CN103242615A - High-abrasion soles and sole material and preparation method of sole material - Google Patents
High-abrasion soles and sole material and preparation method of sole material Download PDFInfo
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- CN103242615A CN103242615A CN2013102002134A CN201310200213A CN103242615A CN 103242615 A CN103242615 A CN 103242615A CN 2013102002134 A CN2013102002134 A CN 2013102002134A CN 201310200213 A CN201310200213 A CN 201310200213A CN 103242615 A CN103242615 A CN 103242615A
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- butadiene
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Abstract
The invention discloses high-abrasion soles, a sole material and a preparation method of the sole material. The sole material comprises the following components in parts by weight: 80-100 parts of styrene-butadiene block polymers, 10-40 parts of polystyrene, 5-20 parts of polybutadiene rubber, 5-30 parts of naphthenic oil, 0.5-3 parts of azodicarbonamide, 0.5-2 parts of zinc stearate and 0.5-2 parts of zinc oxide. The sole material disclosed by the invention has the advantages that materials in the formula are easily available, low in price and convenient to process; the obtained shoe material has high quality, the abrasion resistance of the material is improved under the precondition that no increase of weight of soles. Each sole is provided with a rotating part, the rotating part comprises a base, an upper cover and a rotating shaft, and the rotating part is arranged on the front foot sole of the sole, so that a foot can easily rotate during movement; therefore, the soles have attractive appearance.
Description
Technical field
The present invention relates to a kind of sole and material for sole of shoe, be specially a kind of high abrasion sole and material for sole of shoe and preparation method thereof.
Background technology
On road, the elderly often walks in the street or takes exercise on the square, often has some sharp-pointed article or water mark on the ground.This just requires the elderly's sole must have higher wear resistance and anti-penetration.
On the market high abrasion sole had urgent demand.Existing multiple sole, as at the bottom of the Cowhells, PU sole and corium sole etc., though each tool advantage, often there is following various shortcoming in everybody in actual use:
1. the hardness at the bottom of the Cowhells is big, and dress has the uncomfortable feeling of not fitting;
2.PU sole and frictional ground force are little, non-skid property is poor;
3. the cost height of corium sole, the finished product price is not suitable for mass consumption.
Summary of the invention
The invention provides a kind of high abrasion sole and material for sole of shoe and preparation method thereof, the technical problem that solve is to pass existing sole and the not wear-resisting variety of problems of bringing of material for sole of shoe.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is: a kind of high abrasion sole and material for sole of shoe, wherein its component and parts by weight are as follows: styrene-butadiene block copolymer 80-100 part, polystyrene 10-40 part, cis-butadiene cement 5-20 part, naphthenic oil 5-30 part, Cellmic C 121 0.5-3 part, Zinic stearas 0.5-2 part, zinc oxide 0.5-2 part.
Further, described its component and parts by weight are as follows, 100 parts of styrene-butadiene block copolymers, 15 parts of polystyrene, 5 parts of cis-butadiene cements, 15 parts of naphthenic oils, 1.2 parts of Cellmic C 121s, 0.8 part of Zinic stearas, 1.2 parts in zinc oxide.
Further, described a kind of high abrasion sole and material for sole of shoe also comprise 3 parts of staining agents.
Further, described a kind of high abrasion sole and material for sole of shoe also comprise filler 0-20 part, are specially 5 parts of fillers.
A kind of high abrasion sole and material for sole of shoe, this sole is provided with turning unit, and described turning unit can be divided into base, loam cake and turning axle, and described turning unit is installed in sole forefoot place.
Further, described base is that the right cylinder of hollow and the discoid bottom surface of offering circular port combine; The shape of the hollow circular cylinder of described loam cake and base is suitable, and for offering the disk of circular port, loam cake is offered circular groove, inserts the suitable flexure strip of block-shaped and a groove in the groove; Turning axle is the double-screw bolt that is erected between base and the loam cake.
1. the preparation method of a high abrasion sole and material for sole of shoe, it is characterized in that this method comprise the steps: (1) the styrene-butadiene block copolymer after the grafting add high-speed mixer after by the prescription weighing; (2) by adding formula material polystyrene, cis-butadiene cement, naphthenic oil, Cellmic C 121, Zinic stearas and zinc oxide successively, after height stirs 5～7 minutes, move into Banbury mixer; (3) add staining agent and filler, banburying 15～30 minutes, discharging when 100～90 ℃ of temperature; (4) hit through the two-wheel rubber mixing machine and be transported to tablets press, through granulation, match colors, add auxiliary agent; (5) when 150 ℃ of temperature, molded through the press mold molding machine die, check both had been finished product.
Check both had been finished product.
The beneficial effect that the present invention has:
1. density is big, pliability is moderate, has high-wearing feature and better hardness, and is comfortable and easy to wear;
2. formula materials is easy to get, and low price is easy to process, and the footwear material amount that obtains is good;
3. sole is provided with turning unit, and foot can be rotated free labour-saving during motion.
Description of drawings
Fig. 1, the structural representation of a kind of high abrasion sole of the present invention.
Embodiment
Problem and shortage at existing technology exists the objective of the invention is to propose a kind of high abrasion sole and material for sole of shoe, can improve the wear resisting property of sole.
Embodiment 1
In the preferred embodiment of a kind of high abrasion sole of the present invention and material for sole of shoe, adopt its component and parts by weight as follows: 80 parts of styrene-butadiene block copolymers, 15 parts of polystyrene, 10 parts of cis-butadiene cements, 15 parts of naphthenic oils, 2 parts of azo two formyls, 2 parts of Zinic stearass, 2 parts in zinc oxide.
By the said ratio weighing, by above-mentioned technology manufacturing processing, compression molding under 150 ℃ of conditions.Sample is placed its hardness 59 of the above test of 24h, relative density 1.19g/cm under 25 ℃ of conditions of room temperature
3Press QB/T2884-2007 standard testing DIM abrasion and be 246mm
3
Embodiment 2
Component and parts by weight are as follows, 85 parts of styrene-butadiene block copolymers, 15 parts of polystyrene, 5 parts of cis-butadiene cements, 15 parts of naphthenic oils, 1.2 parts of Cellmic C 121s, 0.8 part of Zinic stearas, 1.5 parts in zinc oxide.
Add 5 parts of 3 parts of staining agents and fillers.Kept softness, elasticity, hardness and the proportion of footwear materials and in the wear resistance that has farthest improved the footwear materials.
By the said ratio weighing, by above-mentioned technology manufacturing processing, compression molding under 150 ℃ of conditions.Sample is placed its hardness 100 of the above test of 24h, relative density 1.15g/cm under 25 ℃ of conditions of room temperature
3Press
QB/T2884-2007 standard testing DIM abrasion are 52mm
3
Embodiment 3
Component and parts by weight are as follows, 100 parts of styrene-butadiene block copolymers, 15 parts of polystyrene, 5 parts of cis-butadiene cements, 15 parts of naphthenic oils, 1.2 parts of Cellmic C 121s, 0.8 part of Zinic stearas, 1.2 parts in zinc oxide.
Also add 5 parts of 3 parts of staining agents and fillers in the preferred embodiments of the present invention.Kept softness, elasticity, hardness and the proportion of footwear materials and in the wear resistance that has farthest improved the footwear materials.
By the said ratio weighing, by above-mentioned technology manufacturing processing, compression molding under 150 ℃ of conditions.Sample is placed its hardness 63 of the above test of 24h, relative density 1.17g/cm under 25 ℃ of conditions of room temperature
3Press QB/T2884-2007 standard testing DIM abrasion and be 273mm
3
With reference to figure 1, a kind of sports shoes with sole spinfunction of the present invention comprises vamp and sole 1, and the sole 1 of this sports shoes is provided with turning unit 2, and described turning unit 2 can be divided into base, loam cake and turning axle, and described turning unit is installed in sole forefoot place.
A kind of sports shoes with sole spinfunction, described base 3 combines with the discoid bottom surface of offering circular port for the right cylinder of hollow; Described loam cake 4 is suitable with the shape of the hollow circular cylinder of base 3, and for offering the disk of circular port, loam cake 4 is offered circular groove, inserts the suitable flexure strip 5 of block-shaped and a groove in the groove; Described turning axle 6 is for being erected at the double-screw bolt between base 3 and the loam cake 4.Footwear sole construction is simple, and is handsome in appearance, in the motion, can adapt to the influence that the changeable environment in the external world moves to the elderly out of doors, in the manufacturing of sports shoes, and functional, the portability of paying attention to that it has and comfortableness.Have the rotation of the foot of convenience, laborsaving saving time during rotation can not cause sole to grab ground scarce capacity, the skidding that causes again.Shoes adopt high abrasion resisting material, have prolonged the work-ing life of shoes, can be for endurable and anti-skidding.
The preparation method of a kind of high abrasion sole and material for sole of shoe:
2. will be styrene-butadiene block copolymer after the grafting add high-speed mixer after by the prescription weighing;
3. by adding formula material polystyrene, cis-butadiene cement, naphthenic oil, Cellmic C 121, Zinic stearas and zinc oxide successively, height stirred 5～7 minutes;
4. the immigration Banbury mixer adds staining agent and filler, banburying 15～30 minutes;
5. discharging when 100～90 ℃ of temperature hits through the two-wheel rubber mixing machine and to be transported to tablets press, through granulation, match colors, add auxiliary agent.
6. when 150 ℃ of temperature, molded through the press mold molding machine die, check both had been finished product.
Be the preferred embodiments of the present invention only below, be not limited to the present invention, for a person skilled in the art, the present invention can have various changes and variation.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. a high abrasion sole and material for sole of shoe, it is characterized in that, its component and parts by weight are as follows: styrene-butadiene block copolymer 80-100 part, polystyrene 10-40 part, cis-butadiene cement 5-20 part, naphthenic oil 5-30 part, Cellmic C 121 0.5-3 part, Zinic stearas 0.5-2 part, zinc oxide 0.5-2 part.
2. a kind of high abrasion sole according to claim 1 and material for sole of shoe, it is characterized in that: described its component and parts by weight are as follows, 100 parts of styrene-butadiene block copolymers, 15 parts of polystyrene, 5 parts of cis-butadiene cements, 15 parts of naphthenic oils, 1.2 parts of Cellmic C 121s, 0.8 part of Zinic stearas, 1.2 parts in zinc oxide.
3. a kind of high abrasion sole according to claim 1 and 2 and material for sole of shoe, it is characterized in that: described a kind of high abrasion material for sole of shoe also comprises 3 parts of staining agents.
4. a kind of high abrasion sole according to claim 1 and 2 and material for sole of shoe, it is characterized in that: described a kind of high abrasion material for sole of shoe also comprises filler 0-20 part.
5. a kind of high abrasion sole according to claim 4 and material for sole of shoe, it is characterized in that: described a kind of high abrasion material for sole of shoe also comprises 5 parts of fillers.
6. a high abrasion sole and material for sole of shoe, it is characterized in that: this sole is provided with turning unit, and described turning unit can be divided into base, loam cake and turning axle, and described turning unit is installed in sole forefoot place.
7. a kind of high abrasion sole according to claim 6 and material for sole of shoe is characterized in that: described base is that the right cylinder of hollow and the discoid bottom surface of offering circular port combine; The shape of the hollow circular cylinder of described loam cake and base is suitable, and for offering the disk of circular port, loam cake is offered circular groove, inserts the suitable flexure strip of block-shaped and a groove in the groove; Turning axle is the double-screw bolt that is erected between base and the loam cake.
8. the preparation method of a high abrasion sole and material for sole of shoe, it is characterized in that this method comprise the steps: (1) the styrene-butadiene block copolymer after the grafting add high-speed mixer after by the prescription weighing; (2) by adding formula material polystyrene, cis-butadiene cement, naphthenic oil, Cellmic C 121, Zinic stearas and zinc oxide successively, after height stirs 5～7 minutes, move into Banbury mixer; (3) add staining agent and filler, banburying 15～30 minutes, discharging when 100～90 ℃ of temperature; (4) hit through the two-wheel rubber mixing machine and be transported to tablets press, through granulation, match colors, add auxiliary agent; (5) when 150 ℃ of temperature, molded through the press mold molding machine die, check both had been finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2013102002134A CN103242615A (en) | 2013-05-25 | 2013-05-25 | High-abrasion soles and sole material and preparation method of sole material |
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| CN2013102002134A CN103242615A (en) | 2013-05-25 | 2013-05-25 | High-abrasion soles and sole material and preparation method of sole material |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104974458A (en) * | 2015-07-23 | 2015-10-14 | 温州市宜和鞋材有限公司 | Novel high-wear-resistance painting-free shoe sole material and preparation method thereof |
| CN105820386A (en) * | 2016-04-27 | 2016-08-03 | 吴银敏 | High-temperature-resistant light-weight environment-friendly sole material and preparation method thereof |
| CN106009097A (en) * | 2016-07-14 | 2016-10-12 | 温州任和教育科技有限责任公司 | Industrial anti-piercing sole material and preparation method thereof |
| CN107920620A (en) * | 2015-07-29 | 2018-04-17 | 韩国挨可深株式会社 | Shoes with spinfunction |
| CN114031884A (en) * | 2021-10-26 | 2022-02-11 | 中国石油化工股份有限公司 | Cracking-resistant children shoe sole material and preparation method thereof |
Citations (5)
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| CN1083079A (en) * | 1992-07-22 | 1994-03-02 | 中国科学院长春应用化学研究所 | The high-impact polystyrene of modified rubber |
| CN1724589A (en) * | 2005-06-17 | 2006-01-25 | 闫俊龙 | Thermoplastic elastomer and its production method |
| CN200950850Y (en) * | 2006-03-31 | 2007-09-26 | 武济群 | Rotary sports shoes |
| CN101747543A (en) * | 2009-12-09 | 2010-06-23 | 浙江仕峰实业有限公司 | Styrene-butadiene copolymer chemical foaming composition containing polystyrene micro-blocks, preparation method and application method thereof |
| CN102585391A (en) * | 2011-01-18 | 2012-07-18 | 苏州汉扬精密电子有限公司 | Modification and recovery formula for defective material of high impact polystyrene |
-
2013
- 2013-05-25 CN CN2013102002134A patent/CN103242615A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083079A (en) * | 1992-07-22 | 1994-03-02 | 中国科学院长春应用化学研究所 | The high-impact polystyrene of modified rubber |
| CN1724589A (en) * | 2005-06-17 | 2006-01-25 | 闫俊龙 | Thermoplastic elastomer and its production method |
| CN200950850Y (en) * | 2006-03-31 | 2007-09-26 | 武济群 | Rotary sports shoes |
| CN101747543A (en) * | 2009-12-09 | 2010-06-23 | 浙江仕峰实业有限公司 | Styrene-butadiene copolymer chemical foaming composition containing polystyrene micro-blocks, preparation method and application method thereof |
| CN102585391A (en) * | 2011-01-18 | 2012-07-18 | 苏州汉扬精密电子有限公司 | Modification and recovery formula for defective material of high impact polystyrene |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104974458A (en) * | 2015-07-23 | 2015-10-14 | 温州市宜和鞋材有限公司 | Novel high-wear-resistance painting-free shoe sole material and preparation method thereof |
| CN107920620A (en) * | 2015-07-29 | 2018-04-17 | 韩国挨可深株式会社 | Shoes with spinfunction |
| CN107920620B (en) * | 2015-07-29 | 2020-11-06 | 韩国挨可深株式会社 | Shoes with rotating function |
| CN105820386A (en) * | 2016-04-27 | 2016-08-03 | 吴银敏 | High-temperature-resistant light-weight environment-friendly sole material and preparation method thereof |
| CN106009097A (en) * | 2016-07-14 | 2016-10-12 | 温州任和教育科技有限责任公司 | Industrial anti-piercing sole material and preparation method thereof |
| CN114031884A (en) * | 2021-10-26 | 2022-02-11 | 中国石油化工股份有限公司 | Cracking-resistant children shoe sole material and preparation method thereof |
| CN114031884B (en) * | 2021-10-26 | 2024-02-23 | 中国石油化工股份有限公司 | Crack-resistant children's shoe sole material and preparation method thereof |
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Application publication date: 20130814 |