CN103232821B - A kind of adhesives in Packaging containing nanometer calcite and preparation method thereof - Google Patents

A kind of adhesives in Packaging containing nanometer calcite and preparation method thereof Download PDF

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CN103232821B
CN103232821B CN201310118573.XA CN201310118573A CN103232821B CN 103232821 B CN103232821 B CN 103232821B CN 201310118573 A CN201310118573 A CN 201310118573A CN 103232821 B CN103232821 B CN 103232821B
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rubber
add
calcite
adhesives
stir
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CN103232821A (en
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刘祥鹏
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Anhui Fenghuangsong Packaging Co ltd
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QINGYANG HUADING PACKAGING CO Ltd
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Abstract

The invention discloses a kind of adhesives in Packaging containing nanometer calcite and preparation method thereof.It is made up of the raw material of following weight part: chloroprene rubber (CR1212) 20-30, hexanaphthene 50-55, toluene 40-50, ethyl acetate 100-120, 120# solvent oil 100-120, 2402 resol 20-25, terpene phenolic resin 5-10, polyacrylamide 4-8, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2-3, morpholine 0.25-0.35, triphenylmethane triisocyanate 1-2, clorafin 3-5, Tween-60? 0.2-0.3, chlorosulfonated polyethylene rubber (TS-320) 8-12, chlorohydrin rubber (H-50) 5-8, active zinc flower 1-2, activated magnesia 2-4, sulphur 0.5-1, nanometer calcite 3-5 etc.Invention adhesive has excellent high-and low-temperature resistance, wear resistance, and cohesive strength is high, excellent storage stability, and the feature of environmental protection is good, and result of use is good and convenient.

Description

A kind of adhesives in Packaging containing nanometer calcite and preparation method thereof
Technical field
The present invention relates to a kind of tackiness agent, be specifically related to a kind of adhesives in Packaging containing nanometer calcite and preparation method thereof.
Background technology
Adhesives in Packaging produces on the basis of packaging industry fast development and develops, the performance of adhesives in Packaging, quality directly affects packaging effect and quality, current wrapping tackiness agent ubiquity thermotolerance is poor, winter hardiness is not good, wear no resistance, the shortcomings such as package stability difference.In order to overcome the shortcoming of traditional tackiness agent, by improving formula, thus producing a kind of novel package and stick with glue agent.
Summary of the invention
The object of this invention is to provide that a kind of temperature tolerance is good, wear resistance is good, cohesive strength is high, adhesives in Packaging containing nanometer calcite of excellent storage stability and preparation method thereof.
The technical solution used in the present invention is as follows:
A kind of adhesives in Packaging containing nanometer calcite, be made up of the raw material of following weight part: chloroprene rubber (CR1212) 20-30, hexanaphthene 50-55, toluene 40-50, ethyl acetate 100-120, 120# solvent oil 100-120, 2402 resol 20-25, terpene phenolic resin 5-10, polyacrylamide 4-8, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2-3, morpholine 0.25-0.35, triphenylmethane triisocyanate 1-2, clorafin 3-5, Tween-60 0.2-0.3, chlorosulfonated polyethylene rubber (TS-320) 8-12, chlorohydrin rubber (H-50) 5-8, active zinc flower 1-2, activated magnesia 2-4, sulphur 0.5-1, nanometer calcite 3-5, magnesium hydroxide 2-3, semi-reinforcing hydrocarbon black 2-3, anti-aging agent MMB1-2, anti-aging agent TPPD0.5-1, Vulcanization accelerator TMTD 0.5-1, promotor ZDC1-2, irgasfos 168 1-1.5, calcium stearate 1-2, acetyl triethyl citrate 3-4, dioctyl sebacate 2-3, treated starch 2-4.
Described treated starch following methods obtains: tapioca (flour) and hydrogen peroxide are carried out being oxidized to obtain cassava oxidized starch in the ratio of 2-3:1, carboxymethyl cellulose, the sodium lignosulfonate of 4-6%, the sodium alginate of 2-3%, the plant ash of 3-5% of 2-3% in cassava oxidized starch, fully mix, be dried to water content 5-8%, then at 140-160 DEG C of heating 2-3h, product is grind into powder after cooling, drying, pulverizing.
A preparation method for adhesives in Packaging containing nanometer calcite, comprises the following steps:
(1) hexanaphthene is added in reactor, add activated magnesia, be uniformly mixed 10-15min, add load weighted 2402 resol more continuously, stirring 3-4h to dissolving completely, adding morpholine stirring reaction 6-10h at 25-28 DEG C, leave standstill 20-24h, filter and remove throw out, obtain pre-reaction liquid, stand-by;
(2) chloroprene rubber is added in twin screw extruder, be warming up to 140-150 DEG C, when it becomes molten state, add nanometer calcite, melt blending 20-30min, then extruding pelletization under the rotating speed of 400-600rpm, be cooled to normal temperature and namely obtain chloroprene rubber clad nano calcite particle;
(3) above-mentioned obtained chloroprene rubber clad nano calcite particle and clorafin, chlorosulfonated polyethylene rubber, chlorohydrin rubber, active zinc flower, sulphur, magnesium hydroxide, semi-reinforcing hydrocarbon black, anti-aging agent MMB, Vulcanization accelerator TMTD, promotor ZDC, irgasfos 168, calcium stearate, acetyl triethyl citrate, dioctyl sebacate are sent into carry out at 40-50 DEG C in rubber mixing machine mixing, mixing 3-5 time, then thin-pass 6-8 bottom sheet, is cut into fragment after being cooled to normal temperature;
(4) get above-mentioned fragment and add toluene, ethyl acetate and 120# solvent oil, stir, fragment is all dissolved, add triphenylmethane triisocyanate, terpene phenolic resin, N-(β mono-aminoethyl again)-γ-aminopropyl front three (second) TMOS and Tween-60, stir reaction 4-6h;
(5) in above-mentioned reaction solution, add pre-reaction liquid, anti-aging agent TPPD, polyacrylamide and treated starch, stir 1-2h and get product.
Beneficial effect of the present invention:
The present invention by process modification, utilizes chloroprene rubber clad nano calcite to granulate, obviously can improve the consistency of nanometer calcite and rubber, thus improves performances such as packing the bending of glue, tensile strength and wear resistance.The present invention utilizes 2402 resol and activated magnesia to generate resin, can improve water tolerance and the thermotolerance of chloroprene rubber adhesive agent, extends tack retention hour.The present invention, by carrying out modification to starch, can improve bonding strength and the water tolerance of packaging glue further, and it is low to have cost, the feature of excellent effect.Invention adhesive has excellent high-and low-temperature resistance, wear resistance, and cohesive strength is high, water-fast protection against the tide, excellent storage stability, and the feature of environmental protection is good, and result of use is good and convenient.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
A kind of adhesives in Packaging containing nanometer calcite, be made up of the raw material of following weight part: chloroprene rubber (CR1212) 25 parts, hexanaphthene 50 parts, toluene 45 parts, ethyl acetate 115 parts, 120# solvent oil 110 parts, 2402 22 parts, resol, terpene phenolic resin 8 parts, polyacrylamide 5, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2 parts, morpholine 0.3 part, triphenylmethane triisocyanate 1.5 parts, clorafin 4 parts, Tween-60 0.2 part, chlorosulfonated polyethylene rubber (TS-320) 10 parts, chlorohydrin rubber (H-50) 5 parts, active zinc flower 1.5 parts, activated magnesia 3 parts, 0.6 part, sulphur, 4 parts, nanometer calcite, magnesium hydroxide 2 parts, semi-reinforcing hydrocarbon black 3 parts, anti-aging agent MMB1 part, anti-aging agent TPPD0.5 part, Vulcanization accelerator TMTD 1 part, promotor ZDC1 part, irgasfos 168 1.5 parts, calcium stearate 1.5 parts, acetyl triethyl citrate 3 parts, dioctyl sebacate 2 parts, treated starch 3 parts.
Described treated starch following methods obtains: tapioca (flour) and hydrogen peroxide are carried out being oxidized to obtain cassava oxidized starch in the ratio of 2:1, the carboxymethyl cellulose of 2%, sodium lignosulfonate, the sodium alginate of 2%, the plant ash of 3% of 4% in cassava oxidized starch, fully mix, be dried to water content 5%, then at 160 DEG C of heating 2h, product is grind into powder after cooling, drying, pulverizing.
A preparation method for adhesives in Packaging containing nanometer calcite, comprises the following steps:
(1) hexanaphthene is added in reactor, add activated magnesia, be uniformly mixed 10min, then add load weighted 2402 resol continuously, stirring 3h to dissolving completely, adding morpholine stirring reaction 8h at 28 DEG C, leave standstill 20h, filter and remove throw out, obtain pre-reaction liquid, stand-by;
(2) chloroprene rubber is added in twin screw extruder, be warming up to 140 DEG C, when it becomes molten state, add nanometer calcite, melt blending 30min, then extruding pelletization under the rotating speed of 400rpm, be cooled to normal temperature and namely obtain chloroprene rubber clad nano calcite particle;
(3) above-mentioned obtained chloroprene rubber clad nano calcite particle and clorafin, chlorosulfonated polyethylene rubber, chlorohydrin rubber, active zinc flower, sulphur, magnesium hydroxide, semi-reinforcing hydrocarbon black, anti-aging agent MMB, Vulcanization accelerator TMTD, promotor ZDC, irgasfos 168, calcium stearate, acetyl triethyl citrate, dioctyl sebacate are sent into carry out at 42 DEG C in rubber mixing machine mixing, mixing 5 times, then thin-pass 6 bottom sheet, are cut into fragment after being cooled to normal temperature;
(4) get above-mentioned fragment and add toluene, ethyl acetate and 120# solvent oil, stir, fragment is all dissolved, add triphenylmethane triisocyanate, terpene phenolic resin, N-(β mono-aminoethyl again)-γ-aminopropyl front three (second) TMOS and Tween-60, stir reaction 5h;
(5) in above-mentioned reaction solution, add pre-reaction liquid, anti-aging agent TPPD, polyacrylamide and treated starch, stir 1h and get product.
The performance test results of the sizing agent that the present embodiment obtains is as follows:
Tensile strength (MPa): 44;
Flexural strength (MPa): 63;
Compressive strength (MPa): 84;
Tensile strength (MPa): 35;
Stripping strength (N/cm): 52;
Shearing resistance (MPa): 27;
Medium-resistance (soaking the shearing resistance conservation rate/% after 3 days in 90 DEG C of solution): 0 #diesel oil 98.7, distilled water 99.7;
Wear resistance (sliding frictional wear volume/mm 3): 3.77;
Heat-resistant aging (at 80-100 DEG C after 7 days bond strength/N/cm): 32;
Lower temperature resistance: do not freeze at-30 DEG C 7 days;
Weather resistance: indoor use 10-20, outdoor 3-5;
Use the carton of binding agent of the present invention to duck in drink, within 48 hours, do not come unstuck, after carton drying, good bonding, mass conservation.

Claims (2)

1. the adhesives in Packaging containing nanometer calcite, it is characterized in that, be made up of the raw material of following weight part: CR1212 chloroprene rubber 20-30, hexanaphthene 50-55, toluene 40-50, ethyl acetate 100-120, 120# solvent oil 100-120, 2402 resol 20-25, terpene phenolic resin 5-10, polyacrylamide 4-8, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS 2-3, morpholine 0.25-0.35, triphenylmethane triisocyanate 1-2, clorafin 3-5, Tween-60 0.2-0.3, TS-320 chlorosulfonated polyethylene rubber 8-12, H-50 chlorohydrin rubber 5-8, active zinc flower 1-2, activated magnesia 2-4, sulphur 0.5-1, nanometer calcite 3-5, magnesium hydroxide 2-3, semi-reinforcing hydrocarbon black 2-3, anti-aging agent MMB1-2, anti-aging agent TPPD0.5-1, Vulcanization accelerator TMTD 0.5-1, promotor ZDC1-2, irgasfos 168 1-1.5, calcium stearate 1-2, acetyl triethyl citrate 3-4, dioctyl sebacate 2-3, treated starch 2-4, described treated starch obtains by the following method: tapioca (flour) and hydrogen peroxide are carried out being oxidized to obtain cassava oxidized starch in the ratio of 2-3:1, the carboxymethyl cellulose of 2-3%, the sodium lignosulfonate of 4-6%, the sodium alginate of 2-3%, the plant ash of 3-5% is added in cassava oxidized starch, fully mix, be dried to water content 5-8%, then at 140-160 DEG C of heating 2-3h, product is grind into powder after cooling, drying, pulverizing.
2. the preparation method of the adhesives in Packaging as claimed in claim 1 containing nanometer calcite, it is characterized in that comprising the following steps: hexanaphthene adds in reactor by (1), add activated magnesia, be uniformly mixed 10-15min, then add load weighted 2402 resol continuously, stir 3-4h to dissolving completely, add morpholine stirring reaction 6-10h at 25-28 DEG C, leave standstill 20-24h, filter and remove throw out, obtain pre-reaction liquid, stand-by; (2) CR1212 chloroprene rubber is added in twin screw extruder, be warming up to 140-150 DEG C, when it becomes molten state, add nanometer calcite, melt blending 20-30min under the rotating speed of 400-600rpm, then extruding pelletization, is cooled to normal temperature and namely obtains chloroprene rubber clad nano calcite particle; (3) above-mentioned obtained chloroprene rubber clad nano calcite particle and clorafin, TS-320 chlorosulfonated polyethylene rubber, H-50 chlorohydrin rubber, active zinc flower, sulphur, magnesium hydroxide, semi-reinforcing hydrocarbon black, anti-aging agent MMB, Vulcanization accelerator TMTD, promotor ZDC, irgasfos 168, calcium stearate, acetyl triethyl citrate, dioctyl sebacate are sent into carry out at 40-50 DEG C in rubber mixing machine mixing, mixing 3-5 time, then thin-pass 6-8 bottom sheet, is cut into fragment after being cooled to normal temperature; (4) get above-mentioned fragment and add toluene, ethyl acetate and 120# solvent oil, stir, fragment is all dissolved, add triphenylmethane triisocyanate, terpene phenolic resin, N-(β mono-aminoethyl again)-γ-aminopropyl front three (second) TMOS and Tween-60, stir reaction 4-6h; (5) in above-mentioned reaction solution, add pre-reaction liquid, anti-aging agent TPPD, polyacrylamide and treated starch, stir 1-2h and get product.
CN201310118573.XA 2013-04-07 2013-04-07 A kind of adhesives in Packaging containing nanometer calcite and preparation method thereof Active CN103232821B (en)

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CN101037577B (en) * 2007-04-30 2010-12-22 湖南神力实业有限公司 Nano chlorobutadiene rubber adhesive and preparation method thereof0}
CN101418197A (en) * 2008-12-01 2009-04-29 广东三和化工科技有限公司 Environmental protection chloroprene rubber adhesive agent and production method thereof
CN102965036B (en) * 2012-11-02 2014-07-16 铜陵祥云消防科技有限责任公司 Nano-wollastonite modified adhesive for packaging

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Effective date of registration: 20180112

Address after: 247100 Qingyang Industrial Park, Chizhou, Anhui

Patentee after: ANHUI FENGHUANGSONG PACKAGING Co.,Ltd.

Address before: Anhui province Chizhou City Shuang Xi Road 242800 Qingyang County Economic Development Zone

Patentee before: QINGYANG HUADING PACKAGING Co.,Ltd.

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Denomination of invention: Package-use adhesive comprising nano-grade calcite, and preparation method thereof

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Pledgee: Qingyang Anhui rural commercial bank Limited by Share Ltd.

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