CN103130383A - Method for treating trace amounts of toxic organic pollutants in drinking water - Google Patents

Method for treating trace amounts of toxic organic pollutants in drinking water Download PDF

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Publication number
CN103130383A
CN103130383A CN201310089966.2A CN201310089966A CN103130383A CN 103130383 A CN103130383 A CN 103130383A CN 201310089966 A CN201310089966 A CN 201310089966A CN 103130383 A CN103130383 A CN 103130383A
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settling tank
fhhh
water
toxic organic
washing
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CN201310089966.2A
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Chinese (zh)
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左玉辉
刘远彬
丁中海
张徐祥
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Nanjing University
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Nanjing University
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Abstract

The invention discloses a method for treating trace amounts of toxic organic pollutants in drinking water, belonging to the technical field of water purification. The method comprises the following steps: 1. constructing an aeration biological filter; 2. sending sewage to be treated into the aeration biological filter through a water inlet to carry out preliminary filtration, and setting the hydraulic load technological parameter of an indigenous bacterium precipitation tank and an Fhhh precipitation tank as 0.5-2.0 mh<-1>; regulating water washing intensity of the indigenous bacterium precipitation tank and Fhhh precipitation tank to 6-20 mh<-1>, water washing duration time to 3-8 minutes and water washing frequency to once a week, and meanwhile, introducing air into the indigenous bacterium precipitation tank and Fhhh precipitation tank, wherein the air washing intensity is controlled to be 15-35 mh<-1>, the air washing duration time is 3-6 minutes, and the air washing frequency is once a week; and 3. after the sewage to be treated is treated by the step 2 by which toxic organic pollutants contained in the sewage are effectively removed, discharging the treated effluent water through a water discharge pipeline. The invention is mainly used for reducing or eliminating trace amounts of toxic organic pollutants in drinking water.

Description

The treatment process of trace toxic organic pollutant in a kind of tap water
Technical field
The present invention relates to a kind of drink water purifying method, more particularly, relate to the treatment process of trace toxic organic pollutant in a kind of tap water.
Background technology
Water is the precious resources that the mankind depend on for existence and development, there is no life without water, just there is no the mankind's civilization and progress.Drinking Water and daily life are closely related, and the quality of its water quality directly affects the healthy of people.Yet, due to explosive population growth and socioeconomic fast development, rural area agricultural chemicals abuse, enterprise's blowdown in violation of rules and regulations, domestic waste polluted source problem is day by day serious, and mankind's daily life drinking water safety is subject to more and more serious threat.Show according to the World Health Organization's investigation, the disease in the whole world 80% is all relevant with poor water quality with 50% death of child.The digestive ailment that causes due to poor water quality, transmissible disease, various tetter, diabetes, cancer, hepatitis, lithiasis, cardiovascular diseases etc. are kind more than 50 nearly.
(July, September, October and December) in 2007 and (March, June, September and December) in 2012 gather the drinking water source water sample from north, Nanjing river mouth water factory.24 kinds of toxic organic pollutant concentration situations that adopt gas-chromatography (GC-MS) method to measure, comprise 12 kinds of polycyclic aromatic hydrocarbonss (PAHs) (acenaphthylene, anthracene, benz (a) anthracene, benzo (a) pyrene, benzo (b) uoranthene, benzo (k) uoranthene, chrysene, dibenz (a, h) anthracene, uorene, phenanthrene, pyrene, indeno (1, 2, 3-cd) pyrene), 6 kinds of peptide acid lipid (PAEs) (bis (2-ethylhexyl) adipate, bis (2-ethylhexyl) phthalate, butyl benzyl phthalate, dibutyl phthalate, diethyl phthalate, dimethyl phthalate) and 6 kinds of oil of mirbane or heterocyclic (isophorone, hexachlorocyclopentadiene, 2, 4-dinitrotoluene, 2, 6-dinitrotoluene, hexachlorobenzene, pentachlorophenol).Detected result shows, total SVOCs(half volatile organic contaminant) concentration is between 1950.81-11097.78 ng/l, and mean concns is 5344.50 ng/l.PAHs, PAEs and other class organic pollutant total concns are respectively 183.79ng/l, 5005.40ng/l and 155.31 ng/l.The detected result of PAHs, PAEs and other type organic concentration all with other regional tap water in corresponding Pollutant levels close.
Adopt the U.S. EPA standard method to analyze potential non-carcinogenic and the carcinogenic risk of trace toxic organic pollutant in the drinking water source, each SVOCs Environmental Health risk is lower than threshold value 1, but benzo (a) is anthraene, bis (2-ethylhexyl) phthalate, benzo (b) uoranthene, benzo (a) pyrene and dibenz (a, h) health risk of anthracene all higher than this threshold value, shows that in source water, these 5 kinds of pollutents may the induced environment health risk.These 5 kinds of pollutents belong to the priority pollutants of USEPA and EU.Studies show that these pollutents exist mutagenesis and carcinogenic effect, the drinking water source exists these pollutents will jeopardize public health and ecological safety.Therefore, be badly in need of the exploitation Advanced Treatment of Drinking Water, subdue or eliminate the health risk that these micro quantity organic pollutants bring out.
Summary of the invention
The technical problem that invention will solve
The object of the invention is to overcome the deficiency that trace toxic organic pollutant in tap water can not be subdued or eliminate to prior art well, the treatment process of trace toxic organic pollutant in a kind of tap water is provided.
Technical scheme
For achieving the above object, technical scheme provided by the invention is:
In a kind of tap water of the present invention, the treatment process of trace toxic organic pollutant, the steps include:
Step 1:
Build BAF, this BAF comprises water-in, valve, grid settling tank, settling tank, indigenous bacterium settling tank, Fhhh settling tank, under meter, outlet conduit, back flushing pipeline and blow-off line, be provided with blow-off line bottom described grid settling tank, settling tank, indigenous bacterium settling tank and Fhhh settling tank, the bottom of described indigenous bacterium settling tank and Fhhh settling tank also is provided with outlet conduit and back flushing pipeline, outlet conduit, back flushing pipeline and blow-off line are equipped with under meter, and valve also is installed on described blow-off line;
Step 2:
Treatment sewage enters BAF by water-in, tentatively filter by grid settling tank and settling tank, regulate the valve of settling tank water outlet, and coordinate under meter to demonstrate discharge, indigenous bacterium settling tank and Fhhh settling tank hydraulic load processing parameter are set to 0.5 ~ 2.0m h 1The washing intensity of regulating indigenous bacterium settling tank and Fhhh settling tank is 6 ~ 20m h 1, the washing time length is 3 ~ 8min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank and Fhhh settling tank simultaneously, and controlling air purge intensity is 15 ~ 35m h 1, the air purge time length is 3 ~ 6min, the air purge frequency is weekly;
Step 3:
Treatment sewage is through after step 2, and the toxic organic pollutant that contains in sewage is effectively removed, and after processing, water outlet is discharged by outlet conduit.
Further, the described indigenous bacterium settling tank of step 2 and Fhhh settling tank hydraulic load processing parameter are set to 1.0 ~ 2.0m h 1
Further, the washing intensity of the described indigenous bacterium settling tank of step 2 and Fhhh settling tank is 8 ~ 15m h 1, the washing time length is 5 ~ 8min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank and Fhhh settling tank simultaneously, and controlling air purge intensity is 15 ~ 30m h 1, the air purge time length is 3 ~ 5min, the air purge frequency is weekly.
Beneficial effect
Adopt technical scheme provided by the invention, compare with existing known technology, have following unusual effect:
(1) treatment process of trace toxic organic pollutant in a kind of tap water of the present invention, indigenous bacterium settling tank and Fhhh settling tank hydraulic load processing parameter are set to 0.5 ~ 2.0m h 1The washing intensity of regulating indigenous bacterium settling tank and Fhhh settling tank is 6 ~ 20m h 1, the washing time length is 3 ~ 8min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank and Fhhh settling tank simultaneously, and controlling air purge intensity is 15 ~ 35m h 1, the air purge time length is 3 ~ 6min, the air purge frequency is weekly, effectively subdues or has eliminated trace toxic organic pollutant in tap water, thereby having cut down the Environmental Health risk, has guaranteed public health and ecological safety;
(2) treatment process of trace toxic organic pollutant in a kind of tap water of the present invention, the tap water biofiltration treatment system of foundation adopts biological aerated filter process, is a kind of efficient, feasible Advanced Treatment of Drinking Water;
(3) treatment process of trace toxic organic pollutant in a kind of tap water of the present invention is subdued or eliminates that the effect of trace toxic organic pollutant in tap water is remarkable, principle is simple, input cost is low, is convenient to promote.
Description of drawings
Fig. 1 is the structural representation of the present invention's BAF of setting up.
Label declaration in schematic diagram:
1, water-in; 2, valve; 3, grid settling tank; 4, settling tank; 5, indigenous bacterium settling tank; 6, Fhhh settling tank; 7, under meter; 8, outlet conduit; 9, back flushing pipeline; 10, blow-off line.
Embodiment
For further understanding content of the present invention, the present invention is described in detail in conjunction with the accompanying drawings and embodiments.
Embodiment 1
In a kind of tap water of the present embodiment, the treatment process of trace toxic organic pollutant, the steps include:
Step 1:
build BAF, in conjunction with Fig. 1, the BAF of the present embodiment comprises water-in 1, valve 2, grid settling tank 3, settling tank 4, original inhabitants bacterium settling tank 5, Fhhh settling tank 6, under meter 7, outlet conduit 8, back flushing pipeline 9 and blow-off line 10, described grid settling tank 3, settling tank 4, original inhabitants' bacterium settling tank 5 and Fhhh settling tank 6 bottoms are provided with blow-off line 10, the bottom of described indigenous bacterium settling tank 5 and Fhhh settling tank 6 also is provided with outlet conduit 8 and back flushing pipeline 9, outlet conduit 8, back flushing pipeline 9 and blow-off line 10 are equipped with under meter 7, on described blow-off line 10, valve 2 is installed also,
Step 2:
Treatment sewage enters BAF by water-in 1, tentatively filter by grid settling tank 3 and settling tank 4, regulate the valve 2 of settling tank 4 water outlets, and coordinating under meter 7 to demonstrate discharge, indigenous bacterium settling tank 5 and Fhhh settling tank 6 hydraulic load processing parameters are set to 0.5m h 1The washing intensity of regulating indigenous bacterium settling tank 5 and Fhhh settling tank 6 is 6m h 1, the washing time length is 8min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank 5 and Fhhh settling tank 6 simultaneously, and controlling air purge intensity is 20m h 1, the air purge time length is 4min, the air purge frequency is weekly;
Step 3:
Treatment sewage is through after step 2, and the toxic organic pollutant that contains in sewage is effectively removed, and after processing, water outlet is discharged by outlet conduit 8.
In the present embodiment, the toxic organic pollutants such as PAHs and PAEs are all effectively removed, and clearance is respectively: PAHs (53.2%), and PAEs (69.8%) and heterocyclic (68.5%), wherein, and in all PAEs, di- nThe clearance best result of-butyl phthalate and bis (2-ethylhexyl) phthalate is not 70.1% and 82.4%.
Embodiment 2
In a kind of tap water of the present embodiment, the treatment process of trace toxic organic pollutant, the steps include:
Step 1:
build BAF, in conjunction with Fig. 1, the BAF of the present embodiment comprises water-in 1, valve 2, grid settling tank 3, settling tank 4, original inhabitants bacterium settling tank 5, Fhhh settling tank 6, under meter 7, outlet conduit 8, back flushing pipeline 9 and blow-off line 10, described grid settling tank 3, settling tank 4, original inhabitants' bacterium settling tank 5 and Fhhh settling tank 6 bottoms are provided with blow-off line 10, the bottom of described indigenous bacterium settling tank 5 and Fhhh settling tank 6 also is provided with outlet conduit 8 and back flushing pipeline 9, outlet conduit 8, back flushing pipeline 9 and blow-off line 10 are equipped with under meter 7, on described blow-off line 10, valve 2 is installed also,
Step 2:
Treatment sewage enters BAF by water-in 1, tentatively filter by grid settling tank 3 and settling tank 4, regulate the valve 2 of settling tank 4 water outlets, and coordinating under meter 7 to demonstrate discharge, indigenous bacterium settling tank 5 and Fhhh settling tank 6 hydraulic load processing parameters are set to 1.0m h 1The washing intensity of regulating indigenous bacterium settling tank 5 and Fhhh settling tank 6 is 20m h 1, the washing time length is 3min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank 5 and Fhhh settling tank 6 simultaneously, and controlling air purge intensity is 15m h 1, the air purge time length is 6min, the air purge frequency is weekly;
Step 3:
Treatment sewage is through after step 2, and the toxic organic pollutant that contains in sewage is effectively removed, and after processing, water outlet is discharged by outlet conduit 8.
In the present embodiment, the toxic organic pollutants such as PAHs and PAEs are all effectively removed, and are respectively: PAHs (56.4%), and PAEs (71.6%) and heterocyclic (65.8%), wherein, and in all PAEs, di- nThe clearance best result of-butyl phthalate and bis (2-ethylhexyl) phthalate is not 71.2% and 84.4%.
Embodiment 3
In a kind of tap water of the present embodiment, the treatment process of trace toxic organic pollutant, the steps include:
Step 1:
build BAF, in conjunction with Fig. 1, the BAF of the present embodiment comprises water-in 1, valve 2, grid settling tank 3, settling tank 4, original inhabitants bacterium settling tank 5, Fhhh settling tank 6, under meter 7, outlet conduit 8, back flushing pipeline 9 and blow-off line 10, described grid settling tank 3, settling tank 4, original inhabitants' bacterium settling tank 5 and Fhhh settling tank 6 bottoms are provided with blow-off line 10, the bottom of described indigenous bacterium settling tank 5 and Fhhh settling tank 6 also is provided with outlet conduit 8 and back flushing pipeline 9, outlet conduit 8, back flushing pipeline 9 and blow-off line 10 are equipped with under meter 7, on described blow-off line 10, valve 2 is installed also,
Step 2:
Treatment sewage enters BAF by water-in 1, tentatively filter by grid settling tank 3 and settling tank 4, regulate the valve 2 of settling tank 4 water outlets, and coordinating under meter 7 to demonstrate discharge, indigenous bacterium settling tank 5 and Fhhh settling tank 6 hydraulic load processing parameters are set to 2.0m h 1The washing intensity of regulating indigenous bacterium settling tank 5 and Fhhh settling tank 6 is 15m h 1, the washing time length is 5min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank 5 and Fhhh settling tank 6 simultaneously, and controlling air purge intensity is 35m h 1, the air purge time length is 3min, the air purge frequency is weekly;
Step 3:
Treatment sewage is through after step 2, and the toxic organic pollutant that contains in sewage is effectively removed, and after processing, water outlet is discharged by outlet conduit 8.
In the present embodiment, the toxic organic pollutants such as PAHs and PAEs are all effectively removed, and are respectively: PAHs (55.3%), and PAEs (70.7%) and heterocyclic (67.9%), wherein, and in all PAEs, di- nThe clearance best result of-butyl phthalate and bis (2-ethylhexyl) phthalate is not 73.2% and 82.1%.
the present invention passes through grid settling tank 3 with treatment sewage, settling tank 4, original inhabitants' bacterium settling tank 5 and Fhhh settling tank 6 filter layer by layer, wherein, indigenous bacterium in original inhabitants' bacterium settling tank 5 and Fhhh settling tank 6 and Fhhh (genetically engineered bacteria) are the extremely strong microorganisms of degraded toxic organic compound, and to the hydraulic load in indigenous bacterium settling tank 5 and Fhhh settling tank 6, washing intensity, the parameter areas such as air purge intensity and backwashing time limit, obtained the treatment process of trace toxic organic pollutant in a kind of tap water of the best, effectively subdue or eliminated trace toxic organic pollutant in tap water.

Claims (3)

1. the treatment process of trace toxic organic pollutant in a tap water, the steps include:
Step 1:
build BAF, this BAF comprises water-in (1), valve (2), grid settling tank (3), settling tank (4), original inhabitants' bacterium settling tank (5), Fhhh settling tank (6), under meter (7), outlet conduit (8), back flushing pipeline (9) and blow-off line (10), described grid settling tank (3), settling tank (4), be provided with blow-off line (10) bottom original inhabitants' bacterium settling tank (5) and Fhhh settling tank (6), the bottom of described indigenous bacterium settling tank (5) and Fhhh settling tank (6) also is provided with outlet conduit (8) and back flushing pipeline (9), outlet conduit (8), back flushing pipeline (9) and blow-off line (10) are equipped with under meter (7), valve (2) also is installed on described blow-off line (10),
Step 2:
Treatment sewage enters BAF by water-in (1), tentatively filter by grid settling tank (3) and settling tank (4), regulate the valve (2) of settling tank (4) water outlet, and coordinating under meter (7) to demonstrate discharge, indigenous bacterium settling tank (5) and Fhhh settling tank (6) hydraulic load processing parameter are set to 0.5 ~ 2.0m h 1The washing intensity of regulating indigenous bacterium settling tank (5) and Fhhh settling tank (6) is 6 ~ 20m h 1, the washing time length is 3 ~ 8min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank (5) and Fhhh settling tank (6) simultaneously, and controlling air purge intensity is 15 ~ 35m h 1, the air purge time length is 3 ~ 6min, the air purge frequency is weekly;
Step 3:
Treatment sewage is through after step 2, and the toxic organic pollutant that contains in sewage is effectively removed, and after processing, water outlet is discharged by outlet conduit (8).
2. the treatment process of trace toxic organic pollutant in a kind of tap water according to claim 1, it is characterized in that: the described indigenous bacterium settling tank of step 2 (5) and Fhhh settling tank (6) hydraulic load processing parameter are set to 1.0 ~ 2.0m h 1
3. the treatment process of trace toxic organic pollutant in a kind of tap water according to claim 2, it is characterized in that: the washing intensity of the described indigenous bacterium settling tank of step 2 (5) and Fhhh settling tank (6) is 8 ~ 15m h 1, the washing time length is 5 ~ 8min, and the washing frequency is weekly, passes into air toward indigenous bacterium settling tank (5) and Fhhh settling tank (6) simultaneously, and controlling air purge intensity is 15 ~ 30m h 1, the air purge time length is 3 ~ 5min, the air purge frequency is weekly.
CN201310089966.2A 2013-03-20 2013-03-20 Method for treating trace amounts of toxic organic pollutants in drinking water Pending CN103130383A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111346417A (en) * 2020-03-16 2020-06-30 嵊州市永诚工艺竹编厂 Filtering device for treating trace toxic pollutants in drinking water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111346417A (en) * 2020-03-16 2020-06-30 嵊州市永诚工艺竹编厂 Filtering device for treating trace toxic pollutants in drinking water

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Application publication date: 20130605