CN103205035A - Sealing gasket for oil filter - Google Patents
Sealing gasket for oil filter Download PDFInfo
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- CN103205035A CN103205035A CN2013101112476A CN201310111247A CN103205035A CN 103205035 A CN103205035 A CN 103205035A CN 2013101112476 A CN2013101112476 A CN 2013101112476A CN 201310111247 A CN201310111247 A CN 201310111247A CN 103205035 A CN103205035 A CN 103205035A
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Abstract
The invention relates to a sealing gasket for an oil filter. The sealing gasket comprises the following components in parts by weight: 100 parts of nitrile-butadiene rubber, 1-3 parts of dicumyl peroxide, 1-10 parts of ZNO, 0.5-2 parts of SA, 0.5-5 parts of anti-aging agent RD and 0.5-5 parts of anti-aging agent MB. The sealing gasket for the oil filter has excellent high and low temperature resistance, low compression resistant permanent deformation rate, good resilience, excellent oil resistance and excellent physical and mechanical properties, and can be used within the temperature ranging from 135 DEG C to 40 DEG C below zero.
Description
Technical field
The present invention relates to a kind of purifier gasket, relate in particular to the purifier gasket that a kind of automobile engine oil is used.
Background technology
Oil filter is arranged in engine lubrication system.Its upstream is lubricating oil pump, and the downstream is to need each component of lubricating in the engine.Its effect is to carrying out filtering from detrimental impurity in the machine oil of oil pan, with kinematic pairs such as the engine oil supplying bent axle of cleaning, connecting rod, camshaft, supercharging blower, piston ring, plays lubricated, cooling, cleanup action, thereby prolongs the life-span of these component.The cover that gasket is made up of one or several part is fixed on lasso of bearing or the packing ring and with another lasso or packing ring and contacts or form narrow labyrinth clearance, prevents that lubricating oil from spilling and foreign object is invaded.
In oil filter, the fluorine glue of selecting for use of the general usefulness of gasket is done the main body material, and it is high temperature resistant to reach 200 degree, low temperature resistantly can arrive-20 and spends.But at northern frore area, fluorine glue then can lose its use properties.Cause the purifier leakage of oil.Perhaps use HNBR hydrogenated nitrile-butadiene rubber gasket, the auspicious father-in-law of chloroprene rubber CR121, hydrogenated nitrile-butadiene rubber ZP2020(Japan), Zinc Stearate, coumarone, 2-thiol group benzimidazolyl, clorafin, semi-reinforcing hydrocarbon black SRF, montmorillonite powder, adipic acid ester, promotor PZ, promotor TETD, linking agent TAC, anti-aging agent RD, antioxidant 1010, modification infusorial earth disclose a kind of sealing-ring for purifier drain pan and loam cake as CN102942723A, it is made up of following raw material:.Or use the nitrile rubber gasket, comprise as the major ingredient of the disclosed rubber seal of CN102952299A: the nitrile rubber 2865 of 28~36 weight parts; Auxiliary material comprises: the carbon black 330 of 10~18 weight parts, half reinforcement of 10~18 weight parts, the dioctyl ester of 1~6 weight part, 0.35 the zinc oxide of~0.65 weight part, 0.02 the sulphur of~0.05 weight part, 0.2 the hard acid ester of~0.7 weight part, 0.3 the antioxidant 4010NA of~0.7 weight part, 0.3 the anti-aging agent RD of~0.7 weight part, 0.15 the promotor T.T.C of~0.3 weight part, the calcium carbonate of 2~7 weight parts, 0.8 the altax of the EN-100 of~1.2 weight parts and 0.15~0.25 weight part.
Summary of the invention
The object of the present invention is to provide a kind of oil filter gasket, select the fine content 33% of propylene for use, the paracril of mooney viscosity 50-60 is that major ingredient is prepared, the gasket processing characteristics that makes is excellent to satisfy the product high and low temperature resistance simultaneously, can satisfy 135 ℃ to-40 ℃ use range.
Oil filter gasket provided by the invention, contain following component by weight: paracril 100, dicumyl peroxide 1~3, as it is 1 part, 1.1 part, 1.3 part, 1.5 part, 1.8 part, 2.2 part, 2.6 part, 2.9 part etc., ZnO1~10, as it is 1.4 parts, 2.1 part, 3.3 part, 4.5 part, 5.8 part, 6.2 part, 7.6 part, 8.9 part, 9.5 part etc., stearic acid 0.5~2, as it is 0.8 part, 1.1 part, 1.3 part, 1.6 part, 1.8 part etc., anti-aging agent RD 0.5~5, as it is 0.8 part, 1.3 part, 1.9 part, 2.3 part, 2.5 part, 2.8 part, 3.3 part, 3.6 part, 4.5 part, 4.7 part etc., antioxidant MB 0.5~5, as be 0.8 part, 1.3 part, 1.9 part, 2.3 part, 2.5 part, 2.8 part, 3.3 part, 3.6 part, 4.5 part, 4.7 part etc.
Paracril is made through emulsion polymerization by divinyl and vinyl cyanide, and paracril mainly adopts the production of low temperature emulsion polymerization, and oil-proofness is fabulous, and wear resistance is higher, and thermotolerance is better.The fine content 33% of propylene in the used paracril of the present invention, mooney viscosity 55, mooney viscosity claim again to rotate (Mooney) viscosity, are the numerical value of measuring with mooney's viscosimeter, can reflect the elastomeric polymerization degree and molecular weight basically.The present invention selects for use specific paracril can guarantee that the product processing characteristics excellence that makes can satisfy the product high and low temperature resistance simultaneously.
Dicumyl peroxide claims vulcanizing agent DCP again, is a kind of strong oxidizer, initiator of polyreaction.The present invention selects for use the superoxide dicumyl peroxide as vulcanizing agent, makes the resistance to elevated temperatures excellence that makes material to have the low compression set rate simultaneously.
ZnO is used as the strengthening agent of rubber in goods of the present invention, so that rubber has good anti-corrosion, tear strength and elasticity, elongation.
Stearic acid is octadecanoic acid, contains the saturated fatty acid of 18 carbon atoms.As vulcanization leveller, also can be used as softening agent and tenderizer in the present invention, also have the effect of releasing agent simultaneously.
Anti-aging agent can prevent or suppress such as factors disrupt product propertiess such as oxygen, heat, light, ozone, mechanical stress, heavy metal ion, prolong gasket storage and the Synergist S-421 95 in work-ing life.Anti-aging agent of the present invention uses RD, the MB combination of amine and heterocyclic, makes the oil resistance excellence that makes product.
As optimal technical scheme, described gasket, contain following component by weight:
As optimal technical scheme, described gasket, contain following component by weight:
As optimal technical scheme, described gasket also comprises a kind or the mixture more than at least 2 kinds in N330 carbon black, spray carbon black, softening agent TOTM, silane coupling agent, the paraffin.Be preferably all components that contains N330 carbon black, spray carbon black, softening agent TOTM, silane coupling agent and paraffin.Consumption those skilled in the art of above-mentioned auxiliary agent can carry out routine according to existing knowledge and select.
Gasket material infill system of the present invention is high wear-resistant carbon black N330 and uses spray carbon black, can guarantee excellent physical and mechanical performance, has higher resilience simultaneously.Add a small amount of macromolecule softening agent TOTM, prevent from being extracted out by machine oil, other softening agent have higher oil-proofness on year-on-year basis.Silane coupling agent can improve bonding strength between resin and the solid surface and an one type of silane of weather resistance.The organic radical of connecting band functional group on the Siliciumatom normally, simultaneously again with an one type of silane of hydrolysable group phase bonding, the present invention uses silane coupling agent can increase the intensity of goods.Gasket of the present invention adds paraffin simultaneously, exceeds the compatible degree of rubber own, can separate out the surface certainly, plays lubricant effect, is convenient to client's production line employee assembling.
Gasket material provided by the present invention can satisfy 135 ℃ to-40 ℃ temperature use range.Under 135 ℃ of high-temperature conditions, soak 30# machine oil and can not have be full of cracks by 96h.
As optimal technical scheme, described gasket, the weight part of described N330 carbon black are 20~60, for example are 25,29,36,42,49,53,57 etc., are preferably 20~50, more preferably 30~40;
Preferably, the weight part of described spray carbon black is 20~60, for example is 25,29,36,42,49,53,57 etc., is preferably 20~50, more preferably 30~50;
Preferably, the weight part of described softening agent TOTM is 1~25, for example is 3,6,9,12,15,16,18,21,23 etc., is preferably 5~20, more preferably 5~15;
Preferably, the weight part of described silane coupling agent is 0.1~1, for example is 0.2,0.6,0.8,0.9 etc., is preferably 0.3~0.5, more preferably 0.3;
Preferably, the weight part of described paraffin is 1~8, for example is 2,4,5,6 etc., is preferably 3~8, more preferably 3~6.
As optimal technical scheme, described gasket, contain following component by weight:
As optimal technical scheme, described gasket, contain following component by weight:
As optimal technical scheme, described gasket, contain following component by weight:
The preparation method of gasket provided by the present invention can be prepared with ordinary method, is prepared as adopting the CN102952299A disclosed method.
Oil filter provided by the present invention has excellent high and low temperature resistance with gasket, can satisfy 135 ℃ to-40 ℃ use range, has anti-low compression set rate, and rebound resilience is good, the oil resistance excellence, and have excellent physical and mechanical performance.
Embodiment
Further specify technical scheme of the present invention below by embodiment.
Embodiment one
Contain following component by weight:
Embodiment two
Contain following component by weight:
Embodiment three
Embodiment four
Embodiment five
Embodiment six
Use properties
The gasket that embodiment one~six is obtained carries out performance test, and test result sees the following form 1.
Table 1
Carry out cold performance test by GB/T1682 :-40 ℃ keep 3min, observe and do not have be full of cracks.
As can be seen from Table 1, gasket of the present invention through high temperature, oil resistant test after, still have excellent physical and mechanical properties, and withstand low-temperature test and do not have be full of cracks.
Applicant's statement, the present invention illustrates detailed process equipment of the present invention and technical process by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and technical process, does not mean that namely the present invention must rely on above-mentioned detailed process equipment and technical process could be implemented.The person of ordinary skill in the field should understand, any improvement in the present invention to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (8)
4. as each described gasket of claim 1~3, it is characterized in that, also contain a kind or the mixture more than at least 2 kinds in N330 carbon black, spray carbon black, softening agent TOTM, silane coupling agent, the paraffin.
5. gasket as claimed in claim 4 is characterized in that, the weight part of described N330 carbon black is 20~60, is preferably 20~50, more preferably 30~40;
Preferably, the weight part of described spray carbon black is 20~60, is preferably 20~50, more preferably 30~50;
Preferably, the weight part of described softening agent TOTM is 1~25, is preferably 5~20, more preferably 5~15;
Preferably, the weight part of described silane coupling agent is 0.1~1, is preferably 0.3~0.5, more preferably 0.3;
Preferably, the weight part of described paraffin is 1~8, is preferably 3~8, more preferably 3~6.
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CN2013101112476A CN103205035A (en) | 2013-04-01 | 2013-04-01 | Sealing gasket for oil filter |
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CN2013101112476A CN103205035A (en) | 2013-04-01 | 2013-04-01 | Sealing gasket for oil filter |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103408819A (en) * | 2013-08-13 | 2013-11-27 | 安徽中鼎密封件股份有限公司 | Rubber sealing assembly between chainsaw carburetor and engine cylinder, and manufacturing method thereof |
CN103509297A (en) * | 2013-09-05 | 2014-01-15 | 安徽省科林电子有限公司 | Anti-aging transformer sealing gasket and preparation method thereof |
CN103665481A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠市时代电子有限公司 | Compound rubber sealing gasket material with favorable wear resistance and sealing performance and preparation method of compound rubber sealing gasket material |
CN103724727A (en) * | 2013-12-13 | 2014-04-16 | 芜湖金鹰机械科技开发有限公司 | Cold-resistant O-shaped ring containing nano calcium carbonate |
CN104004238A (en) * | 2014-05-07 | 2014-08-27 | 宁国市顺达密封件制造有限公司 | Filtration cleaner rubber resisting low temperature of -43 DEG C |
CN104341628A (en) * | 2013-07-28 | 2015-02-11 | 安徽同丰橡塑工业有限公司 | Cold-resistant rubber and preparation method thereof |
CN104829889A (en) * | 2015-05-22 | 2015-08-12 | 罗满清 | Oil-resistant high-temperature-resistant seal gasket rubber for cylinders and preparation method thereof |
CN105504400A (en) * | 2015-12-31 | 2016-04-20 | 宁国市顺达密封件制造有限公司 | Rubber element which is used for filter and resistant to low temperature of -43 DEG C |
CN106750645A (en) * | 2016-12-07 | 2017-05-31 | 陕西省石油化工研究设计院 | A kind of high-low temperature resistant, the ultralow buckling elastomeric material for the diesel oil of resistance to machine and preparation method thereof |
CN107011555A (en) * | 2017-06-05 | 2017-08-04 | 宁波光明橡塑有限公司 | A kind of preparation method of high abrasion nitrile rubber |
CN107573556A (en) * | 2017-08-25 | 2018-01-12 | 启东永兴橡胶制品有限公司 | A kind of automobile oil pan sealing gasket elastomeric material and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101880413A (en) * | 2010-05-24 | 2010-11-10 | 大连理工大学 | Sealant for high temperature pressurized leakage stop-up |
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2013
- 2013-04-01 CN CN2013101112476A patent/CN103205035A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101880413A (en) * | 2010-05-24 | 2010-11-10 | 大连理工大学 | Sealant for high temperature pressurized leakage stop-up |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104341628A (en) * | 2013-07-28 | 2015-02-11 | 安徽同丰橡塑工业有限公司 | Cold-resistant rubber and preparation method thereof |
CN103408819A (en) * | 2013-08-13 | 2013-11-27 | 安徽中鼎密封件股份有限公司 | Rubber sealing assembly between chainsaw carburetor and engine cylinder, and manufacturing method thereof |
CN103408819B (en) * | 2013-08-13 | 2015-10-28 | 安徽中鼎密封件股份有限公司 | Rubber seal element and manufacture method thereof between chain saw carburetor and engine cylinder |
CN103509297A (en) * | 2013-09-05 | 2014-01-15 | 安徽省科林电子有限公司 | Anti-aging transformer sealing gasket and preparation method thereof |
CN103665481A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠市时代电子有限公司 | Compound rubber sealing gasket material with favorable wear resistance and sealing performance and preparation method of compound rubber sealing gasket material |
CN103724727A (en) * | 2013-12-13 | 2014-04-16 | 芜湖金鹰机械科技开发有限公司 | Cold-resistant O-shaped ring containing nano calcium carbonate |
CN104004238A (en) * | 2014-05-07 | 2014-08-27 | 宁国市顺达密封件制造有限公司 | Filtration cleaner rubber resisting low temperature of -43 DEG C |
CN104829889A (en) * | 2015-05-22 | 2015-08-12 | 罗满清 | Oil-resistant high-temperature-resistant seal gasket rubber for cylinders and preparation method thereof |
CN105504400A (en) * | 2015-12-31 | 2016-04-20 | 宁国市顺达密封件制造有限公司 | Rubber element which is used for filter and resistant to low temperature of -43 DEG C |
CN106750645A (en) * | 2016-12-07 | 2017-05-31 | 陕西省石油化工研究设计院 | A kind of high-low temperature resistant, the ultralow buckling elastomeric material for the diesel oil of resistance to machine and preparation method thereof |
CN107011555A (en) * | 2017-06-05 | 2017-08-04 | 宁波光明橡塑有限公司 | A kind of preparation method of high abrasion nitrile rubber |
CN107573556A (en) * | 2017-08-25 | 2018-01-12 | 启东永兴橡胶制品有限公司 | A kind of automobile oil pan sealing gasket elastomeric material and preparation method thereof |
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