CN103265220A - Powdery mica foaming agent - Google Patents

Powdery mica foaming agent Download PDF

Info

Publication number
CN103265220A
CN103265220A CN201310223199XA CN201310223199A CN103265220A CN 103265220 A CN103265220 A CN 103265220A CN 201310223199X A CN201310223199X A CN 201310223199XA CN 201310223199 A CN201310223199 A CN 201310223199A CN 103265220 A CN103265220 A CN 103265220A
Authority
CN
China
Prior art keywords
foaming agent
powdery mica
mica
powdery
attapulgite clay
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201310223199XA
Other languages
Chinese (zh)
Other versions
CN103265220B (en
Inventor
许庆华
蒋文兰
许盛英
袁长兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zheng Zonghua
Original Assignee
许盛英
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 许盛英 filed Critical 许盛英
Priority to CN201310223199.XA priority Critical patent/CN103265220B/en
Publication of CN103265220A publication Critical patent/CN103265220A/en
Application granted granted Critical
Publication of CN103265220B publication Critical patent/CN103265220B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention discloses a powdery mica foaming agent. The foaming agent comprises sericite, high-viscosity attapulgite clay powder, active attapulgite clay, sodium dodecyl sulfate, sodium percarbonate, sodium polyacrylate, sodium pyrophosphate and sodium poly[(naphthaleneformaldehyde)sulfonate]. The finished product of the powdery mica foaming agent is produced by stirring ingredients of the powdery mica foaming agent, milling the ingredients into powder and packaging the powder. The powdery mica foaming agent has the advantages that the powdery mica foaming agent has strong foaming capacity, high foam expansion and high foam yield in unit volume, has good foam outer membrane tenacity and is not easy to break, has good foam stability, can not be defoamed for a long time, is exquisite in foam, is uniform in sizes of holes generated in media and has low bleeding quantity and good compatibility of used media. The products produced by using the powdery mica foaming agent not only can effectively control noise pollution but also have the functions of preserving heat and purifying air. The powdery mica foaming agent is suitable for producing lightweight boards, lightweight walls and noise reducing products.

Description

Powdery mica whipping agent
Technical field
The present invention relates to whipping agent, be specifically related to a kind of powdery mica whipping agent.
Background technology
City noise is having a strong impact on city resident's orthobiosis and health of human body, city noise mainly refers to traffic noise, factory noise, construction noise pollution and noise of social activities, its The noise scope and influence degree are serious day by day, to the influence of civic living environment greatly, become one of noticeable city environmental pollution problem.
The control noise is taked measures such as damping, sound insulation, sound absorption, sourdine, personal protection and architectural composition usually, weaken as far as possible or reduce the vibration of sound source, acoustic energy absorption in propagating is fallen, place obstacles and make that sound is all or part of to reflect away, weaken the effect of noise, to reach the purpose of control noise.
Usually adopt quieter material to produce products such as some acoustical panels, sound insulation Wall, sound-absorbing net and sound damper and control sound pollution, it is after handling by foaming, to improve the performance of the said products that some materials are also arranged.
The kind of whipping agent is more, and for the control sound pollution has been made bigger contribution, but the said products can only be used for control sound pollution, the function that does not purify air.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of powdery mica whipping agent is provided.
Powdery mica whipping agent is made up of sericite, high sticking attapulgite clay powder, activated attapulgite, sodium lauryl sulphate, SPC-D, sodium polyacrylate, trisodium phosphate and poly-naphthaldehyde sulfonate sodium.
The production method of powdery mica whipping agent: will stir in the powdery mica whipping agent batching input stirrer, carry out abrasive dust in the back input grinding machine that stirs, be packaged as the finished product of powdery mica whipping agent.
Mica has characteristics such as good elasticity, toughness, insulativity, high temperature resistant, acid and alkali-resistance, corrosion-resistant, strong adhesion and satin luster, sericite has high resistance, be excellent insulating material and fire-retardant filler, sericite can significantly change a series of physics modulus of material, form or change the visco-elasticity of material, this class material absorbs vibrational energy expeditiously, weakens shock wave and sound wave, is used to prepare noise elimination, sound insulation, damping coating, and the present invention selects sericite for use.
Attapulgite has another name called polygorskite or Palygorskite, be a kind of layer of chain-like structure contain Shuifu County's zeopan clay mineral, attapulgite has unique layer chain-like structure feature, in its structure, there is the lattice displacement, so contain Na+, Ca2+, Fe3+, the Al3+ of non-quantitative in the crystal, crystal is needle-like, fibrous or fiber collection shape.Attapulgite has unique dispersion, high temperature resistant, anti-good colloidal property such as saline and alkaline and higher adsorptive power, and has certain plasticity-and cohesive force.
High sticking attapulgite clay is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, attapulgite clay soil property exquisiteness, oily soapy is arranged, light weight, property are crisp, fracture is conchoidal or irregular shape, and water-absorbent is strong, tool viscosity and plasticity-when wet, its viscosity can reach more than the 3000mPas, is conducive to the bonding between the raw material.
High sticking attapulgite clay powder refers to get 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer, under 11000 rev/mins rotating speed, stirred 20 minutes, to pour in the beaker of 250ml the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value 〉=2200 again through the high-speed stirring sample suspension into MPasThe attapulgite clay powder.
The pH value of attapulgite clay raw ore is 8~9, need to carry out acidification in the present invention, attapulgite clay after the acidified processing is activated attapulgite, the various performances of activated attapulgite all will be greatly improved, particularly strengthened the adsorption cleaning ability of Attapulgite, activated attapulgite pH value is controlled to be 5.5~7.5, water content≤2%.
Sodium lauryl sulphate is white or faint yellow powdery, and is water-soluble, insensitive to alkali and hard water, has decontamination, emulsification and excellent foaming power, is a kind of nontoxic anion surfactant; When powdery mica whipping agent and water mix, a large amount of bubble of the common generation of sodium lauryl sulphate and SPC-D.
SPC-D is a kind of inorganic salt, the granulated powders that is white in color, SPC-D with can decompose rapidly after water contacts, discharge a large amount of oxygen.
Sodium polyacrylate is a kind of new functional macromolecule material, be white or buff powder, be dissolved in cold water, stable to temperature variation, be a kind of tensio-active agent with multiple property, be conducive to improve the thickening, foaming of powdery mica whipping agent, stable, emulsification, dispersion, bonding, film forming and effect of water keeping in the present invention.
Trisodium phosphate is a kind of water white transparency crystallization or white crystalline powder, and is soluble in water, in the present invention as dispersion agent and emulsifying agent.
Poly-naphthaldehyde sulfonate sodium is brown or the dark-brown powder, and soluble in water, acidproof, alkaline-resisting, anti-hard water has good diffustivity; Generate a large amount of bubbles when powdery mica whipping agent and water mixing, the bubble that trisodium phosphate and poly-naphthaldehyde sulfonate sodium are conducive to generate distributes more even.
The present invention is achieved by following technical proposals:
1, powdery mica whipping agent batching is made up of following component by weight percentage: sericite 15~45%, high sticking attapulgite clay powder 5~20%, activated attapulgite 5~25%, sodium lauryl sulphate 1~35%, SPC-D 1~25%, sodium polyacrylate 0.01~5%, trisodium phosphate 0.01~5% and poly-naphthaldehyde sulfonate sodium 0.01~5%.
The production method of described powdery mica whipping agent: will powdery mica whipping agent stir in the batching input stirrer, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter is packaged as the finished product of powdery mica whipping agent.
The sticking attapulgite clay of described height is the attapulgite clay that adopts the complete processing production that improves viscosity of attapulgite clay, it is characterized in that, and from the attapulgite clay of mining area exploitation, need be through 30~120 days natural weathering; Modification processing method is: calculate by weight percentage, take from the attapulgite clay 94~98% after the right weathering, evenly add 2~6% yellow soda ash, import jointly in the fermentation vat, add clear water and soak ageing, soak time is 72~120 hours; Get the attapulgite clay after the immersion, stir in the input stirrer, and the attapulgite clay after will stirring, be extruded into thin slice through extrusion machine, its gauge control is at 0.5~2 millimeter, with the attapulgite clay thin slice, carry out airing, the attapulgite clay thin slice after the airing, its water content≤15%; Batching is calculated by weight percentage: the attapulgite clay 94~98% after the airing, High hydrophilous resin 0.5~5% and Mierocrystalline cellulose 0.5~3%, above-mentioned batching is stirred, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter.
Above-mentioned production technique is to adopt " improving the complete processing of viscosity of attapulgite clay " in application on June 20th, 2005 by the inventor, and the Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
The production method of described activated attapulgite is: the 1. preparation of dilute sulphuric acid, formed by following component by weight percentage: the sulfuric acid 3~5% of concentration 98 ﹪, water 95~97%; 2. the batching of acidification comprises following component by weight percentage: attapulgite clay raw ore 55~65%, and dilute sulphuric acid 35~45% slowly adds dilute sulphuric acid and to carry out acidification in the attapulgite clay raw ore; 3. extruding: with Concavo-convex excellent stone clay after the acidify, push by extrusion machine and to be flap, the thickness of flap≤3 millimeter; 4. roasting: the flap of attapulgite clay is transported to and carries out roasting in the stoving oven, and roasting time is 1.5~3 hours, and maturing temperature is controlled at 320~450 ℃, and the attapulgite clay flap after the roasting is activated attapulgite.
This production method is the production method that adopts by the activated attapulgite of the inventor in " embossed rod medicinal health-care bathing-mud powder " of application on March 7th, 2006, the Chinese patent publication number of embossed rod medicinal health-care bathing-mud powder is: CN1850026, open day: on October 25th, 2006.
Described water content is weight percentage.
Powdery mica whipping agent is added in the medium; after the water mixing and stirring; can discharge a large amount of gas; in medium, produce a large amount of even and stable foams; be used for the multiple foam materials product of cast, layering can not occur in the casting process, the product stripping time is shorter; gas contains a certain amount of oxygen, is conducive to protect the air ambient of working-yard.
The medium that powdery mica whipping agent is suitable for has materials such as various cement, flyash and nonmetalliferous ore composition.
When using sodium lauryl sulphate merely, the generation foam is very fast, but what break and disappear is also fast, cause the less stable of foam, formed a kind of compound foaming agent behind sericite and other batching and the sodium lauryl sulphate compatibility among the present invention, have that foaming power is strong, foam expansion is high, unit volume produces that the bubble amount is big, foam adventitia good toughness is difficult for brokenly, froth stability is good, can be for a long time not froth breaking, foam exquisiteness, advantage such as the hole size that generates in medium is even, bleeding quantity is low and the consistency of working medium is good.
The product that uses powdery mica whipping agent to produce not only can effectively be controlled sound pollution, the function that is incubated in addition and purifies air; These products are used for facilities such as motorway, viaduct, urban light rail, subway, factory, warehouse, public place.
Powdery mica whipping agent is applicable to produces light weight board, lightweight body of wall and sound-deadening and noise-reducing product.
Embodiment
The invention will be further described below in conjunction with embodiment:
1, powdery mica whipping agent batching is made up of following component by weight percentage: sericite 28%, high sticking attapulgite clay powder 10%, activated attapulgite 22%, sodium lauryl sulphate 26%, SPC-D 12.3%, sodium polyacrylate 0.8%, trisodium phosphate 0.6% and poly-naphthaldehyde sulfonate sodium 0.3%.
The production method of described powdery mica whipping agent: will powdery mica whipping agent stir in the batching input stirrer, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.044 millimeter is packaged as the finished product of powdery mica whipping agent.

Claims (1)

1. powdery mica whipping agent, it is characterized in that powdery mica whipping agent batching is made up of following component by weight percentage: sericite 15~45%, high sticking attapulgite clay powder 5~20%, activated attapulgite 5~25%, sodium lauryl sulphate 1~35%, SPC-D 1~25%, sodium polyacrylate 0.01~5%, trisodium phosphate 0.01~5% and poly-naphthaldehyde sulfonate sodium 0.01~5%;
The production method of described powdery mica whipping agent: will powdery mica whipping agent stir in the batching input stirrer, and carry out abrasive dust in the back input grinding machine that stirs, particle fineness≤0.074 millimeter is packaged as the finished product of powdery mica whipping agent;
The sticking attapulgite clay powder of described height refers to get 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add 372g water again, the suspension cup is placed on the homogenizer, under 11000 rev/mins rotating speed, stirred 20 minutes, to pour in the beaker of 250ml the viscosity of using NDJ-1 type rotational viscosimeter to test its suspension, tested viscosity value 〉=2200 again through the high-speed stirring sample suspension into MPasThe attapulgite clay powder.
CN201310223199.XA 2013-06-07 2013-06-07 Powdery mica foaming agent Active CN103265220B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310223199.XA CN103265220B (en) 2013-06-07 2013-06-07 Powdery mica foaming agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310223199.XA CN103265220B (en) 2013-06-07 2013-06-07 Powdery mica foaming agent

Publications (2)

Publication Number Publication Date
CN103265220A true CN103265220A (en) 2013-08-28
CN103265220B CN103265220B (en) 2014-11-05

Family

ID=49008899

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310223199.XA Active CN103265220B (en) 2013-06-07 2013-06-07 Powdery mica foaming agent

Country Status (1)

Country Link
CN (1) CN103265220B (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0474748A (en) * 1990-07-10 1992-03-10 Kao Corp Admixture for cement
US20040028956A1 (en) * 2002-08-07 2004-02-12 Arpad Savoly Dispersant and foaming agent combination
CN101037312A (en) * 2006-03-16 2007-09-19 上海华联建筑外加剂厂有限公司 Middle-effective pumping aid

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0474748A (en) * 1990-07-10 1992-03-10 Kao Corp Admixture for cement
US20040028956A1 (en) * 2002-08-07 2004-02-12 Arpad Savoly Dispersant and foaming agent combination
CN101037312A (en) * 2006-03-16 2007-09-19 上海华联建筑外加剂厂有限公司 Middle-effective pumping aid

Also Published As

Publication number Publication date
CN103265220B (en) 2014-11-05

Similar Documents

Publication Publication Date Title
CN103265318B (en) Powdery talcum foaming agent
CN103265214B (en) Powdery bentonite foamer
CN103253966B (en) Powdery boric sludge foaming agent
CN103253887B (en) Powder coal ash foaming agent
CN103253971B (en) Powdery calcium carbonate foaming agent
CN103265218B (en) Powdery water-quenched slag foaming agent
CN103265308B (en) Powdery red mud foamer
CN103265317B (en) Powdery magnesium oxide foaming agent
CN103265221B (en) Powdery basalt foaming agent
CN103265312B (en) Powdery gypsum foaming agent
CN103253888B (en) Powder pumice foaming agent
CN103274623B (en) Powdery zeolite foaming agent
CN103274629B (en) Powdery gangue foaming agent
CN103265324B (en) Powdery flint clay foaming agent
CN103265219B (en) Powdery quicklime foaming agent
CN103265311B (en) Powdery cement foaming agent
CN103265307A (en) Powdery kieselguhr foamer
CN103253963B (en) Powdery volcanic ash foaming agent
CN103265309B (en) Powdery rectorite foamer
CN103265216B (en) Powdery maifan stone foaming agent
CN103265222B (en) Powdery serpentine foaming agent
CN103265323B (en) Powdery shale foaming agent
CN103274630B (en) Powdery pyroclastic rock foaming agent
CN103265220B (en) Powdery mica foaming agent
CN103265215B (en) Powdery phosphogypsum foaming agent

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170315

Address after: 510640 unit 371-1, public education building, 2414-2416, No. five, Tianhe District, Guangzhou, Guangdong

Patentee after: Guangdong Gaohang Intellectual Property Operation Co., Ltd.

Address before: 211700 Huaian, Xuyi province Timor King international residential area, building 2, unit 202 room 18

Patentee before: Xu Shengying

CB03 Change of inventor or designer information

Inventor after: Ou Yangyun

Inventor before: Xu Qinghua

Inventor before: Jiang Wenlan

Inventor before: Xu Shengying

Inventor before: Yuan Changbing

TR01 Transfer of patent right

Effective date of registration: 20170526

Address after: 414501, Sichuan Province, Yueyang City, Pingjiang County town of Hunan stability cross Sichuan village

Patentee after: VPI MICA INSULATING MATERIALS CO., LTD., PINGJIANG

Address before: 510640 unit 371-1, public education building, 2414-2416, No. five, Tianhe District, Guangzhou, Guangdong

Patentee before: Guangdong Gaohang Intellectual Property Operation Co., Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Powdery mica foaming agent

Effective date of registration: 20171013

Granted publication date: 20141105

Pledgee: Pingjiang, Hunan, Hsbc Rural Bank Co

Pledgor: VPI MICA INSULATING MATERIALS CO., LTD., PINGJIANG

Registration number: 2017430000073

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20191227

Address after: 314300 no.413, Daifeng Road, Wanghai street, Haiyan County, Jiaxing City, Zhejiang Province

Patentee after: Zhejiang Shengshi Ruijin Fastener Co., Ltd

Address before: 414501, Sichuan Province, Yueyang City, Pingjiang County town of Hunan stability cross Sichuan village

Patentee before: VPI MICA INSULATING MATERIALS CO., LTD., PINGJIANG

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20201228

Address after: Group 1, Xintan Zhenzi neighborhood committee, Sheyang County, Yancheng City, Jiangsu Province

Patentee after: Zheng Zonghua

Address before: No. 3144130, HaiHai Road, WangYan County, Zhejiang Province

Patentee before: Zhejiang Shengshi Ruijin Fastener Co.,Ltd.