CN103266324B - A kind of inter process Water-soluble antirust liquid and preparation method thereof - Google Patents
A kind of inter process Water-soluble antirust liquid and preparation method thereof Download PDFInfo
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- CN103266324B CN103266324B CN201310117310.7A CN201310117310A CN103266324B CN 103266324 B CN103266324 B CN 103266324B CN 201310117310 A CN201310117310 A CN 201310117310A CN 103266324 B CN103266324 B CN 103266324B
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- water
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- antirust
- antirust liquid
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of inter process Water-soluble antirust liquid, it is made up of the raw material of following weight parts: Sodium orthomolybdate 5-8, Zinc Gluconate 2-4, Sodium Benzoate 1-2, glycerine 2-4, Xylo-Mucine 0.1-0.2, deionized water 80-90.The Water-soluble antirust liquid that inventing provides does not contain the larger material of the toxicity such as Sodium Nitrite, dichromate or volatile organic amines, and also not containing the phosphoric acid salt, the nitrate component that make body eutrophication, toxicity is lower, has certain feature of environmental protection; When using rust protection liquid provided by the invention to carry out antirust to steel piece, produce without iron mold in 20 ~ 40 days, rust prevention during manufacture and the antirust requirement of short term stored of common iron and steel parts processing can be met, and the method that can wash with water easily removing, there is cost low, prepare advantage easily.
Description
Technical field
The present invention relates generally to a kind of rust protection liquid, particularly relates to a kind of inter process Water-soluble antirust liquid.
Background technology
Steel product generally needs to process through multiple working procedure, the impact that its work in-process to contact etc. owing to being subject to processing medium, damp atmosphere and hand perspiration in the transport of each inter process with storage process can produce corrosion, therefore normal requirement carries out temporary rust prevention during manufacture, wherein adopts rust protection liquid coating workpieces surface to be a kind of common method.Rust protection liquid comprises the waterborne anti-rust liquid using water as dispersion medium and the oiliness rust protection liquid (i.e. slushing oil) using mineral oil as dispersion medium.Oiliness rust protection liquid for main ingredient with mineral oil and oil-soluble inhibitor, when being coated in steel piece surface, being difficult to cleaning and removing; When not washing clean clearly, the operations such as follow-up spraying, assembling can be affected, and a large amount of waste water when cleaning, can be produced, bring certain influence to environment, also make production cost increase.On the other hand, there is oxidation and make its color burn in mineral oil or oil-soluble inhibitor, affects product appearance in atmosphere.Waterborne anti-rust liquid comprises water-latex type and Water-soluble antirust liquid, the emulsification in water of mineral oil and oil-soluble inhibitor is formed emulsion by the effect of emulsifying agent by the former, after moisture evaporation, can form one deck Rust Preventing Oil Film in metallic surface, same with oiliness rust protection liquid exist the shortcoming of cleaning difficulty, easy oxidation discoloration; Water-soluble antirust liquid is then be dissolved in water by water soluble rust inhibitor to form rust protection liquid, has with low cost, prepares easy, the advantage of easily cleaning removal.But traditional Water-soluble antirust liquid adopts the water soluble rust inhibitor preparations such as Sodium Nitrite, dichromate or volatile organic amines, and the material that these toxicity are larger easily causes serious harm to human body and environment.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of inter process Water-soluble antirust liquid.
The present invention is achieved by the following technical solutions:
A kind of inter process Water-soluble antirust liquid, it is made up of the raw material of following weight parts:
Sodium orthomolybdate 5-8, Zinc Gluconate 2-4, Sodium Benzoate 1-2, glycerine 2-4, Xylo-Mucine 0.1-0.2, deionized water 80-90.
A preparation method for inter process Water-soluble antirust liquid, comprises the following steps:
(1) in the deionized water of above-mentioned weight part, add Sodium orthomolybdate, Zinc Gluconate, the Sodium Benzoate of above-mentioned weight part successively, stirring and dissolving obtains mixed inhibitor solution;
(2) in above-mentioned mixed inhibitor solution, the Xylo-Mucine of above-mentioned weight part is added again, stirring and dissolving;
(3) glycerine adding above-mentioned weight part again mixes, and obtains described Water-soluble antirust liquid.
Advantage of the present invention is:
Water-soluble antirust liquid provided by the invention is not containing the material that the toxicity such as Sodium Nitrite, dichromate or volatile organic amines are larger, and also not containing the phosphoric acid salt, the nitrate component that make body eutrophication, toxicity is lower, has certain feature of environmental protection; When using rust protection liquid provided by the invention to carry out antirust to steel piece, produce without iron mold in 20 ~ 40 days, rust prevention during manufacture and the antirust requirement of short term stored of common iron and steel parts processing can be met; Contained by this rust protection liquid, component is water-soluble substances, can remove the rust protection liquid being coated in workpiece surface easily, have preparation and advantage easy to use with a small amount of water cleaning.
Embodiment
Embodiment 1: the rust protection liquid of preparation 100 parts of weight
Take the deionized water of 91.7 parts of weight, add the Sodium orthomolybdate of 1.8 points of weight, stirring and dissolving; Add the Zinc Gluconate of 2.8 parts of weight again, stirring and dissolving; Add the Sodium Benzoate of 1.9 parts of weight, stirring and dissolving; Add the glycerine of 1.8 parts of weight, namely stirring and evenly mixing obtains Water-soluble antirust liquid.
Prepared Water-soluble antirust liquid is brushed be newly processed into and do not have the steel matrix surface of greasy dirt to carry out antirust treatment, be placed in and indoor within 40 days, have no obvious iron mold.
Embodiment 2: the rust protection liquid of preparation 100 parts of weight
Take the deionized water of 91.9 parts of weight, add the Sodium orthomolybdate of 2 points of weight, stirring and dissolving; Add the Zinc Gluconate of 4 parts of weight again, stirring and dissolving; Add the Sodium Benzoate of 2 parts of weight, stirring and dissolving; Add the carboxymethyl cellulose of 0.1 part of weight, namely stirring and evenly mixing obtains Water-soluble antirust liquid.
Prepared Water-soluble antirust liquid is brushed be newly processed into and do not have the steel matrix surface of greasy dirt to carry out antirust treatment, be placed in and indoor within 25 days, have no obvious iron mold.
Embodiment 3: the rust protection liquid of preparation 100 parts of weight
Take the deionized water of 92.2 parts of weight, add the Sodium orthomolybdate of 3.7 points of weight, stirring and dissolving; Add the Zinc Gluconate of 1 part of weight again, stirring and dissolving; Add the Sodium Benzoate of 1 part of weight, stirring and dissolving; Add the glycerine of 2.1 parts of weight, namely stirring and evenly mixing obtains Water-soluble antirust liquid.。
Prepared water soluble rust protection liquid is brushed be newly processed into and do not have the steel matrix surface of greasy dirt to carry out antirust treatment, be placed in and indoor within 20 days, have no obvious iron mold.
Claims (1)
1. an inter process Water-soluble antirust liquid, is characterized in that it is made up of the raw material of following weight parts:
Sodium orthomolybdate 5-8, Zinc Gluconate 2-4, Sodium Benzoate 1-2, glycerine 2-4, Xylo-Mucine 0.1-0.2, deionized water 80-90;
The preparation method of described inter process Water-soluble antirust liquid, comprises the following steps:
(1) in the deionized water of above-mentioned weight part, add Sodium orthomolybdate, Zinc Gluconate, the Sodium Benzoate of above-mentioned weight part successively, stirring and dissolving obtains mixed inhibitor solution;
(2) in above-mentioned mixed inhibitor solution, the Xylo-Mucine of above-mentioned weight part is added again, stirring and dissolving;
(3) glycerine adding above-mentioned weight part again mixes, and obtains described Water-soluble antirust liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310117310.7A CN103266324B (en) | 2013-04-07 | 2013-04-07 | A kind of inter process Water-soluble antirust liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310117310.7A CN103266324B (en) | 2013-04-07 | 2013-04-07 | A kind of inter process Water-soluble antirust liquid and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103266324A CN103266324A (en) | 2013-08-28 |
| CN103266324B true CN103266324B (en) | 2015-12-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310117310.7A Active CN103266324B (en) | 2013-04-07 | 2013-04-07 | A kind of inter process Water-soluble antirust liquid and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115074738B (en) * | 2022-06-13 | 2024-03-08 | 山东国智新材料科技有限公司 | Environment-friendly multi-element composite vapor phase corrosion inhibitor and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102230180A (en) * | 2011-04-10 | 2011-11-02 | 李舰 | Antirust compound glycerin and its preparation method |
| CN102899669A (en) * | 2012-10-23 | 2013-01-30 | 鞍钢股份有限公司 | Antirust agent for cold-rolled steel sheet in cold-rolling process |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050215440A1 (en) * | 2004-03-26 | 2005-09-29 | Singh Arun K | Process for metalworking fluid from heavy alkylate |
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2013
- 2013-04-07 CN CN201310117310.7A patent/CN103266324B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102230180A (en) * | 2011-04-10 | 2011-11-02 | 李舰 | Antirust compound glycerin and its preparation method |
| CN102899669A (en) * | 2012-10-23 | 2013-01-30 | 鞍钢股份有限公司 | Antirust agent for cold-rolled steel sheet in cold-rolling process |
Non-Patent Citations (3)
| Title |
|---|
| 一种不含亚硝酸钠的黑色金属防锈水的研制;刘旭麟 等;《铸造》;20021130;第51卷(第11期);第720-722页 * |
| 钼酸盐复合缓蚀剂对海水中碳钢的缓蚀作用;芮玉兰 等;《腐蚀与防护》;20070228;第28卷(第2期);第61-64页 * |
| 非亚硝酸盐型水基防锈剂的研制;黄竹山 等;《汽车工艺与材料》;20020131(第1期);第28-31页 * |
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| CN103266324A (en) | 2013-08-28 |
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