CN103160206A - Vacuum electroplating primer as well as preparation method and application for same - Google Patents
Vacuum electroplating primer as well as preparation method and application for same Download PDFInfo
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- CN103160206A CN103160206A CN2013101048535A CN201310104853A CN103160206A CN 103160206 A CN103160206 A CN 103160206A CN 2013101048535 A CN2013101048535 A CN 2013101048535A CN 201310104853 A CN201310104853 A CN 201310104853A CN 103160206 A CN103160206 A CN 103160206A
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- vacuum plating
- priming paint
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- plating priming
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Abstract
The invention discloses a vacuum electroplating primer. The prescription of the vacuum electroplating primer comprises the following components in percentage by weight: 10-30% of urethane acrylate, 5-10% of butyl acrylate, 5-10% of hydroxyethyl methacrylate, 5-20% of modified epoxy acrylate, 0-10% of vinyl chloride-acetate copolymer resin, 1-6% of initiator, 20-60% of solvent, and 0.1-0.5% of auxiliaries. The invention further discloses a preparation method and an application for the vacuum electroplating primer. The vacuum electroplating primer disclosed by the invention has an adhesive force on a flexible material and can bend without cracks, so that the problem of electroplating on the flexible material is solved.
Description
Technical field
The present invention relates to a kind of vacuum plating priming paint and its production and use, be specifically related to vacuum plating priming paint on the ultra-soft material and its production and use.
Background technology
Electroplating (Electroplating) utilizes electrolysis principle to plate the process of other metal or alloy of skim on some metallic surface, be to utilize electrolytic action that thereby the technique of the surface attachment layer of metal film of metal or other material product is played to prevent from corrosion from improving the effects such as wear resistance, electroconductibility, reflective and having improved aesthetic appearance.
1) water power plating claims again wet method to electroplate, as the term suggests relevant with water and the aqueous solution, principle of electrochemical reaction is chemical process.Owing to making in a large number water/aqueous solution, pollute large.
2) ultraviolet ray (UV) plated film, use UV coating, at vacuum or ultralow pressure state, utilizes the effect of electric field, makes UV coating move to coated piece surface, and this process is physical process.The part of coated UV coating under the effect of ultraviolet ray (UV), solidifies.This technology is widely used in the outward appearances such as small electric apparatus, electronic product, cosmetic packaging box and applies.
3) vacuum plating is in the ultralow pressure container, utilizes the transporting action of electric field to a kind of technique of plating piece metallizing, metallic compound or non-metallic coating.
The vacuum plating classification is more, and using is the electric field migrating technology more widely.The UV vacuum plating belongs to the vacuum plating category.
The common softness of material that conventional vacuum is electroplated the priming paint plating is 100R (Rockwell hardness).Conventional vacuum is electroplated priming paint and is fit to use on the hard material.
The following difficulty that has at the enterprising electroplating of soft material:
(1) on soft material, poor adhesive force and easy bend resistance.
(2) after electroplating on soft material, plate surface easily ftractures.
When (3) softness reaches the Shore65A index, can't realize electroplating effect.
Summary of the invention
The object of the invention is to, a kind of vacuum plating priming paint and its production and use is provided, to overcome the existing above-mentioned shortcoming and defect of prior art.The present invention is a kind of vacuum plating priming paint that is applicable on the ultra-soft material.
The technical problem that will solve required for the present invention can be achieved through the following technical solutions:
As a first aspect of the present invention, a kind of vacuum plating priming paint is characterized in that, according to weight percent meter, its formula is:
Wherein, described initiator is 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO), 2-hydroxy-2-methyl-1-phenyl-1-acetone are called for short any one or combination of HMPF (vapour bar Ciba company the trade mark be the product of DAROCUR1173), 1-hydroxyl-cyclohexyl-phenyl ketone (vapour bar Ciba company the trade mark be the product of IRGACURE184), benzophenone (BP).
Wherein, described solvent is any one or combination of toluene (TOLUENE), pimelinketone (CYC), mibk (MIBK), ethyl acetate (EAC).
Wherein, described auxiliary agent is flow agent, is the BYK306 product as the trade mark of German Bi Ke.
As a second aspect of the present invention, a kind of preparation method of vacuum plating priming paint is characterized in that: comprise the following steps:
Step 1: according to formula, resin and monomer are added in Scattered Kettle, open stirring at low speed 25～35min;
Step 2: open high speed dispersion and stop after 1 hour stirring after mixing of materials is even;
Step 3: add in proportion light trigger, auxiliary agent, solvent, high speed dispersion stopped after 1 hour, can make coating of the present invention.
Wherein, in step 1, the rotating speed of described stirring at low speed is 500-800r/min.
Wherein, in step 2, the rotating speed of described high speed dispersion is 1200-1500r/min.
As a third aspect of the present invention, a kind of purposes of vacuum plating priming paint is characterized in that: be used for the vacuum plating on soft material.
Beneficial effect of the present invention:
The present invention is vacuum plating priming paint, and the present invention not only has sticking power and bending not to ftracture on soft material, has solved the problem of electroplating on soft material.
Embodiment
Below in conjunction with specific embodiment, the present invention is done progressive explanation.Should be understood that following examples are only for explanation the present invention but not for limiting scope of the present invention.
Soft material refers to be designated as the material of Shore85A.
The ultra-soft material is the material of index Shore65A.
Embodiment 1
A kind of vacuum plating priming paint, according to weight percent meter, its formula is:
Initiator is 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO), 2-hydroxy-2-methyl-1-phenyl-1-acetone are called for short HMPF (vapour bar Ciba company the trade mark be the product of DAROCUR1173), 1-hydroxyl-cyclohexyl-phenyl ketone (vapour bar Ciba company the trade mark be the product of IRGACURE184), benzophenone (BP).
Solvent is toluene (TOLUENE), pimelinketone (CYC), mibk (MIBK), ethyl acetate (EAC)
Auxiliary agent is flow agent, and the trade mark of selecting German Bi Ke is the BYK306 product.
Table 1 detected result weight percent meter (wt%)
Embodiment 2
A kind of preparation method of vacuum plating priming paint comprises the following steps:
Step 1: according to the formula of table 1, resin and monomer are added in Scattered Kettle according to the following formulation, open the 500-800r/min stirring at low speed, stir 30min;
Step 2: open the 1200-1500r/min high speed dispersion after mixing of materials is even, stops after 1 hour stirring;
Step 3: add in proportion light trigger, auxiliary agent, solvent, high speed dispersion stopped after 1 hour, namely got target product.
Embodiment 3
Hundred lattice are adopted in the detection of vacuum plating priming paint, and bending method or standard detect, and result is as shown in table 2.
Comparative Examples 1 is used for vacuum plating priming paint product on ABS for Shanghai long happy coating company limited.
Another is used for the vacuum plating priming paint product on PC to Comparative Examples 2 for the Shanghai happy coating of length company limited.
Table 2 detected result
| ? | Formula 1 | Formula 2 | Formula 3 | Comparative Examples 1 | Comparative Examples 2 |
| Hundred lattice | OK | NG | OK | NG | NG |
| Do not ftracture after bending | OK | OK | NG | NG | NG |
From the data of table 2, can find out, sticking power and the toughness of product on soft base material of the present invention's preparation is better than Comparative Examples 1 and Comparative Examples 2.Wherein, formula 1 is preferred formula.
Above the specific embodiment of the present invention is illustrated, but the present invention is as limit, only otherwise break away from aim of the present invention, the present invention can also have various variations.
Claims (8)
1. a vacuum plating priming paint, is characterized in that, according to weight percent meter, its formula is:
2. vacuum plating priming paint according to claim 1; it is characterized in that: described initiator is 2; any one of 4,6-trimethylbenzoyl-diphenyl phosphate oxidation, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone, benzophenone or combination.
3. vacuum plating priming paint according to claim 1 is characterized in that: described solvent is any one or combination of toluene, pimelinketone, mibk and ethyl acetate.
4. vacuum plating priming paint according to claim 1, it is characterized in that: described auxiliary agent is flow agent.
5. the preparation method of a vacuum plating priming paint as claimed in claim 1 is characterized in that: comprise the following steps:
Step 1: according to formula, resin and monomer are added in Scattered Kettle, open stirring at low speed 25～35min:
Step 2: open high speed dispersion and stop after 1 hour stirring after mixing of materials is even;
Step 3: add in proportion light trigger, auxiliary agent, solvent, high speed dispersion stopped after 1 hour, namely got target product.
6. preparation method according to claim 5, it is characterized in that: in step 1, the rotating speed of described stirring at low speed is 500-800r/min.
7. preparation method according to claim 5, it is characterized in that: in step 2, the rotating speed of described high speed dispersion is 1200-1500r/min.
8. the purposes of vacuum plating priming paint as described in claim 1, is characterized in that: be used for the vacuum plating on soft material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101048535A CN103160206A (en) | 2013-03-28 | 2013-03-28 | Vacuum electroplating primer as well as preparation method and application for same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101048535A CN103160206A (en) | 2013-03-28 | 2013-03-28 | Vacuum electroplating primer as well as preparation method and application for same |
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| CN103160206A true CN103160206A (en) | 2013-06-19 |
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| CN2013101048535A Pending CN103160206A (en) | 2013-03-28 | 2013-03-28 | Vacuum electroplating primer as well as preparation method and application for same |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1803942A (en) * | 2005-12-26 | 2006-07-19 | 中国化工建设总公司常州涂料化工研究院 | Ultraviolet curing coating for metal plating surface protection |
| CN101280154A (en) * | 2007-04-06 | 2008-10-08 | 上海海优威电子技术有限公司 | Ultraviolet curing vacuum metallizing coating |
| CN102167951A (en) * | 2011-05-30 | 2011-08-31 | 江苏宏泰高分子材料有限公司 | Environment-friendly dual-curing vacuum coating primer special for automobile wheel hub |
| WO2013037277A1 (en) * | 2011-09-14 | 2013-03-21 | 中国科学院化学研究所 | Uv-curable ink for direct plate making by ink-jet printing with preparation method and application therefor |
-
2013
- 2013-03-28 CN CN2013101048535A patent/CN103160206A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1803942A (en) * | 2005-12-26 | 2006-07-19 | 中国化工建设总公司常州涂料化工研究院 | Ultraviolet curing coating for metal plating surface protection |
| CN101280154A (en) * | 2007-04-06 | 2008-10-08 | 上海海优威电子技术有限公司 | Ultraviolet curing vacuum metallizing coating |
| CN102167951A (en) * | 2011-05-30 | 2011-08-31 | 江苏宏泰高分子材料有限公司 | Environment-friendly dual-curing vacuum coating primer special for automobile wheel hub |
| WO2013037277A1 (en) * | 2011-09-14 | 2013-03-21 | 中国科学院化学研究所 | Uv-curable ink for direct plate making by ink-jet printing with preparation method and application therefor |
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Owner name: SHAOGUAN CHANGYUE HIGH MOLECULAR MATERIAL CO., LTD Free format text: FORMER OWNER: SHANGHAI CHANGYUE COATING CO., LTD. Effective date: 20130722 |
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Free format text: CORRECT: ADDRESS; FROM: 201706 QINGPU, SHANGHAI TO: 512400 SHAOGUAN, GUANGDONG PROVINCE |
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Effective date of registration: 20130722 Address after: 512400 Guangdong city of Nanxiong province Abas Industrial Park Development Road No. 1 Applicant after: Shaoguan Long Yue polymer materials Co., Ltd. Address before: 201706 Shanghai city Qingpu District Songhua Road No. 1388 Applicant before: Shanghai Changyue Coating Co., Ltd. |
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Application publication date: 20130619 |