CN103184569A - Light-storage fiber, manufacturing method thereof, and light-storage fabric - Google Patents
Light-storage fiber, manufacturing method thereof, and light-storage fabric Download PDFInfo
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- CN103184569A CN103184569A CN2011104550007A CN201110455000A CN103184569A CN 103184569 A CN103184569 A CN 103184569A CN 2011104550007 A CN2011104550007 A CN 2011104550007A CN 201110455000 A CN201110455000 A CN 201110455000A CN 103184569 A CN103184569 A CN 103184569A
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Abstract
The invention discloses light-storage fiber, a manufacturing method of the light-storage fiber, and a light-storage fabric. The fiber is manufactured by screw extrusion after a luminescent polymer is mixed with a light-storage agent, wherein the content of the light-storage agent is 10-25wt%. The light-storage agent is rare earth aluminate with a particle size of 1-20mum. A ratio of a light-storage agent average particle size d to a fiber diameter D is below 0.5. A continuous luminous time of the obtained fiber is longer than 6h. When the light-storage fabric is washed 50 times, a continuous luminous time is still longer than 6h.
Description
Technical field
The present invention relates to a kind of light storage fiber, its manufacture method and hold the light fabric by what this light storage fiber made.
Background technology
Light storage fiber is a kind of novel textile material, this fiber is behind radiation of visible light, light can be stored among the fiber, when being placed on dark state following time, the sustainable luminous quite a while of fiber, can be widely used in fields such as easy suit, full dress, caution clothes, ornament, safety sign to satisfy the needs of various different occasions.
The development technique of light storage fiber and the performance of phosphor are closely related, the conventional fluorescent powder because of poor stability, have shortcoming such as radioactivity and be difficult to use in the light storage fiber that exploitation has practical value.
The technology of preparing of light storage fiber can be divided into three kinds of methods at present: (1) coating; (2) composite spinning method; (3) co-blended spinning method.
Patent CN1346857 discloses a kind of luminous coating composition, but by the coating composition that adhesive and luminescent fibre are formed, is used for the mark of object.Coating or method for printing are simple relatively, and applicable to multiple fiber and fabric, but it is easy to peel off, and service life is shorter.
Patent CN1349007A discloses a kind of luminous composite fibre, this composite fibre is the core-shell-type composite fibre, the mylar that mylar or vistanex by noctilucence pigment make the core composition, do not contain noctilucence pigment is made shell component, but be in the core hold the light particle hold light effect because the obstruction performance of shell component is not obvious.
The co-blended spinning method is the method for preparing luminescent fibre commonly used.The co-blended spinning method is divided into direct blending and master batch blending method again.Direct blending is because light-accumulating agent and polymer flow speed differ the light-accumulating agent skewness.Patent CN1374415 discloses a kind of manufacture method of RE luminous fiber, be in stated polyesters section, add luminous agent and nano assistant make the noctilucence master batch after with big bright PET chips co-blended spinning, but the intensity of this fiber is on the low side.
Summary of the invention
The object of the present invention is to provide the manufacture method of a kind of long-acting light storage fiber, this fiber and the fabric of being made by this fiber.The lasting fluorescent lifetime of this fiber is long, and the interpolation of light-accumulating agent can not exert an influence to the intensity of fiber, still can keep long fluorescent lifetime after the fabric washing repeatedly.
Technical solution of the present invention is:
A kind of light storage fiber is prepared from after extruding through screw rod after having photopolymer and light-accumulating agent to mix, and wherein the content of light-accumulating agent is 10～25wt%; Described light-accumulating agent is rare earth aluminate, and its particle diameter is 1～20 μ m, and the ratio of light-accumulating agent average grain diameter d and fibre diameter D is below 0.5.
Light-accumulating agent used in the present invention is process Eu
2+The alkali earth metal aluminate that activates, its chemical stability is good, and is nontoxic, "dead", brightness is high, fluorescent lifetime is long, heat resisting temperature is more than 220 ℃.The content of light-accumulating agent is 10～25wt% in the fiber, and when light-accumulating agent content was less than 10wt% in the fiber, the amount of fiber unit volume light-accumulating agent was fewer, did not reach the long-acting light effect that holds; And when light-accumulating agent content in the fiber greater than 25% the time because a large amount of existence of light-accumulating agent, the spinnability variation of polymer, the rerum natura of fiber reduce.Preferred 15～the 20wt% of its content, in this scope, fiber can either reach the long-acting light effect that holds, and its rerum natura can not reduce because of the existence of light-accumulating agent yet.
The particle diameter of light-accumulating agent used in the present invention is 1～20 μ m, its particle diameter is more little, and the dispersiveness in polymer is more good, if but the particle diameter of light-accumulating agent is too little, in process, light-accumulating agent is penetrated into fiber surface easily to be caused holding the hold optical property of light fabric after washing and declines to a great extent.Preferred 5～15 μ m of the particle diameter of light-accumulating agent.The particle diameter d of light-accumulating agent of the present invention and the ratio of fibre diameter D can guarantee the throwing that polymer is good again like this below 0.5 when guaranteeing the light-accumulating agent good dispersion.If the ratio of the particle diameter d of light-accumulating agent and fibre diameter D is greater than 0.5, because the size ratio of light-accumulating agent is bigger, form at the screen pack place easily in the spinning process and pile up, cause spinning pressure to rise, finally obtain in the fiber light-accumulating agent content and be not inconsistent with initial addition, it is not obvious to hold light effect.
It is above-mentioned that photopolymer is arranged is that the content of wherein titanium compound has photopolymer greatly, preferred glossy polyester or the light polyamide is arranged less than 0.2wt%.
The intensity of above-mentioned fiber is more than the 3.0cN/dtex, and degree of stretching is 20～50%, continues fluorescent lifetime more than 6 hours.
The manufacture method of light storage fiber of the present invention is, light-accumulating agent is added by positive displacement powder adding set, with have photopolymer to mix after extrude through screw rod and to make light storage fiber; The addition of described light-accumulating agent is 10～25wt% of final light storage fiber total amount; Described light-accumulating agent is rare earth aluminate, and its particle diameter is 1～20 μ m, and the ratio of light-accumulating agent average grain diameter d and fibre diameter D is below 0.5.
When will have photopolymer section to import to be arranged on the feed bin directly over the screw extruder charging aperture, in feed bin, add light-accumulating agent by the opening pipe arrangement continuously; Said opening pipe arrangement is arranged on from below that part is piled up in section in the feed bin upwards to 10%～50% position of the piling height of cutting into slices position straight down.
The invention still further relates to a kind of light fabric that holds, contain the above-mentioned light storage fiber of 50wt% in this fabric at least, and this fabric through 50 times the washing after lasting fluorescent lifetime be more than 6 hours.This is held the light textile dyeing, test that it is fast light, colorfastness to rubbing is all more than 4 grades.
Gained light storage fiber of the present invention has the better spinnability energy, and physical property is close with general polyester/polyamide fiber.And low, the easy operating of manufacture method cost of fiber.The fabric that is obtained by this fiber production still can keep long fluorescent lifetime after repeatedly washing.
The performance of above-mentioned light storage fiber and fabric adopts following method to test:
1, continue fluorescent lifetime:
Adopt the illumination 10 minutes of the D65 light source of 400lx, remove light source, after 6 hours in the naked eye observed every 1 hour, estimate by following benchmark,
◎: the same with postradiation residual luminous intensity, naked eyes can obviously be observed,
Zero: than postradiation residual luminous intensity a little a little less than, naked eyes can be observed,
△: naked eyes can be observed residual light a little,
*: naked eyes can not be observed residual light.
2, fibre strength:
Earlier tested fiber is carried out damping and handle, picked at random is through the tested fiber of damping, the fiber head end is clamped in goes up in the clamper, adds suitable pre-tension, and fiber is fixed in the lower gripper, finishes the fixing of tested fiber.Tested fiber is stretched, until fibrous fracture.The intensity of fibrous fracture point is fibre strength.
3, light resistance: test according to GB/T 8427-1998.
4, washing: carry out according to GB/T 3921.1-1997.
5, colorfastness to rubbing: test according to GB/T 3920-1997.
6, spinnability:
Spinning situation in the spinning 2 hours is estimated by following method, zero and △ be judged to be qualified,
Zero: no fracture of wire,
△: a small amount of fracture of wire (1～3 time) is arranged,
*: fracture of wire is frequent.
The specific embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1
Be that 15 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before glossy polyester enters screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 10wt% of final light storage fiber total amount.Mixed glossy polyester and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 280～295 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, preliminary draft, batch (coiling speed is 2700m/min) and handle finally by spinnerets, obtain the preorientation fiber.The preorientation fiber that obtains is carried out drawing-off processing, and the drawing-off multiplying power is 1.75, processing temperature is 90 ℃/130 ℃, coiling speed 500m/min, obtains light storage fiber.After tested, the fracture strength of gained fiber is 3.75cN/dtex, and degree of stretching is that 39.4%, d/D is 0.4, and the photosensitiveness that holds of fiber sees Table 1.
Light storage fiber made hold the light fabric, contain 60%, 130 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Embodiment 2
Be that 10 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before glossy polyester enters screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 15wt% of final light storage fiber total amount.Mixed glossy polyester and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 280～295 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, preliminary draft, batch (coiling speed is 2700m/min) and handle finally by spinnerets, obtain the preorientation fiber.The preorientation fiber that obtains is carried out drawing-off processing, and the drawing-off multiplying power is 1.75, processing temperature is 90 ℃/130 ℃, coiling speed 500m/min, obtains light storage fiber.After tested, the fracture strength of gained fiber is 3.45cN/dtex, and degree of stretching is that 38.4%, d/D is 0.3, and the photosensitiveness that holds of fiber sees Table 1.
Light storage fiber made hold the light fabric, contain 50%, 130 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Embodiment 3
Be that 10 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before glossy polyester enters screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 25wt% of final light storage fiber total amount.Mixed glossy polyester and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 280～295 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, preliminary draft, batch (coiling speed is 2700m/min) and handle finally by spinnerets, obtain the preorientation fiber.The preorientation fiber that obtains is carried out drawing-off processing, and the drawing-off multiplying power is 1.75, processing temperature is 90 ℃/130 ℃, coiling speed 500m/min, obtains light storage fiber.After tested, the fracture strength of gained fiber is 3.25cN/dtex, and degree of stretching is that 37.4%, d/D is 0.3, and the photosensitiveness that holds of fiber sees Table 1.
Light storage fiber made hold the light fabric, contain 50%, 130 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Embodiment 4
Be that 20 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before having the light polyamide to enter screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 10wt% of final light storage fiber total amount.Mixed have light polyamide and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 250～275 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, extend, batch (coiling speed is 4590m/min) and handle finally by spinnerets, obtain the FDY light storage fiber.After tested, the fracture strength of gained fiber is 4.75cN/dtex, and degree of stretching is that 45.5%, d/D is 0.5, and the photosensitiveness that holds of fiber sees Table 1.
Light storage fiber made hold the light fabric, contain 60%, 98 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Embodiment 5
Be that 15 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before having the light polyamide to enter screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 15wt% of final light storage fiber total amount.Mixed have light polyamide and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 250～275 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, extend, batch (coiling speed is 4590m/min) and handle finally by spinnerets, obtain the FDY light storage fiber.After tested, the fracture strength of gained fiber is 4.65cN/dtex, and degree of stretching is that 44.5%, d/D is 0.4, and the photosensitiveness that holds of fiber sees Table 1.
Light storage fiber made hold the light fabric, contain 50%, 98 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 5 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Embodiment 6
Be that 5 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before having the light polyamide to enter screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 15wt% of final light storage fiber total amount.Mixed have light polyamide and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 250～275 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, extend, batch (coiling speed is 4590m/min) and handle finally by spinnerets, obtain the FDY light storage fiber.After tested, the fracture strength of gained fiber is 4.45cN/dtex, and degree of stretching is that 43.5%, d/D is 0.2, and the photosensitiveness that holds of fiber sees Table 1.
Light storage fiber made hold the light fabric, contain 50%, 98 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Comparative example 1
Be that 20 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before glossy polyester enters screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 5wt% of final light storage fiber total amount.Mixed glossy polyester and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 280～295 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, preliminary draft, batch (coiling speed is 2700m/min) and handle finally by spinnerets, obtain the preorientation fiber.The preorientation fiber that obtains is carried out drawing-off processing, and the drawing-off multiplying power is 1.75, processing temperature is 90 ℃/130 ℃, coiling speed 500m/min, obtains fiber.After tested, the fracture strength of gained fiber is 3.85cN/dtex, and degree of stretching is that 38.4%, d/D is 0.5, and the photosensitiveness that holds of fiber sees Table 1.
Fiber is made fabric, contain 60%, 130 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Comparative example 2
Be that 15 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before glossy polyester enters screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 30wt% of final light storage fiber total amount.Mixed glossy polyester and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 280～295 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, preliminary draft, batch (coiling speed is 2700m/min) and handle finally by spinnerets, obtain the preorientation fiber.The preorientation fiber that obtains is carried out drawing-off processing, and the drawing-off multiplying power is 1.75, processing temperature is 90 ℃/130 ℃, coiling speed 500m/min, obtains fiber.After tested, the fracture strength of gained fiber is 2.75cN/dtex, and degree of stretching is that 38.6%, d/D is 0.5, and the photosensitiveness that holds of fiber sees Table 1.
Fiber is made fabric, contain 40%, 130 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 3 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Comparative example 3
Be that 15 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before having the light polyamide to enter screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 5wt% of final light storage fiber total amount.Mixed have light polyamide and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 250～275 ℃, and polymer melt is transported to measuring pump successively, spinning manifold, filament spinning component, extrude finally by spinnerets, cooling, oil supply, interlacing, extend, batching (coiling speed is 4590m/min) handles, obtain the FDY fiber. after tested, the fracture strength of gained fiber is 4.85cN/dtex, degree of stretching is 46.5%, d/D is 0.5, and the photosensitiveness that holds of fiber sees Table 1.
Fiber is made fabric, contain 60%, 98 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 4 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Comparative example 4
Be that 15 μ m light-accumulating agent rare earth aluminates add by positive displacement powder adding set with particle diameter, before having the light polyamide to enter screw rod, mix with it, control both interpolation speed, make that the addition of light-accumulating agent is the 30wt% of final light storage fiber total amount.Mixed have light polyamide and light-accumulating agent through the melt extruded of screw extruder become can spinning polymer melt, the melt extruded process of screw extruder is provided with 3～5 sections thermals treatment zone, the heating-up temperature in each district is made as 250～275 ℃, and polymer melt is transported to measuring pump, spinning manifold, filament spinning component successively, extrude, cooling, oil supply, interlacing, extend, batch (coiling speed is 4590m/min) and handle finally by spinnerets, obtain the FDY fiber.After tested, the fracture strength of gained fiber is 3.55cN/dtex, and degree of stretching is that 46.5%, d/D is 0.5, and the photosensitiveness that holds of fiber sees Table 1.
Fiber is made fabric, contain 40%, 98 ℃ of light storage fiber in this fabric down behind the dyeing 60min, test its light resistance, colorfastness to rubbing is 3 grades, the hold photosensitiveness of fabric after through 50 washings sees Table 1.
Claims (6)
1. light storage fiber is characterized in that: described fiber is prepared from after extruding through screw rod after having photopolymer and light-accumulating agent to mix, and wherein the content of light-accumulating agent is 10～25wt%; Described light-accumulating agent is rare earth aluminate, and its particle diameter is 1～20 μ m, and the ratio of light-accumulating agent average grain diameter d and fibre diameter D is below 0.5.
2. light storage fiber according to claim 1 is characterized in that: described photopolymer is arranged is glossy polyester or the light polyamide is arranged.
3. light storage fiber according to claim 1 and 2, it is characterized in that: the intensity of described fiber is more than the 3.0cN/dtex.
4. light storage fiber according to claim 1 and 2, it is characterized in that: the lasting fluorescent lifetime of described fiber is more than 6 hours.
5. the manufacture method of the described light storage fiber of claim 1 is characterized in that: light-accumulating agent is added by positive displacement powder adding set, with have photopolymer to mix after extrude through screw rod and to make light storage fiber; The addition of described light-accumulating agent is 10～25wt% of final light storage fiber total amount; Described light-accumulating agent is rare earth aluminate, and its particle diameter is 1～20 μ m, and the ratio of light-accumulating agent average grain diameter d and fibre diameter D is below 0.5.
6. one kind is held the light fabric, it is characterized in that: contain 50wt% light storage fiber as claimed in claim 1 in the described fabric at least, and this fabric through 50 times the washing after lasting fluorescent lifetime be more than 6 hours.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104088028A (en) * | 2014-07-08 | 2014-10-08 | 南通华纶化纤有限公司 | Preparation method of fluorescent chemical fibers |
| CN105133142A (en) * | 2015-09-25 | 2015-12-09 | 太仓市虹鹰印花有限公司 | Fabric with light-storing special effect |
| JP2020186502A (en) * | 2019-05-16 | 2020-11-19 | 青▲島▼永利良品国▲際▼▲貿▼易有限公司 | Luminous woven fabric, and preparation method and application thereof |
| CN112810261A (en) * | 2020-12-31 | 2021-05-18 | 际华三五零九纺织有限公司 | Novel insulating light-storing fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215731A (en) * | 2008-01-08 | 2008-07-09 | 浙江东华纤维制造有限公司 | Method for preparing self-luminescence polyester chopped fiber |
| CN101298705A (en) * | 2008-05-26 | 2008-11-05 | 清华大学深圳研究生院 | Method for preparing luminous Lyocell fibre |
| CN101759963A (en) * | 2008-12-18 | 2010-06-30 | 上海馨笛伦实业有限公司 | Color luminous polyester plastic piece and manufacture method of short fibers thereof |
| CN102086536A (en) * | 2009-12-03 | 2011-06-08 | 刘达 | Luminous polyamide fiber, manufacturing method thereof and fabric knitted by using luminous polyamide fiber |
| CN102150960A (en) * | 2010-12-08 | 2011-08-17 | 吴江市合欣转移印花有限公司 | Colorful fluorescent fabric |
-
2011
- 2011-12-31 CN CN2011104550007A patent/CN103184569A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215731A (en) * | 2008-01-08 | 2008-07-09 | 浙江东华纤维制造有限公司 | Method for preparing self-luminescence polyester chopped fiber |
| CN101298705A (en) * | 2008-05-26 | 2008-11-05 | 清华大学深圳研究生院 | Method for preparing luminous Lyocell fibre |
| CN101759963A (en) * | 2008-12-18 | 2010-06-30 | 上海馨笛伦实业有限公司 | Color luminous polyester plastic piece and manufacture method of short fibers thereof |
| CN102086536A (en) * | 2009-12-03 | 2011-06-08 | 刘达 | Luminous polyamide fiber, manufacturing method thereof and fabric knitted by using luminous polyamide fiber |
| CN102150960A (en) * | 2010-12-08 | 2011-08-17 | 吴江市合欣转移印花有限公司 | Colorful fluorescent fabric |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104088028A (en) * | 2014-07-08 | 2014-10-08 | 南通华纶化纤有限公司 | Preparation method of fluorescent chemical fibers |
| CN105133142A (en) * | 2015-09-25 | 2015-12-09 | 太仓市虹鹰印花有限公司 | Fabric with light-storing special effect |
| JP2020186502A (en) * | 2019-05-16 | 2020-11-19 | 青▲島▼永利良品国▲際▼▲貿▼易有限公司 | Luminous woven fabric, and preparation method and application thereof |
| CN112810261A (en) * | 2020-12-31 | 2021-05-18 | 际华三五零九纺织有限公司 | Novel insulating light-storing fabric |
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Application publication date: 20130703 |