CN103189594A - Hydrate deposit inhibition with surface-chemical combination - Google Patents
Hydrate deposit inhibition with surface-chemical combination Download PDFInfo
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- CN103189594A CN103189594A CN2011800517169A CN201180051716A CN103189594A CN 103189594 A CN103189594 A CN 103189594A CN 2011800517169 A CN2011800517169 A CN 2011800517169A CN 201180051716 A CN201180051716 A CN 201180051716A CN 103189594 A CN103189594 A CN 103189594A
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- crude oil
- pipeline
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- well
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Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
- E21B37/06—Methods or apparatus for cleaning boreholes or wells using chemical means for preventing or limiting, e.g. eliminating, the deposition of paraffins or like substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/14—Linings or internal coatings
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/01—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells specially adapted for obtaining from underwater installations
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
- F16L58/08—Coatings characterised by the materials used by metal
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
- F16L58/10—Coatings characterised by the materials used by rubber or plastics
- F16L58/1009—Coatings characterised by the materials used by rubber or plastics the coating being placed inside the pipe
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
- F16L58/10—Coatings characterised by the materials used by rubber or plastics
- F16L58/1009—Coatings characterised by the materials used by rubber or plastics the coating being placed inside the pipe
- F16L58/1045—Coatings characterised by the materials used by rubber or plastics the coating being placed inside the pipe the coating being an extruded or a fused layer
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
- F16L58/14—Coatings characterised by the materials used by ceramic or vitreous materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/0318—Processes
- Y10T137/0391—Affecting flow by the addition of material or energy
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Geology (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Fluid Mechanics (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Lubricants (AREA)
- Pipeline Systems (AREA)
- Paints Or Removers (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Detergent Compositions (AREA)
Abstract
A system for producing and transporting crude oil, comprising a well for producing the crude oil; a processing facility for processing the crude oil; and a pipeline traversing at least a portion of the distance between the well and the processing facility, wherein at least a portion of the pipeline travels through an atmosphere having a temperature less than 20 DEG C, wherein the pipeline comprises a coating on an inner surface of the pipeline, and wherein the crude oil comprises a surfactant additive.
Description
Technical field
The present invention relates to carry fluid to be down to the hydrate accumulation minimum through pipeline.
Background technology
Usually by with one or more well earth penetratings and pumping or allow oil gentle flow through these wells come from the subsurface formations recovery of oil gentle.The gentle process that produces oil from deep well, bottom-water temperature is low can to cause forming gas hydrate with the fluid pressure height.Gas hydrate can reach the degree that obstruction takes place the surface line that makes pit shaft and carry gas.The obstruction that this gas hydrate and/or other sediment cause can influence the gentle ground substation that flows to of oil.
U.S. Patent Application Publication 2006/0186023 discloses a kind of being limited in simultaneously through pipeline conveying produced fluid and has produced the method that deposits on the required pipeline inner wall position, this method comprises that inside surface roughness Ra that described required pipeline inner wall position place is provided is less than 2.5 microns pipeline, force described produced fluid through this pipeline, the wall shear stress that wherein said produced fluid is every square centimeter at described required pipeline inner wall position place is at least 1 dyne.U.S. Patent Application Publication 2006/0186023 here is incorporated herein by reference in full.
PCT patent application PCT/the US2010/020420 of common pending trial discloses a kind of not sticking device, and this device comprises fluid storage or the transportation goods that comprise first material; The coating that comprises second material at the inner surface of goods; Wherein the critical surface tension value of second material less than 75mN/m and in Mohs' scale (Moh's scale) hardness number less than 5.PCT patent application PCT/US2010/020420 here is incorporated herein by reference in full.
Summary of the invention
One aspect of the present invention provide a kind of for the production of with the system of conveying crude oil, this system comprises: for the production of the well of crude oil; Treatment facility for the treatment of crude oil; And pass the pipeline of at least a portion distance between well and the treatment facility, wherein at least a portion pipeline is walked in temperature is lower than 20 ℃ atmosphere, wherein pipeline be included on the pipeline inner surface coating and wherein crude oil comprise surfactant additive.
Description of drawings
Fig. 1 has shown the offshore production well.
Fig. 2 is the schematic diagram of liquid and surface of solids contact angle.
Fig. 3 advances and the schematic diagram of receding contact angle at the surface of solids.
The specific embodiment
On the one hand, embodiment disclosed herein relates to the system and method that is suppressed at hydrate deposition on the probing tube wall with surperficial chemical combination.More particularly, embodiment disclosed herein relates to by adding the system and method that combinations-of surfactants gets up to be suppressed at hydrate sediment on the probing tube wall with the wall coating with to the output logistics.
Oil and gas well are pierced subsurface formations contain natural gas in these subsurface formations with production.The deep water drilling operation has been realized exploration and the production of hydrocarbon.May exist carbon dioxide, hydrogen sulfide and multiple hydrate to form hydrocarbon such as methane, ethane, propane and butane in the natural gas.Water also can form hydrocarbon with these hydrates with different amounts and exist with other oil composition.Under low bottom-water temperature and high fluid pressure, when hydrocarbon, oil composition and other hydrate formation material mix with water, can form cage shape hydrate.Cage shape hydrate is hydrated crystal, and it forms hydrocarbon formation cage structure around guest molecule such as hydrate.Gas hydrate is a cage-like shape hydrate and is subjected to special concern in petroleum industry.The gathering of hydrate cause the production of natural gas and other petroleum fluids and/or carry during pipeline takes place stops up.Therefore, stop or what minimize this obstruction that is caused by hydrate is the primary goal that flows and guarantee.
Fig. 1:
With reference to Fig. 1, comprise that the system 100 of well 10 is connected to offshore drilling platform 11.Under elevated pressure, comprising in the subsurface formations 12 of natural gas, oil or their combination and finishing well 10.Well 10 adds cover by the sleeve pipe 13 with hole 14 of leading to subsurface formations 12.Produce pipe 15 and be suspended in the sleeve pipe 13, it has with subsurface formations 12 and produces the annular space 16 that pipe 15 fluids are communicated with.Produce pipe 15 and extend up to platform 11 from well 10 through tedge 17.Packer element 18 separates the top of oil well and the production area of subsurface formations 12.
Gas and other petroleum fluids enter from subsurface formations 12 through annular space 16 and produce pipe 15, flow to platform 11.From subsurface formations outflow process, gas, oil or their combination temp reduce.This may be since well self temperature is low or since when flowing to the face of land pressure in the gas reduce big.This temperature reduction can cause forming undesirable hydrate and/or may form other solid.Sedimentally need to continue the bonding force of deposit and wall to be enough to deposit is remained on the wall.
Embodiment of the present disclosure provides to stop to stop up the minimized new method of occurrence frequency has taken place maybe will stop up.The chemicals that embodiment disclosed herein is used than conventional method lacks, therefore environmental friendliness more.Embodiment disclosed herein relates to the system and method that forms hydrate on the inner surface that is suppressed at production and/or conveying device and deposition takes place, this method comprises: (a) deposited coatings and (b) add surfactant with 1 to the output logistics) material that reduces precipitated solid or precipitated solid and production and/or conveying device inner surface contact and 2) reduce the adhesive effect of hydrate sediment and production and/or conveying device inner surface.
Can realize reducing the material of precipitated solid or precipitated solid and contacting of production and/or conveying device inner surface by the contact angle (θ) that face coat and interpolation combinations-of surfactants are got up to increase the produced fluid logistics.Contact angle (θ) be liquid solid sprawl or solid by the wetting quantitative measure of liquid.Therefore, if water droplet at the lip-deep contact angle of flat solid less than 90 °, then the surface of solids is called as " water-wet ", and if water droplet at the lip-deep contact angle of flat solid greater than 90 °, then can not water-wet.Can use the contact angle mensuration to measure the surface energy of solid indirectly.
Fig. 2:
Substantially, with reference to Fig. 2, as the explanation on the contact angle ordinary meaning, drop 21 is placed on the surface of solids 20.Geometrically, contact angle is defined as the angle that is formed by liquid at the three-phase boundary place that liquid 21, steam 22 and solid 20 contact.Relation between contact angle and solid 20, liquid 21 and steam 22 three-phases between the interface energy is defined by Young's equation:
Cosθ=(γ
SV-γ
SL)/γ
LV
γ wherein
SV, γ
SLAnd γ
LVRepresent solid/vapor, solid/liquid and liquid interfacial tension at the interface respectively.The surface can relate to γ by following relational expression
SV:
γ
SV=γ
S-π
e
γ wherein
SBe the real surface energy of solid, π
eBe the balance spreading pressure, it is to be adsorbed onto measuring of the energy that discharges on solid 20 surfaces by steam 22.When energy surface tension high and liquid in the surface of solid was low, it was important having only the balance spreading pressure.
Can static state or kinetic measurement contact angle.Static contact angle is by θ
StaticExpression, it has reflected the system that is in balance.Usually use goniometry to measure θ
StaticThe angle that the set of liquid or free drop 21 form between the contact angle on the surface of solids 20 is by solid 20 and liquid drop 21 tangent line is from the teeth outwards determined.
Dynamic contact angle has reflected the system that solid/liquid/vapor phase is kept in motion.Dynamic contact angle can be that to advance is θ
AdvAnd that retreat is θ
RecWith reference to Fig. 3 a, the contact angle θ that measurement is advanced when using capillary syring 32 to add liquid
AdvWhen adding drop, the meniscus of drop 31 is shifted to the not wetting surface of solids 30.With reference to Fig. 3 b, the contact angle θ that measurement retreats when using capillary syring 32 to remove liquid
RecWhen removing liquid, the meniscus of drop 31 is return from the wetting surface of solids 30.θ
AdvInformation about the hydrophobic of the surface of solids or low-surface-energy character is provided, and θ
RecThe hydrophilic of the surface of solids or high surface energy character have been reflected.Hysteresis θ
ΔBe the difference (θ between the contact angle that advances and retreat
Δ=θ
Adv-θ
Rec).
For the disclosure, there are several contact angles to need to pay close attention to.Especially, in the continuous fluid of the fluid stream of output, exist salt solution at supravasal contact angle α
bWith the precipitation hydrate at supravasal contact angle α
hAs explained above, the salt solution of precipitation hydrate can be called β on supravasal surface, and the adhesive effect of the hydrate of precipitation can be called γ.
A kind of approach that the minimizing precipitated solid contacts with conduit is to select the catheter surface of coating-interpolation combinations-of surfactants, the contact angle α of hydrate on catheter surface of the fluid stream precipitation of output in the continuous fluid of the fluid stream of this combination increase output
hPerhaps precipitate the contact angle α of salt solution on catheter surface of hydrate
bFormed contact angle is more big, and is just more few with contacting of wall, therefore can still less stop up.The second kind of approach that realizes this result is to select the combinations-of surfactants of the catheter surface-interpolation of coating, and this combination reduces the surface energy β of salt solution on catheter surface in continuous fluid.If realized this method, then to compare with the undressed conduit with surface energy β, the salt solution that contacts with catheter surface more may namely be removed before forming hydrate sediment.
Embodiment of the present invention are not to have the contact force that reduces, but alternatively strive for reducing the adhesive effect of hydrate sediment on wall.A kind of method that realizes this target is to select wall coating-chemicals (anti-coalescent chemicals) combination, and this combination reduces in the continuous fluid precipitated solid at supravasal bonding force γ.Bonding force is more low, and deposit is the more impossible catheter surface that is attached to just.
Therefore, embodiment of the present disclosure relates to a kind of system of combination, and this system uses the coating conduit with the chemical addition agent that increases contact angle, or has used the coating conduit that reduces the chemical addition agent of adhesive effect, perhaps their combination.
According to the disclosure, coating can comprise nonmetallic coating (as silicon coating, ceramic coating) and the minimal adhesion polymer coating that is prepared by siloxanes, fluorosilicone and fluoropolymer, this is because their surface can be low, this can reduce polarity and with the interaction of hydrogen bond of ambient water molecule, therefore reduce adhesion energy.In another embodiment of the present disclosure, coating can comprise metal coating.
According to the disclosure, coating can comprise any coating that can use those technology disclosed herein to use.For example, in an embodiment of the present disclosure, can by make produce and/or the inner surface hydrophiling of conveying device and subsequently grafting low surface energy polymeric chain apply coating, make contact angle higher thus.In another embodiment of the present disclosure, can form coating by using cross-linked polymeric material such as siloxanes, fluorosilicone and fluoropolymer.In another embodiment of the present disclosure, can form coating by self assembly.
According to the disclosure, coating can comprise it can being any coating of " basic coating uniformly "." uniformly basic coating " used herein refers to the production that can be covered fully by the coating of desired thickness and/or the inner surface of conveying device.For example, in one embodiment, according to types of coatings and application process, coating layer thickness can be at least about 0.5 μ m.In another embodiment, according to types of coatings and application process, coating layer thickness can be about 1 μ m or more.In another embodiment, according to types of coatings and application process, coating layer thickness can be about 10 μ m or more.
As mentioned above, can be by face coat be got up to realize to reduce the material of precipitated solid or precipitated solid and contacting of production and/or conveying device inner surface with interpolation combinations-of surfactants in the logistics of output.Surfactant used herein refers to usually for changing oil effectively and for changing the effective surfactant of matrix rock wetability in that permeable material such as subsurface reservoir are built-in.The example that can inject the surfactant of subsurface formations or flowline can comprise: the water-based anion surfactant, as the mixture of aromatic ether polysulfonates and alkoxyl alcohol sulfuric ester; The organic sulfonic acid ester surfactant, those as can extensively being purchased as " Bryton Chemical F467 ", " Witco Chemical TRS-10 " and " American Cynamid Aerosol OT " with trade name; Non-ionic surface active agent is as polyethoxylated alkyl phenol, polyethoxylated fatty alcohol, carboxylate, carboxylic acid amide and polyoxyethylene fatty acid acid amides; The combination of anion and non-ionic surface active agent; Many with other.
According to the disclosure, can by surfactant solution inject is injected well and/or producing well add for the treatment of surfactant.
According to the disclosure, can add anti-aggregating agent prepared therefrom and be gathered into bigger hydrate crystal to stop less hydrate substantially, but thus less hydrate pumping by producing and/or the conveying device inner surface.The example that can be coated to the anti-aggregating agent prepared therefrom molecule of production and/or conveying device inner surface can comprise bromination tributyl cetyl
, bromination tributyl cetyltrimethyl ammonium and other alkylating ammonium,
Or sulfonium compound, zwitterionic compound such as R (CH
3)
2N
+-(CH
2)
4-SO
3 31
Advantageously, embodiment of the present disclosure can minimize or even eliminate to be formed at and produce and/or the hydrate of induction system inner surface forms.In addition, embodiment of the present disclosure can also make increase be used for minimizing or eliminate chemicals dosage that gas hydrate forms need reduce.
Exemplary:
In one embodiment, disclose a kind of for the production of with the system of conveying crude oil, this system comprises: for the production of the well of crude oil; Treatment facility for the treatment of crude oil; And pass the pipeline of at least a portion distance between well and the treatment facility, wherein at least a portion pipeline is walked in temperature is lower than 20 ℃ atmosphere, wherein pipeline be included on the pipeline inner surface coating and wherein crude oil comprise surfactant additive.In some embodiments, atmospheric temperature is lower than 15 ℃.In some embodiments, atmospheric temperature is lower than 10 ℃.In some embodiments, coating comprises polymer.In some embodiments, coating comprises siloxanes and/or PTFE (polytetrafluoroethylene (PTFE)).In some embodiments, surfactant comprises anion surfactant.
In one embodiment, disclose the method for a kind of production and conveying crude oil, this method comprises: extract crude oil from well; With crude oil place pipeline with conveying crude oil from well; Apply at least a portion inner surface of pipeline with nonmetallic surface; Before being placed pipeline, crude oil adds surfactant to crude oil; Wherein at least a portion pipeline is walked in environment temperature is lower than 20 ℃ atmosphere.In some embodiments, atmospheric temperature is lower than 15 ℃.In some embodiments, atmospheric temperature is lower than 10 ℃.In some embodiments, coating comprises the material that is selected from teflon and siloxanes.In some embodiments, pipeline comprises first material, and its floating coat comprises second material and wherein second conductivity of electrolyte materials is lower than first material.In some embodiments, has the adhesive effect of crude oil in the pipeline of coating than the adhesive effect low at least 25% of crude oil in the pipeline that does not have coating.In some embodiments, the contact angle with crude oil in the pipeline of coating and surfactant is than the contact angle that does not have coating and do not have crude oil in the pipeline of surfactant greatly at least 25%.
In one embodiment, disclose a kind of not sticking device, this device comprises: the fluid storage or the transportation goods that comprise first material; The coating that comprises second material at the inner surface of goods; The liquid that comprises surfactant additive in the goods.In some embodiments, first material is selected from steel, stainless steel, cast iron, copper and plastics.In some embodiments, second material comprises nonmetal polymeric binder or coating.In some embodiments, goods comprise pipe.In some embodiments, goods comprise groove.In some embodiments, surfactant additive comprises hydrophilic head and hydrophobic tail.
The present invention is described with regard to the embodiment of limited quantity, can design other embodiment that does not deviate from the scope of the invention disclosed herein but have benefited from of the present disclosure it will be understood to those of skill in the art that.Therefore, scope of the present invention should only be limited by the accompanying claims.
Claims (19)
- One kind for the production of with the system of conveying crude oil, this system comprises:Well for the production of crude oil;Treatment facility for the treatment of crude oil; WithCross the pipeline of at least a portion distance between described well and the described treatment facility, wherein the described pipeline of at least a portion is walked in temperature is lower than 20 ℃ atmosphere, wherein said pipeline comprise on the described pipeline inner surface coating and wherein crude oil comprise surfactant additive.
- 2. the system of claim 1, wherein atmospheric temperature is lower than 15 ℃.
- 3. each system of claim 1-2, wherein atmospheric temperature is lower than 10 ℃.
- 4. each system of claim 1-3, wherein said coating comprises polymer.
- 5. each system of claim 1-4, wherein said coating comprises siloxanes and/or PTFE (polytetrafluoroethylene (PTFE)).
- 6. each system of claim 1-5, wherein said surfactant comprises anion surfactant.
- 7. the method for a production and conveying crude oil, this method comprises:From well, extract crude oil;With crude oil place pipeline with conveying crude oil from well;Apply at least a portion inner surface of described pipeline with nonmetallic surface;Before being placed described pipeline, crude oil adds surfactant to crude oil;Wherein at least a portion pipeline is walked in environment temperature is lower than 20 ℃ atmosphere.
- 8. the method for claim 7, wherein atmospheric temperature is lower than 15 ℃.
- 9. each method of claim 7-8, wherein atmospheric temperature is lower than 10 ℃.
- 10. each method of claim 7-9, wherein said coating comprises the material that is selected from teflon and siloxanes.
- 11. each method of claim 7-10, wherein said pipeline comprises first material, and wherein said coating comprises second material and wherein second conductivity of electrolyte materials is lower than first material.
- 12. each method of claim 7-11 wherein has the adhesive effect of crude oil in the pipeline of coating than the adhesive effect low at least 25% of crude oil in the pipeline that does not have coating.
- 13. each method of claim 7-12, the contact angle that wherein has crude oil in the pipeline of coating and surfactant is than the contact angle that does not have coating and do not have crude oil in the pipeline of surfactant greatly at least 25%.
- 14. not sticking device, this device comprises:The fluid storage or the transportation goods that comprise first material;The coating that comprises second material at the inner surface of described goods;The liquid that comprises surfactant additive in the described goods.
- 15. the device of claim 14, wherein first material is selected from steel, stainless steel, cast iron, copper and plastics.
- 16. each device of claim 14-15, wherein second material comprises nonmetal polymeric binder or coating.
- 17. each device of claim 14-16, wherein said goods comprise pipe.
- 18. each device of claim 14-16, wherein said goods comprise groove.
- 19. each device of claim 14-18, wherein said surfactant additive comprise hydrophilic head and hydrophobic tail.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40674810P | 2010-10-26 | 2010-10-26 | |
| US61/406,748 | 2010-10-26 | ||
| PCT/US2011/057459 WO2012058144A2 (en) | 2010-10-26 | 2011-10-24 | Hydrate deposit inhibition with surface-chemical combination |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103189594A true CN103189594A (en) | 2013-07-03 |
| CN103189594B CN103189594B (en) | 2018-11-16 |
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ID=45994679
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| CN201180051716.9A Expired - Fee Related CN103189594B (en) | 2010-10-26 | 2011-10-24 | Use hydrate deposit inhibition with surface-chemical combination |
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| Country | Link |
|---|---|
| US (1) | US10036489B2 (en) |
| CN (1) | CN103189594B (en) |
| AU (1) | AU2011320622B2 (en) |
| BR (1) | BR112013009822A2 (en) |
| GB (1) | GB2498472A (en) |
| MY (1) | MY167193A (en) |
| NO (1) | NO20130720A1 (en) |
| WO (1) | WO2012058144A2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110700774A (en) * | 2019-10-16 | 2020-01-17 | 中国石油集团川庆钻探工程有限公司长庆钻井总公司 | Circulating tank and automatic induction cleaning method for drilling fluid circulating tank |
| CN118222263A (en) * | 2024-03-13 | 2024-06-21 | 中国石油大学(华东) | Composite hydrate blocking remover and application thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9790104B2 (en) * | 2012-02-17 | 2017-10-17 | Hydrafact Limited | Water treatment |
| CN102853209A (en) * | 2012-09-21 | 2013-01-02 | 中国海洋石油总公司 | Use of polytetrafluoroethylene in crude oil extraction equipment |
| US9279321B2 (en) * | 2013-03-06 | 2016-03-08 | Lawrence Livermore National Security, Llc | Encapsulated microsensors for reservoir interrogation |
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- 2011-10-24 AU AU2011320622A patent/AU2011320622B2/en not_active Ceased
- 2011-10-24 BR BR112013009822A patent/BR112013009822A2/en not_active Application Discontinuation
- 2011-10-24 GB GB201305900A patent/GB2498472A/en not_active Withdrawn
- 2011-10-24 WO PCT/US2011/057459 patent/WO2012058144A2/en active Application Filing
- 2011-10-24 CN CN201180051716.9A patent/CN103189594B/en not_active Expired - Fee Related
- 2011-10-24 US US13/881,321 patent/US10036489B2/en not_active Expired - Fee Related
- 2011-10-24 MY MYPI2013700580A patent/MY167193A/en unknown
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| US6251836B1 (en) * | 1995-03-23 | 2001-06-26 | Bp Exploration Operating Company Limited | Hydrate inhibition |
| CN1441147A (en) * | 2003-03-14 | 2003-09-10 | 国玉江 | Production process of metal pipe and rod with hydrophobic, olephobic and three-preventing functions and the paint used |
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| CN101094969A (en) * | 2004-12-30 | 2007-12-26 | 科诺科菲利浦公司 | Remote delivery of latex drag-reducing agent |
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| CN118222263A (en) * | 2024-03-13 | 2024-06-21 | 中国石油大学(华东) | Composite hydrate blocking remover and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2011320622B2 (en) | 2016-09-22 |
| GB2498472A (en) | 2013-07-17 |
| US10036489B2 (en) | 2018-07-31 |
| BR112013009822A2 (en) | 2016-07-26 |
| MY167193A (en) | 2018-08-13 |
| US20130213490A1 (en) | 2013-08-22 |
| GB201305900D0 (en) | 2013-05-15 |
| NO20130720A1 (en) | 2013-05-23 |
| CN103189594B (en) | 2018-11-16 |
| WO2012058144A2 (en) | 2012-05-03 |
| WO2012058144A3 (en) | 2012-08-16 |
| AU2011320622A1 (en) | 2013-05-02 |
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