CN103214993A - Acrylic ester electrostatic flocking binding agent and preparation method thereof - Google Patents
Acrylic ester electrostatic flocking binding agent and preparation method thereof Download PDFInfo
- Publication number
- CN103214993A CN103214993A CN2013101606052A CN201310160605A CN103214993A CN 103214993 A CN103214993 A CN 103214993A CN 2013101606052 A CN2013101606052 A CN 2013101606052A CN 201310160605 A CN201310160605 A CN 201310160605A CN 103214993 A CN103214993 A CN 103214993A
- Authority
- CN
- China
- Prior art keywords
- gram
- grams
- deionized water
- emulsion
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to an acrylic ester electrostatic flocking binding agent and a preparation method thereof. The acrylic ester electrostatic flocking binding agent is a polymer emulsion which is prepared from the raw materials: polyoxyethylene dodecyl alcohol (50), sodium dodecyl sulfate, itaconic acid, N-hydroxymethyl acrylamide, acyclic acid, butyl acrylate, 2-ethylhexyl acrylate, styrene, gamma-methacryloxy propyl trimethoxyl silan, epoxy resin E-44, adipic acid dihydrazide, sodium acetate, ammonium persulfate and deionized water through seeded emulsion polymerization. The acrylic ester electrostatic flocking binding agent is an epoxy resin and organic silicon resin jointly-modified acrylic ester electrostatic flocking binding agent. The product has the advantages of flexibility, cold endurance, weather resistance and thermosetting stability and particularly has prominent water resistance and adhesive force.
Description
Technical field
That the present invention relates to is a kind of flocking adhesive and preparation method, and it is the acrylic ester polymerization emulsion of a kind of Resins, epoxy and the common modification of silicone resin, is specially adapted to the demand of electrostatic flocking for high fastness.
Background technology
The static flocking product has been widely used in industries such as weaving, automotive trim, toy because it is wear-resisting, sealing, sound insulation, utility function such as heat insulation, anti-scald, antifouling.Flocking adhesive is one of critical material that influences the static flocking quality product.Flocking adhesive can be divided into emulsion-type and solvent-borne type two classes usually.The solvent-borne type advantage is that solidification value is lower, but has shortcoming such as seriously polluted, easy presence of fire of when oven dry.Emulsion Adhesive is to use maximum class tackiness agents because it is easy to operate, nontoxic, pollution-free.
In Emulsion Adhesive, polyacrylate(s) is because of its preparation and safe in utilization nontoxic, has good film-forming properties, snappiness, ageing-resistant, weathering resistance and remarkable mechanical property, and the acquisition widespread use.Ventilation property is poor, the sticking power deficiency but it exists, and is not water-fast, the hardening that becomes fragile of low temperature feel, high temperature feel problem such as be clamminess.For the use function that improves the emulsion acrylate flocking adhesive is carried out modification to it.
The CN94104553.6 patent disclosure a kind of name be called " electrostatic flocking adhesives solidifying under normal temperature ", it is disclosed to be a kind of preparation method who contains the interpenetrating(polymer)networks copolymer emulsion of esters of acrylic acid, epoxy resin, vinylformic acid or vinylformic acid and amides.It adopts Resins, epoxy that acrylate is carried out modification, selects for use self-vulcanizing agent and Resins, epoxy to solidify under normal temperature condition.This invention needing to be suitable for the product of ambient cure, and set time is longer, is 48 hours, is unfavorable for the big production of continuity.
Other is introduced the relevant technical literature data of flocking adhesive and also just introduces the modification to acrylate of single Resins, epoxy or silicone resin.Often can not satisfy electrostatic flocking simultaneously, winter hardiness, high fastness, the demand of aspects such as water tolerance through the acrylate flocking adhesive after the modification in flexibility.
Summary of the invention
The purpose of this invention is to provide a kind of softness, cold-resistant (being test data) to implanted article limit embrittlement temperature, strong adhesion, water tolerance is excellent, thermosetting stability is excellent, a kind of Resins, epoxy of good weatherability and acrylate flocking adhesive of the common modification of silicone resin and preparation method thereof.
Acrylate flocking adhesive of the present invention:
The raw material weight ratio is: dodecyl alcohol polyoxyethylene (50) ether 1.2-1.5, sodium lauryl sulphate 1.2-1.5, methylene-succinic acid 0.5-1, N hydroxymethyl acrylamide 2.5-3.0, vinylformic acid 2-2.5, butyl acrylate 75-85, Isooctyl acrylate monomer 21-26, vinylbenzene 10-12, γ-methacryloxypropyl trimethoxy silane (KH-570) 2.39-2.84, epoxy resin E-44 5-7, adipic acid dihydrazide 3.92-5.49, sodium-acetate 0.07-0.08, ammonium persulphate 0.4-0.5, deionized water 145-170, the polymer emulsion that after letex polymerization, forms;
Technical indicator:
Outward appearance: white emulsion
Ionic: the moon
PH value: 7-8
Solid content: 45 ± 1%.
Acrylate flocking adhesive preparation method of the present invention:
The raw material weight proportioning:
Dodecyl alcohol polyoxyethylene (50) ether 1.2-1.5 gram, sodium lauryl sulphate 1.2-1.5 gram, methylene-succinic acid 0.5-1 gram, N hydroxymethyl acrylamide 2.5-3.0 gram, vinylformic acid 2-2.5 gram, butyl acrylate 75-85 gram, Isooctyl acrylate monomer 21-26 gram, vinylbenzene 10-12 gram, γ-methacryloxypropyl trimethoxy silane 2.39-2.84 gram, epoxy resin E-44 5-7 gram, adipic acid dihydrazide 3.92-5.49 gram, sodium-acetate 0.07-0.08 gram, ammonium persulphate 0.4-0.5 gram, deionized water 145-170 gram.
The preparation method:
1) be that dodecyl alcohol polyoxyethylene (50) ether 1.2-1.5 gram, sodium lauryl sulphate 1.2-1.5 gram join pre-newborn still with deionized water 50-75 gram with whole emulsifying agent, fully dissolving, adding monomer then is methylene-succinic acid 0.5-1 gram, N hydroxymethyl acrylamide 2.5-3.0 gram, vinylformic acid 2-2.5 gram, butyl acrylate 75-85 gram, Isooctyl acrylate monomer 21-26 gram, vinylbenzene 10-12 gram, epoxy resin E-44 5-7 gram, fully stirring and emulsifying forms pre-emulsion;
2) get the pre-emulsion of weight 1% and γ-methacryloxypropyl trimethoxy silane 2.39-2.84 gram and mix, standby;
3) ammonium persulphate 0.4-0.5 gram is mixed and made into ammonium persulfate aqueous solution with deionized water 10 grams, and is standby;
4) sodium-acetate 0.07-0.08 gram is mixed and made into sodium acetate aqueous solution with deionized water 2 grams, and is standby;
5) adipic acid dihydrazide 3.92-5.49 gram is mixed and made into the adipic acid dihydrazide aqueous solution with deionized water 15 grams, and is standby;
6) pre-emulsion with 68 gram deionized waters and weight 5% joins in the reactor, be warmed up to 70-75 ℃, add whole sodium acetate aqueous solutions and 2 gram ammonium persulfate aqueous solutions, reacted 20-30 minute, begin to drip ammonium persulfate aqueous solution 6.5 gram and remaining pre-emulsions then, dropwised at 2.5-3 hour; Drip step 2 then) mixed solution and remaining ammonium persulfate aqueous solution, dropwised at 0.5-1 hour, temperature of reaction is controlled at 78-82 ℃;
7) be warmed up to 85-90 ℃, slaking 1-1.5 hour, cool to 30-40 ℃ then, with mass percent concentration is that 25% ammoniacal liquor adjust pH equals 7-7.5, adds the adipic acid dihydrazide aqueous solution, stirs, transfer solid content to equal 45 ± 1% with deionized water, get product.
Adjust the used deionized water of emulsion solid content in the aforesaid method and be not among the amount of deionized water of proportioning raw materials.
Solid content is meant under 105 ± 1 ℃ of conditions, dries the percentage ratio that remainder after 2 hours accounts for total amount.
The present invention adopts seed emulsion polymerization, uses soft monomer butyl acrylate, Isooctyl acrylate monomer can increase flexibility, winter hardiness and the sticking power of raising fine hair on base cloth of implanted article.Use hard monomer vinylbenzene and can strengthen polymkeric substance force of cohesion, thereby improve the wear resistance of implanted article.N-methylol and carboxylic group can further improve polymkeric substance to the sticking power of fabric with to the bonding fastness of fine hair on base cloth after crosslinked, improve elasticity behind the polymer film forming simultaneously.
Acrylate flocking adhesive of the present invention, its used organosilicon is γ-methacryloxypropyl trimethoxy silane, the Si-O key (bond energy is up to 450KJ/mol) that contains high bond energy in the organosilicon main chain, so have performances such as excellent high temperature resistant, chemicals-resistant, ultraviolet resistance, surface of silicone resin can be lower simultaneously, therefore has good water tolerance and anti-stain characteristic.Unmodified acrylic acid emulsion polymer is a linear polymeric, has the polar group of acrylate on the main chain, and is responsive to water; And with organic-silicon-modified emulsion polymer, on the high molecular segment of linearity, introduced siloxane groups, the surface tension that contains the acrylate copolymer of siloxanes is lower than the surface tension of not siliceous acrylate copolymer, cause being separated of interlaminar resin, for the surface energy that reaches system minimum, the component of low surface energy will be gradually to external migration, and the component of high surface energy is inwardly migration gradually, and the polymkeric substance that contains siloxanes is so just moved to coatingsurface.Siloxanes forms the Si-O-Si key through hydrolysis-condensation reaction again, can strengthen the density on the top layer of filming, and improves the water tolerance of filming.The present invention adopts organosilane monomer to postpone the technology that drips, effectively prevented transition hydrolysis and the condensation reaction of γ-methacryloxypropyl trimethoxy silane in emulsion polymerization process, improved the content of organosilicon chain link in the polymer macromolecule chain, thereby made resulting polymers have the advantage of silicone resin and acroleic acid resin concurrently.
High fastness flocking adhesive of the present invention, its used Resins, epoxy can be cycloaliphatic epoxy resin, aromatic epoxy resin, aliphatic epoxy resin; Usually adopt bisphenol A type epoxy resin, as E-51, E-44, E-33, E-31 etc.Because Resins, epoxy is along with the reduction of molecular weight, molecular chain shortens, and oxirane value raises, and viscosity reduces.Molecular chain is more little, and solidifying product hardness is high more, and snappiness is low more, so the present invention selects epoxy resin E-44 for use.In polymerization process, epoxy group(ing) is opened oxirane ring, receives on the main polymer chain, thereby has given the characteristics of polymer ring epoxy resins.Epoxy group(ing), hydroxyl are given resin reaction in the bisphenol A type epoxy resin, make polymkeric substance have very strong force of cohesion and bonding force.Ehter bond and hydroxyl are polar groups, help to improve wetting property and adhesive power.Phenyl ring is given polymkeric substance with thermotolerance and rigidity, the bond energy height of-O-C-key, thus improved alkali resistance.Because these constructional features of bisphenol A type epoxy resin have determined that reaction post polymerization thing has the force of cohesion height, bonding force is strong, solvent resistance good, and the characteristics that can be used with multiple solidifying agent.When selecting solidifying agent for use, can select the ambient cure agent for use, but exist the emulsion shelf-time of preparation short, set time is long, is unfavorable for the shortcoming of producing.The present invention selects the latent curing agent adipic acid dihydrazide for use, but only otherwise the heating long-term storage helps production application.
Embodiment
Embodiment 1
Proportioning raw materials:
Dodecyl alcohol polyoxyethylene (50) ether 1.2 grams, sodium lauryl sulphate 1.2 grams, methylene-succinic acid 0.5 gram, N hydroxymethyl acrylamide 2.5 grams, vinylformic acid 2 grams, butyl acrylate 75 grams, Isooctyl acrylate monomer 21 grams, vinylbenzene 10 grams, γ-methacryloxypropyl trimethoxy silane 2.39 grams, epoxy resin E-44 5 grams, adipic acid dihydrazide 3.92 grams, sodium-acetate 0.07 gram, ammonium persulphate 0.4 gram, deionized water 145 grams;
The preparation method:
1) removing ionized water 50 gram is that dodecyl alcohol polyoxyethylene (50) ether, sodium lauryl sulphate join pre-newborn still with whole emulsifying agent, fully dissolve, adding monomer then is methylene-succinic acid, N hydroxymethyl acrylamide, vinylformic acid, butyl acrylate, Isooctyl acrylate monomer, vinylbenzene and Resins, epoxy, fully stirring and emulsifying forms pre-emulsion;
2) pre-emulsion and the γ-methacryloxypropyl trimethoxy silane of getting weight 1% mixes, and be standby;
3) ammonium persulphate 0.4 gram is mixed and made into ammonium persulfate aqueous solution with deionization 10 grams, and is standby;
4) sodium-acetate 0.07 gram is mixed and made into sodium acetate aqueous solution with deionized water 2 grams, and is standby;
5) adipic acid dihydrazide 3.92 is mixed and made into the adipic acid dihydrazide aqueous solution with deionized water 15 grams, and is standby;
6) getting 68 pre-emulsions that restrain deionized waters and weight 5% joins in the reactor, be warmed up to 70-75 ℃, add whole sodium acetate aqueous solutions and 2 gram ammonium persulfate aqueous solutions, reacted 20-30 minute, begin to drip ammonium persulfate aqueous solution 6.5 gram and remaining pre-emulsions then, at 2.5-3 hour, dropwise; Drip step 2 then) mixed solution and remaining ammonium persulfate aqueous solution, 0.5-1 hour the reaction finish, temperature of reaction is controlled at 78-82 ℃ all the time;
7) be warmed up to 85-90 ℃, slaking 1 hour cools to 30-40 ℃ again, is that 25% ammoniacal liquor is neutralized to pH value 7-7.5 with mass percent concentration, adds the adipic acid dihydrazide aqueous solution, stirs, and transfers solid content to 45 ± 1% with deionized water, product.
Embodiment 2
Proportioning raw materials: dodecyl alcohol polyoxyethylene (50) ether 1.3 grams, sodium lauryl sulphate 1.3 grams, methylene-succinic acid 0.6 gram, N hydroxymethyl acrylamide 2.6 grams, vinylformic acid 2.2 grams, butyl acrylate 78 grams, Isooctyl acrylate monomer 23 grams, vinylbenzene 11 grams, γ-methacryloxypropyl trimethoxy silane 2.54 grams, epoxy resin E-44 5.5 grams, adipic acid dihydrazide 4.31 grams, sodium-acetate 0.072 gram, ammonium persulphate 0.43 gram, deionized water 155 grams, wherein pre-newborn still use deionized water 60 grams; Production process is with embodiment 1.
Embodiment 3
Proportioning raw materials: dodecyl alcohol polyoxyethylene (50) ether 1.4 grams, sodium lauryl sulphate 1.4 grams, methylene-succinic acid 0.8 gram, N hydroxymethyl acrylamide 2.8 grams, vinylformic acid 2.4 grams, butyl acrylate 82 grams, Isooctyl acrylate monomer 25 grams, vinylbenzene 11.5 grams, γ-methacryloxypropyl trimethoxy silane 2.7 grams, epoxy resin E-44 6 grams, adipic acid dihydrazide 4.70 grams, sodium-acetate 0.075 gram, ammonium persulphate 0.45 gram, deionized water 165 grams, wherein pre-newborn still make and spend dried up 70 grams; Production process is with embodiment 1.
Embodiment 4
Proportioning raw materials: dodecyl alcohol polyoxyethylene (50) ether 1.5 grams, sodium lauryl sulphate 1.5 grams, methylene-succinic acid 1 gram, N hydroxymethyl acrylamide 3 grams, vinylformic acid 2.5 grams, butyl acrylate 85 grams, Isooctyl acrylate monomer 26 grams, vinylbenzene 12 grams, γ-methacryloxypropyl trimethoxy silane 2.84 grams, epoxy resin E-44 7 grams, adipic acid dihydrazide 5.49 grams, sodium-acetate 0.08 gram, ammonium persulphate 0.5 gram, deionization 170 grams, wherein pre-newborn still water 75 grams; Production technique is with embodiment 1.
Experimental example:
Get present embodiment 1-4 product 200 grams and aminoresin 10 grams, thickening material 5 gram mixed preparing emulsions respectively, viscosity is 25 ℃ of 20000 ± 2000mPa.S(temperature), with the scraper coating, spread is 320 g/m on the T/C fleece
2, carry out static flocking.Baked 3 minutes at 150 ℃ after the flocking, remove floating hair, washing is dried and is got final product.Detected result such as following table:
Winter hardiness: according to national textile industry mark FZ/T01007-2008 test.
Dried, wet fastness: according to standard GB/T21196.2-2007 test.
The result shows that the index of the winter hardiness of product of the present invention, abrasion resistance and flexibility is compared with comparative sample has apparent in view advantage.
Also can be called dodecyl polyoxyethylene (50) ether about dodecyl alcohol polyoxyethylene (50) ether, it is a kind of product that is obtained after addition polymerization by the pure and mild oxyethane of dodecyl, dodecyl alcohol polyoxyethylene ether is a class emulsifying agent of often using in the acrylic ester emulsion polymerization, it is the general name of this class material, the adduct number of the digitized representation intramolecularly oxyethane in the bracket is such as 50 just to represent this be the addition dodecyl alcohol polyoxyethylene ethers of 50 oxyethane.For example in the article " the non-covalent functionalization of tensio-active agent prepares carbon nanotube suspension " of periodical " process engineering journal " the 10th the 1st phase of volume of February in 2010, just used such title of dodecyl polyoxyethylene (23) ether.
Claims (3)
1. acrylate flocking adhesive is characterized in that:
The raw material weight ratio is: dodecyl alcohol polyoxyethylene (50) ether 1.2-1.5, sodium lauryl sulphate 1.2-1.5, methylene-succinic acid 0.5-1, N hydroxymethyl acrylamide 2.5-3.0, vinylformic acid 2-2.5, butyl acrylate 75-85, Isooctyl acrylate monomer 21-26, vinylbenzene 10-12, γ-methacryloxypropyl trimethoxy silane 2.39-2.84, epoxy resin E-44 5-7, adipic acid dihydrazide 3.92-5.49, sodium-acetate 0.07-0.08, ammonium persulphate 0.4-0.5, deionized water 145-170, the polymer emulsion that after letex polymerization, forms;
Technical indicator:
Outward appearance: white emulsion
Ionic: the moon
PH value: 7-8
Solid content: 45 ± 1%.
2. acrylate flocking adhesive preparation method:
1) deionized water 50-75 gram, dodecyl alcohol polyoxyethylene (50) ether 1.2-1.5 gram, sodium lauryl sulphate 1.2-1.5 gram are joined pre-newborn still, fully dissolving, add methylene-succinic acid 0.5-1 gram, N hydroxymethyl acrylamide 2.5-3.0 gram, vinylformic acid 2-2.5 gram, butyl acrylate 75-85 gram, Isooctyl acrylate monomer 21-26 gram, vinylbenzene 10-12 gram, epoxy resin E-44 5-7 gram then, fully stirring and emulsifying forms pre-emulsion;
2) get the pre-emulsion of weight 1% and γ-methacryloxypropyl trimethoxy silane 2.39-2.84 gram and mix, standby;
3) ammonium persulphate 0.4-0.5 gram is mixed and made into ammonium persulfate aqueous solution with deionized water 10 grams, and is standby;
4) sodium-acetate 0.07-0.08 gram is mixed and made into sodium acetate aqueous solution with deionized water 2 grams, and is standby;
5) adipic acid dihydrazide 3.92-5.49 gram is mixed and made into the adipic acid dihydrazide aqueous solution with deionized water 15 grams, and is standby;
6) pre-emulsion with deionized water 68 grams and weight 5% joins in the reactor, be warmed up to 70-75 ℃, add whole sodium acetate aqueous solutions and 2 gram ammonium persulfate aqueous solutions, reacted 20-30 minute, begin to drip ammonium persulfate aqueous solution 6.5 gram and remaining pre-emulsions then, dropwised at 2.5-3 hour; Drip step 2 then) mixed solution and remaining ammonium persulfate aqueous solution, dropwised at 0.5-1 hour, temperature of reaction is controlled at 78-82 ℃;
7) be warmed up to 85-90 ℃, slaking 1-1.5 hour, cool to 30-40 ℃ then, with mass percent concentration is that 25% ammoniacal liquor adjust pH equals 7-7.5, adds the adipic acid dihydrazide aqueous solution, stirs, transfer solid content to equal 45 ± 1% with deionized water, get product.
3. the acrylate flocking adhesive that obtains of claim 2 method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310160605.2A CN103214993B (en) | 2013-05-04 | 2013-05-04 | Acrylic ester electrostatic flocking binding agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310160605.2A CN103214993B (en) | 2013-05-04 | 2013-05-04 | Acrylic ester electrostatic flocking binding agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103214993A true CN103214993A (en) | 2013-07-24 |
| CN103214993B CN103214993B (en) | 2015-01-28 |
Family
ID=48813173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310160605.2A Active CN103214993B (en) | 2013-05-04 | 2013-05-04 | Acrylic ester electrostatic flocking binding agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103214993B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103526580A (en) * | 2013-10-23 | 2014-01-22 | 合肥聚合辐化技术有限公司 | Printing adhesive for knitted fabrics and preparation method thereof |
| CN105602494A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof |
| CN105885742A (en) * | 2016-06-20 | 2016-08-24 | 苏州市绫罗美纺植绒有限公司 | Acrylic acid and its ester flocking adhesive, and preparation method and flocking process of adhesive |
| CN106478894A (en) * | 2016-10-03 | 2017-03-08 | 辽宁恒星精细化工有限公司 | High resiliency flocking adhesive |
| CN106543333A (en) * | 2016-10-27 | 2017-03-29 | 万华化学集团股份有限公司 | High antiseptic property acrylic emulsion and preparation method thereof, water soluble acrylic acid anticorrosive paint |
| CN106634741A (en) * | 2016-12-10 | 2017-05-10 | 冯文晖 | Weather-resistant water-proof fluoridized epoxy resin modified acrylic emulsion adhesive and preparation method thereof |
| CN109233704A (en) * | 2018-09-05 | 2019-01-18 | 嘉善欣达胶业有限公司 | A kind of flock glue and preparation method thereof |
| CN109569983A (en) * | 2018-12-22 | 2019-04-05 | 东莞市诚嘉隆植绒制品有限公司 | A kind of paper jam flocking method |
| CN110951428A (en) * | 2018-09-26 | 2020-04-03 | 浙江久大纺织科技有限公司 | APEO-free acrylate electrostatic flocking adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122355A (en) * | 1994-05-03 | 1996-05-15 | 北京联合大学化学工程学院 | Electrostatic flocking adhesives solidifying under normal temperature |
| EP1681328A2 (en) * | 2005-01-18 | 2006-07-19 | Rohm and Haas Company | Water-based flock adhesives for thermoplastic substrates |
| CN102504129A (en) * | 2011-11-09 | 2012-06-20 | 闫宏飞 | Organic silicon modified acrylate electrostatic flocking formaldehydeless adhesive and preparation method thereof |
| CN102516470A (en) * | 2011-11-21 | 2012-06-27 | 北京高盟新材料股份有限公司 | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof |
-
2013
- 2013-05-04 CN CN201310160605.2A patent/CN103214993B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122355A (en) * | 1994-05-03 | 1996-05-15 | 北京联合大学化学工程学院 | Electrostatic flocking adhesives solidifying under normal temperature |
| EP1681328A2 (en) * | 2005-01-18 | 2006-07-19 | Rohm and Haas Company | Water-based flock adhesives for thermoplastic substrates |
| CN102504129A (en) * | 2011-11-09 | 2012-06-20 | 闫宏飞 | Organic silicon modified acrylate electrostatic flocking formaldehydeless adhesive and preparation method thereof |
| CN102516470A (en) * | 2011-11-21 | 2012-06-27 | 北京高盟新材料股份有限公司 | Aqueous acrylate electrostatic flocking bonding agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨蕊等: ""有机硅改性醋丙乳液的制备与表征"", 《粘接》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103526580A (en) * | 2013-10-23 | 2014-01-22 | 合肥聚合辐化技术有限公司 | Printing adhesive for knitted fabrics and preparation method thereof |
| CN105602494A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof |
| CN105885742A (en) * | 2016-06-20 | 2016-08-24 | 苏州市绫罗美纺植绒有限公司 | Acrylic acid and its ester flocking adhesive, and preparation method and flocking process of adhesive |
| CN106478894A (en) * | 2016-10-03 | 2017-03-08 | 辽宁恒星精细化工有限公司 | High resiliency flocking adhesive |
| CN106478894B (en) * | 2016-10-03 | 2018-09-07 | 辽宁恒星精细化工有限公司 | High resiliency flocking adhesive |
| CN106543333A (en) * | 2016-10-27 | 2017-03-29 | 万华化学集团股份有限公司 | High antiseptic property acrylic emulsion and preparation method thereof, water soluble acrylic acid anticorrosive paint |
| CN106543333B (en) * | 2016-10-27 | 2020-03-03 | 万华化学集团股份有限公司 | High-corrosion-resistance acrylic emulsion, preparation method thereof and water-based acrylic anticorrosive paint |
| CN106634741A (en) * | 2016-12-10 | 2017-05-10 | 冯文晖 | Weather-resistant water-proof fluoridized epoxy resin modified acrylic emulsion adhesive and preparation method thereof |
| CN109233704A (en) * | 2018-09-05 | 2019-01-18 | 嘉善欣达胶业有限公司 | A kind of flock glue and preparation method thereof |
| CN110951428A (en) * | 2018-09-26 | 2020-04-03 | 浙江久大纺织科技有限公司 | APEO-free acrylate electrostatic flocking adhesive and preparation method thereof |
| CN109569983A (en) * | 2018-12-22 | 2019-04-05 | 东莞市诚嘉隆植绒制品有限公司 | A kind of paper jam flocking method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103214993B (en) | 2015-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103214993B (en) | Acrylic ester electrostatic flocking binding agent and preparation method thereof | |
| CN109868026B (en) | Organic silicon modified acrylate resin, preparation method thereof and hydrophobic weather-resistant slow-release modified acrylic resin coating | |
| CN103045113B (en) | Preparation method of self-crosslinking IPN (interpenetrating network) organosilicone-acrylate copolymer emulsion pressure-sensitive adhesive | |
| CN106749856B (en) | Silica solution and preparation method thereof, acrylic resin, acrylic acid double-component polyurethane coating | |
| CN104744639B (en) | A kind of preparation method of organic-silicon-modified normal-temperature multiple self-cross-linking epoxy resin emulsion | |
| CN102464784A (en) | Synthesis method of organic silicon modified acrylate copolymer | |
| CN105273557A (en) | Waterborne wood paint and preparation method thereof | |
| CN101696263B (en) | Epoxy resin curing agent, method for preparing same and application thereof | |
| CN102977257A (en) | Water-whitening proof maishi paint emulsion of core-shell structure and method for preparing same | |
| CN103602193A (en) | Priming paint for water-borne heavy anti-corrosion coating and preparation method thereof | |
| CN102585650A (en) | High-silicon-content organic silicon-polyurethane-acrylate composite coating agent and preparation method thereof | |
| CN103409029B (en) | A kind of Hydrophobic weather-resistant paint and preparation method thereof | |
| CN103450797A (en) | Room-temperature cured epoxy polysiloxane resin | |
| CN105255438A (en) | Bisphenol a epoxy resin modified room temperature vulcanized silicone rubber and preparation method thereof | |
| CN103627286A (en) | Water-based finishing coat for heavy-duty coating and preparation method of water-based finishing coat | |
| CN109135460B (en) | High-strength high-water-resistance polymer emulsion building waterproof coating and preparation method thereof | |
| CN102268138B (en) | Aqueous organosilicon grafted (methyl) acrylic polymer and preparation method of emulsion thereof | |
| CN110527364A (en) | A kind of polymer emulsion building water-proof paint and preparation method thereof | |
| CN113683958A (en) | Environment-friendly water-based asphalt waterproof coating and preparation method thereof | |
| CN111808505B (en) | Heat-reflection high-corrosion-resistance weather-resistant steel plate coil metal coating and preparation method thereof | |
| CN105367697A (en) | Silicone acrylic emulsion having core-shell structure and preparation method thereof | |
| CN105238133A (en) | Printing ink applied to coated glass and application method of printing ink | |
| CN112048174A (en) | Friction-resistant high-toughness nylon 6 composite material and preparation method thereof | |
| CN105802462B (en) | A kind of MODIFIED PP material polyurethane paint and preparation method thereof | |
| CN101967255A (en) | Waterborne resin for plastic film coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |