CN103224790A - Material for conversion of ultraviolet light and emission of near-infrared light and its preparation method and use - Google Patents
Material for conversion of ultraviolet light and emission of near-infrared light and its preparation method and use Download PDFInfo
- Publication number
- CN103224790A CN103224790A CN2013100247300A CN201310024730A CN103224790A CN 103224790 A CN103224790 A CN 103224790A CN 2013100247300 A CN2013100247300 A CN 2013100247300A CN 201310024730 A CN201310024730 A CN 201310024730A CN 103224790 A CN103224790 A CN 103224790A
- Authority
- CN
- China
- Prior art keywords
- ion
- compound
- contain
- arbitrary combination
- near infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 238000006243 chemical reaction Methods 0.000 title abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 17
- 230000005284 excitation Effects 0.000 claims abstract description 4
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 3
- -1 rare earth erbium ion Chemical group 0.000 claims description 68
- 150000001875 compounds Chemical class 0.000 claims description 48
- 238000001354 calcination Methods 0.000 claims description 32
- 150000002500 ions Chemical class 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 23
- 238000005303 weighing Methods 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 238000000227 grinding Methods 0.000 claims description 18
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 13
- 229940010552 ammonium molybdate Drugs 0.000 claims description 13
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 13
- 239000011609 ammonium molybdate Substances 0.000 claims description 13
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 claims description 13
- 229910003454 ytterbium oxide Inorganic materials 0.000 claims description 13
- 229940075624 ytterbium oxide Drugs 0.000 claims description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 12
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- 239000011733 molybdenum Substances 0.000 claims description 7
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 6
- 229910052691 Erbium Inorganic materials 0.000 claims description 6
- 229910052693 Europium Inorganic materials 0.000 claims description 6
- 229910052689 Holmium Inorganic materials 0.000 claims description 6
- 229910052765 Lutetium Inorganic materials 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052772 Samarium Inorganic materials 0.000 claims description 6
- 229910052771 Terbium Inorganic materials 0.000 claims description 6
- 229910052775 Thulium Inorganic materials 0.000 claims description 6
- 229910001422 barium ion Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910001424 calcium ion Inorganic materials 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 6
- RJOJUSXNYCILHH-UHFFFAOYSA-N gadolinium(3+) Chemical compound [Gd+3] RJOJUSXNYCILHH-UHFFFAOYSA-N 0.000 claims description 6
- CZMAIROVPAYCMU-UHFFFAOYSA-N lanthanum(3+) Chemical compound [La+3] CZMAIROVPAYCMU-UHFFFAOYSA-N 0.000 claims description 6
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 6
- WCWKKSOQLQEJTE-UHFFFAOYSA-N praseodymium(3+) Chemical compound [Pr+3] WCWKKSOQLQEJTE-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910001427 strontium ion Inorganic materials 0.000 claims description 6
- PWYYWQHXAPXYMF-UHFFFAOYSA-N strontium(2+) Chemical compound [Sr+2] PWYYWQHXAPXYMF-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 239000008139 complexing agent Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 3
- 238000003836 solid-state method Methods 0.000 claims description 3
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 3
- KUBYTSCYMRPPAG-UHFFFAOYSA-N ytterbium(3+);trinitrate Chemical compound [Yb+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O KUBYTSCYMRPPAG-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052710 silicon Inorganic materials 0.000 abstract description 8
- 239000010703 silicon Substances 0.000 abstract description 8
- 229910015667 MoO4 Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000010532 solid phase synthesis reaction Methods 0.000 abstract 1
- 238000005245 sintering Methods 0.000 description 26
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 20
- 239000002994 raw material Substances 0.000 description 12
- 238000001228 spectrum Methods 0.000 description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 10
- 238000000634 powder X-ray diffraction Methods 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 8
- 238000000695 excitation spectrum Methods 0.000 description 8
- 239000004570 mortar (masonry) Substances 0.000 description 6
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 244000191761 Sida cordifolia Species 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229910003440 dysprosium oxide Inorganic materials 0.000 description 2
- NLQFUUYNQFMIJW-UHFFFAOYSA-N dysprosium(iii) oxide Chemical compound O=[Dy]O[Dy]=O NLQFUUYNQFMIJW-UHFFFAOYSA-N 0.000 description 2
- ZXGIFJXRQHZCGJ-UHFFFAOYSA-N erbium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Er+3].[Er+3] ZXGIFJXRQHZCGJ-UHFFFAOYSA-N 0.000 description 2
- 238000002189 fluorescence spectrum Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
Landscapes
- Luminescent Compositions (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310024730.0A CN103224790B (en) | 2013-01-23 | 2013-01-23 | Material for conversion of ultraviolet light and emission of near-infrared light and its preparation method and use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310024730.0A CN103224790B (en) | 2013-01-23 | 2013-01-23 | Material for conversion of ultraviolet light and emission of near-infrared light and its preparation method and use |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103224790A true CN103224790A (en) | 2013-07-31 |
CN103224790B CN103224790B (en) | 2015-05-06 |
Family
ID=48835439
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310024730.0A Expired - Fee Related CN103224790B (en) | 2013-01-23 | 2013-01-23 | Material for conversion of ultraviolet light and emission of near-infrared light and its preparation method and use |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103224790B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103834400A (en) * | 2014-03-13 | 2014-06-04 | 重庆理工大学 | Calcium tungstate fluorescent powder and preparation method thereof |
CN104673308A (en) * | 2015-02-02 | 2015-06-03 | 江苏师范大学 | Material for realizing near-infrared luminescence under ultraviolet excitation and preparation method thereof |
CN109652011A (en) * | 2019-01-21 | 2019-04-19 | 广东工业大学 | Ultraviolet-near infrared absorption material of one kind and the preparation method and application thereof |
-
2013
- 2013-01-23 CN CN201310024730.0A patent/CN103224790B/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
HAIYAN DU ET.AL.: "《Synthesis and upconversion luminescence properties of Yb3+/Er3+ codoped BaGd2(MoO4)4 powder》", 《MATERIALS RESEARCH BULLETIN》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103834400A (en) * | 2014-03-13 | 2014-06-04 | 重庆理工大学 | Calcium tungstate fluorescent powder and preparation method thereof |
CN103834400B (en) * | 2014-03-13 | 2015-06-17 | 重庆理工大学 | Calcium tungstate fluorescent powder and preparation method thereof |
CN104673308A (en) * | 2015-02-02 | 2015-06-03 | 江苏师范大学 | Material for realizing near-infrared luminescence under ultraviolet excitation and preparation method thereof |
CN104673308B (en) * | 2015-02-02 | 2017-02-22 | 江苏师范大学 | Material for realizing near-infrared luminescence under ultraviolet excitation and preparation method thereof |
CN109652011A (en) * | 2019-01-21 | 2019-04-19 | 广东工业大学 | Ultraviolet-near infrared absorption material of one kind and the preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN103224790B (en) | 2015-05-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103421511B (en) | Bismuth oxyhalide light-emitting material with doped rare earth ions and preparation method thereof | |
CN103113892B (en) | A kind of tungstate rare earth light conversion material, preparation method and application | |
CN103215038B (en) | A kind ofly under ultraviolet excitation, realize near-infrared luminous molybdate material, preparation method and application | |
CN102942929B (en) | Ytterbium ion Yb<3+> activated borotungstate upconversion luminescent material and preparation method thereof | |
Rambabu et al. | Synthesis and luminescence properties of broad band greenish-yellow emitting LnVO4: Bi3+ and (Ln1, Ln2) VO4: Bi3+ (Ln= La, Gd and Y) as down conversion phosphors | |
CN101456570B (en) | Method for preparing cerium doped yttrium aluminum garnet | |
CN102585828B (en) | Yb3+-doped vanadate up-conversion fluorescent material and preparation method thereof | |
CN101148357A (en) | Method for preparing Yb3+ mixed lanthanum yttrium oxide upconversion luminous transparent laser ceramic | |
CN101974328B (en) | Molybdate and tungstate rare-earth optical conversion material and preparation method thereof | |
Li et al. | Energy transfer in Tb3+, Yb3+ codoped Lu2O3 near-infrared downconversion nanophosphors | |
CN103275716B (en) | Erbium-ytterbium co-doped tungstate upconversion luminescent material, preparation method and application of material | |
CN103194232A (en) | Wideband ultraviolet-visible light exited near infrared fluorescent emitting material and preparation method and application thereof | |
CN103224790B (en) | Material for conversion of ultraviolet light and emission of near-infrared light and its preparation method and use | |
CN104673314A (en) | Vanadate-based down-conversion luminescent material and preparation method thereof | |
CN104789220B (en) | Material capable of realizing ultraviolet light conversion and near infrared light emission and preparation method and application thereof | |
CN103756679A (en) | Upconversion material capable of being excited by wide-spectrum incoherent light as well as preparation method of upconversion material | |
CN101962545B (en) | Alkaline earth molybdate rare earth light conversion material and preparation method thereof | |
CN104004519B (en) | A kind of near infrared down-conversion luminescent material, preparation method and application thereof | |
CN107312539B (en) | Yb (Yb)3+Ion-activated near-infrared luminescent vanadium silicate material and preparation method and application thereof | |
CN101864303A (en) | Alkali metal alkaline earth metal phosphate phosphor and preparation method thereof | |
CN111484848B (en) | Near-infrared luminescent material and preparation method thereof | |
CN104673308B (en) | Material for realizing near-infrared luminescence under ultraviolet excitation and preparation method thereof | |
CN103421508B (en) | Fluorescent powder for solar cell and preparation method thereof | |
CN104031646A (en) | Down-conversion fluorescent material for solar cell and preparation method thereof | |
CN103849388A (en) | High-efficiency ytterbium-doped molybdenum/tungstate light conversion material, and preparation method and applications thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160601 Address after: 200135 room D02, building, No. 2000, Pudong Avenue, Pudong New Area Free Trade Zone, Shanghai Patentee after: ABESS NANOTECHNOLOGY (SHANGHAI) Co.,Ltd. Address before: 215123 Suzhou City, Suzhou Province Industrial Park, No. love road, No. 199 Patentee before: Soochow University |
|
CP03 | Change of name, title or address |
Address after: 200135 Shanghai, Pudong New Area, China (Shanghai) free trade zone, Pudong Avenue, No. 2000, building D02 room, room 23 Patentee after: ABS INTERNATIONAL Inc. Address before: 200135 room D02, building, No. 2000, Pudong Avenue, Pudong New Area Free Trade Zone, Shanghai Patentee before: ABESS NANOTECHNOLOGY (SHANGHAI) Co.,Ltd. |
|
CP03 | Change of name, title or address | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170317 Address after: 215138 Suzhou, Xiangcheng District Yangcheng Lake Town, Lake Road, painter, No. 13, No. Patentee after: SUZHOU HEXIANG TEXTILE CO.,LTD. Address before: 200135 Shanghai, Pudong New Area, China (Shanghai) free trade zone, Pudong Avenue, No. 2000, building D02 room, room 23 Patentee before: ABS INTERNATIONAL Inc. |
|
TR01 | Transfer of patent right | ||
CP01 | Change in the name or title of a patent holder |
Address after: 215138 Suzhou, Xiangcheng District Yangcheng Lake Town, Lake Road, painter, No. 13, No. Patentee after: SUZHOU HEXIANG TEXTILE TECHNOLOGY CO.,LTD. Address before: 215138 Suzhou, Xiangcheng District Yangcheng Lake Town, Lake Road, painter, No. 13, No. Patentee before: SUZHOU HEXIANG TEXTILE CO.,LTD. |
|
CP01 | Change in the name or title of a patent holder | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150506 |
|
CF01 | Termination of patent right due to non-payment of annual fee |