CN103231062A - Powder metallurgy planetary gear and preparation method thereof - Google Patents
Powder metallurgy planetary gear and preparation method thereof Download PDFInfo
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- CN103231062A CN103231062A CN2013101076179A CN201310107617A CN103231062A CN 103231062 A CN103231062 A CN 103231062A CN 2013101076179 A CN2013101076179 A CN 2013101076179A CN 201310107617 A CN201310107617 A CN 201310107617A CN 103231062 A CN103231062 A CN 103231062A
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- 238000004663 powder metallurgy Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 37
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000005245 sintering Methods 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 8
- 239000000956 alloy Substances 0.000 claims abstract description 8
- 239000012188 paraffin wax Substances 0.000 claims abstract description 8
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims abstract description 7
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 7
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 229910052582 BN Inorganic materials 0.000 claims abstract description 4
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 19
- 239000002956 ash Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 16
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 230000004048 modification Effects 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000005255 carburizing Methods 0.000 claims description 7
- 239000007822 coupling agent Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 6
- BDIZXIOWAPGQTJ-UHFFFAOYSA-N bis(2-ethylhexyl) phosphono phosphate Chemical compound CCCCC(CC)COP(=O)(OP(O)(O)=O)OCC(CC)CCCC BDIZXIOWAPGQTJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 claims description 6
- 235000012054 meals Nutrition 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 3
- 238000005256 carbonitriding Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000005496 tempering Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 abstract 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000010803 wood ash Substances 0.000 abstract 1
- 239000011812 mixed powder Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Powder Metallurgy (AREA)
Abstract
The invention provides a powder metallurgy planetary gear which is formed by compressing the following power stocks in part by weight: 100 parts of iron powder, 1.8 to 2.0 parts of copper powder, 0.5 to 0.8 part of titanium powder, 0.1 to 0.3 part of vanadium powder, 0.8 to 1.2 part of bismuth powder, 0.5 to 0.8 part of graphite powder, 0.1 to 0.3 part of modified wood ash, 0.2 to 0.6 part of rare earth ferrosilicon alloy, 0.1 to 0.3 part of paraffin, 0.1 to 0.2 part of ethylene bis stearamide, 0.1 to 0.3 part of molybdenum disulfide, 0.2 to 0.4 part of aluminium oxide, 0.2 to 0.4 part of boron nitride, and 0.4 to 0.5 part of LiF. When in preparation, mixing the powder stocks stepwise firstly, and obtaining the finished product planetary gear through compressing and manufacturing, sintering, heat treatment and surface treatment. The produced powder metallurgy planetary gear has the advantages that the planetary gear is good in abrasion resistance, high in strength and rigidity, good in machinability, is corrosion resistant and less susceptible to breakage, and has a long service life.
Description
Technical field
The present invention relates to field of powder metallurgy, be specifically related to a kind of powder metallurgy planetary gear and preparation method thereof.
Background technology
PM technique can reduce the cutting cost significantly with the parts of the shape production requirement high dimensional accuracy extremely close with article shape, complicated shape.Therefore, sintered metal product is as the parts of various machineries, device and utilize in many-side.
Generally speaking, alloy such as mixing graphite powder is with lubricant powders such as powder and stearic acid, paraffin and after forming the iron-based powder mixed powder in the iron-based powder, this iron-based powder mixed powder is filled into metal die, press molding and make powder metallurgical with iron-based powder formed body (press-powder body).Wherein, iron-based powder can be divided into iron powder (straight iron powder etc.), powdered alloy steel etc. according to composition.And iron-based powder also can be divided into atomized iron powder, reduced iron powder etc. according to manufacture method.The density of iron-based powder formed body is generally 6.6-7.1 mg/m3.Further implement sintering processes and form sintered body for these iron-based powder formed bodies, and implement finishing, machining as required and form sintered metal product.When needing to improve hot strength, fatigue strength, also implement carburizing heat treatment, brightness heat treatment behind the sintering.But existing powdered metal parts is because the proportion difference of various raw materials in the prescription, be difficult to guarantee during mixing to mix, cause the density unevenness of the green compact that are pressed into even, by heat treatment, the global density of the part of gained is inhomogeneous, causes every mechanical property bad.
Summary of the invention
The invention provides a kind of powder metallurgy planetary gear and preparation method thereof, with special raw material proportioning and the technology of science, produce the powder metallurgy planetary gear to have wearability good, intensity height, hardness height, machinability are good, corrosion-resistant, be not prone to fracture, the characteristics of long service life.
The technical solution used in the present invention is as follows:
A kind of powder metallurgy planetary gear, it is characterized in that, powder stock compacting by following weight portion forms: iron powder 100, copper powder 1.8-2.0, titanium valve 0.5-0.8, vanadium powder 0.1-0.3, bismuth meal 0.8-1.2, graphite powder 0.5-0.8, modification trees ashes 0.1-0.3, rare earth ferrosilicon alloy 0.2-0.6, paraffin 0.1-0.3, ethylene bis stearic acid amide 0.1-0.2, molybdenum bisuphide 0.1-0.3, alundum (Al 0.2-0.4, boron nitride 0.2-0.4, LiF 0.4-0.5, described rare earth ferrosilicon alloy the trade mark be FeSiRE23, granularity 5-20 mm.
The planetary preparation method of described powder metallurgy is characterized in that, may further comprise the steps:
(1) at first the base-material iron powder of 40-50% is packed in the high-speed mixer, to the silane resin acceptor kh-550 that wherein adds base-material iron powder quality 0.3-0.6%, high-speed stirred 5-6 minute, then with copper powder, titanium valve, vanadium powder, bismuth meal, graphite powder, modification trees ashes powder, paraffin, ethylene bis stearic acid amide and remaining iron powder add wherein successively, the heating of high-speed mixing limit, limit, when temperature is raised to 125-130 ℃, all the other components in will filling a prescription all add wherein, continue again to mix 8-10 minute, allow its cooling then, obtain the uniform iron base powder mixture of density end;
(2) pack in the mould in the iron base powder mixture end that step (1) is obtained, press forming under 550-580Mpa pressure;
(3) green compact of press forming are placed in the sintering furnace, in the protective atmosphere of hydrogen and nitrogen mixture body, it is 1000～1050 ℃ in temperature at first, sintering time is 10-20 minute, then with 10-20 ℃/minute speed rising temperature to 1150-1180 ℃, under this temperature, knot 10-15 minute reburns, room temperature is down in cooling then, is carrying out fine finishining;
(4) carry out Quenching Treatment after the heat treatment fine finishining again, hardening heat is 805～815 ℃, cool time 2-3 hour; Under 500-520 ℃, carry out high tempering then and handle, be incubated 1.5-2 hour; Carry out lonneal at 155～165 ℃ then, 2-3 hour;
(5) the 700 ℃ of carbo-nitridings 50 minutes in atmosphere controlled heat treatment furnace of gas carburizing nitrogen, the powder metallurgy planetary gear after the lonneal are cooled to 120 ℃, are incubated 5-8 hour, then cool to room temperature;
(6) the powder metallurgy planetary gear behind the steam treatment carburizing nitrogen nitrogen carries out steam treatment, and vapor (steam) temperature 600-700 ℃, processing time 3-4 hour, be incubated 2-3 hour down at 200-250 ℃ then, naturally cool to room temperature at last, get final product.
Described powder metallurgy planetary gear is characterized in that, the particle diameter of various metal dusts is in 200-400 order scope in the described raw material.
The planetary preparation method of described powder metallurgy, it is characterized in that, described modification trees ashes powder is prepared from by the following method: with the trees ashes earlier with 25% salt acid soak 30-40 minute, neutralize with alkali lye then, use the deionized water rinsing impurity elimination again, mix again and with small amount of ethanol dissolved dilution NDZ-311 titanate coupling agent, the consumption of NDZ-311 titanate coupling agent is the 1-2% of trees ashes weight, add in the high speed mixer with Sprayable, discharging behind the stirring 15-20min, oven dry grinds to form 300-400 order powder, obtains modification trees ashes powder.
Advantage of the present invention and beneficial effect:
1. powder metallurgy planetary gear of the present invention, adopt substep to mix, guaranteed the density uniformity of finished parts, improved planetary comprehensive mechanical performance, add man-hour, in the operation of mixed-powder material, at first wetting to the part iron powder with coupling agent, and then alloyed powder and lubricant added in the wetting iron powder in proportion mix, adding wherein through remaining iron powder at last, fully mix, the mixed-powder of gained is repressed, sintering, heat treatment, surface treatment obtains final product at last, the powder metallurgy processing technology of employing, significantly reduce manufacturing cost, improved stock utilization and productivity ratio.
2. powder metallurgy planetary gear of the present invention adds the metal dust of different proportion in composition of raw materials, make the planetary gear of preparing reach high strength, the performance of high rigidity and high abrasion; In prescription, add an amount of kollag, increased the self-lubricating property of product; Add an amount of vanadium powder, modification trees ashes powder, improved intensity and anti-wear performance and the self-lubricating property of product.
The specific embodiment
Below by embodiment, the present invention is described in further detail, but the present invention not only is confined to following examples.
Embodiment takes by weighing following raw material (kg) iron powder 100, copper powder 1.9, titanium valve 0.6, vanadium powder 0.2, bismuth meal 1.0, graphite powder 0.7, modification trees ashes 0.2, rare earth ferrosilicon alloy 0.5, paraffin 0.2, ethylene bis stearic acid amide 0.15, molybdenum bisuphide 0.2, alundum (Al 0.3, boron nitride 0.3, LiF 0.45, described rare earth ferrosilicon alloy the trade mark be FeSiRE23, granularity 5-20 mm
The preparation method may further comprise the steps:
(1) at first the base-material iron powder of 40-50% is packed in the high-speed mixer, to the silane resin acceptor kh-550 that wherein adds base-material iron powder quality 0.3-0.6%, high-speed stirred 5-6 minute, then with copper powder, titanium valve, vanadium powder, bismuth meal, graphite powder, modification trees ashes powder, paraffin, ethylene bis stearic acid amide and remaining iron powder add wherein successively, the heating of high-speed mixing limit, limit, when temperature is raised to 125-130 ℃, all the other components in will filling a prescription all add wherein, continue again to mix 8-10 minute, allow its cooling then, obtain the uniform iron base powder mixture of density end;
(2) pack in the mould in the iron base powder mixture end that step (1) is obtained, press forming under 550-580Mpa pressure;
(3) green compact of press forming are placed in the sintering furnace, in the protective atmosphere of hydrogen and nitrogen mixture body, it is 1000～1050 ℃ in temperature at first, sintering time is 10-20 minute, then with 5-8 ℃/minute speed rising temperature to 1150-1180 ℃, under this temperature, knot 10-15 minute reburns, room temperature is down in cooling then, is carrying out fine finishining;
(4) carry out Quenching Treatment after the heat treatment fine finishining again, hardening heat is 805～815 ℃, cool time 2-3 hour; Under 500-520 ℃, carry out high tempering then and handle, be incubated 1.5-2 hour; Carry out lonneal at 155～165 ℃ then, 2-3 hour;
(5) the 700 ℃ of carbo-nitridings 50 minutes in atmosphere controlled heat treatment furnace of gas carburizing nitrogen, the powder metallurgy planetary gear after the lonneal are cooled to 120 ℃, during insulation 5-8, and cool to room temperature then;
(6) the powder metallurgy planetary gear behind the steam treatment carburizing nitrogen nitrogen carries out steam treatment, and vapor (steam) temperature 600-700 ℃, processing time 3-4 hour, be incubated 2-3 hour down at 200-250 ℃ then, naturally cool to room temperature at last, get final product.
The particle diameter of various metal dusts is in 300-400 order scope in the raw material.
Modification trees ashes powder is prepared from by the following method: with the trees ashes earlier with 25% salt acid soak 30-40 minute, neutralize with alkali lye then, use the deionized water rinsing impurity elimination again, mix again and with small amount of ethanol dissolved dilution NDZ-311 titanate coupling agent, the consumption of NDZ-311 titanate coupling agent is the 1-2% of trees ashes weight, adds in the high speed mixer discharging behind the stirring 15-20min with Sprayable, oven dry grinds to form the 300-350 powder, obtains modification trees ashes powder.
The Performance Detection of the powder metallurgical gear that present embodiment makes is as follows:
Tensile strength sigma b (MPa): 785
Yield strength σ s (MPa): 568
Percentage elongation δ 5 (%): 17.1
Contraction percentage of area ψ (%): 36.
Claims (4)
1. powder metallurgy planetary gear, it is characterized in that, powder stock compacting by following weight portion forms: iron powder 100, copper powder 1.8-2.0, titanium valve 0.5-0.8, vanadium powder 0.1-0.3, bismuth meal 0.8-1.2, graphite powder 0.5-0.8, modification trees ashes 0.1-0.3, rare earth ferrosilicon alloy 0.2-0.6, paraffin 0.1-0.3, ethylene bis stearic acid amide 0.1-0.2, molybdenum bisuphide 0.1-0.3, alundum (Al 0.2-0.4, boron nitride 0.2-0.4, LiF 0.4-0.5, described rare earth ferrosilicon alloy the trade mark be FeSiRE23, granularity 5-20 mm.
2. the planetary preparation method of powder metallurgy as claimed in claim 1 is characterized in that, may further comprise the steps:
(1) at first the base-material iron powder of 40-50% is packed in the high-speed mixer, to the silane resin acceptor kh-550 that wherein adds base-material iron powder quality 0.3-0.6%, high-speed stirred 5-6 minute, then with copper powder, titanium valve, vanadium powder, bismuth meal, graphite powder, modification trees ashes powder, paraffin, ethylene bis stearic acid amide and remaining iron powder add wherein successively, the heating of high-speed mixing limit, limit, when temperature is raised to 125-130 ℃, all the other components in will filling a prescription all add wherein, continue again to mix 8-10 minute, allow its cooling then, obtain the uniform iron base powder mixture of density end;
(2) pack in the mould in the iron base powder mixture end that step (1) is obtained, press forming under 550-580Mpa pressure;
(3) green compact of press forming are placed in the sintering furnace, in the protective atmosphere of hydrogen and nitrogen mixture body, it is 1000～1050 ℃ in temperature at first, sintering time is 10-20 minute, then with 10-20 ℃/minute speed rising temperature to 1150-1180 ℃, under this temperature, knot 10-15 minute reburns, room temperature is down in cooling then, is carrying out fine finishining;
(4) carry out Quenching Treatment after the heat treatment fine finishining again, hardening heat is 805～815 ℃, cool time 2-3 hour; Under 500-520 ℃, carry out high tempering then and handle, be incubated 1.5-2 hour; Carry out lonneal at 155～165 ℃ then, 2-3 hour;
(5) the 700 ℃ of carbo-nitridings 50 minutes in atmosphere controlled heat treatment furnace of gas carburizing nitrogen, the powder metallurgy planetary gear after the lonneal are cooled to 120 ℃, during insulation 5-8, and cool to room temperature then;
(6) the powder metallurgy planetary gear behind the steam treatment carburizing nitrogen nitrogen carries out steam treatment, and vapor (steam) temperature 600-700 ℃, processing time 3-4 hour, be incubated 2-3 hour down at 200-250 ℃ then, naturally cool to room temperature at last, get final product.
3. powder metallurgy planetary gear according to claim 1 is characterized in that, the particle diameter of various metal dusts is in 200-400 order scope in the described raw material.
4. the planetary preparation method of powder metallurgy according to claim 2, it is characterized in that, described modification trees ashes powder is prepared from by the following method: with the trees ashes earlier with 25% salt acid soak 30-40 minute, neutralize with alkali lye then, use the deionized water rinsing impurity elimination again, mix again and with small amount of ethanol dissolved dilution NDZ-311 titanate coupling agent, the consumption of NDZ-311 titanate coupling agent is the 1-2% of trees ashes weight, add in the high speed mixer with Sprayable, discharging behind the stirring 15-20min, oven dry grinds to form 300-400 order powder, obtains modification trees ashes powder.
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| CN103422005A (en) * | 2013-08-19 | 2013-12-04 | 四川大学 | Method for preparing iron-based friction material by carbothermic in-situ reaction sintering of vanadium-titanium magnetite |
| CN103537663A (en) * | 2013-10-11 | 2014-01-29 | 芜湖市鸿坤汽车零部件有限公司 | Powder metallurgy gear disk and manufacturing method thereof |
| CN104588642A (en) * | 2014-12-25 | 2015-05-06 | 铜陵市经纬流体科技有限公司 | High-and-low-temperature-resistant valve ferrum-based powder metallurgy material and preparing method of high-and-low-temperature-resistant valve ferrum-based powder metallurgy material |
| CN106319364A (en) * | 2016-06-29 | 2017-01-11 | 浙江鑫和粉末冶金制品有限公司 | Car model differential gear and powder metallurgy process |
| CN109972046A (en) * | 2019-04-06 | 2019-07-05 | 苏州中鼎冶金有限公司 | A kind of processing technology of powder metallurgy planetary gear |
| CN113005278A (en) * | 2021-03-25 | 2021-06-22 | 德阳应和机械制造有限责任公司 | Finish machining treatment process for water pump impeller |
| CN115823212A (en) * | 2022-09-14 | 2023-03-21 | 广东极亚精机科技有限公司 | Powder metallurgy planetary gear and preparation method and application thereof |
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| CN102982946A (en) * | 2012-11-23 | 2013-03-20 | 天长市昭田磁电科技有限公司 | La2O3-containing ferromagnetic core manufacturing method |
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Address after: The new town 241000 Anhui city of Wuhu province Fanchang County of Curry Village Patentee after: Anhui Hengyu powder metallurgical Polytron Technologies Inc. Address before: The new town 241202 Anhui city of Wuhu province Fanchang County of Curry Village Patentee before: ANHUI HENGYU POWDER METALLURGY Co.,Ltd. |
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Correction item: Patentee|Address Correct: ANHUI HENGJUN POWDER METALLURGY TECHNOLOGY Co.,Ltd.|241000 Keli village, Xingang Town, Fanchang County, Wuhu City, Anhui Province False: Anhui Hengyu powder metallurgical Polytron Technologies Inc.|241000 Keli village, Xingang Town, Fanchang County, Wuhu City, Anhui Province Number: 49-02 Volume: 33 |
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