CN103146877B - Steelmaking refining agent containing bamboo charcoal and preparation method thereof - Google Patents

Steelmaking refining agent containing bamboo charcoal and preparation method thereof Download PDF

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Publication number
CN103146877B
CN103146877B CN201310042859.4A CN201310042859A CN103146877B CN 103146877 B CN103146877 B CN 103146877B CN 201310042859 A CN201310042859 A CN 201310042859A CN 103146877 B CN103146877 B CN 103146877B
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parts
bamboo charcoal
refining agent
agent containing
powder
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CN103146877A (en
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沈升好
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Jiangsu Binxin Steel Group Co Ltd
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Anhui Fanchang Wannan Valve Casting Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses a steelmaking refining agent containing bamboo charcoal and a preparation method of the steelmaking refining agent containing the bamboo charcoal. The steelmaking refining agent containing the bamboo charcoal comprises the following raw materials, by weight, 28 parts-32 parts of calcium fluoride, 18 parts-22 parts of ferric oxide, 17 parts-19 parts of boron carbide, 15 parts-17 parts of iron-ore slag, 10 parts-15 parts of the bamboo charcoal, 6 parts-8 parts of fluorite slag, 20 parts-25 parts of water talcum powder, and 3 parts-5 parts of modified nanometer powder. According to the steelmaking refining agent containing the bamboo charcoal, the calcium fluoride and the ferric oxide are used as main raw materials, the bamboo charcoal, the fluorite slag, the water talcum powder and the modified nanometer powder are added into the steelmaking refining agent containing the bamboo charcoal, waste is turned into wealth, an adsorptive property of the steelmaking refining agent containing the bamboo charcoal is made full used of, effects of desulfuration and dephosphorization are good, phenomena of rephosphorization are reduced, and meanwhile due to the fact that content of the calcium fluoride is high, production cost is reduced.

Description

A kind of steel-making refining agent that contains bamboo charcoal
Technical field
The present invention relates to steelmaking technical field, be specifically related to a kind of steel-making refining agent that contains bamboo charcoal and preparation method thereof.
Background technology
At present, STEELMAKING PRODUCTION rate and cost and steel products quality have been proposed to more and more higher requirement, for being applicable to this requirement, external refining particularly ladle furnace refining becomes the important production process in modern refining flow process, be used widely at each smelter, a main metallurgical function of ladle furnace refining is to utilize refining agent to carry out refining to molten steel, to reach the object that reduces steel water oxygen, sulphur and inclusion content, the performance that improves steel, refining agent kind is a lot.
Summary of the invention
The object of the present invention is to provide a kind of steel-making refining agent that contains bamboo charcoal and preparation method thereof, bamboo charcoal, fluorite slag, neatly stone flour and modified Nano powder in refining agent formula of the present invention, are increased, take full advantage of its absorption property, refining agent desulfurization, dephosphorization effect are good, and cost is low.
The present invention adopts following technical scheme to achieve these goals:
The steel-making refining agent that contains bamboo charcoal, the weight part of its constitutive material is: Calcium Fluoride (Fluorspan) 28-32, ferric oxide 18-22, norbide 17-19, Iron-ore Slag 15-17, bamboo charcoal 10-15, fluorite slag 6-8, neatly stone flour 20-25 and modified Nano powder 3-5.
The steel-making refining agent that contains bamboo charcoal, the weight part of its constitutive material is: Calcium Fluoride (Fluorspan) 30, ferric oxide 20, norbide 18, Iron-ore Slag 16, bamboo charcoal 12, fluorite slag 7, neatly stone flour 22 and modified Nano powder 4.
The preparation method of the steel-making refining agent that contains bamboo charcoal, comprises the following steps:
(1) fragmentation: each raw material is broken respectively with crusher;
(2) mix: each raw material good fragmentation, by formula requirement mixing, and is mixed with ball mill;
(3) sieve: the raw material mixing is sieved with 150 eye mesh screens;
(4) dry: the raw material after sieving is placed in baking oven and is toasted, remove moisture, storing temperature is 90-120 DEG C, according to the volatilization extent control baking time of moisture.
The preparation method of described modified Nano powder is as follows: sepiolite powder is melted at temperature 1600-1700 DEG C, add the plant ash agitating of the iron powder, the 1-2% that are equivalent to its weight 2-4% even, pour in cold water, dry, be ground into powder.
Beneficial effect of the present invention:
The present invention is taking Calcium Fluoride (Fluorspan) and ferric oxide as main raw material, bamboo charcoal, fluorite slag, neatly stone flour and modified Nano powder are wherein added, turn waste into wealth, take full advantage of its absorption property, refining agent desulfurization, dephosphorization effect are good, have reduced rephosphorization phenomenon, simultaneously, wherein Calcium Fluoride Content is high, has reduced production cost.
Embodiment
Embodiment 1: the steel-making refining agent that contains bamboo charcoal, the weight part (kg) of its constitutive material is: Calcium Fluoride (Fluorspan) 30, ferric oxide 20, norbide 18, Iron-ore Slag 16, bamboo charcoal 12, fluorite slag 7, neatly stone flour 22 and modified Nano powder 4.
The preparation method of the steel-making refining agent that contains bamboo charcoal, comprises the following steps:
(1) fragmentation: each raw material is broken respectively with crusher;
(2) mix: each raw material good fragmentation, by formula requirement mixing, and is mixed with ball mill;
(3) sieve: the raw material mixing is sieved with 150 eye mesh screens;
(4) dry: the raw material after sieving is placed in baking oven and is toasted, remove moisture, storing temperature is 105 DEG C, according to the volatilization extent control baking time of moisture.
The preparation method of described modified Nano powder is as follows: sepiolite powder is melted at temperature 1600-1700 DEG C, add that to be equivalent to iron powder, 2% the plant ash agitating of its weight 4% even, pour in cold water, dry, be ground into powder.
Below in conjunction with the Preparation Example of above-mentioned refining agent, specifically describe the using method of steel-making refining agent of the present invention:
Adopt the refining agent described in embodiment 1, addition method routinely, a point secondary adds, and test molten steel is surrounded by No. 1-5, and desulfurization, sulphur phosphorus effect are as following table:
No. 1: molten steel condition: S 0.037%, P 0.169%; Desulfurization degree 61%, dephosphorization rate 45%;
No. 2: molten steel condition: S 0.043%, P 0.164%; Desulfurization degree 51%, dephosphorization rate 50%;
No. 3: molten steel condition: S 0.042%, P 0.162%; Desulfurization degree 52%, dephosphorization rate 53%;
No. 4: molten steel condition: S 0.046%, P 0.167%; Desulfurization degree 47%, dephosphorization rate 47%;
No. 5: molten steel condition: S 0.039%, P 0.165%; Desulfurization degree 58%, dephosphorization rate 49%.
Illustrate that refining agent of the present invention has higher desulfurization, sulphur phosphorus rate, and good stability, cost is lower, can substantially meet steel mill's technical requirements.

Claims (2)

1. contain a steel-making refining agent for bamboo charcoal, it is characterized in that the weight part of its constitutive material is: Calcium Fluoride (Fluorspan) 28-32, ferric oxide 18-22, norbide 17-19, Iron-ore Slag 15-17, bamboo charcoal 10-15, fluorite slag 6-8, neatly stone flour 20-25 and modified Nano powder 3-5;
Its preparation method comprises the following steps:
(1) fragmentation: each raw material is broken respectively with crusher;
(2) mix: each raw material good fragmentation, by formula requirement mixing, and is mixed with ball mill;
(3) sieve: the raw material mixing is sieved with 150 eye mesh screens;
(4) dry: the raw material after sieving is placed in baking oven and is toasted, remove moisture, storing temperature is 90-120 DEG C, according to the volatilization extent control baking time of moisture;
The preparation method of described modified Nano powder is as follows: sepiolite powder is melted at temperature 1600-1700 DEG C, add the plant ash agitating of the iron powder, the 1-2% that are equivalent to its weight 2-4% even, pour in cold water, dry, be ground into powder.
2. the steel-making refining agent that contains bamboo charcoal according to claim 1, is characterized in that the weight part of its constitutive material is: Calcium Fluoride (Fluorspan) 30, ferric oxide 20, norbide 18, Iron-ore Slag 16, bamboo charcoal 12, fluorite slag 7, neatly stone flour 22 and modified Nano powder 4.
CN201310042859.4A 2013-02-04 2013-02-04 Steelmaking refining agent containing bamboo charcoal and preparation method thereof Active CN103146877B (en)

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Application Number Priority Date Filing Date Title
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CN103146877B true CN103146877B (en) 2014-06-11

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CN112593152A (en) * 2020-11-26 2021-04-02 安徽金阳金属结构工程有限公司 High-strength H-shaped steel for fabricated building and production process thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102758054A (en) * 2012-06-21 2012-10-31 芜湖县天海耐火炉料有限公司 Calcium-aluminium-silicon molten steel external refining agent and preparation method thereof

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Publication number Priority date Publication date Assignee Title
US20070084306A1 (en) * 2005-10-17 2007-04-19 Jones Jeremy A Composition for reducing steelmaking slag
WO2009152643A1 (en) * 2008-06-19 2009-12-23 鞍钢股份有限公司 An additive used in secondary refining process, the producing method and the application thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102758054A (en) * 2012-06-21 2012-10-31 芜湖县天海耐火炉料有限公司 Calcium-aluminium-silicon molten steel external refining agent and preparation method thereof

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Effective date of registration: 20190704

Address after: 222000 Xiangshi Village, Zhewang Town, Ganyu District, Lianyungang City, Jiangsu Province

Patentee after: JIANGSU BINXIN STEEL GROUP CO., LTD.

Address before: 241200 E Shan Industrial Park, Fanchang County, Wuhu, Anhui

Patentee before: Anhui Fanchang County Wannan Valve Casting Co.,Ltd.

TR01 Transfer of patent right