Summary of the invention
Technical problem to be solved by this invention is to overcome existing dye sublimation fastness low, comprehensive fastness difference and to defects such as the Color differences of polyester woven material and blend fibre goods thereof, and provides a kind of application of DISPERSE DYES.Disperse dyes structure novelty of the present invention has higher sublimation reliability and comprehensive fastness, bright-colored, be applicable to dyeing and the stamp of polyester woven material or its blend fibre goods, be specially adapted to dyeing and the stamp of the outdoor exercises weaving face fabrics such as swimming suit, and the synthesis technique of DISPERSE DYES of the present invention is simple, be easy to operation, environmental friendliness.
The invention provides a kind of compound as shown in Equation 1
Wherein, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl; R
4for C
1-4alkyl; D is
Wherein, R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.Described compound 1 is a kind of DISPERSE DYES.
Present invention also offers the preparation method of compound as shown in Equation 1, it comprises the following steps: in a solvent, under acid catalyzed condition, diazol as shown in Equation 3 and compound is as shown in Equation 2 carried out coupling reaction, obtains compound 1;
Wherein, A is Cl
-, CH
2cOO
-, H
2pO
4 -, HSO
4 -or NO
3 -, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl; R
4for C
1-4alkyl; D is
In the method preparing compound 1, R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.Described compound 1 is a kind of DISPERSE DYES.
In the method preparing compound 1, described coupling reaction can be carried out according to the conventional method of such reaction in this area, preferred following reaction condition and step:
In the method preparing compound 1, described solvent preferred water.
In the method preparing compound 1, the volume mass of described solvent and described compound 2 than preferred 4mL/g ~ 12mL/g, preferred 6mL/g ~ 9mL/g further.
In the method preparing compound 1, one or more in the preferred hydrochloric acid of described acid, acetic acid, phosphoric acid, nitric acid and sulfuric acid, one or more further preferably in hydrochloric acid, acetic acid and sulfuric acid, then preferably sulfuric acid and/or hydrochloric acid further.Described acid can participate in reaction with the form of aqueous acid, the mass percent concentration of described aqueous acid preferably 1% ~ 20%, and further preferably 3% ~ 15%.
In the method preparing compound 1, the volume ratio of described acid and described solvent preferably 0.005 ~ 0.02, further preferably 0.008 ~ 0.012.
In the method preparing compound 1, the preferred 1:1 ~ 1:1.5 of mol ratio of described compound 2 and the diazol of compound 3, further preferred 1:1 ~ 1:1.2.
In the method preparing compound 1, the temperature of described coupling reaction preferably-10 DEG C ~ 30 DEG C, preferred-10 DEG C ~ 10 DEG C further, more preferred-5 DEG C ~ 5 DEG C further.
In the method preparing compound 1, the process of described coupling reaction can be monitored by traditional test methods in this area (as filter paper oozes circle method), and no longer carry out as reaction end to react, the preferred reaction time is 1h ~ 3h, further preferred 2h.
Above-mentioned diazol as shown in Equation 3 can obtain by the following method: under sour existent condition, by nitrite or nitrosyl sulfuric acid, carries out diazo-reaction with aromatic amine as shown in Equation 8, obtains the diazol of compound 3; Compound 1 is obtained again according to the above-mentioned method preparing compound 1;
Wherein, A is Cl
-, CH
2cOO
-, H
2pO
4 -, HSO
4 -or NO
3 -; D is
Described diazo-reaction can be carried out according to the conventional method in this area, preferred following reaction condition:
In described diazo-reaction, described solvent preferred water.
In described diazo-reaction, one or more in the preferred hydrochloric acid of described acid, acetic acid and sulfuric acid, further preferably sulfuric acid and/or hydrochloric acid.Described acid can participate in reaction with the form of aqueous acid, the mass percent concentration of described aqueous acid preferably 10% ~ 90%, and further preferably 20% ~ 80%.
In described diazo-reaction, the preferred natrium nitrosum of described nitrite.
In described diazo-reaction, the volume mass of described solvent and described aromatic amine as shown in Equation 8 than preferred 1mL/g ~ 10mL/g, preferred 2mL/g ~ 5mL/g further.
In described diazo-reaction, the preferred 1:1 ~ 1:1.2 of mol ratio of described aromatic amine as shown in Equation 8 and described nitrite or nitrosyl sulfuric acid, further preferred 1:1 ~ 1:1.1.
In described diazo-reaction, the temperature of described reaction preferably-10 DEG C ~ 30 DEG C, preferred-10 ~ 20 DEG C further.
The process of described diazo-reaction can by traditional test methods (as TLC) monitoring in this area, and disappear for reaction end with described aromatic amine as shown in Equation 8, the preferred reaction time is 1h ~ 5h, further preferred 2h ~ 3h.
Above-claimed cpd 2 can be obtained by following method: compound 4 and acid anhydrides are as shown in Equation 5 carried out acylation reaction, obtains compound 2;
Prepare compound 3 according to the above-mentioned method preparing compound 3 again, then prepare compound 1 according to the above-mentioned method preparing compound 1; Wherein, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl; R
4for C
1-4alkyl.
In the method preparing compound 2, R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.Described compound 1 is a kind of DISPERSE DYES.
In the method preparing compound 2, described acylation reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 2, described reaction can be carried out in a solvent, also can carry out in the absence of a solvent.The preferred organic acid of described solvent, the preferred acetic acid of described organic acid.
In the method preparing compound 2, the volume mass of described solvent and described compound 4 than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 2, described acid anhydrides 5 and the preferred 1:1 ~ 1:1.2 of mol ratio of described compound 4, further preferred 1:1 ~ 1:1.1.
In the method preparing compound 2, the temperature of described acylation reaction preferably 20 DEG C ~ 100 DEG C, preferably 25 DEG C ~ 75 DEG C further, more preferably 50 DEG C further.
In the method preparing compound 2, the process of described acylation reaction can by traditional test methods (as HPLC) monitoring in this area, and reacted for reaction end with compound 4, the preferred reaction time is 2h ~ 6h, further preferred 4 ~ 5h.
Above-claimed cpd 4 can be obtained by following method: compound 6 and amine are as shown in Equation 7 reacted, obtain compound 4;
Obtain compound 2 according to the above-mentioned method preparing compound 2 again, then prepare compound 3 according to the above-mentioned method preparing compound 3, then prepare compound 1 according to the above-mentioned method preparing compound 1; Wherein, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl.
In the method preparing compound 4, R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.Described compound 1 is a kind of DISPERSE DYES.
In the method preparing compound 4, described reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 4, described reaction can be carried out also can carrying out in the absence of a solvent in a solvent.The preferred organic acid of described solvent, the preferred acetic acid of described organic acid.
In the method preparing compound 4, the volume mass of described solvent and described compound 7 than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 4, described compound 6 and the preferred 1:1 ~ 1:2 of mol ratio of described compound 7, further preferred 1:1 ~ 1:1.1.
In the method preparing compound 4, the temperature of described reaction preferably 20 DEG C ~ 100 DEG C, preferably 25 DEG C ~ 75 DEG C further, more preferably 50 DEG C further.
In the method preparing compound 4, the process of described reaction can by traditional test methods (as HPLC) monitoring in this area, and reacted for reaction end with compound 7, the preferred reaction time is 1h ~ 5h, further preferred 2h ~ 4h.
Above-claimed cpd 6 can be obtained by following method: in a solvent, under the condition of alkali existence and catalyst, phenol and epoxychloropropane is reacted, obtains compound 6;
Obtain compound 4 according to the above-mentioned method preparing compound 4 again, obtain compound 2 according to the above-mentioned method preparing compound 2, then prepare compound 3 according to the above-mentioned method preparing compound 3, then prepare compound 1 according to the above-mentioned method preparing compound 1.
In the method preparing compound 6, described reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 6, described solvent preferred water.
In the method preparing compound 6, the preferred PEG-400(PEG400 of described catalyst).
In the method preparing compound 6, described catalyst and the mass percent of phenol preferably 1% ~ 30%, further preferably 5% ~ 25%, more further preferably 10%.
In the method preparing compound 6, the volume mass of described solvent and described compound phenol than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 6, described phenol and the preferred 1:1 ~ 1:1.8 of the mol ratio of epoxychloropropane, further preferred 1:1 ~ 1:1.5.
In the method preparing compound 6, the preferred inorganic base of described alkali, one or more in the preferred NaOH of described inorganic base, potassium hydroxide, potash, sodium bicarbonate, saleratus and sodium carbonate, further preferred NaOH.
In the method preparing compound 6, described alkali can participate in reaction with the form of the aqueous solution of alkali, the mass percent concentration of the aqueous solution of described alkali preferably 10% ~ 40%, and further preferably 25% ~ 35%, more further preferably 30%.
In the method preparing compound 6, described alkali and the preferred 1:1 ~ 1:1.2 of the mol ratio of phenol, further preferred 1:1.
In the method preparing compound 6, the temperature of described reaction preferably 0 DEG C ~ 100 DEG C, preferably 20 DEG C ~ 75 DEG C further, more preferably 50 DEG C ~ 55 DEG C further.
In the method preparing compound 6, the process of described reaction can by traditional test methods (as HPLC) monitoring in this area, and complete for reaction end with phenol fundamental reaction, the preferred reaction time is 1h ~ 6h, further preferred 2h ~ 5h.
The invention provides a kind of preparation method of compound as shown in Equation 2, it comprises the following steps: compound 4 and acid anhydrides are as shown in Equation 5 carried out acylation reaction, obtains compound 2;
Wherein, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl; R
4for C
1-4alkyl.
In the method preparing compound 2, R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.
In the method preparing compound 2, described acylation reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 2, described reaction can be carried out in a solvent, also can carry out in the absence of a solvent.The preferred organic acid of described solvent, the preferred acetic acid of described organic acid.
In the method preparing compound 2, the volume mass of described solvent and described compound 4 than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 2, described acid anhydrides 5 and the preferred 1:1 ~ 1:1.2 of mol ratio of described compound 4, further preferred 1:1 ~ 1:1.1.
In the method preparing compound 2, the temperature of described acylation reaction preferably 20 DEG C ~ 100 DEG C, preferably 25 DEG C ~ 75 DEG C further, more preferably 50 DEG C further.
In the method preparing compound 2, the process of described acylation reaction can by traditional test methods (as HPLC) monitoring in this area, and reacted for reaction end with compound 4, the preferred reaction time is 2h ~ 6h, further preferred 4 ~ 5h.
The invention provides the preparation method of compound 1, it preferably comprises the following steps:
Step 1: in a solvent, under the condition of alkali existence and catalyst, reacts phenol and epoxychloropropane, obtains compound 6;
Step 2: compound 6 obtained in step 1 is reacted with amine as shown in Equation 7, obtains compound 4;
Step 3: compound 4 obtained in step 2 is carried out acylation reaction with acid anhydrides as shown in Equation 5, obtains compound 2;
Step 4: under sour existent condition, carries out diazo-reaction by aromatic amine as shown in Equation 8 and nitrite or nitrosyl sulfuric acid, obtains the diazol of compound 3;
Step 5: in a solvent, under acid catalyzed condition, carries out coupling reaction by compound as shown in Equation 2 obtained in diazol as shown in Equation 3 obtained in step 4 and step 3, obtains compound 1;
Wherein, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl; R
4for C
1-4alkyl; D is
Wherein, R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.Described compound 1 is a kind of DISPERSE DYES.
In the method preparing compound 6, described reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 6, described solvent preferred water.
In the method preparing compound 6, the preferred PEG-400(PEG400 of described catalyst).
In the method preparing compound 6, described catalyst and the mass percent of phenol preferably 1% ~ 30%, further preferably 5% ~ 25%, more further preferably 10%.
In the method preparing compound 6, the volume mass of described solvent and described compound phenol than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 6, described phenol and the preferred 1:1 ~ 1:1.8 of the mol ratio of epoxychloropropane, further preferred 1:1 ~ 1:1.5.
In the method preparing compound 6, the preferred inorganic base of described alkali, one or more in the preferred NaOH of described inorganic base, potassium hydroxide, potash, sodium bicarbonate, saleratus and sodium carbonate, further preferred NaOH.
In the method preparing compound 6, described alkali can participate in reaction with the form of the aqueous solution of alkali, the mass percent concentration of the aqueous solution of described alkali preferably 10% ~ 40%, and further preferably 25% ~ 35%, more further preferably 30%.
In the method preparing compound 6, described alkali and the preferred 1:1 ~ 1:1.2 of the mol ratio of phenol, further preferred 1:1.
In the method preparing compound 6, the temperature of described reaction preferably 0 DEG C ~ 100 DEG C, preferably 20 DEG C ~ 75 DEG C further, more preferably 50 DEG C ~ 55 DEG C further.
In the method preparing compound 6, the process of described reaction can by traditional test methods (as HPLC) monitoring in this area, and complete for reaction end with phenol fundamental reaction, the preferred reaction time is 1h ~ 6h, further preferred 2h ~ 5h.
In the method preparing compound 4, described reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 4, described reaction can be carried out also can carrying out in the absence of a solvent in a solvent.The preferred organic acid of described solvent, the preferred acetic acid of described organic acid.
In the method preparing compound 4, the volume mass of described solvent and described compound 7 than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 4, described compound 6 and the preferred 1:1 ~ 1:2 of mol ratio of described compound 7, further preferred 1:1 ~ 1:1.1.
In the method preparing compound 4, the temperature of described reaction preferably 20 DEG C ~ 100 DEG C, preferably 25 DEG C ~ 75 DEG C further, more preferably 50 DEG C further.
In the method preparing compound 4, the process of described reaction can by traditional test methods (as HPLC) monitoring in this area, and reacted for reaction end with compound 7, the preferred reaction time is 1h ~ 5h, further preferred 2h ~ 4h.
In the method preparing compound 2, described acylation reaction can be carried out according to the conventional method of this area, particularly preferably following reaction condition in the present invention:
In the method preparing compound 2, described reaction can be carried out in a solvent, also can carry out in the absence of a solvent.The preferred organic acid of described solvent, the preferred acetic acid of described organic acid.
In the method preparing compound 2, the volume mass of described solvent and described compound 4 than preferred 1mL/g ~ 10mL/g, preferred 1mL/g ~ 5mL/g further.
In the method preparing compound 2, described acid anhydrides 5 and the preferred 1:1 ~ 1:1.2 of mol ratio of described compound 4, further preferred 1:1 ~ 1:1.1.
In the method preparing compound 2, the temperature of described acylation reaction preferably 20 DEG C ~ 100 DEG C, preferably 25 DEG C ~ 75 DEG C further, more preferably 50 DEG C further.
In the method preparing compound 2, the process of described acylation reaction can by traditional test methods (as HPLC) monitoring in this area, and reacted for reaction end with compound 4, the preferred reaction time is 2h ~ 6h, further preferred 4 ~ 5h.
Described diazo-reaction can be carried out according to the conventional method in this area, preferred following reaction condition:
In described diazo-reaction, described solvent preferred water.
In described diazo-reaction, one or more in the preferred hydrochloric acid of described acid, acetic acid and sulfuric acid, further preferably sulfuric acid and/or hydrochloric acid.Described acid can participate in reaction with the form of aqueous acid, the mass percent concentration of described aqueous acid preferably 10% ~ 90%, and further preferably 20% ~ 80%.
In described diazo-reaction, the preferred natrium nitrosum of described nitrite.
In described diazo-reaction, the volume mass of described solvent and described aromatic amine as shown in Equation 8 than preferred 1mL/g ~ 10mL/g, preferred 2mL/g ~ 5mL/g further.
In described diazo-reaction, the preferred 1:1 ~ 1:1.2 of mol ratio of described aromatic amine as shown in Equation 8 and described nitrite or nitrosyl sulfuric acid, further preferred 1:1 ~ 1:1.1.
In described diazo-reaction, the temperature of described reaction preferably-10 DEG C ~ 30 DEG C, preferred-10 ~ 20 DEG C further.
Can by traditional test methods (as TLC) monitoring in this area in the process of described diazo-reaction, disappear for reaction end with described aromatic amine as shown in Equation 8, the preferred reaction time is 1h ~ 5h, further preferred 2h ~ 3h.
In the method preparing compound 1, described coupling reaction can be carried out according to the conventional method of such reaction in this area, preferred following reaction condition and step:
In the method preparing compound 1, described solvent preferred water.
In the method preparing compound 1, the volume mass of described solvent and described compound 2 than preferred 4mL/g ~ 12mL/g, preferred 6mL/g ~ 9mL/g further.
In the method preparing compound 1, one or more in the preferred hydrochloric acid of described acid, acetic acid, phosphoric acid, nitric acid and sulfuric acid, one or more further preferably in hydrochloric acid, acetic acid and sulfuric acid, then preferably sulfuric acid and/or hydrochloric acid further.Described acid can participate in reaction with the form of aqueous acid, the mass percent concentration of described aqueous acid preferably 1% ~ 20%, and further preferably 3% ~ 15%.
In the method preparing compound 1, the volume ratio of described acid and described solvent preferably 0.005 ~ 0.02, further preferably 0.008 ~ 0.012.
In the method preparing compound 1, the preferred 1:1 ~ 1:1.5 of mol ratio of described compound 2 and the diazol of compound 3, further preferred 1:1 ~ 1:1.2.
In the method preparing compound 1, the temperature of described coupling reaction preferably-10 DEG C ~ 30 DEG C, preferred-10 DEG C ~ 10 DEG C further, more preferred-5 DEG C ~ 5 DEG C further.
In the method preparing compound 1, the process of described coupling reaction can be monitored by traditional test methods in this area (as filter paper oozes circle method), and no longer carry out as reaction end to react, the preferred reaction time is 1h ~ 3h, further preferred 2h.
Present invention also offers above-mentioned compound as shown in Equation 1 as the application of DISPERSE DYES in the dyeing and stamp of fibre.
Compound 1 of the present invention can process according to the conventional treatment method (as sand milling) in this area, obtains commercialization DISPERSE DYES.
The commercialization DISPERSE DYES that compound of the present invention is obtained, can be applied to dyeing and the stamp of polyester fiber goods or its blend fibre goods according to the common staining method of this type disperse dye in this area.Described polyester fiber goods or its blend fibre goods can be polyester fiber goods conventional in this area or its blend fibre goods; The preferred pet fiber goods of described polyester fiber goods, described blend fibre goods preferred polyester/cotton or polyester/wool.DISPERSE DYES of the present invention is preferred for the outdoor exercises weaving face fabrics such as swimming suit further; The outdoor exercises weaving face fabrics such as described swimming suit are polyester fiber goods or its blend fibre goods.Described polyester fiber goods or its blend fibre goods can be the conventional existence form of this area, as fiber, yarn, woven fabric, knitted fabric or nonwoven.
Present invention also offers a kind of compound as shown in Equation 2:
Wherein, R
1for C
1-4alkoxyl or hydrogen; R
2for C
1-4acylamino-or hydrogen; R
3for C
1-4alkyl; R
4for C
1-4alkyl.
R
1be preferably methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy or hydrogen.R
2be preferably formamido group, acetylamino, propionamido, butyrylamino or hydrogen.R
3be preferably methyl, ethyl, propyl group or butyl.R
4be preferably methyl, ethyl, propyl group or butyl.R
1more preferably methoxyl group, ethyoxyl or hydrogen.R
2more preferably acetylamino, propionamido or hydrogen.R
3more preferably methyl or ethyl.R
4more preferably methyl or ethyl.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can be combined, obtain the preferred embodiments of the invention.
Agents useful for same of the present invention and raw material are all commercially.
Room temperature in the present invention is 10 DEG C ~ 30 DEG C.
Number in the present invention, except specified otherwise, all refers to mass fraction.
LC-MS data described in the present invention are that mobile phase is acetonitrile/water system by Waters UPLC-SQD LC-MS instrument, and 60%-90% acetonitrile V/V, tests under the condition that column temperature is 40 DEG C.
Positive progressive effect of the present invention is: disperse dyes structure novelty of the present invention has higher sublimation reliability and comprehensive fastness, bright-colored, be applicable to dyeing and the stamp of polyester woven material and blend fibre goods thereof, be specially adapted to dyeing and the stamp of the outdoor exercises weaving face fabrics such as swimming suit, and the synthesis technique of DISPERSE DYES of the present invention is simple, be easy to operation, environmental friendliness.