CN103233398A - Aluminum-plating paper and production method thereof - Google Patents

Aluminum-plating paper and production method thereof Download PDF

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Publication number
CN103233398A
CN103233398A CN2013101627896A CN201310162789A CN103233398A CN 103233398 A CN103233398 A CN 103233398A CN 2013101627896 A CN2013101627896 A CN 2013101627896A CN 201310162789 A CN201310162789 A CN 201310162789A CN 103233398 A CN103233398 A CN 103233398A
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paper
polyvinyl alcohol
layer
aluminum
water
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CN2013101627896A
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CN103233398B (en
Inventor
赵光剑
刘建国
赵利民
胡军
徐继伟
赵金玲
冯怀玉
刘珩
宫永生
张连华
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QINGZHOU GOLD QINGYUN NEW MATERIAL CO Ltd
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QINGZHOU GOLD QINGYUN NEW MATERIAL CO Ltd
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Abstract

The invention belongs to the technical field of producing aluminum-plating paper, and in particular relates to aluminum-plating paper and a production method thereof. The production method comprises the steps of: (1) offset paper coating: applying and coating a polyvinyl alcohol solution on the surface of offset paper, and drying; (2) BOPP (Biaxially-oriented Polypropylene) thin film coating: coating hydro-alcoholic color materials on the surface of a BOPP thin film, drying, and forming a dyeing layer on the surface of the BOPP thin film; (3) aluminum plating: carrying out vacuum aluminum plating on the dyeing layer of the BOPP thin film to form an aluminum-plating layer; and (4) compounding and stripping: coating aquatic composite glue on the aluminum-plating layer of the BOPP thin film, then carrying out wet type compounding together with the offset paper coated with polyvinyl alcohol glue film layer, drying, stripping the BOPP thin film, and obtaining the product, namely the offset paper coated with the dyeing layer, the aluminum-plating layer and the polyvinyl alcohol glue film layer. The aluminum-plating paper produced by adopting the production method has a metallization appearance and lower cost.

Description

The paper of aluminizing of productive method of aluminized paper and production
Technical field
The invention belongs to the paper producing technology field of aluminizing, relate in particular to the paper of aluminizing of a kind of productive method of aluminized paper and production.
Background technology
The paper of aluminizing mainly is made up of body paper, aluminium coated and coating, because of glossiness, smoothness and pliability good, sprayed-on Al layer fastness height, environmental protection attractive in appearance, good printing performance and machining property are arranged simultaneously, be widely used in the fineness packing of products such as cigarette, wine, bottle subsides, tealeaves, food, cosmetics, daily use chemicals, general merchandise, gift, handicraft, also can be used for Building Decoration Material.
Existing surface has the printing of the effect that metallizes, as auspiciousness, the good fortune word of using red-letter day, printed matters such as distich generally are to adopt electrochemical aluminium gold-stamped explained hereafter, and its cost is very high, as the metallized printed matter of the full version of need, gilding technology can't be processed, and can only generally adopt art paper and produce the paper of aluminizing with body paper with traditional paper of aluminizing, art paper is the text paper made from body paper coating whitewash, and its cost is higher.
Summary of the invention
The object of the present invention is to provide the paper of aluminizing of a kind of productive method of aluminized paper and production, be intended to solve existing relatively poor, the production cost problem of higher of paper metal appearance sense effect of aluminizing.
For solving the problems of the technologies described above, technical scheme of the present invention is:
Productive method of aluminized paper uses offset paper as body paper, may further comprise the steps:
(1) offset paper coating: at the surface application poly-vinyl alcohol solution of described offset paper, oven dry forms the polyvinyl alcohol adhesive film on the surface of described offset paper;
(2) BOPP film coated: be coated with the dual-purpose colorant of water distribution alcohol on the surface of described BOPP film, oven dry forms dye layer on the surface of described BOPP film;
(3) aluminize: carry out vacuum aluminum-coatedly at the dye layer of described BOPP film, form aluminium coated;
(4) compound peeling off: at the compound glue of aluminium coated coating water-based of described BOPP film, to carry out wet type compound with the offset paper that is covered with the polyvinyl alcohol adhesive film described in the step (1) again, oven dry, peel off described BOPP film, the described offset paper that is covered with dye layer, aluminium coated, compound adhesive water layer and polyvinyl alcohol adhesive film is products obtained therefrom.
Preferably, that described offset paper quantitatively is 40~90g/ ㎡.
Preferably, the concentration of described poly-vinyl alcohol solution is 5~10%, and described percentage is weight percentage, and the wet coating weight of described poly-vinyl alcohol solution is 5~10g/ ㎡.
Preferably, the concentration of the dual-purpose colorant of described water alcohol is 14~26%, and described percentage is weight percentage.
Preferably, the dual-purpose colorant of described water alcohol comprises 5~15% look essences, 40~60% acrylic emulsion and 30~55% pure water, and described percentage is weight percentage.
Preferably, the thickness of described polyvinyl alcohol adhesive film is 3~15 μ m.
Preferably, the thickness of described dye layer is 3~15 μ m.
Preferably, the thickness of described aluminium coated is 30~50nm.
Preferably, the thickness of described BOPP film is 12~30 μ m.
Preferably, the thickness of described compound adhesive water layer is 3~25 μ m.
A kind of paper of aluminizing that makes according to aforementioned production method, the described paper of aluminizing is followed successively by hectograph ply of paper, polyvinyl alcohol adhesive film, compound adhesive water layer, aluminium coated and dye layer from bottom to up.
Owing to adopted technique scheme, the invention has the beneficial effects as follows:
Productive method of aluminized paper provided by the invention, replace traditional art paper with offset paper, because offset paper is cheap, thereby reduced the production cost of the paper of aluminizing widely, scribble the polyvinyl alcohol adhesive film on the surface of offset paper, the polyvinyl alcohol adhesive film can reach and the gold stamping type same effect of paper of aluminizing, and according to customer requirement pattern is embossed on the polyvinyl alcohol adhesive film, finished product after compound like this need not to republish the pattern that just can realize that the client needs, has saved printing cost; Aluminium coated can be given the paper of aluminizing with metallized appearance effect, gives valuable sense and solid sense; The feasible paper of aluminizing of dye layer can have different colors, has increased the designs and varieties of the paper of aluminizing, thereby has improved the aesthetic degree of printing packaging product.
Description of drawings
Fig. 1 is the technological process of production figure of the paper of aluminizing that provides of the embodiment of the invention;
Fig. 2 is the structural representation of paper of aluminizing;
Wherein: 1-hectograph ply of paper, 2-polyvinyl alcohol adhesive film, 3-compound adhesive water layer, 4-aluminium coated, 5-dye layer.
The specific embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explaining the present invention, and be not used in restriction the present invention.
Fig. 1 shows the technological process of production figure of the paper of aluminizing among the embodiment one to embodiment three;
Embodiment one
Productive method of aluminized paper uses offset paper as body paper, and it may further comprise the steps:
(1) offset paper painting process: at surface application 5% poly-vinyl alcohol solution (percentage by weight) of coating machine with commercially available roll type offset paper, the quantitative of offset paper is 40g/ ㎡, the wet coating weight of poly-vinyl alcohol solution is 8g/ ㎡, oven dry, surface at offset paper forms the polyvinyl alcohol adhesive film, and the thickness of polyvinyl alcohol adhesive film is 3 μ m;
(2) BOPP film coated operation: adopt the surface that the mode of intaglio plate coating will commercially available BOPP film to be coated with the pure dual-purpose colorant (percentage by weight) of 14% water at coating machine, the thickness of BOPP film is 12 μ m, the dual-purpose colorant of water alcohol comprises 5~15% look essences, 40~60% acrylic emulsion and 30~55% pure water, described percentage is weight percentage, oven dry, surface at the BOPP film forms dye layer, and the thickness of dye layer is 3 μ m;
(3) operation of aluminizing: with the BOPP film that is covered with dye layer that obtains in the step (2) vacuumize at the take-up type vacuum aluminum-spraying machine, evaporation, form aluminium coated, the thickness of aluminium coated is 30nm;
(4) compound stripping process: at the compound glue of aluminium coated coating water-based of BOPP film, the thickness of the compound glue of water-based is 3 μ m, to be covered with the offset paper that is covered with the polyvinyl alcohol adhesive film that obtains in the BOPP film of water-based compound adhesive water layer, aluminium coated and dye layer and the step (1) on compound stripping machine, to carry out wet type compound, oven dry then, the BOPP film is stripped down, the neat back of rolling is for producing use next time, and the offset paper of peeling off behind the BOPP film that is covered with dye layer, aluminium coated, compound adhesive water layer and polyvinyl alcohol adhesive film is products obtained therefrom.
Embodiment two
Productive method of aluminized paper uses offset paper as body paper, and it may further comprise the steps:
(1) offset paper painting process: at surface application 8% poly-vinyl alcohol solution (percentage by weight) of coating machine with commercially available roll type offset paper, the quantitative of offset paper is 65g/ ㎡, the wet coating weight of poly-vinyl alcohol solution is 5g/ ㎡, oven dry, surface at offset paper forms the polyvinyl alcohol adhesive film, and the thickness of polyvinyl alcohol adhesive film is 9 μ m;
(2) BOPP film coated operation: adopt the surface that the mode of intaglio plate coating will commercially available BOPP film to be coated with the pure dual-purpose colorant (percentage by weight) of 20% water at coating machine, the thickness of BOPP film is 21 μ m, the dual-purpose colorant of water alcohol comprises 5~15% look essences, 40~60% acrylic emulsion and 30~55% pure water, described percentage is weight percentage, oven dry, surface at the BOPP film forms dye layer, and the thickness of dye layer is 9 μ m;
(3) operation of aluminizing: with the BOPP film that is covered with dye layer that obtains in the step (2) vacuumize at the take-up type vacuum aluminum-spraying machine, evaporation, form aluminium coated, the thickness of aluminium coated is 40nm;
(4) compound stripping process: at the compound glue of aluminium coated coating water-based of BOPP film, the thickness of the compound glue of water-based is 14 μ m, to be covered with the offset paper that is covered with the polyvinyl alcohol adhesive film that obtains in the BOPP film of water-based compound adhesive water layer, aluminium coated and dye layer and the step (1) on compound stripping machine, to carry out wet type compound, oven dry then, the BOPP film is stripped down, the neat back of rolling is for producing use next time, and the offset paper of peeling off behind the BOPP film that is covered with dye layer, aluminium coated, compound adhesive water layer and polyvinyl alcohol adhesive film is products obtained therefrom.
Embodiment three
Productive method of aluminized paper uses offset paper as body paper, and it may further comprise the steps:
(1) offset paper painting process: at surface application 8% poly-vinyl alcohol solution (percentage by weight) of coating machine with commercially available roll type offset paper, the quantitative of offset paper is 90g/ ㎡, the wet coating weight of poly-vinyl alcohol solution is 10g/ ㎡, oven dry, surface at offset paper forms the polyvinyl alcohol adhesive film, and the thickness of polyvinyl alcohol adhesive film is 15 μ m;
(2) BOPP film coated operation: adopt the surface that the mode of intaglio plate coating will commercially available BOPP film to be coated with the pure dual-purpose colorant (percentage by weight) of 26% water at coating machine, the thickness of BOPP film is 30 μ m, the dual-purpose colorant of water alcohol comprises 5~15% look essences, 40~60% acrylic emulsion and 30~55% pure water, described percentage is weight percentage, oven dry, surface at the BOPP film forms dye layer, and the thickness of dye layer is 15 μ m;
(3) operation of aluminizing: with the BOPP film that is covered with dye layer that obtains in the step (2) vacuumize at the take-up type vacuum aluminum-spraying machine, evaporation, form aluminium coated, the thickness of aluminium coated is 50nm;
(4) compound stripping process: at the compound glue of aluminium coated coating water-based of BOPP film, the thickness of the compound glue of water-based is 25 μ m, to be covered with the offset paper that is covered with the polyvinyl alcohol adhesive film that obtains in the BOPP film of water-based compound adhesive water layer, aluminium coated and dye layer and the step (1) on compound stripping machine, to carry out wet type compound, oven dry then, the BOPP film is stripped down, the neat back of rolling is for producing use next time, and the offset paper of peeling off behind the BOPP film that is covered with dye layer, aluminium coated, compound adhesive water layer and polyvinyl alcohol adhesive film is products obtained therefrom.
Embodiment four
As shown in Figure 2, a kind of paper of aluminizing that makes with the either party's method in above-described embodiment is followed successively by hectograph ply of paper 1, polyvinyl alcohol adhesive film 2, compound adhesive water layer 3, aluminium coated 4 and dye layer 5 from bottom to up.
The above only is preferred embodiment of the present invention, not in order to limiting the present invention, all any modifications of doing within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.

Claims (10)

1. productive method of aluminized paper is characterized in that: use offset paper as body paper, may further comprise the steps:
(1) offset paper coating: at the surface application poly-vinyl alcohol solution of described offset paper, oven dry forms the polyvinyl alcohol adhesive film on the surface of described offset paper;
(2) BOPP film coated: be coated with the dual-purpose colorant of water distribution alcohol on the surface of described BOPP film, oven dry forms dye layer on the surface of described BOPP film;
(3) aluminize: carry out vacuum aluminum-coatedly at the dye layer of described BOPP film, form aluminium coated;
(4) compound peeling off: at the compound glue of aluminium coated coating water-based of described BOPP film, to carry out wet type compound with the offset paper that is covered with the polyvinyl alcohol adhesive film described in the step (1) again, oven dry, peel off described BOPP film, the described offset paper that is covered with dye layer, aluminium coated, compound adhesive water layer and polyvinyl alcohol adhesive film successively is products obtained therefrom.
2. productive method of aluminized paper as claimed in claim 1 is characterized in that: described offset paper quantitatively be 40~90g/ ㎡.
3. productive method of aluminized paper as claimed in claim 1, it is characterized in that: the concentration of described poly-vinyl alcohol solution is 5~10%, and described percentage is weight percentage, and the wet coating weight of described poly-vinyl alcohol solution is 5~10g/ ㎡.
4. productive method of aluminized paper as claimed in claim 1, it is characterized in that: the concentration of the dual-purpose colorant of described water alcohol is 14~26%, the dual-purpose colorant of described water alcohol comprises 5~15% look essences, 40~60% acrylic emulsion and 30~55% pure water, and described percentage is weight percentage.
5. as each described productive method of aluminized paper of claim 1-4, it is characterized in that: the thickness of described polyvinyl alcohol adhesive film is 3~15 μ m.
6. as each described productive method of aluminized paper of claim 1-4, it is characterized in that: the thickness of described dye layer is 3~15 μ m.
7. as each described productive method of aluminized paper of claim 1-4, it is characterized in that: the thickness of described aluminium coated is 30~50nm.
8. as each described productive method of aluminized paper of claim 1-4, it is characterized in that: the thickness of described BOPP film is 12~30 μ m.
9. as each described productive method of aluminized paper of claim 1-4, it is characterized in that: the thickness of described compound adhesive water layer is 3~25 μ m.
10. the paper of aluminizing that productive method of aluminized paper as claimed in claim 1 makes is characterized in that: the described paper of aluminizing is followed successively by hectograph ply of paper, polyvinyl alcohol adhesive film, compound adhesive water layer, aluminium coated and dye layer from bottom to up.
CN201310162789.6A 2013-05-06 2013-05-06 Aluminum-plating paper and production method thereof Active CN103233398B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115125768A (en) * 2022-07-25 2022-09-30 孝感市雅都新材料防伪包装有限公司 Colorful laser transfer paper and production method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01198398A (en) * 1988-02-04 1989-08-09 Honshu Paper Co Ltd Transfer metallized paper and manufacture thereof
CN101508215A (en) * 2009-03-13 2009-08-19 淄博泰宝包装制品有限公司 Low VOCs environmental protection laser holographic transfer film and paper
US20110317269A1 (en) * 2010-06-28 2011-12-29 Toray Plastics (America) Inc. Releasable metalized embossed transfer film
CN102774159A (en) * 2012-07-31 2012-11-14 中国印刷科学技术研究所 Large-format hot gold stamping method and hot stamping film
CN102864683A (en) * 2012-08-21 2013-01-09 湖南中烟工业有限责任公司 Preparation process of laser golden vacuum aluminized paper and transfer coating used for preparation process
CN102966007A (en) * 2012-10-16 2013-03-13 绍兴京昇光信息科技有限公司 Preparation method of Fresnel lens vacuum aluminized paper and produced product thereby
CN102995486A (en) * 2012-08-21 2013-03-27 湖南中烟工业有限责任公司 Preparation process of sliver vacuum aluminum-plated paper and transfer paint for paper

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01198398A (en) * 1988-02-04 1989-08-09 Honshu Paper Co Ltd Transfer metallized paper and manufacture thereof
CN101508215A (en) * 2009-03-13 2009-08-19 淄博泰宝包装制品有限公司 Low VOCs environmental protection laser holographic transfer film and paper
US20110317269A1 (en) * 2010-06-28 2011-12-29 Toray Plastics (America) Inc. Releasable metalized embossed transfer film
CN102774159A (en) * 2012-07-31 2012-11-14 中国印刷科学技术研究所 Large-format hot gold stamping method and hot stamping film
CN102864683A (en) * 2012-08-21 2013-01-09 湖南中烟工业有限责任公司 Preparation process of laser golden vacuum aluminized paper and transfer coating used for preparation process
CN102995486A (en) * 2012-08-21 2013-03-27 湖南中烟工业有限责任公司 Preparation process of sliver vacuum aluminum-plated paper and transfer paint for paper
CN102966007A (en) * 2012-10-16 2013-03-13 绍兴京昇光信息科技有限公司 Preparation method of Fresnel lens vacuum aluminized paper and produced product thereby

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115125768A (en) * 2022-07-25 2022-09-30 孝感市雅都新材料防伪包装有限公司 Colorful laser transfer paper and production method thereof

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