CN103223747A - Composite matrix based carrier modified asphalt self-adhesive waterproof coiled material - Google Patents
Composite matrix based carrier modified asphalt self-adhesive waterproof coiled material Download PDFInfo
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- CN103223747A CN103223747A CN2013101331187A CN201310133118A CN103223747A CN 103223747 A CN103223747 A CN 103223747A CN 2013101331187 A CN2013101331187 A CN 2013101331187A CN 201310133118 A CN201310133118 A CN 201310133118A CN 103223747 A CN103223747 A CN 103223747A
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Abstract
The invention discloses a composite matrix based carrier modified asphalt self-adhesive waterproof coiled material, which is composed of three parts. Specifically, the first part is an HDPE film carrier, the second part is a high polymer modified asphalt self-adhesive glue film coating, and the third part is a low-alkaline glass fiber mesh cloth embedded and fixed in a high polymer modified asphalt self-adhesive material. The three parts are sticked and compounded together by the high polymer modified asphalt self-adhesive glue film coating to form the waterproof coiled material. The composite matrix based carrier modified asphalt self-adhesive waterproof coiled material disclosed in the invention can be made into an efficient waterproof material on the basis of maximumly reducing natural resource consumption, thus providing safety guarantee for engineering waterproofing.
Description
Technical field
The present invention relates to a kind of compound tire base carrier modified pitch adhesive waterproof coil, belong to architectural waterproof material, civil construction project waterproof field
Background technology
Along with the scarcity day by day of natural resources, the material economy in civil construction project field comes into one's own day by day.As the waterproof roll that engineering waterproofing must be used, the engineering property, the reduction comsumption of natural resources that improve constantly product have its very important meaning.
Yet, the improvement of waterproof material itself is paid attention in traditionally research more in this area, CN1110301A for example, CN2358140Y, CN1105744C, CN2804216Y, CN2926229Y etc., although in the such scheme part disclosed " with EPDM; asphalt felt or haloflex are as coiled material layer; with the inorganic silicate insulation material as insulating; with the three-decker of fiberglass gridding cloth as enhancement layer ", but this kind structure exists some to be difficult to the problem that overcomes in essence: in long-term the use, the EPDM that top layer can be taken in the intermediate layer separates with glass fiber mesh, lose due waterproof thermal-insulated effect, and construction effort when this structure is laid, and the bottom that glass fibre is located at heat-insulation layer does not have the shear strain performance to the coiled material body, has used of a specified duration and will produce cracking.
Current, civil construction project percolating water is multiple disease, and percolating water not only has a strong impact on effective use of building function, can also cause multiple building disease, causes building the reduction in service life.A large amount of buildings is arranged in the modern times buildings because do not carry out that engineering waterproofing causes keeping in repair, the maintenance in the use is with high costs, has many buildings to have to remove in advance.
The country existing construction standards in order to ensure buildings waterproof safety, advocating new building adopts many to the technical measures of setting up defences, how to cause the consumption of a large amount of waterproof materials and the consumption of natural resources on the one hand, also bring heavy purchase cost burden on the other hand to the user to setting up defences.
Therefore, invention is efficient, practical, durable waterproof roll has far-reaching social effect and value safely.
Summary of the invention
Needs at prior art, the applicant is in conjunction with long-term practical experience, invented a kind of compound tire base carrier modified pitch adhesive waterproof coil, be applied to building field, especially build basement, roof water-proof engineering, not only have good thermal-insulating waterproof characteristic, and construction is simple, long service life.
For achieving the above object, the present invention is achieved through the following technical solutions:
A kind of compound tire base carrier modified pitch adhesive waterproof coil, form by three parts, first is the HDPE thin-film carrier, second portion is a modified pitch self-adhesion sizing material film coating, third part is the fiberglass gridding cloth that is mounted in the high-polymer modified pitch self-adhesion sizing material, described three parts are bonded togather by high-polymer modified pitch self-adhesion sizing material thin layer, form waterproof roll.
By said structure, the HDPE thin-film carrier makes that waterproof roll can acid and alkali-resistance, and organic solvent-resistant has good toughness, case hardness, hot strength, and mechanical strengths such as rigidity have effectively guaranteed service life of product; Prevented its cracking in the modified pitch self-adhesion sizing material and fiberglass gridding cloth is embedded in; High-polymer modified pitch self-adhesion sizing material film coating then has the excellent waterproof insulation effect.
In the present invention, used three layers thickness is not subjected to special qualification, and preferred, HDPE thin-film carrier thickness is 0.1-0.2mm, and modified pitch self-adhesion sizing material film coating thickness is 1.0-2.0mm, and the fiberglass gridding cloth specification is 30-120g/m2.
In the present invention, the HDPE of used HDPE film is a kind of industrial common polymeric material, and available molecular weight is between 40000-300000, and preferred molecular weight ranges is 150000-300000.
In the present invention, the chemical composition of the used high-polymer modified pitch self-adhesion sizing material of described high-polymer modified pitch self-adhesion sizing material film coating is:
In mentioned component, asphalt is a kind of product in the petroleum refining process, be liquid, semisolid or the solid of the thickness of black or pitchy at normal temperatures, mainly contain the hydro carbons and the non-hydrocarbons derivative that dissolve in trichloro-ethylene, although it forms more complicated, but the petroleum asphalt product of extensively selling all has identical or very close physical and chemical parameter in the market, all can be used for the present invention, preferably building stone oil asphalt series of products.
In mentioned component, naphthenic oil is the cut that extract from naphthene base crude, has the saturated cyclic carbon-chain structure, characteristics such as have low pour point, high density, high viscosity, have no side effect, and on its ring, also can connect saturated side chain usually.Because this structure, make naphthenic oil both have aromatic hydrocarbon sector of breakdown character, the part character that has straight-chain hydrocarbons again, again since naphthenic oil from natural oil, advantages such as cheap, from the horse's mouth are arranged, its physical and chemical parameter can be inquired about from common chemical industry dictionary, and this series products of selling on the market all can be used for the present invention.
In mentioned component, SBS, SBR are two kinds of common modified asphalt materials of chemical field, repeat no more herein.
In mentioned component, used polyisobutene is low-molecular-weight polyisobutylene (1000<molecular weight<3500), and main effect is the tack that improves product.
In mentioned component, used hydrogenation resin is the C5 hydrogenated petroleum resin.
In mentioned component, polyvinyl acetate is PVAc, and preferably its polymerization degree n is between 250-600.
In mentioned component, flexibilizer is this area common used material, includes but not limited to common ACM, chlorosulfonated polyethylene, ABS, polyvinyl butyral resin, polyvinyl acetate etc.
In mentioned component, ultra-violet absorber adopts this area product commonly used, phenyl salicytate, Ultraviolet Absorber UV-P, UV-O, UV-531, light stabilizer GW-540 etc.
In mentioned component, age resister claims crosslinking agent again, can open two strands after the adding, thereby forms network structure, makes structure tightr, is mainly sulphur or organic peroxide.
In mentioned component, antistripping agent has another name called development of anti stripping agent for asphalt, and common product such as TJ066, ASA9304, Carlow amine, AR-68 etc. all can be used for the present invention.
In mentioned component, filler is the chemical industry auxiliary material of using always, all can be used for the present invention as fillers such as PP, PE, RPP, PVC, CPVC, PVDF.
2. properties of product
In the present invention, described fiberglass gridding cloth is low alkali glass fiber grid cloth or alkali-free glass fiber grid cloth (alkaline metal oxide content is lower than 0.5%), be preferably low alkali glass fiber grid cloth, alkaline metal oxide content wherein is not higher than 3%, production cost is low, has good chemical stability and structural strength again.
In the present invention, the HDPE film can be incomplete for the covering of modified pitch self-adhesion sizing material film coating, that is to say that described HDPE film portion covers modified pitch self-adhesion sizing material film coating, and an end leaves unlapped exposure band.
In this case, more excellent coverage be described HDPE film one end to leave this size of 20-30mm(be to change, according to the construction needs) modified pitch self-adhesion sizing material film coating expose band, another side covers to the edge.
In the present invention, fiberglass gridding cloth is provided with in the full section scope of waterproof roll, the degree of depth of fiberglass gridding cloth build-in in modified pitch self-adhesion sizing material film coating comprises any building-in depth, that is to say that fiberglass gridding cloth can be positioned at any internal depth of modified pitch self-adhesion sizing material film coating.
The installation and application of waterproof roll of the present invention by pasting, adopt the bonding interface inorganic agent to paste certainly or adopting bonded adhesives to paste, is normally pasted at building surface.
Because when the industrial package of reality, wrap the silicone oil barrier film outside the meeting, therefore normally following several at industrial application process:
1, tear off the silicone oil barrier film, directly stick on coiled material on the xoncrete structure basal plane of handling through base treatment agent or on the structure basal plane of other material.
2, tear off the silicone oil barrier film, use complementary bonded adhesives directly to stick on coiled material on the xoncrete structure basal plane or the structure basal plane of other material on.
3, tear the silicone oil barrier paper off, the mode of employing lap belt self-adhesive is finished the splicing of waterproof roll.
Applicant's experiment confirm, waterproof roll of the present invention, by above-mentioned specific architecture advances, low consumption of resources, high waterproof performance.
Description of drawings
Fig. 1 is a waterproof roll structural representation of the present invention.
The specific embodiment
In order more to be expressly understood technical spirit of the present invention, the applicant elaborates to the specific embodiment of the present invention in conjunction with the accompanying drawings below.These explanations all are not the restrictions that constitutes the present invention program; therefore, anyone is as long as made under the present invention program's enlightenment sheerly pro forma and be not to change and remodeling all should be considered as technical scheme category disclosed in this invention and be considered as advocating the scope of rights protection for substantial equivalence.
Embodiment 1
Its concrete product structure of waterproof roll of the present invention can be gone into shown in the accompanying drawing 1, in accompanying drawing 1, the applicant provides a kind of concrete structure of typical waterproof roll of the present invention: wherein the HDPE(molecular weight 160000) film thickness is 0.15mm, modified pitch self-adhesion sizing material film coating thickness is 1.35mm, and the fiberglass gridding cloth specification is 60g/m
2The entire length of waterproof roll is 1000mm, and HDPE film one end covers modified pitch self-adhesion sizing material film coating fully, and the other end leaves 25mm and exposes band, fiberglass gridding cloth crosses whole modified pitch self-adhesion sizing material film coating, is positioned at the 1mm degree of depth under its top layer.
Barrier paper in the accompanying drawing (the upper surface both sides are respectively waxdip silicone oil barrier paper, and following laminar surface is silicone oil barrier film/paper) is the attachment component that is increased as required when the product integral construction is used, and does not limit protection scope of the present invention.
Fiberglass gridding cloth wherein is a low alkali glass fiber grid cloth, and sodium metal potassium oxide content wherein is not higher than 1.5%.
Wherein modified pitch self-adhesion sizing material film coating representative formula and preparation method are as follows:
Prescription: (polyisobutene molecular weight 1200, the polyvinyl acetate degree of polymerization 300, flexibilizer are that ACM, Ultraviolet Absorber UV-P, age resister are sulphur, antistripping agent AR68, filler PP)
Preparation technology:
1. add matrix pitch and naphthenic oil, be warming up to 180 ℃;
2. add formula ratio SBS, SBR, control temperature swelling l h in 180~185 ℃ of scopes starts colloid mill afterwards and grinds 2h, till the visible granule of no naked eyes;
3. add formula ratio polyisobutene, resin, polyvinyl acetate, control temperature swelling l h in 180~185 ℃ of scopes is till the visible granule of no naked eyes;
4. add flexibilizer, age resister, ultra-violet absorber, antistripping agent, more than the high-speed stirred 30min
5. add filler, stir more than the 45min;
7. squeeze into holding vessel and prepare to reach the standard grade production.
Embodiment 2
Product structure similar to Example 1, wherein the HDPE(molecular weight 280000) film thickness is 0.2mm, modified pitch self-adhesion sizing material film coating thickness is 1.95mm, the fiberglass gridding cloth specification is 110g/m2, the entire length of waterproof roll is 1000mm, and HDPE film one end covers modified pitch self-adhesion sizing material film coating fully, and the other end leaves 20mm and exposes band, fiberglass gridding cloth crosses whole modified pitch self-adhesion sizing material film coating, is positioned at the 0.6mm degree of depth under its top layer.
Fiberglass gridding cloth wherein is a low alkali glass fiber grid cloth, and sodium metal potassium oxide content wherein is not higher than 1.5%.
Modified pitch self-adhesion sizing material film coating representative formula wherein is as follows:
Prescription (polyisobutene molecular weight 2000, the polyvinyl acetate degree of polymerization 480, flexibilizer are that ABS, ultraviolet absorbent UV-531, age resister are cumyl peroxide, antistripping agent TJ066, filler PVC):
Shown in preparation method's reference example 1.
Embodiment 3
Product structure similar to Example 1, wherein the HDPE(molecular weight 200000) film thickness is 0.1mm, modified pitch self-adhesion sizing material film coating thickness is 1.04mm, the fiberglass gridding cloth specification is 40g/m2, the entire length of waterproof roll is 1000mm, and HDPE film one end covers modified pitch self-adhesion sizing material film coating fully, and the other end leaves 30mm and exposes band, fiberglass gridding cloth crosses whole modified pitch self-adhesion sizing material film coating, is positioned at the 1.4mm degree of depth under its top layer.
Fiberglass gridding cloth wherein is a low alkali glass fiber grid cloth, and sodium metal potassium oxide content wherein is not higher than 1.5%.
Modified pitch self-adhesion sizing material film coating representative formula wherein is as follows:
Prescription (polyisobutene molecular weight 3400, the polyvinyl acetate degree of polymerization 600, flexibilizer are that polyvinyl acetate, ultraviolet absorbent UV-531, age resister are cumyl peroxide, antistripping agent ASA9304, filler PE):
Shown in preparation method's reference example 1.
The applicant has tested the physicochemical property of waterproof roll of the present invention, the waterproof roll that shows the foregoing description 1-3 is in phenomenons such as the equal flawless of subzero 30 degree, crackings, its pulling force is not less than 500N/50mm, elongation at break is not less than 400%, be not less than 2.4N/mm with the peel strength of aluminium sheet, impermeability is not less than 50min in the following retention time of 0.3MPa.
The detection method that adopts is GB/T328.14-2007, GB/T328.9-2007, GB/T328.10-2007, GB/T328.20-2007, GB23441-2009, and the index of examining all meets and be higher than self-adhering polymer modification bitumen waterproof roll GB23441-2009 standard-required.
Claims (9)
1. compound tire base carrier modified pitch adhesive waterproof coil, form by three parts, it is characterized in that first is the HDPE thin-film carrier, second portion is a high-polymer modified pitch self-adhesion sizing material film coating, third part is the fiberglass gridding cloth that is mounted in the high-polymer modified pitch self-adhesion sizing material, described three parts are bonded togather by high-polymer modified pitch self-adhesion sizing material thin layer, form waterproof roll.
2. waterproof roll according to claim 1 is characterized in that described HDPE thin-film carrier thickness is 0.1-0.2mm, and modified pitch self-adhesion sizing material film coating thickness is 1.0-2.0mm, and the fiberglass gridding cloth specification is 30-120g/m2.
3. waterproof roll according to claim 1, the molecular weight ranges that it is characterized in that the HDPE that the HDPE film is used is 150000-300000.
5. waterproof roll according to claim 1 is characterized in that described fiberglass gridding cloth is low alkali glass fiber grid cloth or alkali-free glass fiber grid cloth.
6. waterproof roll according to claim 1 is characterized in that described HDPE film portion covers modified pitch self-adhesion sizing material film coating, and an end leaves unlapped exposure band.
7. waterproof roll according to claim 5 is characterized in that described HDPE film one end leaves the modified pitch self-adhesion sizing material film coating exposure band of 20-30mm, and another side covers to the edge.
8. waterproof roll according to claim 1 is characterized in that fiberglass gridding cloth is provided with in the full section scope of waterproof roll, the degree of depth of fiberglass gridding cloth build-in in modified pitch self-adhesion sizing material film coating comprises any building-in depth.
9. the installation and application of the described waterproof roll of above-mentioned arbitrary claim is characterized in that by pasting, adopt the bonding interface inorganic agent to paste certainly or adopting bonded adhesives to paste.
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Cited By (14)
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CN103526891A (en) * | 2013-09-05 | 2014-01-22 | 湖北永阳材料股份有限公司 | Special modified asphalt waterproof sheet material based on BIPV technique and manufacturing method thereof |
CN103540147A (en) * | 2013-10-23 | 2014-01-29 | 潍坊市晨鸣新型防水材料有限公司 | High-strength and anti-stripping elastomer modified asphalt waterproof coiled material and production process |
CN103696540A (en) * | 2013-12-30 | 2014-04-02 | 刘启东 | Planted roof root-resistance waterproof roll and production process thereof |
CN104085145A (en) * | 2014-07-08 | 2014-10-08 | 云南欣城防水科技有限公司 | Modified asphalt waterproofing coiled material with self-adhering layer and preparation method thereof |
CN104910639A (en) * | 2015-06-23 | 2015-09-16 | 深圳中佳和化工有限公司 | Asphalt rubber material for producing SBS elastomer modified asphalt waterproof roll material as well as preparation method and application thereof |
CN104927372A (en) * | 2015-06-23 | 2015-09-23 | 深圳中佳和化工有限公司 | Asphalt size used for producing APP plastic body modified asphalt waterproofing material and preparation method and application thereof |
CN105038592A (en) * | 2015-07-28 | 2015-11-11 | 蚌埠南自仪表有限公司 | Organic silicon asphalt waterproof roll material |
CN105346166A (en) * | 2015-11-17 | 2016-02-24 | 北京东方雨虹防水技术股份有限公司 | Self-adhesive polymer modified asphalt waterproof coiled material |
CN106280155A (en) * | 2016-08-08 | 2017-01-04 | 佛山市可达佳建材有限公司 | It is applied to water-soluble film, the preparation method of water-soluble film and waterproof roll that wet-laying overlays on waterproof roll |
CN106760243A (en) * | 2016-11-28 | 2017-05-31 | 北京东方雨虹防水技术股份有限公司 | One kind exposes modified asphalt waterproof coiled material |
CN109111872A (en) * | 2018-07-28 | 2019-01-01 | 安徽禹王防水建材有限公司 | A kind of no-wadding adhesive polymer modified asphalt waterproof roll |
CN110080473A (en) * | 2019-05-05 | 2019-08-02 | 宏源防水科技集团有限公司 | A kind of flat roof waterproof heat-insulation system and its construction method |
CN113427858A (en) * | 2020-03-23 | 2021-09-24 | 北京世纪洪雨科技有限公司 | Sound-insulation waterproof coiled material |
CN113462082A (en) * | 2020-09-09 | 2021-10-01 | 庞志清 | Composite functional master batch, preparation material for film preparation and application |
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CN105038592A (en) * | 2015-07-28 | 2015-11-11 | 蚌埠南自仪表有限公司 | Organic silicon asphalt waterproof roll material |
CN105346166A (en) * | 2015-11-17 | 2016-02-24 | 北京东方雨虹防水技术股份有限公司 | Self-adhesive polymer modified asphalt waterproof coiled material |
CN106280155A (en) * | 2016-08-08 | 2017-01-04 | 佛山市可达佳建材有限公司 | It is applied to water-soluble film, the preparation method of water-soluble film and waterproof roll that wet-laying overlays on waterproof roll |
CN106280155B (en) * | 2016-08-08 | 2018-10-26 | 佛山市可达佳建材有限公司 | The preparation method and waterproof roll of water-soluble film on waterproof roll, water-soluble film are overlay applied to wet-laying |
CN106760243A (en) * | 2016-11-28 | 2017-05-31 | 北京东方雨虹防水技术股份有限公司 | One kind exposes modified asphalt waterproof coiled material |
CN109111872A (en) * | 2018-07-28 | 2019-01-01 | 安徽禹王防水建材有限公司 | A kind of no-wadding adhesive polymer modified asphalt waterproof roll |
CN110080473A (en) * | 2019-05-05 | 2019-08-02 | 宏源防水科技集团有限公司 | A kind of flat roof waterproof heat-insulation system and its construction method |
CN113427858A (en) * | 2020-03-23 | 2021-09-24 | 北京世纪洪雨科技有限公司 | Sound-insulation waterproof coiled material |
CN113427858B (en) * | 2020-03-23 | 2023-09-15 | 北京世纪洪雨科技有限公司 | Sound insulation waterproof coiled material |
CN113462082A (en) * | 2020-09-09 | 2021-10-01 | 庞志清 | Composite functional master batch, preparation material for film preparation and application |
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