CN103132126B - Novel electroplating hard chrome process method - Google Patents

Novel electroplating hard chrome process method Download PDF

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Publication number
CN103132126B
CN103132126B CN201110392569.3A CN201110392569A CN103132126B CN 103132126 B CN103132126 B CN 103132126B CN 201110392569 A CN201110392569 A CN 201110392569A CN 103132126 B CN103132126 B CN 103132126B
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washing
water
spray
plating tank
achieve
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CN103132126A (en
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张汝山
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TIANJIN DAGANG GALVANIZED FACTORY
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TIANJIN DAGANG GALVANIZED FACTORY
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Abstract

The present invention provides the processing method of the hard chromium of a kind of Novel electroplating. Achieve the cleaner production of chrome-plated process, use is all reclaimed in all washings in technique, especially washing water treatment after plating, it adopts multistage overflow automatic spray method, the steam output of water spray and plating tank water is allowed to keep balance, both achieve the zero release of water, achieve again the recycling of chromium. The superiority of the present invention: the cleaner production achieving chrome-plated process, use is all reclaimed in all washings in technique, especially washing water treatment after plating, it adopts multistage overflow automatic spray method, the steam output of water spray and plating tank water is allowed to keep balance, both achieve the zero release of water, achieve again the recycling of chromium. Without the need to extras and resource, save old, it is to increase economic benefit, truly achieve cleaner production.

Description

Novel electroplating hard chrome process method
(1) technical field
The present invention relates to a kind of electroplating process, particularly relate to the processing method of the hard chromium of a kind of Novel electroplating.
(2) background technology
Traditional electroplating technology is by pre-treatment → plating → passivation → drying → packaging, performance and appearance requirement to product are all not high, and the development along with national economy, the requirement of product surface quality is improved constantly by people, and then drive the development of process for treating surface, electroplate as the application of the most general process for treating surface also more and more extensive. The pollution substance that the consequent is disposed in environment is paid attention to people by national. Traditional wastewater treatment process is the combination of the final program element such as process of a series of physics, chemistry, biology and mud, and so its treating processes redundant and complicated, cost remains high, and operationally often has many restrictions. My company fully responds the call of country's cleaner production, processes decontamination from source of pollution, reaches cleaner production truly.
(3) summary of the invention
It is an object of the invention to design the processing method of the hard chromium of a kind of Novel electroplating. Achieve the cleaner production of chrome-plated process, use is all reclaimed in all washings in technique, especially washing water treatment after plating, it adopts multistage overflow automatic spray method, the steam output of water spray and plating tank water is allowed to keep balance, both achieve the zero release of water, achieve again the recycling of chromium.
The technical scheme of the present invention: the processing method of the hard chromium of a kind of Novel electroplating. It is characterized in that whole technique by pre-treatment, antipole, electroplate and drain and form, wherein pre-treatment comprises electrolytic degreasing, 3 road washings, activation and the washing of 2 roads, wherein utilize acid-base neutralisation principle by 2 roads acidity washing water after activation by 3 roads alkalescence washing water after blowback electrolytic degreasing, more unnecessary waste water is extracted into coarse filter by pump, after adsorption tower, accurate filter and exchange resin tower, returns to the washing of the twice after activation again. Achieve the wastewater zero discharge of pre-treatment. Washing in the plating process adopts multistage overflow automatic spray method, by water being added to during spray washing product the washing tank minimum containing chromium concn, again the washing fountain solution the highest containing chromium concn is added to plating tank, and the steam output keeping water spray and plating tank liquid balances, the realization washing water zero discharge of continuity and waste liqouor utilize.
Multistage overflow automatic spray method as above, multistage overflow automatic spray comprises 5 road washings, it is followed successively by washing one, washing two, washing three, washing four and washing five, its water contains chromium concn by high to Low, from plating tank away from washing five minimum close to pure water containing chromium concn, the pure water of pure water tank is supplemented by pump and washes in five grooves by being added to by water during spray washing product, successively utilize pump be extracted into washing five grooves in Water spray supplement washing four, washing three is supplemented with reason, washing two is being supplemented by washing three overflow port overflows, washing one is supplemented with reason, plating tank will be added to again containing chromium concn the highest washing one liquid.And the steam output keeping water spray and plating tank liquid balances, the realization washing water zero discharge of continuity and waste liqouor utilize.
The superiority of the present invention: the cleaner production achieving chrome-plated process, use is all reclaimed in all washings in technique, especially washing water treatment after plating, it adopts multistage overflow automatic spray method, the steam output of water spray and plating tank water is allowed to keep balance, both achieve the zero release of water, achieve again the recycling of chromium. Without the need to extras and resource, save old, it is to increase economic benefit, truly achieve cleaner production.
(4) accompanying drawing explanation
Accompanying drawing 1 is the structural representation of the present invention. 1 is pure water tank, and 2 is pump, and 3 is pre-treatment, and 4 is overflow port, 5 is pipeline, and 6 is plating tank, and 7 is that washing one, 8 washes two, 9 be washing three, 10 be washing four, 11 be washing five, 12 is plating, 13 is antipole, and 14 is drain, and 31 is adsorption tower, and 32 is exchange resin tower, 33 is accurate filter, and 34 is coarse filter, and 35 is washing, 36 is washing, and 37 is electrolytic degreasing, 38 activation.
(5) embodiment
Example as shown in Figure 1: the processing method of the hard chromium of a kind of Novel electroplating. It is characterized in that whole technique by pre-treatment 3, antipole 13, plating 12 and drains 14 and forms, wherein pre-treatment 3 comprises electrolytic degreasing 37,3 road washing 36, activation 38 and 2 road washing 35, wherein utilize acid-base neutralisation principle by 2 roads acidity washing 35 water after activation by 3 roads alkalescence washing 36 water after pump 2 reuse electrolytic degreasing 37, more unnecessary waste water is extracted into coarse filter 34 by pump 2, after adsorption tower 31, accurate filter 33 and exchange resin tower 32, returns to the washing of the twice after activation 35 again. Achieve the wastewater zero discharge of pre-treatment 3. Multistage overflow automatic spray method is adopted in the washing electroplated in 6 operations, by water being added to during spray washing product washing five tank minimum containing chromium concn, again washing one fountain solution the highest containing chromium concn is added to plating tank, and the steam output keeping water spray and plating tank liquid balances, the realization washing water zero discharge of continuity and waste liqouor utilize.
Multistage overflow automatic spray method as above, multistage overflow automatic spray comprises washing 1, wash 28, wash 39, wash 4 10, wash 5 11, its water contains chromium concn by high to Low, wash 5 11 containing chromium concn minimum close to pure water, the pure water of pure water tank 1 is sprayed by pump 2 and drenches product and supplement and wash 5 11 by supplementary for water when pass through spray washing product, the pump 2 that utilizes successively is extracted into the washing 5 11 supplementary washing 4 10 of spray pouring, washing 39 is supplemented with reason, washing 28 is being supplemented by washing 39 overflow port overflows, washing 1 is supplemented with reason, plating tank 6 will be added to again containing chromium concn the highest washing 1 liquid. and the steam output keeping water spray and plating tank liquid balances, the realization washing water zero discharge of continuity and waste liqouor utilize.

Claims (2)

1. the processing method of a durionise, it is characterized in that whole technique is by pre-treatment, antipole, electroplate and drain composition, wherein pre-treatment comprises electrolytic degreasing, 3 road washings, activation and the washing of 2 roads, wherein utilize acid-base neutralisation principle by 2 road acidity washing water after activation by 3 road alkalescence washing water after blowback electrolytic degreasing, again unnecessary waste water is extracted into coarse filter by pump, again through adsorption tower, the washing of the twice after activation is returned to after accurate filter and exchange resin tower, achieve the wastewater zero discharge of pre-treatment, washing in the plating process adopts multistage overflow automatic spray method, by water being added to during spray washing product the washing tank minimum containing chromium concn, again the washing fountain solution the highest containing chromium concn is added to plating tank, and the steam output keeping water spray and plating tank liquid balances, the realization washing water zero discharge of continuity and waste liqouor utilize.
2. processing method according to claim 1, it is characterized in that, described multistage overflow automatic spray method, multistage overflow automatic spray comprises 5 road washings, it is followed successively by washing one, washing two, washing three, washing four and washing five, its water contains chromium concn by high to Low, from plating tank away from washing five minimum close to pure water containing chromium concn, the pure water of pure water tank is supplemented by pump and washes in five grooves by being added to by water during spray washing product, successively utilize pump be extracted into washing five grooves in Water spray supplement washing four, washing three is supplemented with reason, washing two is being supplemented by washing three overflow port overflows, washing one is supplemented with reason, plating tank will be added to again containing chromium concn the highest washing one liquid, and the steam output keeping water spray and plating tank liquid balances, the realization washing water zero discharge of continuity and waste liqouor utilize.
CN201110392569.3A 2011-12-01 2011-12-01 Novel electroplating hard chrome process method Active CN103132126B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104674330A (en) * 2014-03-25 2015-06-03 胡国绵 Electroplating zero-wastewater emission engineering technology
CN108677241A (en) * 2018-07-20 2018-10-19 陈志荣 A kind of electroplating device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87102036A (en) * 1987-06-13 1987-12-23 铁道部株洲电力机车工厂 Treatment for rinsig waste water from low chromium passivating process during zinc plating
CN101230480A (en) * 2007-10-29 2008-07-30 山东九鑫机械工具有限公司 Electroplating reverse-flow rinsing process
CN201778140U (en) * 2010-06-30 2011-03-30 胡明辉 Circulation water-saving device for plating line
CN202011920U (en) * 2010-12-10 2011-10-19 天津市大港镀锌厂 Zero-emission recycling system for eletrodeposited chromium washing wastewater

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87102036A (en) * 1987-06-13 1987-12-23 铁道部株洲电力机车工厂 Treatment for rinsig waste water from low chromium passivating process during zinc plating
CN101230480A (en) * 2007-10-29 2008-07-30 山东九鑫机械工具有限公司 Electroplating reverse-flow rinsing process
CN201778140U (en) * 2010-06-30 2011-03-30 胡明辉 Circulation water-saving device for plating line
CN202011920U (en) * 2010-12-10 2011-10-19 天津市大港镀锌厂 Zero-emission recycling system for eletrodeposited chromium washing wastewater

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
逆流喷淋自动清洗封闭循环处理镀锌钝化含铬废水;舒彩陶;《环境工程》;19830825;第一节新工艺概述 *

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