CN103146117A - Inflaming retarding acrylonitrile butadiene styrene (ABS)/copolyester alloy, preparation method thereof and product thereof - Google Patents
Inflaming retarding acrylonitrile butadiene styrene (ABS)/copolyester alloy, preparation method thereof and product thereof Download PDFInfo
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- CN103146117A CN103146117A CN2013100414746A CN201310041474A CN103146117A CN 103146117 A CN103146117 A CN 103146117A CN 2013100414746 A CN2013100414746 A CN 2013100414746A CN 201310041474 A CN201310041474 A CN 201310041474A CN 103146117 A CN103146117 A CN 103146117A
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Abstract
The invention discloses an inflaming retarding acrylonitrile butadiene styrene (ABS)/copolyester alloy, a preparation method of the inflaming retarding ABS/copolyester alloy and a product of the inflaming retarding ABS/copolyester alloy. The inflaming retarding ABS/copolyester alloy comprises, by weight, 50 parts-99 parts of ABS, 1 part-50 parts of copolyester resin, 5 parts-44 parts of flame retardant, 1 part-40 parts of flame retardant synergist, 0 part-50 parts of additive, 0 part-100 parts of filler, and 0 part-10 parts of other assistant agents, wherein the sum of parts of the flame retardant and parts of the flame retardant synergist is 20-45, the flame retardant synergist is ammonium salt with at least one ammonium (NH4+), and other additives are charring agents and/or stabilizing agents. According to the inflaming retarding ABS/copolyester alloy, the preparation method of the inflaming retarding ABS/copolyester alloy and the product of the inflaming retarding ABS/copolyester alloy, inflaming retarding efficiency of hypophosphite or alkyl group hypophosphite flame retardant in the inflaming retarding ABS/copolyester alloy can be greatly improved by reasonable selection of the flame retardant synergist, usage amount of the hypophosphite or alkyl group hypophosphite flame retardant in the inflaming retarding ABS/copolyester alloy is greatly reduced, and thus ABS/copolyester is enabled to reach a high flame retardant rating under the condition that additive amount of the flame retardant is small.
Description
Technical field
The present invention relates to the flame retardance of polymer field, particularly a kind of flame-proof ABS/copolyesters Alloy And Preparation Method and goods.
Background technology
In existing flame-retardant modified ABS/ copolyesters, in order to satisfy non-halogen requirement, need to select phosphorous, nitrogen or its compound system.Use now the most general phosphonium flame retardant and composition thereof mainly contain micro encapsulation red phosphorus, phosphoric acid ester, with ammonium polyphosphate as the Intumscent Flame Retardant System of main body etc.These flame-retardant systems are all to realize fire-retardant by solid phase mechanism.Compare with traditional bromo-antimony compositional flame-retardant system, the phosphonium flame retardant of solid phase fire retardant mechanism and compositional flame-retardant system thereof have the low shortcoming of flame retarding efficiency.
Phosphinates is the phosphonium flame retardant that a class can act on gas phase, but has equally the low problem of flame retarding efficiency, and not during the compositional flame-retardant synergist, needing to add a large amount of phosphinates, just can to reach the UL94V-0 level fire-retardant.Patent CN1660857B and CN100348653C disclose the composition of the composite amino-contained ring texture of a kind of alkyl phosphinate fire retarding synergist, although these fire retarding synergists can play synergistic effect to a certain extent, but its synergistic degree is limited, and therefore the consumption of phosphinates is still higher, has greatly increased the cost of fire-retardant combination.
Summary of the invention
Goal of the invention of the present invention, be in order to overcome the deficiencies in the prior art, a kind of flame-proof ABS/copolyesters alloy to be provided, this flame-proof ABS/copolyesters alloy is by the choose reasonable to fire retarding synergist, can in the situation that the fire retardant addition is less, reach high flame retardant rating.
Another object of the present invention is to provide the preparation method of described flame-proof ABS/copolyesters alloy.
The goods that provide described flame-proof ABS/copolyesters alloy to prepare are provided another object of the present invention.
Above-mentioned purpose of the present invention is achieved by following technical solution:
A kind of flame-proof ABS/copolyesters alloy in described flame-proof ABS/copolyesters alloy, comprises the following component of calculating by weight:
50 ~ 99 parts of ABS;
1 ~ 50 part of conjugated polyester resin;
5 ~ 44 parts of fire retardants;
1 ~ 40 part of fire retarding synergist;
0 ~ 50 part of additive;
0 ~ 100 part of filler;
0 ~ 10 part of other auxiliary agent;
Wherein, the summation of ABS and conjugated polyester resin is 100 parts;
Wherein, the weight part sum of described fire retardant and fire retarding synergist is 20 ~ 45 parts;
Described fire retardant has structure shown in formula I:
Wherein, R
1And R
2Can simultaneously or not be hydrogen or alkyl simultaneously, M be Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or be protonated nitrogen base, and wherein m is 1,2,3 or 4;
Described fire retarding synergist is for containing at least a NH
4 +Ammonium salt;
Described additive is char-forming agent and/or stablizer.
A kind of flame-proof ABS/copolyesters alloy in described flame-proof ABS/copolyesters alloy, is comprised of the following component of calculating by weight:
50 ~ 99 parts of ABS;
1 ~ 50 part of conjugated polyester resin;
5 ~ 44 parts of fire retardants;
1 ~ 40 part of fire retarding synergist;
0 ~ 50 part of additive;
0 ~ 100 part of filler;
0 ~ 10 part of other auxiliary agent;
Wherein, the summation of ABS and conjugated polyester resin is 100 parts;
Wherein, the weight part sum of described fire retardant and fire retarding synergist is 20 ~ 45 parts;
Described fire retardant has structure shown in formula I:
Wherein, R
1And R
2Can simultaneously or not be hydrogen or alkyl simultaneously, M be Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or be protonated nitrogen base, and wherein m is 1,2,3 or 4;
Described fire retarding synergist is for containing at least a NH
4 +Ammonium salt;
Described additive is char-forming agent and/or stablizer.
Wherein, described conjugated polyester resin is PETG or PCTG.Described PETG, PCTG are by terephthalic acid (TPA), ethylene glycol (EG) and three kinds of monomers of 1,4 cyclohexane dimethanol (CHDM) product with the ester-interchange method polycondensation.Wherein, terephthalic acid is as dicarboxylic acid monomer, and ethylene glycol and 1,4 cyclohexane dimethanol are as the dibasic alcohol monomer.Wherein, lower than ethylene glycol content, namely in two kinds of dibasic alcohol, the mole number of CHDM is less than 50% the time when 1,4 cyclohexane dimethanol content, and copolyesters is PETG, otherwise is PCTG.More intuitively, its structure can be as shown in formula II:
Wherein, be PETG when the add-on of 1,4 cyclohexane dimethanol during less than 50mol%, be PCTG during greater than 50mol%, in formula, m〉1.
Wherein, the weight part of described ABS interpolation is 70 ~ 99 parts; 1 ~ 30 part of the weight part that described copolyesters adds.
Wherein, described filler is this area filler commonly used, the effect that its effect is normally played enhancing, improved dimensional stability or satisfy some special purposes the performance of ABS/ copolyesters alloy, these fillers can be glass fibre, carbon fiber, natural fiber, talcum powder, kaolin, wollastonite, mica, wilkinite, glass microballon, calcium carbonate, barium sulfate etc.
Wherein, described char-forming agent is this area char-forming agent commonly used, its effect is to help matrix resin to form stable, firm charcoal layer in combustion processes, thereby reach oxygen barrier every the fire retardation of matter, described char-forming agent is selected from the mixture of tetramethylolmethane, pentaerythritol ester, linear phenolic aldehyde, Mierocrystalline cellulose etc. or these materials.
Wherein, described stablizer is this area stablizer commonly used, its effect is the stability of composite flame-retardant agent in processing and moulding process of improving time phosphine (phosphorus) hydrochlorate fire retardant and fire retarding synergist composition thereof, and described stablizer is selected from the mixture of magnesium oxide, calcium oxide, aluminum oxide, zinc oxide, manganese oxide, stannic oxide, zinc borate, zinc, zinc hydroxyl stannate etc. or these materials.
Wherein, the weight part of described fire retardant interpolation is 5 ~ 29 parts; The weight part that more preferably adds is 5 ~ 15 parts.
Wherein, the weight part of described fire retarding synergist interpolation is 1 ~ 25 part; The weight part that more preferably adds is 15 ~ 25 parts.
Wherein, described additive weight part is 0 ~ 25 part.
Wherein, the weight part that adds of described glass fibre is 0 ~ 80 part.
Wherein, the weight part that adds of described other auxiliary agents is 0 ~ 5 part.
Wherein, the weight part of described fire retardant is 5 ~ 15 parts; The weight part of fire retarding synergist is 15 ~ 25 parts.
Wherein, the weight part sum of described fire retardant and fire retarding synergist is preferably 25 ~ 33 parts.
Wherein, the heat decomposition temperature of described fire retarding synergist is more than 180 ℃.
Wherein, the negative ion of described fire retarding synergist is SO
4 2-, HSO
4 -, S
2O
7 2-, Br
-, Cl
-, the aliphatic carboxylic acid root of C1 ~ C3 or the aromatic carboxylic acid root of C7 ~ C10.
Wherein, described fire retarding synergist is ammonium sulfate, aluminium ammonium sulfate, ammonium sulfate magnesium, ammonium sulfate zinc, ammonium sulfate calcium, ammonium sulfate iron, monoammonium sulfate, ammonium pyrosulfate, ammonium chloride, brometo de amonio, ammonium formiate, ammonium acetate, propionic acid ammonium, isopropyl acid ammonium, ammonium benzoate, toluylic acid ammonium, ammonium phthalate, m-phthalic acid ammonium, terephthalic acid ammonium, phenylpropionic acid ammonium, 2-methylphenyl acetic acid ammonium, 3-methylphenyl acetic acid ammonium, 4-methylphenyl acetic acid ammonium, 2-ethyl benzoate ammonium, 3-ethyl benzoate ammonium, 4-ethyl benzoate ammonium.
Wherein, described fire retarding synergist is ammonium sulfate, aluminium ammonium sulfate, monoammonium sulfate, ammonium pyrosulfate, ammonium chloride or brometo de amonio.
Wherein, in described fire retardant, R
1And r
2Can simultaneously or not be the alkyl of hydrogen or C1 ~ C6 simultaneously.
Wherein, in described fire retardant, M is Al, Mg, Ca, Zn, Sn or Fe.
wherein, described fire retardant is hypo-aluminum orthophosphate, magnesium hypophosphite, calcium propionate, ferric hypophosphite, diethyl phospho acid aluminium, diethyl phospho acid magnesium, diethyl phospho acid zinc, diethyl phospho acid calcium, diethyl phospho acid iron, dimethyl phospho acid aluminium, dimethyl phospho acid magnesium, dimethyl phospho acid zinc, dimethyl phospho acid calcium, dimethyl phospho acid iron, dipropyl phospho acid aluminium, dibutyl phospho acid aluminium, diamyl phospho acid aluminium, dihexyl phospho acid aluminium, methylethyl phospho acid aluminium, methyl-propyl phospho acid aluminium, methyl butyl phospho acid aluminium, ethyl propyl phospho acid aluminium, ethyl-butyl phospho acid aluminium, monomethyl phospho acid aluminium, single ethyl phospho acid aluminium, single propyl group phospho acid aluminium, monobutyl phospho acid aluminium, single amyl group phospho acid aluminium, single ethylhexyl hypophosphorous acid aluminium, monomethyl phospho acid magnesium, single ethyl phospho acid magnesium, single propyl group phospho acid magnesium, monobutyl phospho acid magnesium, monomethyl phospho acid calcium, single ethyl phospho acid calcium, single propyl group phospho acid calcium, monobutyl phospho acid calcium.
The preparation method of described flame-proof ABS/copolyesters alloy is characterized in that, comprises the steps: in proportion said components to be mixed, and extrudes to obtain under 180 ~ 230 ℃.
By the goods that described flame-proof ABS/the copolyesters alloy is made.
Compared with prior art, the present invention has following beneficial effect:
The present invention is by the choose reasonable to fire retarding synergist, can significantly improve hypophosphite or the alkyl phosphinate fire retardant flame retarding efficiency in ABS/ copolyesters alloy, greatly reduce the consumption of hypophosphite in ABS/ copolyesters alloy or alkyl phosphinate fire retardant, therefore can in the situation that the fire retardant addition is less, make ABS/ copolyesters alloy reach high flame retardant rating.
Embodiment
Below in conjunction with some embodiments, composite flame-retardant agent of the present invention, preparation method and application thereof are described further.Specific embodiment is for further describing the present invention, non-limiting protection scope of the present invention.
Embodiments of the invention adopt following raw material:
Hypophosphite used in embodiment is available from continent, Wuhan chemical industry;
Dialkylphosphinic salts is available from German Clariant;
Ammonium sulfate is available from Baoqing, Yueyang chemical industry company limited;
Ammonium chloride is available from sea, river, Zhuzhou environmental protection Industrial Co., Ltd.;
Brometo de amonio is available from reaching chemical industry in the Suzhou City;
Ammonium pyrosulfate is available from chemical industry far away company limited in the permanent industry in Beijing;
Aluminium ammonium sulfate is available from Wuhan gold promise chemical industry company limited;
Ammonium formiate is available from Shanghai gold one-tenth chemical industry company limited;
Ammonium benzoate is available from Shanghai gold one-tenth chemical industry company limited;
Linear phenolic aldehyde: PF-204, Huantai County converge chemical industry company limited forever;
Zinc oxide: rubber grade zinc oxide, Weifang dragon reach zinc industry company limited;
ABS:3904, the Shanghai Gaoqiao petrochemical industry;
PETG：GN071，EASTAMN；
PCTG：DN011，EASTAMN；
Filler: glass fibre, megalith;
Composition vertical combustion grade criterion: UL-94;
Extrude processing characteristics criterion: in visual inspection extruding pelletization process, whether the material strip of extruding has the situations such as foaming, variable color, surface irregularity to occur, and judges and extrudes processing characteristics according to extruding material strip foaming, variable color, surface roughness.When the situations such as foaming, variable color, surface irregularity do not appear in material strip, extrude processing characteristics for well; During the situations such as the few foaming of material strip appearance, light discolouration, not roughen of surface, extruding processing characteristics decomposes for slight; The slightly situation such as roughen but still can accept the time, extruding processing characteristics is decomposed of less foaming, light discolouration, surface appears in material strip.
Below be illustrated in the mode of specific embodiment, described raw material is weight part.
Embodiment 1 ~ 18 and Comparative Examples 1 ~ 6
Ratio in table 1 ~ 3 record mixes each component, extrudes under 180 ~ 230 ℃, prepares the flame-proof ABS of embodiment 1 ~ 18 and Comparative Examples 1 ~ 6/copolyesters alloy.The test result of its flame retardant properties and processing characteristics is as shown in table 4.
Table 1
Table 2
Table 3
The performance test of embodiment 1 ~ 18 and Comparative Examples 1 ~ 4 is as shown in table 4:
Table 4
From the results shown in Table 4, when adopting existing MCA/MPP not good as the flame retardant effect of fire retarding synergist.As can be seen from Table 4, flame-proof ABS of the present invention/copolyesters alloy can in the situation that the fire retardant addition is few, reach high flame retardant effect by the choose reasonable to fire retardant and fire retarding synergist.
The above is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or equivalent flow process conversion that utilizes description of the present invention to do; or directly or indirectly be used in other relevant technical fields, all in like manner be included in scope of patent protection of the present invention.
Claims (10)
1. flame-proof ABS/copolyesters alloy, is characterized in that, in described flame-proof ABS/copolyesters alloy, comprises the following component of calculating by weight:
50 ~ 99 parts of ABS;
1 ~ 50 part of conjugated polyester resin;
5 ~ 44 parts of fire retardants;
1 ~ 40 part of fire retarding synergist;
0 ~ 50 part of additive;
0 ~ 100 part of filler;
0 ~ 10 part of other auxiliary agent;
Wherein, the summation of ABS and conjugated polyester resin is 100 parts;
Wherein, the weight part sum of described fire retardant and fire retarding synergist is 20 ~ 45 parts;
Described fire retardant has structure shown in formula I:
Wherein, R
1And R
2Can simultaneously or not be hydrogen or alkyl simultaneously, M be Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or be protonated nitrogen base, and wherein m is 1,2,3 or 4;
Described fire retarding synergist is for containing at least a NH
4 +Ammonium salt;
Described additive is char-forming agent and/or stablizer.
2. flame-proof ABS/copolyesters alloy, is characterized in that, in described flame-proof ABS/copolyesters alloy, is comprised of the following component of calculating by weight:
50 ~ 99 parts of ABS;
1 ~ 50 part of conjugated polyester resin;
5 ~ 44 parts of fire retardants;
1 ~ 40 part of fire retarding synergist;
0 ~ 50 part of additive;
0 ~ 100 part of filler;
0 ~ 10 part of other auxiliary agent;
Wherein, the summation of ABS and conjugated polyester resin is 100 parts;
Wherein, the weight part sum of described fire retardant and fire retarding synergist is 20 ~ 45 parts;
Described fire retardant has structure shown in formula I:
Wherein, R
1And R
2Can simultaneously or not be hydrogen or alkyl simultaneously, M be Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or be protonated nitrogen base, and wherein m is 1,2,3 or 4;
Described fire retarding synergist is for containing at least a NH
4 +Ammonium salt;
Described additive is char-forming agent and/or stablizer.
3. flame-proof ABS/copolyesters alloy as claimed in claim 1 or 2, is characterized in that, the weight part of described fire retardant is 5 ~ 15 parts; The weight part of fire retarding synergist is 15 ~ 25 parts.
4. flame-proof ABS/copolyesters alloy as claimed in claim 1 or 2, is characterized in that, the heat decomposition temperature of described fire retarding synergist is more than 180 ℃.
5. flame-proof ABS/copolyesters alloy as claimed in claim 1 or 2, is characterized in that, the negative ion of described fire retarding synergist is SO
4 2-, HSO
4 -, S
2O
7 2-, Br
-, Cl
-, the aliphatic carboxylic acid root of C1 ~ C3 or the aromatic carboxylic acid root of C7 ~ C10.
6. flame-proof ABS/copolyesters alloy as claimed in claim 1 or 2, it is characterized in that, described fire retarding synergist is ammonium sulfate, aluminium ammonium sulfate, ammonium sulfate magnesium, ammonium sulfate zinc, ammonium sulfate calcium, ammonium sulfate iron, monoammonium sulfate, ammonium pyrosulfate, ammonium chloride, brometo de amonio, ammonium formiate, ammonium acetate, the propionic acid ammonium, the isopropyl acid ammonium, ammonium benzoate, the toluylic acid ammonium, ammonium phthalate, the m-phthalic acid ammonium, the terephthalic acid ammonium, the phenylpropionic acid ammonium, 2-methylphenyl acetic acid ammonium, 3-methylphenyl acetic acid ammonium, 4-methylphenyl acetic acid ammonium, 2-ethyl benzoate ammonium, 3-ethyl benzoate ammonium and/or 4-ethyl benzoate ammonium.
7. flame-proof ABS/copolyesters alloy as claimed in claim 1 or 2, is characterized in that, in described fire retardant, and R
1And R
2Can simultaneously or not be the alkyl of hydrogen or C1 ~ C6 simultaneously.
8. flame-proof ABS/copolyesters alloy as claimed in claim 1 or 2, is characterized in that, described fire retardant is hypo-aluminum orthophosphate, magnesium hypophosphite, calcium propionate, ferric hypophosphite, diethyl phospho acid aluminium, diethyl phospho acid magnesium, diethyl phospho acid zinc, diethyl phospho acid calcium, diethyl phospho acid iron, dimethyl phospho acid aluminium, dimethyl phospho acid magnesium, dimethyl phospho acid zinc, dimethyl phospho acid calcium, dimethyl phospho acid iron, dipropyl phospho acid aluminium, dibutyl phospho acid aluminium, diamyl phospho acid aluminium, dihexyl phospho acid aluminium, methylethyl phospho acid aluminium, methyl-propyl phospho acid aluminium, methyl butyl phospho acid aluminium, ethyl propyl phospho acid aluminium, ethyl-butyl phospho acid aluminium, monomethyl phospho acid aluminium, single ethyl phospho acid aluminium, single propyl group phospho acid aluminium, monobutyl phospho acid aluminium, single amyl group phospho acid aluminium, single ethylhexyl hypophosphorous acid aluminium, monomethyl phospho acid magnesium, single ethyl phospho acid magnesium, single propyl group phospho acid magnesium, monobutyl phospho acid magnesium, monomethyl phospho acid calcium, single ethyl phospho acid calcium, single propyl group phospho acid calcium and/or monobutyl phospho acid calcium.
9. the preparation method of the described flame-proof ABS of claim 1 ~ 8 any one claim/copolyesters alloy, is characterized in that, comprises the steps: in proportion said components to be mixed, and extrudes to obtain under 180 ~ 230 ℃.
10. by the claim 1 ~ 8 any one claim goods that described flame-proof ABS/the copolyesters alloy is made.
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|---|---|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105734428A (en) * | 2016-03-14 | 2016-07-06 | 昆山一邦泰汽车零部件制造有限公司 | Preparation method of light vehicle seat frame |
| CN107793691A (en) * | 2016-08-29 | 2018-03-13 | 合肥杰事杰新材料股份有限公司 | A kind of bloom chemicals-resistant ABS/ copolyester alloy materials and preparation method thereof |
| CN114230963A (en) * | 2021-12-22 | 2022-03-25 | 湖州伟悦高分子材料有限公司 | Oil-resistant high-impact ABS/PBT composite material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060041042A1 (en) * | 2004-08-17 | 2006-02-23 | Clariant Gmbh | Fire-protection coating |
| CN101724219A (en) * | 2008-10-17 | 2010-06-09 | 金发科技股份有限公司 | Thermoplastic flame-retardant alloy and preparation method thereof |
| CN102392674A (en) * | 2011-08-29 | 2012-03-28 | 北京工业大学 | Compounded latex retardant for preventing coal spontaneous combustion and preparation method thereof |
-
2013
- 2013-02-01 CN CN201310041474.6A patent/CN103146117B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060041042A1 (en) * | 2004-08-17 | 2006-02-23 | Clariant Gmbh | Fire-protection coating |
| CN101724219A (en) * | 2008-10-17 | 2010-06-09 | 金发科技股份有限公司 | Thermoplastic flame-retardant alloy and preparation method thereof |
| CN102392674A (en) * | 2011-08-29 | 2012-03-28 | 北京工业大学 | Compounded latex retardant for preventing coal spontaneous combustion and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105734428A (en) * | 2016-03-14 | 2016-07-06 | 昆山一邦泰汽车零部件制造有限公司 | Preparation method of light vehicle seat frame |
| CN107793691A (en) * | 2016-08-29 | 2018-03-13 | 合肥杰事杰新材料股份有限公司 | A kind of bloom chemicals-resistant ABS/ copolyester alloy materials and preparation method thereof |
| CN114230963A (en) * | 2021-12-22 | 2022-03-25 | 湖州伟悦高分子材料有限公司 | Oil-resistant high-impact ABS/PBT composite material and preparation method thereof |
| CN114230963B (en) * | 2021-12-22 | 2022-06-14 | 湖州伟悦高分子材料有限公司 | Oil-resistant high-impact ABS/PBT composite material and preparation method thereof |
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Address after: Ke Feng Lu Science City high tech Industrial Development Zone of Guangzhou City, Guangdong Province, No. 33 510663 Patentee after: Kingfa Technology Co., Ltd. Patentee after: SICHUAN KINGFA TECHNOLOGY DEVELOPMENT CO., LTD. Address before: Ke Feng Lu Science City high tech Industrial Development Zone of Guangzhou City, Guangdong Province, No. 33 510663 Patentee before: Kingfa Technology Co., Ltd. Patentee before: Mianyang Changxin New Material Development Co., Ltd. |