CN103254695A - Powder coating with high density polyethylene as main ingredient and preparation method thereof - Google Patents
Powder coating with high density polyethylene as main ingredient and preparation method thereof Download PDFInfo
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- CN103254695A CN103254695A CN2013101199747A CN201310119974A CN103254695A CN 103254695 A CN103254695 A CN 103254695A CN 2013101199747 A CN2013101199747 A CN 2013101199747A CN 201310119974 A CN201310119974 A CN 201310119974A CN 103254695 A CN103254695 A CN 103254695A
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- Prior art keywords
- powder
- density polyethylene
- high density
- stone flour
- powder coating
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- 239000000843 powder Substances 0.000 title claims abstract description 46
- 229920001903 high density polyethylene Polymers 0.000 title claims abstract description 38
- 239000004700 high-density polyethylene Substances 0.000 title claims abstract description 38
- 239000011248 coating agent Substances 0.000 title claims abstract description 29
- 238000000576 coating method Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002075 main ingredient Substances 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 239000004693 Polybenzimidazole Substances 0.000 claims abstract description 6
- 239000006004 Quartz sand Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 6
- 229920002480 polybenzimidazole Polymers 0.000 claims abstract description 6
- 235000013312 flour Nutrition 0.000 claims description 24
- 239000004575 stone Substances 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 11
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 239000008103 glucose Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 5
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 claims description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical class CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 229910039444 MoC Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 229960001545 hydrotalcite Drugs 0.000 claims description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003595 mist Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 abstract 2
- 238000005187 foaming Methods 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical class C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a powder coating with high density polyethylene as a main ingredient and a preparation method thereof. The powder coating comprises the following raw materials by weight part: 48-55 of high density polyethylene, 27-33 of polybenzimidazole, 18-22 of quartz sand, 25-30 of montmorillonite powder, 4.5-5.5 of activated carbon powder, 2.0-3.0 of cobaltic oxide, 5.0-7.0 of hydrotalcite powder, 6.0-8.0 of a dispersing agent NNO and 5.0-6.5 of a film-forming agent. In the invention, high density polyethylene is adopted as the main raw material, and the hydrotalcite powder and the film forming agent are added so as to enhance the mixing performance among each raw material and improve the surface leveling of the powder coating simultaneously. With high gloss retention, the powder coating has improved decorative performance. And the prepared product has a high qualified rate.
Description
Technical field
The present invention relates to powder coating, being specifically related to a kind of is the powder coating and preparation method thereof of major ingredient with the high density polyethylene(HDPE).
Background technology
Along with the sustained, stable growth of China's economy and improving constantly of living standards of the people, the powder coating business of hardware also constantly increases, especially industries such as instrument, traffic facilities, aluminium section bar, powder coating can provide good corrosionproof protection and decorate properties to metal, but owing to the antifouling property of the existing coating that is used for above-mentioned field is undesirable, often adhere to all kinds of dusts, dirt or even greasy dirt on the coating; Anti-stick subsides ability is also undesirable, and the coating that forms of existing powder coating phenomenon such as be prone to foaming under the effect of natural conditions, ftracture, peel off such as be exposed to the sun for a long time out of doors, drench with rain, and therefore, the mechanical property of coating is also undesirable.
Summary of the invention
The object of the present invention is to provide a kind of is the powder coating and preparation method thereof of major ingredient with the high density polyethylene(HDPE).
The present invention adopts following technical scheme to achieve these goals:
Be the powder coating of major ingredient with the high density polyethylene(HDPE), the weight part of its constitutive material is: high density polyethylene(HDPE) 48-55, polybenzimidazole 27-33, quartz sand 18-22, montmorillonite powder 25-30, activity charcoal powder 4.5-5.5, cobalt sesquioxide 2.0-3.0, neatly stone flour 5.0-7.0, dispersing agent NNO 6.0-8.0 and membrane-forming agent 5.0-6.5.
Be the powder coating of major ingredient with the high density polyethylene(HDPE), the weight part of its constitutive material is: high density polyethylene(HDPE) 49, polybenzimidazole 28, quartz sand 19, montmorillonite powder 26, activity charcoal powder 5.0, cobalt sesquioxide 2.5, neatly stone flour 6.0, dispersing agent NNO 7.0 and membrane-forming agent 5.8.
Be the preparation method of the powder coating of major ingredient with the high density polyethylene(HDPE), may further comprise the steps:
(1) carbon coats the neatly stone flour:
A: the neatly stone flour is crushed to the 120-130 order, and the weight part by constitutive material joins in the deionized water then, and neatly stone flour and deionized water weight ratio are 1:2.3-2.8, evenly mixes;
B: add the glucose that accounts for hydrotalcite opaque amount 10-15% in the gained mixed solution, stir, evenly mix, and then add the molybdenum carbide that accounts for glucose quality 1.0-1.6%, mixing stirs; Mist projection granulating obtains the neatly stone flour powder that organic carbon coats, and spray-dired inlet temperature 190-220 ℃, temperature out 66-78 ℃;
C: gained neatly stone flour powder is packed in the crucible, vacuumizes, and feeds inert atmosphere, keeps being heated to 270-330 ℃ of sintering 3.0-3.5h under the inert atmosphere conditions, and cooling obtains carbon and coats the neatly stone flour then;
(2) preparation of membrane-forming agent:
A: at first 9-11 part chloroprene rubber CR322,1.5-3.0 part dimethylbenzene, 2.0-3.0 part ethylene glycol diglycidylether, 8-12 part E-12 Resins, epoxy are mixed in the adding reactor, reaction is 2-3 hour under 90-110 ℃ of temperature;
B: in the reactor of step (1), add 15-17 part MALEIC ANHYDRIDE, 1.8-2.5 part 2,6 ditertbutylparacresols, 0.6-1.2 part vinyltrimethoxy silane, 1.0-1.8 part linking agent TAIC, mix, reaction is 3-5 hour under 75-95 ℃ of temperature condition, namely;
(3) take by weighing each raw material beyond dewater talcum powder and the membrane-forming agent by the weight part of constitutive material, then and step (1) and (2) raw material after handling prepare burden and put into the mixing machine mixing, the compound that mixes is put into twin screw extruder extrudes; After the sheet material cooling after extruding, put into crusher for crushing, grind to form 220-280 purpose powder, the packing warehouse-in, the powder curing condition is: solidification value 180-200 ℃, be incubated 20-30 minute.
Advantage of the present invention:
It is main raw material that the present invention has adopted high density polyethylene(HDPE), has added neatly stone flour and membrane-forming agent, strengthens the Combination between each raw material, improved the surperficial levelling of powder coating simultaneously, have high gloss retention, improved the ornamental of powder coating, the product qualified rate height for preparing.
Embodiment
Embodiment 1: be the powder coating of major ingredient with the high density polyethylene(HDPE), the weight part of its constitutive material (kg) is: high density polyethylene(HDPE) 49, polybenzimidazole 28, quartz sand 19, montmorillonite powder 26, activity charcoal powder 5.0, cobalt sesquioxide 2.5, neatly stone flour 6.0, dispersing agent NNO 7.0 and membrane-forming agent 5.8.
Be the preparation method of the powder coating of major ingredient with the high density polyethylene(HDPE), may further comprise the steps:
(1) carbon coats the neatly stone flour:
A: the neatly stone flour is crushed to the 120-130 order, and the weight part by constitutive material joins in the deionized water then, and neatly stone flour and deionized water weight ratio are 1:2.5, evenly mixes;
B: add the glucose that accounts for hydrotalcite opaque amount 12% in the gained mixed solution, stir, evenly mix, and then add the molybdenum carbide that accounts for glucose quality 1.3%, mixing stirs; Mist projection granulating obtains the neatly stone flour powder that organic carbon coats, 200 ℃ of spray-dired inlet temperatures, 75 ℃ of temperature outs;
C: gained neatly stone flour powder is packed in the crucible, vacuumizes, and feeds inert atmosphere, keeps being heated to 300 ℃ of sintering 3.3h under the inert atmosphere conditions, and cooling obtains carbon and coats the neatly stone flour then;
(2) preparation of membrane-forming agent:
A: at first 10 parts of chloroprene rubber CR322,2.3 parts of dimethylbenzene, 2.5 parts of ethylene glycol diglycidylethers, 10 parts of E-12 Resins, epoxy are mixed and add in the reactor, reaction is 2.5 hours under 100 ℃ of temperature;
B: add 16 parts of MALEIC ANHYDRIDE, 2.2 part of 2,6 ditertbutylparacresol, 0.9 part of vinyltrimethoxy silane, 1.4 parts of linking agent TAIC in the reactor of step (1), mix, reaction is 4 hours under 85 ℃ of temperature condition, namely;
(3) take by weighing each raw material beyond dewater talcum powder and the membrane-forming agent by the weight part of constitutive material, then and step (1) and (2) raw material after handling prepare burden and put into the mixing machine mixing, the compound that mixes is put into twin screw extruder extrudes; After the sheet material cooling after extruding, put into crusher for crushing, grind to form 250 purpose powder, the packing warehouse-in, the powder curing condition is: 190 ℃ of solidification values are incubated 25 minutes.
Adopt the electrostatic spraying constructional method to act on the steel tube surface of spray treatment this powder coating, abundant curing through 210 ℃, naturally cool to room temperature, after placing 24h, measure coating performance, its coating shock strength 〉=102cm, salt-fog resistant time 〉=2890h, artificial accelerated aging time 〉=3050h, resistance toheat 〉=575, exposure to weather(ing) 16 months is non-foaming, non-corrosive, do not ftracture, do not peel off.
Claims (3)
1. one kind is the powder coating of major ingredient with the high density polyethylene(HDPE), it is characterized in that the weight part of its constitutive material is: high density polyethylene(HDPE) 48-55, polybenzimidazole 27-33, quartz sand 18-22, montmorillonite powder 25-30, activity charcoal powder 4.5-5.5, cobalt sesquioxide 2.0-3.0, neatly stone flour 5.0-7.0, dispersing agent NNO 6.0-8.0 and membrane-forming agent 5.0-6.5.
2. according to claim 1 is the powder coating of major ingredient with the high density polyethylene(HDPE), it is characterized in that the weight part of its constitutive material is: high density polyethylene(HDPE) 49, polybenzimidazole 28, quartz sand 19, montmorillonite powder 26, activity charcoal powder 5.0, cobalt sesquioxide 2.5, neatly stone flour 6.0, dispersing agent NNO 7.0 and membrane-forming agent 5.8.
One kind as claimed in claim 1 be the preparation method of the powder coating of major ingredient with the high density polyethylene(HDPE), it is characterized in that may further comprise the steps:
(1) carbon coats the neatly stone flour:
A: the neatly stone flour is crushed to the 120-130 order, and the weight part by constitutive material joins in the deionized water then, and neatly stone flour and deionized water weight ratio are 1:2.3-2.8, evenly mixes;
B: add the glucose that accounts for hydrotalcite opaque amount 10-15% in the gained mixed solution, stir, evenly mix, and then add the molybdenum carbide that accounts for glucose quality 1.0-1.6%, mixing stirs; Mist projection granulating obtains the neatly stone flour powder that organic carbon coats, and spray-dired inlet temperature 190-220 ℃, temperature out 66-78 ℃;
C: gained neatly stone flour powder is packed in the crucible, vacuumizes, and feeds inert atmosphere, keeps being heated to 270-330 ℃ of sintering 3.0-3.5h under the inert atmosphere conditions, and cooling obtains carbon and coats the neatly stone flour then;
(2) preparation of membrane-forming agent:
A: at first 9-11 part chloroprene rubber CR322,1.5-3.0 part dimethylbenzene, 2.0-3.0 part ethylene glycol diglycidylether, 8-12 part E-12 Resins, epoxy are mixed in the adding reactor, reaction is 2-3 hour under 90-110 ℃ of temperature;
B: in the reactor of step (1), add 15-17 part MALEIC ANHYDRIDE, 1.8-2.5 part 2,6 ditertbutylparacresols, 0.6-1.2 part vinyltrimethoxy silane, 1.0-1.8 part linking agent TAIC, mix, reaction is 3-5 hour under 75-95 ℃ of temperature condition, namely;
(3) weight part by constitutive material takes by weighing dewater talcum powder and membrane-forming agent each raw material in addition, then and step (1) and (2) raw material after handling prepare burden and put into the mixing machine mixing, the compound that mixes is put into twin screw extruder to be extruded, after the sheet material cooling after extruding, put into crusher for crushing, grind to form 220-280 purpose powder, the packing warehouse-in, the powder curing condition is: solidification value 180-200 ℃, be incubated 20-30 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310119974.7A CN103254695B (en) | 2013-04-09 | 2013-04-09 | A kind of take high density polyethylene(HDPE) as powder coating of major ingredient and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310119974.7A CN103254695B (en) | 2013-04-09 | 2013-04-09 | A kind of take high density polyethylene(HDPE) as powder coating of major ingredient and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103254695A true CN103254695A (en) | 2013-08-21 |
| CN103254695B CN103254695B (en) | 2015-12-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310119974.7A Expired - Fee Related CN103254695B (en) | 2013-04-09 | 2013-04-09 | A kind of take high density polyethylene(HDPE) as powder coating of major ingredient and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103254695B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483931A (en) * | 2013-09-03 | 2014-01-01 | 蚌埠市鸿安精密机械有限公司 | Powder paint |
| CN103773127A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Lusterless radiating coating |
| CN103773126A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Radiating paint with good peeling resistance |
| CN103937336A (en) * | 2014-03-25 | 2014-07-23 | 安徽柏拉图涂层织物有限公司 | High levelling property paint |
| CN106477977A (en) * | 2016-10-10 | 2017-03-08 | 杭州金庭悦环保科技有限公司 | A kind of radiation shielding coating with formaldehyde reduced for a long time effect and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4007298A (en) * | 1974-04-26 | 1977-02-08 | United States Pipe And Foundry Company | Polyethylene coating for ferrous metals |
| CN1082574A (en) * | 1992-08-07 | 1994-02-23 | 中国兵器工业第五三研究所 | Modified poly propylene powdered coating and preparation method |
| CN101240134A (en) * | 2008-03-06 | 2008-08-13 | 大庆石油管理局 | Epoxy modifying polyethylene bi-component powdery paints |
| CN102676018A (en) * | 2011-03-08 | 2012-09-19 | 中国石油化工股份有限公司 | Composition for preparing monolayer antiseptic polyethylene powder coating and method for preparing composition |
-
2013
- 2013-04-09 CN CN201310119974.7A patent/CN103254695B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4007298A (en) * | 1974-04-26 | 1977-02-08 | United States Pipe And Foundry Company | Polyethylene coating for ferrous metals |
| CN1082574A (en) * | 1992-08-07 | 1994-02-23 | 中国兵器工业第五三研究所 | Modified poly propylene powdered coating and preparation method |
| CN101240134A (en) * | 2008-03-06 | 2008-08-13 | 大庆石油管理局 | Epoxy modifying polyethylene bi-component powdery paints |
| CN102676018A (en) * | 2011-03-08 | 2012-09-19 | 中国石油化工股份有限公司 | Composition for preparing monolayer antiseptic polyethylene powder coating and method for preparing composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483931A (en) * | 2013-09-03 | 2014-01-01 | 蚌埠市鸿安精密机械有限公司 | Powder paint |
| CN103483931B (en) * | 2013-09-03 | 2016-05-25 | 蚌埠市鸿安精密机械有限公司 | A kind of powdery paints |
| CN103773127A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Lusterless radiating coating |
| CN103773126A (en) * | 2014-01-15 | 2014-05-07 | 芜湖市宝艺游乐科技设备有限公司 | Radiating paint with good peeling resistance |
| CN103937336A (en) * | 2014-03-25 | 2014-07-23 | 安徽柏拉图涂层织物有限公司 | High levelling property paint |
| CN106477977A (en) * | 2016-10-10 | 2017-03-08 | 杭州金庭悦环保科技有限公司 | A kind of radiation shielding coating with formaldehyde reduced for a long time effect and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103254695B (en) | 2015-12-23 |
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Inventor after: Qin Feng Inventor before: Liu Qingfang |
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Effective date of registration: 20170703 Address after: Huang Town in Guangdong province Dongguan City Tianxin village 523000 Patentee after: Dongguan Yong glaze coating Co., Ltd. Address before: Fan Yang Zhen 241200 Anhui city of Wuhu province Fanchang County Yingchun Road, Xiyuan area 17 Patentee before: Liu Qingfang |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151223 Termination date: 20200409 |