CN103232162A - Method for preparing compound microcrystalline glass based on raw material of iron tailings - Google Patents
Method for preparing compound microcrystalline glass based on raw material of iron tailings Download PDFInfo
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- CN103232162A CN103232162A CN2013101373298A CN201310137329A CN103232162A CN 103232162 A CN103232162 A CN 103232162A CN 2013101373298 A CN2013101373298 A CN 2013101373298A CN 201310137329 A CN201310137329 A CN 201310137329A CN 103232162 A CN103232162 A CN 103232162A
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Abstract
The invention relates to a method for preparing compound microcrystalline glass based on a raw material of iron tailings. The method comprises the following steps of: paving and sprinkling the raw material for preparing the microcrystalline glass on a refractory slab according to a microcrystalline glass aggregate of a certain thickness, wherein the nucleation temperature is 880-890 DEG C, the holding time is 50-60 minutes, the crystallization temperature is 1130-1140 DEG C, and the holding time is 85-95 minutes; then gradually cooling down until the temperature is less than or equal to 100 DEG C; drawing; and shaping. According to the method, the microcrystalline glass aggregate prepared from the iron tailings is used as a filler, the prepared compound microcrystalline glass is not taupe anymore, and silicon, aluminum, zinc, calcium and magnesium of different colors can be added as main components to form the microcrystalline glass aggregate of a wollastonite crystallization system, so that the color of the compound microcrystalline glass based on the raw material of the iron tailings is enriched, and decorative needs are met.
Description
Technical field
The present invention relates to a kind of preparation method of composite microcrystallite glass, especially a kind of is the preparation method of the composite microcrystallite glass of raw material based on iron tailings.
Background technology
Iron tailings is the waste that a kind of iron ore is produced, and iron tailings is realized that innoxious use is the best method that solves iron tailings, and utilizing iron tailings to produce microcrystalline glass decorative plate is important means with other devitrified glass products.And because the iron tailings iron content is high and color is gloomy, the devitrified glass of formation is beige, can not play decorative effect.
Summary of the invention
In order to overcome above-mentioned technical disadvantages, the purpose of this invention is to provide a kind of is the preparation method of the composite microcrystallite glass of raw material based on iron tailings, and therefore having enriched based on iron tailings is the color of the composite microcrystallite glass of raw material, has satisfied the decoration needs.
For achieving the above object, the technical scheme that the present invention takes is: a kind of is the preparation method of the composite microcrystallite glass of raw material based on iron tailings, the steps include: the raw material of producing devitrified glass is spilt on refractory slab by certain thickness devitrified glass pellet shop, nucleation temperature is 880 ℃-890 ℃, soaking time 50-60 minute, crystallization temperature was 1130 ℃-1140 ℃, soaking time 85-95 minute, be cooled to gradually then≤100 ℃ of kiln discharges, be shaped.
The present invention has designed, by weight: 32-37% iron tailings and 63-68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of-1480 ℃ of temperature, glass solution is produced particle through the shrend method, be the devitrified glass pellet, produce the devitrified glass pellet that the raw material of devitrified glass is set to produce according to the method described above.
The present invention has designed, and the raw material of producing devitrified glass is set to by weight: the mixture of 94-98% devitrified glass pellet and 2-6% whipping agent.
The present invention has designed, and whipping agent is set to rhombspar.
The present invention has designed, and the raw material of producing devitrified glass is set to by weight: the mixture of the devitrified glass pellet of 70-80 % and other devitrified glass pellet of 20-30 %.
The present invention has designed, and the raw material of producing devitrified glass is set to by weight: the mixture of other devitrified glass pellet of the devitrified glass pellet of 66-78 %, 20-28 % and the whipping agent of 2-6 %.
In the technical program, by weight: 32-37% iron tailings and 63-68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of-1480 ℃ of temperature, glass solution is produced granule through the shrend method, be the devitrified glass pellet in the technical program.Be that wollastonite crystallizing system devitrified glass pellet that main ingredient forms is other devitrified glass pellet in the technical program with silicon, aluminium, zinc, calcium, magnesium.
Produce the raw material of devitrified glass through 6-9 hour crystallization, burn till processing and can obtain compound iron tailings devitrified glass, owing to designed whipping agent and silicon, aluminium, zinc, calcium, magnesium is the wollastonite crystallizing system devitrified glass pellet that main ingredient forms, being based on the devitrified glass pellet of being produced by iron tailings is filler, the composite microcrystallite glass of producing no longer is beige, the silicon that can add different colours, aluminium, zinc, calcium, magnesium is the wollastonite crystallizing system devitrified glass pellet that main ingredient forms, therefore having enriched based on iron tailings is the color of the composite microcrystallite glass of raw material, has satisfied the decoration needs.
Embodiment
Below in conjunction with embodiment, the present invention is further described, following examples are intended to illustrate the present invention rather than limitation of the invention further.A kind of is the preparation method of the composite microcrystallite glass of raw material based on iron tailings, and first embodiment the steps include:
One, by weight: 32% iron tailings and 68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the devitrified glass pellet devitrified glass pellet that step 1 is produced is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 880 ℃, soaking time 50 minutes, crystallization temperature is 1130 ℃, soaking time 85 minutes is cooled to 100 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, iron tailings refer to Shandong conquer east the area iron tailings, its chemical composition is as follows:
| Sequence number | Chemical ingredients | The 1# sample | The 2# sample | The 3# sample | The 4# sample | The homogenizing sample |
| 1 | SiO 2 | 69.93 | 70.05 | 68.80 | 69.1 | 68,96 |
| 2 | Al 2O 3 | 4.72 | 4.73 | 4.95 | 5.12 | 5.93 |
| 3 | Fe 2O 3 | 15.30 | 12.90 | 13.80 | 13.40 | 13.88 |
| 4 | MgO | 2.88 | 3.04 | 3.10 | 2.67 | 2.97 |
| 5 | CaO | 3.91 | 4.03 | 3.71 | 3.68 | 3.59 |
| 6 | Na 2O | 0.64 | 0.67 | 0.65 | 0．98 | 0.92 |
| 7 | K 2O | 0.77 | 0.80 | 0.78 | 0.90 | 1.32 |
| 8 | TiO 2 | 0.11 | 0.07 | 0.90 | 0.68 | 0.14 |
| 9 | Trace adds up to | About 1.0 | About 1.0 | About 1.0 | About 1.0 | About 1.0 |
| 13 | Loss on ignition | 1.39 | 0.28 | 0.97 | 0.74 | 1.06 |
In the present embodiment, be that the chemical ingredients combination of composite microcrystallite glass of raw material is as follows based on iron tailings:
| Composition | SiO2 | AL2O3 | Zno | Cao | MgO | NaO | K2O | Fe2O3 | Bao | B2O3 | Finings | Toner or whipping agent |
| % | 55.5 | 5 | 6 | 15 | 2.5 | 4 | 1 | 5.5 | 2.5 | 3 | ? | ? |
The performance index that based on iron tailings are the composite microcrystallite glass of raw material are:
| Test item | Density | Water-intake rate | Mohs' hardness | Strength at break | The modulus of rupture | Acidproof | Alkaline-resisting |
| Detected result | 2.66 | 0.05 | 4 | 4192（N） | 30.16（MPa） | UHA | ULC |
Second embodiment the steps include:
One, by weight: quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and the manganese oxide mixing formation mixture of 37% iron tailings and 63 %, mixture is placed in the glass melter, make glass solution 1480 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the devitrified glass pellet devitrified glass pellet that step 1 is produced is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 890 ℃, soaking time 60 minutes, crystallization temperature is 1140 ℃, soaking time 85-95 minute, be cooled to 55 ℃ of kiln discharges then gradually, be shaped.
The 3rd embodiment the steps include:
One, by weight: 35% iron tailings and 65% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1465 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the devitrified glass pellet devitrified glass pellet that step 1 is produced is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 885 ℃, soaking time 55 minutes, crystallization temperature is 1135 ℃, soaking time 90 minutes is cooled to 80 ℃ of kiln discharges then gradually, is shaped.
The 4th embodiment the steps include:
One, by weight: quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and the manganese oxide mixing formation mixture of 37% iron tailings and 63 %, mixture is placed in the glass melter, make glass solution 1480 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of the devitrified glass pellet that 98% step 1 is produced and 2% whipping agent is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 890 ℃, soaking time 60 minutes, crystallization temperature is 1140 ℃, soaking time 95 minutes is cooled to 90 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, whipping agent refers to rhombspar.
The 5th embodiment the steps include:
One, by weight: 32% iron tailings and 68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of the devitrified glass pellet that the step 1 of 94 % is produced and 6% whipping agent is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 880 ℃, soaking time 50 minutes, crystallization temperature is 1130 ℃, soaking time 85 minutes is cooled to 100 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, whipping agent refers to rhombspar.
The 6th embodiment the steps include:
One, by weight: 35% iron tailings and 65% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1465 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of the devitrified glass pellet that 96% step 1 is produced and 4% whipping agent is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 885 ℃, soaking time 55 minutes, crystallization temperature is 1135 ℃, soaking time 90 minutes is cooled to≤50 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, whipping agent refers to rhombspar.
The 7th embodiment the steps include:
One, by weight: by weight: 32% iron tailings and 68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of other devitrified glass pellet of the devitrified glass pellet that the step 1 of 70 % is produced and 30 % is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 880 ℃, soaking time 50 minutes, crystallization temperature is 1130 ℃, soaking time 85 minutes is cooled to 100 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, other devitrified glass pellet refers to silicon, aluminium, zinc, calcium, magnesium to be the wollastonite crystallizing system devitrified glass pellet of the white of main ingredient formation.
The 8th embodiment the steps include:
One, by weight: by weight: quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and the manganese oxide mixing formation mixture of 37% iron tailings and 63 %, mixture is placed in the glass melter, make glass solution 1480 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of other devitrified glass pellet of the devitrified glass pellet that the step 1 of 80 % is produced and 20 % is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 890 ℃, soaking time 60 minutes, crystallization temperature is 1140 ℃, soaking time 95 minutes is cooled to 80 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, other devitrified glass pellet refers to silicon, aluminium, zinc, calcium, magnesium to be the wollastonite crystallizing system devitrified glass pellet of the yellow of main ingredient formation.
The 9th embodiment the steps include:
One, by weight: by weight: 35% iron tailings and 65% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1465 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of other devitrified glass pellet of the devitrified glass pellet that the step 1 of 75 % is produced and 25 % is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 885 ℃, soaking time 55 minutes, crystallization temperature is 1135 ℃, soaking time 90 minutes is cooled to 60 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, other devitrified glass pellet refers to silicon, aluminium, zinc, calcium, magnesium to be the wollastonite crystallizing system devitrified glass pellet of the green of main ingredient formation.
The tenth embodiment the steps include:
One, by weight: by weight: the iron tailings of 32 % and 68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of the whipping agent of other devitrified glass pellet of the devitrified glass pellet that the step 1 of 66 % is produced, 20 % and 2 % is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 880 ℃, soaking time 50 minutes, crystallization temperature is 1130 ℃, soaking time 85 minutes is cooled to 100 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, whipping agent refers to rhombspar.
In the present embodiment, other devitrified glass pellet refers to silicon, aluminium, zinc, calcium, magnesium to be the wollastonite crystallizing system devitrified glass pellet of the grey of main ingredient formation.
The 11 embodiment the steps include:
One, by weight: by weight: quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and the manganese oxide mixing formation mixture of 37% iron tailings and 63 %, mixture is placed in the glass melter, make glass solution 1480 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of the whipping agent of other devitrified glass pellet of the devitrified glass pellet that the step 1 of 78 % is produced, 28 % and 6 % is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 890 ℃, soaking time 60 minutes, crystallization temperature is 1140 ℃, soaking time 95 minutes is cooled to 87 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, whipping agent refers to rhombspar.
In the present embodiment, other devitrified glass pellet refers to silicon, aluminium, zinc, calcium, magnesium to be the wollastonite crystallizing system devitrified glass pellet of the green of main ingredient formation.
The 12 embodiment the steps include:
One, by weight: by weight: 35% iron tailings and 65% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1465 ℃ of temperature, glass solution is produced granule through the shrend method, as the devitrified glass pellet.
Two, the mixture of the whipping agent of other devitrified glass pellet of the devitrified glass pellet that the step 1 of 72 % is produced, 24 % and 4 % is as the raw material of producing devitrified glass, produce the raw material shop of devitrified glass spills on refractory slab by the handle of the thickness identical with the thickness of composite microcrystallite glass, nucleation temperature is 885 ℃, soaking time 55 minutes, crystallization temperature is 1135 ℃, soaking time 90 minutes is cooled to 61 ℃ of kiln discharges then gradually, is shaped.
In the present embodiment, whipping agent refers to rhombspar.
In the present embodiment, other devitrified glass pellet refers to silicon, aluminium, zinc, calcium, magnesium to be the wollastonite crystallizing system devitrified glass pellet of the yellow of main ingredient formation.
Be that the wollastonite crystallizing system devitrified glass pellet of the main ingredient white, yellow, green and the grey that form consists predominantly of aluminosilicate devitrified glass pellet, silicophosphate devitrified glass pellet, K2O-Al2O3-SiO2 system glass ceramics pellet, SiO2-Al2O3-Fe2O3-R2O-RO system (basalt) devitrified glass pellet, SiO2-Al2O3-ZnO-MgO system glass ceramics pellet and Fluorosilicate Glass-Ceramics pellet with silicon, aluminium, zinc, calcium, magnesium.
Iron tailings is a kind of mine waste, and it is occupied arable land, contaminate environment even might cause the catastrophic failure of the crisis securities of the lives and property such as dam break.With it as resource in addition innoxious use will have a tremendous social and economic benefits, therefore, national three ministries and commissions all tailing microcrystal glass is listed in national emphasis encourages to support to recommend and 11 emphasis new and high technology examples of rewarding among.Yet mine tailing class devitrified glass is because iron content and other impurity are more, the product colour dimness, and aesthetic effect is low, and use value is very low.Improved even if add expensive toner, also can only produce dark products such as black, coffee color, not only production cost is high, and can only be used for supportingly, and is that mine tailing class devitrified glass can't be realized at all based on white and pale yellow main product.Just because of this, although national policy supports that energetically mine tailing class devitrified glass still can not get promoting and large-area applications.
The present invention has proposed feasible solution for solving the low problem of mine tailing class decorative devitrified glass effect, and its advantage and effect are as follows:
1, with the iron tailings devitrified glass be matrix, with other color microcrystalline glass serve as the table body iron tailings composite microcrystallite glass dalle formed based on iron tailings devitrified glass pellet, be the product general layout of assisting with other color microcrystalline glass pellets, two kinds of employed ratios of raw material are about 70:30.Owing to as the Decorative watch body, can not take the quality as the iron tailings devitrified glass color of matrix with other color microcrystalline glass into account, save to improveing the gloomy color of iron tailings devitrified glass and added the formed great number cost of expensive toner.Under the constant situation of iron tailings devitrified glass, only need the color of change table body layer just can produce the compound iron tailings crystallizing glass decoration board of different decorative colors, be convenient to expect from microcrystallite organization of production and the scheduling of assortment.Owing to can change table body color arbitrarily according to market demand, fundamentally changed the low defective of mine tailing class decorative devitrified glass effect, promote use value and the use range of mine tailing class devitrified glass greatly, thereby also improved the usage quantity of mine tailing greatly.
2, in the iron tailings microcrystalline glass formula, add whipping agent, be the new decorative material of conventional devitrified glass by producing matrix with first described identical technology for foaming iron tailings devitrified glass, table body, its advantage is as follows: light decorative plate material, intensity is good, is suitable for family and engineering inside fitting; Along with national energy-saving and emission-reduction and Sustainable development policy are implemented dynamics and continued to increase, the skin insulation has become Compulsory Feature.The product that the present invention relates to is because foaming has formed closed micropore, this material has the function of sound-insulating, according to regional natural temperature difference, can produce the matrix of different thickness, and meet the table body ornament layer that sintering is suitable for color, forming rare collection insulation, sound insulation and decoration functions is the novel external wall light thermal-insulation finishing material of one; Foaming iron tailings devitrified glass also can be used as the light partition wall material.
In sum, the invention solves mine tailing class decorative devitrified glass effect low, use serious limited problem, widened the use range of mine tailing class devitrified glass greatly, can play active effect for popularization and the development of tailing microcrystal glass.
The present invention has following characteristics:
1, be the wollastonite crystallizing system devitrified glass pellet that main ingredient forms owing to having designed whipping agent and silicon, aluminium, zinc, calcium, magnesium, being based on the devitrified glass pellet of being produced by iron tailings is filler, the composite microcrystallite glass of producing no longer is beige, silicon, aluminium, zinc, calcium, the magnesium that can add different colours is the wollastonite crystallizing system devitrified glass pellet that main ingredient forms, therefore having enriched based on iron tailings is the color of the composite microcrystallite glass of raw material, has satisfied the decoration needs.
2, owing to designed whipping agent, alleviated the weight of composite microcrystallite glass, high insulating effect.
3, owing to designed iron tailings, combine the character of iron tailings, improved the intensity of composite microcrystallite glass.
Above-described embodiment be provided by the present invention be a kind of way of realization in preparation method's technical field of composite microcrystallite glass of raw material based on iron tailings; other distortion according to scheme provided by the present invention; increase or reduce wherein composition or step; the technical field that approaches with the present invention that perhaps the present invention is used for other all belongs to protection scope of the present invention.
Claims (6)
1. one kind is the preparation method of the composite microcrystallite glass of raw material based on iron tailings; It is characterized in that: the steps include: the raw material of producing devitrified glass is spilt on refractory slab by certain thickness devitrified glass pellet shop, nucleation temperature is 880 ℃-890 ℃, soaking time 50-60 minute, crystallization temperature is 1130 ℃-1140 ℃, soaking time 85-95 minute, be cooled to gradually then≤100 ℃ of kiln discharges, be shaped.
2. according to claim 1 is the preparation method of the composite microcrystallite glass of raw material based on iron tailings; It is characterized in that: by weight: 32-37% iron tailings and 63-68% quartz, feldspar, wollastonite, aluminum oxide, zinc oxide, boron oxide, barium oxide and manganese oxide mixing formation mixture, mixture is placed in the glass melter, make glass solution 1450 ℃ of-1480 ℃ of temperature, glass solution is produced particle through the shrend method, be the devitrified glass pellet, produce the devitrified glass pellet that the raw material of devitrified glass is set to produce according to the method described above.
3. according to claim 1 is the preparation method of the composite microcrystallite glass of raw material based on iron tailings; It is characterized in that: the raw material of producing devitrified glass is set to by weight: the mixture of 94-98% devitrified glass pellet and 2-6% whipping agent.
4. according to claim 1 is the preparation method of the composite microcrystallite glass of raw material based on iron tailings; It is characterized in that: the raw material of producing devitrified glass is set to by weight: the mixture of the devitrified glass pellet of 70-80 % and other devitrified glass pellet of 20-30 %.
5. according to claim 1 is the preparation method of the composite microcrystallite glass of raw material based on iron tailings; It is characterized in that: the raw material of producing devitrified glass is set to by weight: the mixture of other devitrified glass pellet of the devitrified glass pellet of 66-78 %, 20-28 % and the whipping agent of 2-6 %.
According to claim 3 or 5 described be the preparation method of the composite microcrystallite glass of raw material based on iron tailings; It is characterized in that: whipping agent is set to rhombspar.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104016589A (en) * | 2014-06-27 | 2014-09-03 | 北京国泰珝天科技有限公司 | Iron tailing microcrystalline glass and preparation method thereof |
| CN104058591A (en) * | 2014-07-09 | 2014-09-24 | 北京璞晶科技有限公司 | Method for producing foam microcrystal thermal insulating decoration board by use of fluorite tailings |
| CN107382075A (en) * | 2017-08-24 | 2017-11-24 | 陕西科技大学 | A kind of method for preparing wollastonite devitrified glass |
| RU2800174C1 (en) * | 2022-09-30 | 2023-07-19 | федеральное государственное бюджетное образовательное учреждение высшего образования (Белгородский государственный технологический университет им. В.Г. Шухова) | Charging for producing marblet based on man-made production waste |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101445325A (en) * | 2008-12-25 | 2009-06-03 | 广东博德精工建材有限公司 | Method for producing microcrystalline glass-ceramics composite board with novel microcrystalline phase |
| CN101851064A (en) * | 2010-06-23 | 2010-10-06 | 浮山县晋盛新型建筑材料有限责任公司 | Blue glass ceramics and preparation method thereof |
-
2013
- 2013-04-19 CN CN201310137329.8A patent/CN103232162B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101445325A (en) * | 2008-12-25 | 2009-06-03 | 广东博德精工建材有限公司 | Method for producing microcrystalline glass-ceramics composite board with novel microcrystalline phase |
| CN101851064A (en) * | 2010-06-23 | 2010-10-06 | 浮山县晋盛新型建筑材料有限责任公司 | Blue glass ceramics and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104016589A (en) * | 2014-06-27 | 2014-09-03 | 北京国泰珝天科技有限公司 | Iron tailing microcrystalline glass and preparation method thereof |
| CN104058591A (en) * | 2014-07-09 | 2014-09-24 | 北京璞晶科技有限公司 | Method for producing foam microcrystal thermal insulating decoration board by use of fluorite tailings |
| CN104058591B (en) * | 2014-07-09 | 2016-06-08 | 北京璞晶科技有限公司 | A kind of processing method utilizing fluorite mine tailing to produce foam crystallite heat insulating decorative board |
| CN107382075A (en) * | 2017-08-24 | 2017-11-24 | 陕西科技大学 | A kind of method for preparing wollastonite devitrified glass |
| CN107382075B (en) * | 2017-08-24 | 2020-10-20 | 陕西科技大学 | Method for preparing wollastonite microcrystalline glass |
| RU2800174C1 (en) * | 2022-09-30 | 2023-07-19 | федеральное государственное бюджетное образовательное учреждение высшего образования (Белгородский государственный технологический университет им. В.Г. Шухова) | Charging for producing marblet based on man-made production waste |
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