CN103146852B - Leather and leather product, and processing method thereof - Google Patents

Leather and leather product, and processing method thereof Download PDF

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Publication number
CN103146852B
CN103146852B CN201210320790.2A CN201210320790A CN103146852B CN 103146852 B CN103146852 B CN 103146852B CN 201210320790 A CN201210320790 A CN 201210320790A CN 103146852 B CN103146852 B CN 103146852B
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wax
liquid
leather
processing method
wax liquid
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CN103146852A (en
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欧阳海峰
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Huang Fuli
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Abstract

The invention provides a leather and a leather product, and a processing method thereof. The processing method comprises the following treatments on a defatted and depilated raw hide material: liming, deashing pickling, tanning, retanning and bottom dyeing, toggling drying, finishing, gloss oil spraying, ironing and milling. The finishing process is as below: dropwise adding liquid wax on back of a dry hide blank subjected to toggling drying, and infiltrating the liquid wax to the front of the dry hide blank to show liquid wax stain; rubbing the front of the dry hide blank with the liquid wax for 1-5 times, drying, and continuing to rub the liquid wax for 1-3 times; and spraying gloss oil on the hide blank applied with a cracking liquid and ironing the hide blank at the temperature 90-115DEG C for 3-15 s. The invention also provides the leather processed by the above method. Through improving the finishing process, the invention endows the appearance of the leather with rich color changes and varied texture, so as to produce different visual and sensory effects.

Description

A kind of leather and leatherware and working method thereof
Technical field
The present invention relates to a kind of leather and leatherware and working method thereof, belong to leather processing technical field.
Background technology
The development of leather industry and human lives and national economy is closely bound up, is the mainstay industry of light industry.At present, leatherware on market has had good, the fashionable and coloury feature of use properties, but be subject to the restriction of complete processing, leatherware is common " uniform " on style and tone, for example, can there is not notable difference in for example, outward appearance and feel with the homochromy naughty goods of style (case and bag), human consumer is in use difficult to embody individual character, even there will be the embarrassment of " collision ", in this case, even very high-grade goods, its quality and effect also can be had a greatly reduced quality.Along with improving constantly of consumption idea, people also improve the requirement of leather thereupon, human consumer of today not only payes attention to leather quality, and the abundant variation that brings of the outward appearance vision of more pursuing leatherware and the diversity effect of leather skin texture texture, thereby reach embodiment individual character, lead the object of trend.Therefore, personalization that how can more perfect embodiment leatherware, enriches leatherware and brings people's visual effect, to meet human consumer's higher demand, is the unremitting pursuit of people and yearning always.
Summary of the invention
Technical problem underlying solved by the invention is to provide a kind of working method of leather, by the improvement to covering with paint technique, make the outward appearance of leather there is abundant chromatic aberration and various skin texture texture, even if utilize same skin base to process the goods of identical style, also can produce different visions and sensory effects.
The present invention also provides a kind of leather and leatherware that utilizes aforesaid method processing.
The invention provides a kind of leather processing method capable, comprise the raw stock through degreasing depilation is handled as follows: liming, deliming pickling, tanning, retanning dye the end, toggling oven dry, covering with paint, blast finishing ink, it is soft to press, fall, wherein, described covering with paint technique is as follows:
Drip oily wax liquid at the reverse side of dry hide base of drying through toggling, and it is positive and manifest fuel-displaced wax liquid stain trace to make dripped oily wax liquid infiltrate into dry hide base;
Utilize oily wax liquid to carry out obliterating 1-5 time in dry hide base front, after it is dry, continue obliterating be full of cracks liquid 1-3 time;
Described leather processing method capable has also comprised that to obliterating the skin base of be full of cracks liquid carries out after blast finishing ink hot pressure 3-15 second at temperature 90-115 ℃.
The present invention is in covering with paint technique, and the raw material composition of used oil wax liquid can be (% by weight): oily 5-20%, wax 45-70%, permeate agent 5-15% and water 20-40%.
The present invention is in covering with paint technique, and the raw material composition of be full of cracks liquid used can be (% by weight): cracking resin for synthesizing 10-30%, casein 30-50%, permeate agent 2-8%, light agent 3-7% and water 20-40%.
The present invention is in covering with paint technique, and in this oil wax liquid, described grease separation, from vegetables oil or animal oil, is known in this field and conventional oil, and those skilled in the art can suitably select as required.
The present invention is in covering with paint technique, and in this oil wax liquid, described wax for example can be, petroleum wax and the derivatives such as paraffin, Microcrystalline Wax, Vaseline; The polyolefin-wax such as polyethylene wax, Poly Propylene Wax and derivative; The synthetic waxs such as Fischer-Tropsch wax; The natural series waxes such as rice wax, carnauba wax; Ester is that wax, department of botany's wax, animal are wax, SOLID ORGANIC silicon wax, montanin wax etc., is known in this field and conventional wax.
The present invention is in covering with paint technique, in this oil wax liquid, the effective constituent of described permeate agent is selected from alkylphenol polyoxyethylene, aliphatic alcohol polyethenoxy alcohol, aliphatic poly ammoniacum emulsion or aerosol-OT salt etc., be known in this field and conventional permeate agent, those skilled in the art can select as required.
The present invention is in covering with paint technique, in this be full of cracks liquid, the effective constituent of described permeate agent is selected from alkylphenol polyoxyethylene, aliphatic alcohol polyethenoxy alcohol, aliphatic poly ammoniacum emulsion or aerosol-OT salt etc., be known in this field and conventional permeate agent, those skilled in the art can select as required.
The present invention is in covering with paint technique, and in this be full of cracks liquid, described light agent is known to the skilled person and conventional leather polish, can select as required.
Method of the present invention is particularly useful for processing the finer and close rawhide of texture, such as various ox-hides, sheepskin, pigskin etc.
The present invention also provides a kind of leather, and this leather can be that the method for recording according to the present invention obtains.In the present invention, utilize the leather of this working method production because of the variation of its chromatic aberration and cortex skin texture, be also referred to as " month covering ".
Adopt " month covering " provided by the invention can the various case and bag of processing and fabricating, furniture or article overcoat (such as cell-phone cover, IPAD protective sleeve etc.), the grain effect on surface, makes it in numerous leathercrafts, can demonstrate noble quality, cultured and unusual.
Compared with prior art, technical scheme of the present invention has following beneficial effect:
The present invention has changed in conventional leather working method and has covered with paint, lacquer, colour wash, etc. technique,, traditional covering with paint processing requirement is at the dry hide base front face surface spraying daub of drying through toggling and wiping or waxing wet goods, require evenly to embrocate as much as possible, the final consistence of monoblock skin base on outward appearance and tone of pursuing, utilize the goods of such skin base processing also just inevitable uniform, and lacking individuality difference; And the present invention is dripped oiling wax liquid at the reverse side of skin base, again at positive obliterating oil wax liquid and be full of cracks liquid, and drip and be coated with and the ununiformity of obliterating process by control, thereby process and there is the abundant and various leather of skin texture texture of aberration, even if utilizing the goods that such leather is processed is same style, same to tone, for example can process various case and bag, can not there is duplicate appearance effect yet, user no longer worries the embarrassment that " collision " brings, more be beneficial to and meet that human consumer looks for novelty, the individual sexual demand of changes persuing, be also beneficial to the quality that promotes leathercraft.
Embodiment
For making the object, technical solutions and advantages of the present invention clearer, in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment in the present invention, those of ordinary skills, not making the every other embodiment obtaining under creative work prerequisite, belong to the scope of protection of the invention.
A kind of leather processing method capable, comprises being handled as follows through the raw stock of degreasing depilation: liming, deliming pickling, tanning, retanning dye the end, toggling oven dry, covering with paint, blast finishing ink, it is soft etc. to press, fall.
In the course of processing, the degreasing of rawhide depilation, and each manufacturing procedure except covering with paint, lacquer, colour wash, etc. operation, all implement according to common process, so the present invention is all not particularly limited these, in the situation that having met covering with paint processing requirement, all can changes as one sees fit or adjust.Below only master operation has been carried out to concise and to the point narration.
Liming technique is called again " alkali swelling ", refers to and adds alkali (the normally used Ca of being (OH) 2) to make skin expand into certain thickness, is beneficial to and cuts open layer.
Process for tanning is to utilize trivalent chromic ion that the collagen group of hide fiber is coupled together, and gives leather plentiful feel, increases the anti-tensile of leather, the intensity of anti tear.
Bottom technique is dyed in retanning can supplement tanning effect, improves content of tannin, can give leather certain color simultaneously.
Cover with paint, lacquer, colour wash, etc. the object of technique and be attractive in appearance, the disability defect of revising leather surface in order to increase leather surface, improve the durability of leather and increase the assortment of leather.
Blast finishing ink technique essence is that leather surface coatings is carried out suitably to reasonably protection.
In above-mentioned the method, cover with paint, lacquer, colour wash, etc. technique and be specially:
Drip oily wax liquid at the reverse side of dry hide base of drying through toggling, and it is positive and manifest fuel-displaced wax liquid stain trace to make dripped oily wax liquid infiltrate into dry hide base;
Utilize oily wax liquid to carry out obliterating 1-5 time in dry hide base front, after it is dry, continue obliterating be full of cracks liquid 1-3 time;
Described leather processing method capable has also comprised that to obliterating the skin base of be full of cracks liquid carries out after blast finishing ink hot pressure 3-15 second at temperature 90-115 ℃.
Through the skin base of oily wax liquid and be full of cracks liquid processing through the suitable processing of rubbing, surface presents irregular pattern and effect, the various case and bag goods that process can provide abundant aberration and the various grain pattern of skin texture texture changing, and are called in the present invention " month covering ".
In following specific embodiment, be only illustrated covering with paint, lacquer, colour wash, etc. technique, and other manufacturing procedure all completes according to the technological operation of leather processing routine and requirement, so repeat no more.
Embodiment 1
A kind of leather processing method capable, comprises processing through the raw stock of degreasing depilation: liming, deliming pickling, tanning, retanning dye the end, toggling oven dry, covering with paint, blast finishing ink, it is soft etc. to press, fall.
In above-mentioned technique, described covering with paint technique is as follows:
The composition of raw materials of oil wax liquid and be full of cracks liquid:
The raw material composition (% by weight) of oil wax liquid: permeate agent 10%, water 30% that vegetables oil 10%, paraffin 50%, effective constituent are alkylphenol polyoxyethylene.
The raw material composition (% by weight) of be full of cracks liquid: permeate agent 5%, light agent 5%, water 30% that be full of cracks liquid 20%, casein 40%, effective constituent are alkylphenol polyoxyethylene.
Cover with paint, lacquer, colour wash, etc. technique:
Manual above-mentioned oily wax liquid dropping lain against to the dry hide base reverse side of crossing through toggling drying and processing in platform case, make its naturally osmotic to dry hide base front, until dry hide base front manifests fuel-displaced wax liquid stain trace, and in the time dripping oily wax liquid, can control consciously distribution and the dripping quantity of drop, make them produce difference at the positive oily wax liquid stain trace size and shape forming of dry hide base, and be uneven distribution, thereby demonstrate desirable skin texture grain pattern, and the position that forms oily wax liquid stain trace has different handle effects;
Utilize oily wax liquid to carry out obliterating 1-5 time in dry hide base front, after it is dry, continue obliterating be full of cracks liquid 1-3 time;
After above-mentioned covering with paint technique, the skin base of obliterating be full of cracks liquid is carried out after blast finishing ink, hot pressure 3-15 second at temperature 90-115 ℃, finally carry out rotary drum and beat, complete complete processing.
The dropping of above-mentioned oily wax liquid and obliterating, and the obliterating process of be full of cracks liquid, can drip the inhomogeneous or irregular of the dynamics of region, dripping quantity and obliterating and mode by control, make the grain effect that leather surface finally presents more enrich changeable, these operations both can complete by hand, also can utilize relevant equipment to complete.The leather obtaining, due to the effect of oily wax liquid stain trace, can present as skin texture grain pattern and chromatic aberration as moon earth's surface from front, is called in the present invention " month covering ".
Embodiment 2
In embodiment 2, leather processing method capable is substantially the same manner as Example 1, and the composition of raw materials of oily wax liquid and be full of cracks liquid is converted.
The composition of raw materials of oil wax liquid and be full of cracks liquid:
The raw material composition (% by weight) of oil wax liquid: animal oil 15%, polyethylene wax 45%, effective constituent are permeate agent 10%, the water 30% of aliphatic poly ammoniacum emulsion.
The raw material composition (% by weight) of be full of cracks liquid: be full of cracks liquid 25%, casein 35%, effective constituent are permeate agent 6%, light agent 4%, the water 30% of aliphatic poly ammoniacum emulsion.
Cover with paint, lacquer, colour wash, etc. technique:
Manual above-mentioned oily wax liquid dropping lain against to the dry hide base reverse side of crossing through toggling drying and processing in platform case, make its naturally osmotic to dry hide base front, until dry hide base front manifests fuel-displaced wax liquid stain trace, and in the time dripping oily wax liquid, can control consciously distribution and the dripping quantity of drop, make them produce difference at the positive oily wax liquid stain trace size and shape forming of dry hide base, and be uneven distribution, thereby demonstrate desirable skin texture grain pattern, and the position that forms oily wax liquid stain trace has different handle effects;
Utilize oily wax liquid to carry out obliterating 1-5 time in dry hide base front, after it is dry, continue obliterating be full of cracks liquid 1-3 time;
After above-mentioned covering with paint technique, the skin base of obliterating be full of cracks liquid is carried out after blast finishing ink, hot pressure 3-15 second at temperature 90-115 ℃, finally carry out rotary drum and beat, complete complete processing.
The dropping of above-mentioned oily wax liquid and obliterating, and the obliterating process of be full of cracks liquid, can drip the inhomogeneous or irregular of the dynamics of region, dripping quantity and obliterating and mode by control, make the grain effect that leather surface finally presents more enrich changeable, these operations both can complete by hand, also can utilize relevant equipment to complete.The leather obtaining, due to the effect of oily wax liquid stain trace, can present as skin texture grain pattern and chromatic aberration as moon earth's surface from front, is called in the present invention " month covering ".
Embodiment 3
In embodiment 3, leather processing method capable is substantially the same manner as Example 1, and the composition of raw materials of oily wax liquid and be full of cracks liquid is converted.
The composition of raw materials of oil wax liquid and be full of cracks liquid:
The raw material composition (% by weight) of oil wax liquid: animal oil 8%, Fischer-Tropsch wax 50%, effective constituent are permeate agent 12%, the water 30% of aerosol-OT salt.
The raw material composition (% by weight) of be full of cracks liquid: be full of cracks liquid 15%, casein 45%, effective constituent are permeate agent 5%, light agent 5%, the water 30% of aerosol-OT salt.
Cover with paint, lacquer, colour wash, etc. technique:
Manual above-mentioned oily wax liquid dropping lain against to the dry hide base reverse side of crossing through toggling drying and processing in platform case, make its naturally osmotic to dry hide base front, until dry hide base front manifests fuel-displaced wax liquid stain trace, and in the time dripping oily wax liquid, can control consciously distribution and the dripping quantity of drop, make them produce difference at the positive oily wax liquid stain trace size and shape forming of dry hide base, and be uneven distribution, thereby demonstrate desirable skin texture grain pattern, and the position that forms oily wax liquid stain trace has different handle effects;
Utilize oily wax liquid to carry out obliterating 1-5 time in dry hide base front, after it is dry, continue obliterating be full of cracks liquid 1-3 time;
After above-mentioned covering with paint technique, the skin base of obliterating be full of cracks liquid is carried out after blast finishing ink, hot pressure 3-15 second at temperature 90-115 ℃, finally carry out rotary drum and beat, complete complete processing.
The dropping of above-mentioned oily wax liquid and obliterating, and the obliterating process of be full of cracks liquid, can drip the inhomogeneous or irregular of the dynamics of region, dripping quantity and obliterating and mode by control, make the grain effect that leather surface finally presents more enrich changeable, these operations both can complete by hand, also can utilize relevant equipment to complete.The leather obtaining, due to the effect of oily wax liquid stain trace, can present as skin texture grain pattern and chromatic aberration as moon earth's surface from front, is called in the present invention " month covering ".
" month covering " obtaining in above embodiment; especially can be ox-hide (such as wild ox skin, cattle hide, Corii Bubali etc.), sheepskin, pigskin; can be processed into various men and women's case and bag, furniture (various sofas, bookcase, wine cabinet etc.), container for packing and article overcoat (cell-phone cover, IPAD protective sleeve etc.); its surperficial leather texture effect coordinates the style moulding of goods; can make quality and the class of goods be promoted, more can meet the demand that user's individual character is shown.
Finally it should be noted that: above each embodiment, only in order to technical scheme of the present invention to be described, is not intended to limit; Although the present invention is had been described in detail with reference to aforementioned each embodiment, those of ordinary skill in the art is to be understood that: its technical scheme that still can record aforementioned each embodiment is modified, or some or all of technical characterictic is wherein equal to replacement; And these modifications or replacement do not make the essence of appropriate technical solution depart from the scope of various embodiments of the present invention technical scheme.

Claims (9)

1. a leather processing method capable, comprises the raw stock through degreasing depilation is handled as follows: liming, deliming pickling, tanning, retanning dye the end, toggling oven dry, covering with paint, blast finishing ink, it is soft to press, fall, and it is characterized in that, described covering with paint technique is as follows:
Drip oily wax liquid at the reverse side of dry hide base of drying through toggling, and it is positive and manifest fuel-displaced wax liquid stain trace to make dripped oily wax liquid infiltrate into dry hide base;
Utilize oily wax liquid to carry out obliterating 1-5 time in dry hide base front, after it is dry, continue obliterating be full of cracks liquid 1-3 time;
Described leather processing method capable has also comprised that to obliterating the skin base of be full of cracks liquid carries out after blast finishing ink hot pressure 3-15 second at temperature 90-115 ℃;
Wherein, in described covering with paint technique, used oil wax liquid is made up of the raw material of following weight percent: oily 5-20%, wax 45-70%, permeate agent 5-15% and water 20-40%; Be full of cracks liquid used is made up of the raw material of following weight percent: cracking resin for synthesizing 10-30%, casein 30-50%, permeate agent 2-8%, light agent 3-7% and water 20-40%.
2. leather processing method capable according to claim 1, is characterized in that, in this oil wax liquid, described grease separation is from vegetables oil or animal oil.
3. leather processing method capable according to claim 1, is characterized in that, in this oil wax liquid, described wax is synthetic wax or natural series wax.
4. leather processing method capable according to claim 1, is characterized in that, in this oil wax liquid, described wax is petroleum wax and derivative or polyolefin-wax and derivative thereof.
5. leather processing method capable according to claim 1, is characterized in that, in this oil wax liquid, the effective constituent of described permeate agent is selected from alkylphenol polyoxyethylene, aliphatic alcohol polyethenoxy alcohol or aerosol-OT salt.
6. leather processing method capable according to claim 1, is characterized in that, in this be full of cracks liquid, the effective constituent of described permeate agent is selected from alkylphenol polyoxyethylene, aliphatic alcohol polyethenoxy alcohol or aerosol-OT salt.
7. a leather of processing by the method described in claim 1-6 any one.
8. a leatherware, for leather processing described in employing claim 7 forms.
9. leatherware according to claim 8, is characterized in that, comprises case and bag, furniture or article overcoat.
CN201210320790.2A 2012-08-31 2012-08-31 Leather and leather product, and processing method thereof Expired - Fee Related CN103146852B (en)

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CN103146852B true CN103146852B (en) 2014-06-25

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104074073B (en) * 2014-07-06 2016-02-17 广州德谱皮具实业有限公司 A kind of production method of the sense leather that chaps
CN105220539B (en) * 2014-07-06 2017-08-18 时代(英德)皮具制品有限公司 A kind of batik method of leather
CN111139321B (en) * 2020-01-08 2021-09-21 漳州信德皮革有限公司 Leather production process
CN114540557A (en) * 2021-12-14 2022-05-27 浙江中辉裘革科技有限公司 Production process of sheepskin-like amber fur leather

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FR2110560A5 (en) * 1970-10-13 1972-06-02 Didier Edmond Resin impregnated leathers - treated in a grid pattern to retain permeability and flexibility
CN1095760A (en) * 1993-05-24 1994-11-30 黎小雄 Snowflake leather sand-washing process
CN1089304A (en) * 1993-12-09 1994-07-13 买胜荣 Ox-hide is had a shave, the wax discoloration effect is removed from office and production method
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CN101838712A (en) * 2010-06-10 2010-09-22 中国皮革和制鞋工业研究院 Manufacturing process of unrepeatable patterned leather

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