2010-11-04 | Dow Agrosciences Llc | Safening penoxsulam herbicide injury in water-seeded, direct-seeded and transplanted paddy rice |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130132933A (en) | 2013-12-05 |
| JP5841613B2 (en) | 2016-01-13 |
| JP2014500325A (en) | 2014-01-09 |
| CN103269594B (en) | 2017-03-01 |
| WO2012087998A1 (en) | 2012-06-28 |
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