CN103109225B - Imaging optical system - Google Patents

Imaging optical system Download PDF

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Publication number
CN103109225B
CN103109225B CN201180044617.8A CN201180044617A CN103109225B CN 103109225 B CN103109225 B CN 103109225B CN 201180044617 A CN201180044617 A CN 201180044617A CN 103109225 B CN103109225 B CN 103109225B
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optical system
imaging
reflecting mirror
reticle
mirror
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CN103109225A (en
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H-J.曼恩
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Carl Zeiss SMT GmbH
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Carl Zeiss SMT GmbH
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Priority claimed from DE102010040811A external-priority patent/DE102010040811A1/en
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Publication of CN103109225A publication Critical patent/CN103109225A/en
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Abstract

A kind of imaging optical system (9) for projecting exposure system, it has at least one deformation imaging optic element (M1 to M6).This permission illuminates image field the most completely with the big object-side numerical aperture on first direction, without expanding the scope of reticle to be imaged, and does not reduce the production capacity of projection exposure system.

Description

Imaging optical system
Technical field
The present invention relates to the imaging optical system for projecting exposure system, for projecting the illumination optical system of exposure system System and there is the optical system of the type imaging optical system.The invention still further relates to the projection exposure with the type optical system System, for projecting the reticle of exposure system, the method manufacturing micro-structural assembly by means of this projection exposure system With the assembly manufactured by the method.
Background technology
From DE102007062198A1, US7,414,781B2, US7,682,031B2, and from WO2010/091800A1 Would know that imaging optical system.Etching system is would know that from US2008/0036986A1.
Summary of the invention
It is an object of the invention to the imaging optical system being developed for projecting exposure system so that be modified to picture element further Amount.
According to the present invention, it is appreciated that, along with the increase of object-side numerical aperture, thing side's main beam angle must increase, and this can Cause the capture-effect caused by absorbent structure, and cause layer to transmit the problem of (layer transmission) aspect, The strong apodization effect especially caused by reticle coating.According to the present invention, it is further appreciated that, can be by deformation (anamorphically) imaging optical system, especially by being deformed into as projectoscope (lens) system, with predetermined imaging ratio Example, by the reticle of preliminary dimension from thing field imaging to predetermined illuminated field, on the direction of the first imaging scale, illumination Field is illuminated completely, simultaneously the production capacity (throughput) to projection exposure system of the reduction imaging scale in second direction Not there is negative effect, but this reduction imaging scale can be compensated by suitable measure.
Therefore, distorting lens system allow illuminate image planes completely with big object-side numerical aperture in a first direction, without Expand the scope of reticle to be imaged on this first direction, and the subtracting of production capacity of exposure system does not occur to project Little, and also allow to minimize the loss of the image quality caused by the oblique incidence of illumination light.
By having the imaging scale that symbol is identical on the direction of two principal planes, avoid as upset.Optical system, Especially on the direction of two principal planes, there is positive imaging scale.
Preferably, described at least one be deformed into as projectoscope system has at least two part mirror system, at least a part of which One shifting ground imaging.The imaging optical system with at least two part mirror system (imaging of at least one of which shifting ground) is special You Liyu not construct, and allow imaging verify each require particularly flexible adaptation.Especially, the first (i.e. thing side) portion Divide the imaging of mirror system shifting ground.This can ensure that the radiation being incident on thing field and therefore reflecting is the most overlapping.Part II mirror system Also it is deformation (anamorphic).It can also be non-deformed (non-anamorphic).
Preferably, projectoscope system has the emergent pupil of circle.Image-side numerical aperture therefore independent of direction.Which ensure that with It is orientated unrelated resolution.Therefore, especially, mirror system has the entrance pupil of elliptical shape according to a modification of this invention.Therefore, ellipse The semiaxis relation each other of circle is identical from different imaging scale or different object-side numerical aperture relation each other or phase Instead.
Preferably, described at least one be deformed into as projectoscope system comprises at least one reflecting mirror, the most described instead At least one penetrating mirror has free shape surface.Thus, it is deformed into as projectoscope system comprises at least one reflecting mirror.This In, the reflecting mirror of lesser amt causes less loss (transmission loss).Large number of reflecting mirror allows Correction that is more flexible to image error and that improve, and allow higher numerical aperture.According to the present invention, projectoscope system comprises At least one, the most multiple, especially at least four, especially at least six, especially eight reflecting mirrors.Especially, instead Penetrate mirror and can be configured to reflect the reflecting mirror of EUV-radiation.
The optical element with free shape surface allows the particularly flexible design to imaging character.Particularly in imaging Optical system to determined number reflecting mirror in the case of, these give the further degree of freedom for correcting image error.
Preferably, the half as much again of the imaging scale that imaging scale in a first direction is at least in second direction is big.Especially It is that the twice of its imaging scale being at least in second direction is big.Here and hereinafter, imaging scale is used for referring to by becoming As size and dimension of object (that is, in the image field of projectoscope system the size of the structure of imaging with will imaging in thing field The size of structure) the absolute value of imaging scale that is given of ratio.Thus it is ensured that scanning direction can be perpendicular to, at whole width On degree, exposure has the illuminated field of preset width, and this illuminated field has predetermined mask mother matrix, especially has covering of preliminary dimension Mould mother matrix.Otherwise, the less imaging scale on the direction vertical with the width of illuminated field can be compensated, the strongest minification, Especially by the scanning speed increased, therefore this less imaging scale does not have disadvantageous effect.Especially, with scanning direction The imaging scale of the vertical minimizing on direction is not resulted in the loss of production capacity.
Preferably, the different object-side numerical aperture of directional dependence allow the expedients of imaging optical system.Particularly, The problem that thus can avoid transmitting about the capture-effect on mask and layer.Especially, the object-side numerical aperture on specific direction (NAO) the object-side numerical aperture half as much again on the direction being at least perpendicularly to the direction, especially at least twice.
Preferably, illuminator has emergent pupil, and its shape design is corresponding with the entrance pupil of projectoscope system.According to this Bright, it is thus provided that the illuminator with oval emergent pupil.
Especially, this is by oval pupil facet reflecting mirror or next by the oval layout of the pupil facet on pupil facet reflecting mirror Realizing, this envelope being arranged as all pupil facet forms the layout of ellipse.
Especially, the semiaxis of the emergent pupil of the pupil facet reflecting mirror of elliptical configuration or illuminator relation each other with The different imaging scale of projectoscope system or the semiaxis relation each other of its entrance pupil are identical.
There is big image-side numerical aperture, little main beam angle and the image optics system of big image space scanning seam (slot) width System, it is allowed to the structure of reticle is projected in image field particularly well.
The present invention also provides for a kind of lamp optical system for projecting exposure system, and it is anti-that it comprises at least one pupil facet Penetrating mirror (18), be characterised by oval emergent pupil, the half shaft length of this emergent pupil differs at least 10% each other.This has ellipse and goes out The lamp optical system of pupil is particularly well-suited for being deformed into as projectoscope system.Utilize the elliptical configuration of pupil facet reflecting mirror, Can be particularly easy to realize the oval emergent pupil of lamp optical system.
Optical system according to the present invention has the imaging optical system according to the present invention, and lamp optical system, its Radiation transmission for autoradiolysis in future source is to thing field.Projection exposure system according to the present invention is according to the optical system of the present invention System, and radiation source.Optical system according to the present invention and the advantage of the projection exposure system of the present invention corresponding to above in association with Imaging optical system have been described above those.Preferably, have can displacement in a scanning direction for above-mentioned projection exposure system Reticle keeper, to keep reticle, it is characterised in that imaging optical system imaging scale in a scanning direction is little Imaging scale on the direction vertical with scanning direction.By this projection exposure system, wherein imaging optical system is in scanning Imaging scale on direction, can be complete by higher scanning speed less than the imaging scale on the direction vertical with the direction Production capacity loss on compensated scanning direction.Especially, imaging optical system 9 imaging scale in a scanning direction is up to The half of the imaging scale on direction being perpendicularly to the direction.Imaging scale on scanning direction and the direction vertical with the direction On ratio especially 1:2,1:3,1:4,1:5,1:6,1:8,1:10,2:3,2:5 or 3:4 of imaging scale.Radiation source can be EUV (extreme ultraviolet) light source, such as LPP (laser-produced plasma) light source or GDP (plasma that gas discharge produces) Light source.
Critical with on the direction being perpendicularly to the direction of critical dimension (critical dimension) on scanning direction The reticle that size is different is particularly suitable for and is deformed into as projection optics system is used together.It is preferably according on scanning direction And the different imaging scale on the direction vertical from the direction, construct the structure on reticle to be imaged on and overall size two thereof Person.In order to consider bigger minification, correspondingly reticle is configured to bigger, the most in a scanning direction.
The present invention also provides for a kind of method of assembly for manufacturing micro-structural, and it has following methods step: provide Reticle and the wafer with radiation-sensitive layer;By means of above-mentioned projection exposure system by the arrangement projects on reticle extremely Radiation-sensitive layer on wafer.The present invention also provides for the assembly that said method manufactures.Manufacturing method according to the invention and according to The advantage of the assembly of the present invention is corresponding to those having been described above above with reference to the projection exposure system according to the present invention.
Accompanying drawing explanation
By means of accompanying drawing, the further advantage of the present invention and details occur, wherein in the explanation of multiple embodiments:
Fig. 1 schematically illustrates the meridional section through the projection exposure system for EUV lithography;
Fig. 2 schematically illustrates the part figure of the projection exposure system according to Fig. 1, to be shown according to first embodiment Light path in imaging optical system;
Fig. 3 shows the view in the plane vertical with the plane in Fig. 2 according to Fig. 2;
Figure 4 and 5 show the view of further embodiment according to Fig. 2 and 3;
Fig. 6 and 7 shows the corresponding views of the 3rd embodiment;And
Fig. 8 and 9 shows the corresponding views of the 4th embodiment.
Detailed description of the invention
Fig. 1 schematically illustrates the assembly of the projection exposure system 1 for micro-lithography with meridional section.Projection exposure system The illuminator 2 of 1 comprises radiation source 3, and for exposing the lamp optical system 4 of the thing field 5 in object plane 6.It is arranged in thing Only it being only partially shown in 5 and by reticle keeper 8() reticle 7 that keeps is exposed at this.
The projection optics system 9 shown schematically only illustrated in Fig. 1 for imaging in the image field 10 in image plane 11 by thing field 5 In.Therefore, projection optics system 9 also referred to as imaging optical system.Structure on reticle 7 is imaged in the photosensitive of wafer 12 On layer, wafer 12 is arranged in the region of the image field 10 in image plane 11, and by the wafer holders 13 being also schematically outlined Keep.
Radiation source 3 is EUV radiation source, and it launches EUV-radiation 14.EUV radiation source 3 launch useful radiation wavelength from In the range of 5nm to 30nm.Also possible for photoetching and other wavelength that can obtain from suitable light source.Radiation source 3 can For plasma source, such as DPP source or LPP source.Radiation source based on synchrotron also is used as radiation source 3.This area skill Art personnel can obtain the information of the type radiation source from such as US6859515B2.Condenser (collector) 15 is provided, with Make EUV-radiation 14 bunchy from EUV radiation source 3.
EUV-radiation 14 also referred to as illumination light or imaging.
Lamp optical system 4 comprises a facet reflecting mirror 16, and it has substantial amounts of field facet (facet) 17.Field facet is anti- Penetrate mirror 16 be arranged in lamp optical system 4 and in the plane of object plane 6 optical conjugate.EUV-radiation 14 is by field facet reflecting mirror The 16 pupil facet reflecting mirrors 18 reflexing to lamp optical system 4.Pupil facet reflecting mirror 18 has substantial amounts of pupil facet 19.By means of Pupil facet reflecting mirror 18, images in the field facet 17 of field facet reflecting mirror 16 in thing field 5.
For each facet 17 on field facet reflecting mirror 16, the most just on pupil facet reflecting mirror 18, there is one The pupil facet 19 of association.Between facet 17 on the scene and pupil facet 19, it is configured with optical channel the most respectively.Facet reflecting mirror 16,18 The facet 17,19 of at least one is reversible (switchable).For this purpose, it is possible to provide MEMS (MEMS). Especially, facet 17,19 can tiltably be arranged on facet reflecting mirror 16,18.Here it is possible to only by facet 17,19 A part, the most at most 30%, at most 50% or at most 70% are configured to tiltable.May be alternatively provided as all of facet 17, 19 is all tiltable.Especially, reversible facet 17,19 is a facet 17.By inclined field facet 17, it is to corresponding pupil The structure of the distribution of facet 19 and therefore optical channel can be changed.In order to understand the facet with tiltable facet 17,19 The details of reflecting mirror 16,18 and the details of lamp optical system 4, with reference to DE102008009600A1.
Lamp optical system 4 also can comprise other reflecting mirror 20,21 and 22, and reflecting mirror 20,21 and 22 forms transmission light System 23.Last reflecting mirror 22 of transmission optical system 23 is grazing incidence mirror.Pupil facet reflecting mirror 18 and transmission Optical system 23 forms optical system subsequently, for illumination light 14 being transmitted to thing field 5.Especially, reflect when pupil facet When mirror 18 is arranged in the entrance pupil of projection optics system 9, transmission optical system 23 can be omitted.
Lamp optical system 4 has emergent pupil, its shape adaptation in the shape of the entrance pupil of projection optics system 9, especially with The latter is the most consistent.Especially, the emergent pupil of lamp optical system 4 is oval.This especially can be divided by the pupil of elliptical configuration Face reflecting mirror 18 realizes.As its replacement, pupil facet 19 is also disposed on pupil reflecting mirror 18 so that pupil facet has ellipse The envelope of circular structure.
Especially, the semiaxis of oval pupil facet reflecting mirror 18 has two different half shaft length, half bigger axial length Extremely a little less five times of degree the especially first half shaft length, especially at least twice.Especially, half shaft length have 1:2,1:3, The ratio of 1:4,1:5,1:6,1:8,1:10,2:3,2:5 or 3:4.
Therefore, the semiaxis of the emergent pupil of lamp optical system 4 has two different half shaft length, and bigger half shaft length is outstanding Its with the first half shaft length to a little less five times, especially at least twice is the biggest.Especially, half shaft length have 1:2,1: 3, the ratio of 1:4,1:5,1:6,1:8,1:10,2:3,2:5 or 3:4.
In order to more simply describe position relationship, depict Descartes's xyz-coordinate system the most respectively.In Fig. 1 X-axle is perpendicular to the plane of accompanying drawing and extends inwardly.Y-axle is towards right extension.Z-axis downwardly extends.Object plane 6 and image plane 11 2 Person is parallel to xy-plane and extends.
Can displacement reticle keeper 8 in a controlled manner so that in projection exposure system, reticle 7 can Direction of displacement top offset in object plane 6.It is thus possible in check mode displacement wafer holders 13 so that wafer 12 can Direction of displacement top offset in image plane 11.As a result, it is possible on the one hand scanning reticle 7 is through thing field 5, and the most brilliant Sheet 12 passes image field 10,.Direction of displacement in accompanying drawing is parallel to y-direction.Hereinafter, this is also referred to as scanning direction.Preferably, Reticle 7 and wafer 12 displacement in a scanning direction are carried out about synchronized with each other.
Fig. 2 and 3 shows the optical design of the first structure of projection optics system 9.Show radiation 14 from center thing The light path of the independent light beam that two homologue site of site and two relative edges from qualifier field 5 extend.According to Fig. 2 and 3 Projection optics system 9 there are six reflecting mirrors altogether, it starts by the most numbered M1 from thing field 5 on the direction of light path To M6.Figure shows the reflecting surface of the reflecting mirror M1 to M6 calculated in the design of projection optics system 9.The face only illustrated A part is actually partially used for radiating the reflection of 14, as seen from accompanying drawing.In other words, to that indicated in the drawings compare, The actual configuration of reflecting mirror M1 to M6 may be less, the most only comprises a part for the reflecting surface of calculating shown in the drawings.
Pupil face 24 is between reflecting mirror M2 and reflecting mirror M3.Pupil face 24 is not necessary to as flat.It can be bending.This Outward, intermediate image plane is between reflecting mirror M4 and reflecting mirror M5.Intermediate image plane 25 is not necessary to as flat.It can be bending. Therefore, reflecting mirror M1 to M4 forms Part I mirror system 26.Reflecting mirror M5 and M6 forms Part II mirror system 27.
Part I mirror system 26 is distorting lens, i.e. its shifting ground imaging.Part II mirror system 27 is also distorting lens, i.e. Its shifting ground imaging.It is however also possible that Part II mirror system 27 can be configured to non-deformed.
At least one in reflecting mirror M1 to M6 is configured to deform imaging optic element.Especially, projection optics system 9 Comprise at least one, the most multiple, especially at least two, especially at least three, especially at least four, the most extremely Few five, especially at least six, especially at least seven, especially at least eight deformation imaging mirrors.
Therefore, projection optics system 9 has the first imaging scale in a first direction, and has difference in a second direction The second imaging scale in the first imaging scale.Especially, the second imaging scale is extremely a little less five times of the first imaging scale, Especially at least twice is big.
Especially, projection optics system 9 is constructed so that the amount of imaging scale in a scanning direction is less than and the direction The vertical imaging scale on direction.Especially, the amount of imaging scale in a scanning direction is the direction vertical with the direction On imaging scale at most 3/4ths, especially up to 2/3rds, especially up to half.
Projection optics system 9 has the object-side numerical aperture (NAO) of directional dependence, i.e. entrance pupil and round-shaped deviation. Especially, at specific direction, i.e. the object-side numerical aperture (NAO) on big imaging scale direction, vertical with the direction Extremely a little less five times of object-side numerical aperture on direction, especially at least twice.
Reflecting mirror M6 has the through hole 28 passed through for radiation 14.Is another pupil face between reflecting mirror M5 and M6 29.Pupil face 29 is not necessary to as flat.It can be bending.
Reflecting mirror M1 to M6 is configured to reflect EUV-radiation.Especially, they carry multiple reflecting layer, are used for optimizing it For the reflection of EUV illumination light 14 irradiated.The irradiating angle of the independent light beam in mirror surface is closer to vertically entering Penetrating, reflection can optimised obtain more preferably.
Reflecting mirror M1 to M5 has reflecting surface, and it is Guan Bi, does not i.e. have through hole.
Reflecting mirror M1, M4 and M6 have recessed reflecting surface.Reflecting mirror M2, M3 and M5 have convex reflecting surface.
The reflecting mirror M1 to M6 of projection optics system 9 is configured to the free shape table that can not be described by rotationally symmetrical function Face.Other structures of projection optics system 9 are also possible, and wherein at least one of reflecting mirror M1 to M6 has oneself of the type By shaped reflecting surface.The free shape surface of the type can be manufactured from the rotationally symmetrical plane of reference.From US2007-0058269A1 Know the free shape of the type of the reflecting surface of the reflecting mirror of the projection optics system of the projection exposure system for micro-lithography Surface.
Mathematically by below equation free shape surface can be described:
Wherein apply:
j = ( m + n ) 2 + m + 3 n 2 + 1
Z is that free shape surface is at an x, the rise at y, wherein x2+y2=r2
C is constant, and it corresponds to corresponding aspheric vertex curvature.K corresponds to corresponding aspheric conic constants.CjFor Monomial xmynCoefficient.Typically, desired optical characteristics based on the reflecting mirror in projection optics system 9, determine c, k and CjValue.NRadiusIt is coefficient CjNormalization factor.The exponent number m+n of monomial can change on demand.The monomial of higher-order number can Cause the design with the projection optics system of more preferable image error correction, but calculate more complicated.M+n may select 3 with big Value between 20.
Free shape surface mathematically can be described by zernike polynomial, such as at optical design procedureHandbook described in.Alternatively, by means of two-dimensional spline curved surface, free shape surface can be described.It shows Example is Bezier or non-uniform rational B-spline (NURBS).Two-dimensional spline curved surface such as can be by the net of the point in x/y plane The z value of network and association describes, or by these points and describes about these gradients put.Depend on each class of spline surface Type, uses multinomial or the function such as about its seriality and differential with special nature, by interleaving at nexus Value, it is thus achieved that complete surface.The example of function is analytical function.
Below, by summing up the optical design data of projection optics system 9 in table, by means of optical design procedureHave been obtained for described data.
With first optical surface for optical module of following table and sets forth summit song for aperture diaphragm The reciprocal value (radius) of rate and thickness, this thickness corresponding to adjacent elements from image plane 11 light path (in other words, it is simply that And light is in opposite direction) on z interval.Second table gives the free shape surface provided above with respect to reflecting mirror M1 to M6 In monomial xmynCoefficient Cj
In another table, give also the amount in units of mm, each reflecting mirror starts bias from reflecting mirror Reference Design (Y-is eccentric) and (X-rotation) this amount of rotation.This is corresponding to the translation in the method for designing of free shape surface and inclination.This In, this displacement betides on y direction, and tilts about x-axis.Here, the anglec of rotation is in units of degree.
Surface Radius Thickness Mode of operation
Image plane Infinitely great 852.884
M6 -889.919 -802.884 Reflection
M5 -219.761 1800.787 Reflection
M4 -999.946 -434.619 Reflection
M3 -1033.356 483.832 Reflection
M2 2464.083 -947.116 Reflection
M1 1323.688 1047.116 Reflection
Object plane Infinitely great 0.000
Coefficient M6 M5 M4
K 3.303831E-03 2.041437E-02 -1.056546E-01
Y 0.000000E+00 0.000000E+00 0.000000E+00
X2 1.106645E+00 4.620513E+00 1.065419E+00
Y2 1.316656E+00 4.632819E+00 2.089523E+00
X2Y -6.987016E-02 6.244905E-02 2.322141E-01
Y3 -1.544816E-01 -2.303227E-01 -2.158981E-01
X4 3.297744E-02 9.371547E-02 7.579352E-02
X2Y2 6.476911E-02 1.671737E-01 8.744751E-02
Y4 5.431530E-02 7.743085E-02 2.360575E-01
X4Y -7.040479E-04 4.607809E-03 3.961681E-03
X2Y3 -6.159827E-03 -1.034287E-02 9.782459E-03
Y5 -4.061987E-03 -3.840440E-03 -1.297054E-01
X6 1.398226E-03 3.085471E-03 6.847894E-03
X4Y2 2.977799E-03 8.906352E-03 6.372742E-03
X2Y4 4.433992E-03 8.678073E-03 -2.569810E-02
Y6 1.255594E-03 1.683572E-03 9.106731E-02
X6Y 2.969767E-04 1.881484E-04 1.342374E-03
X4Y3 -2.820109E-04 -1.123168E-03 -5.896992E-03
X2Y5 -3.654895E-04 -5.949903E-04 1.660704E-03
Y7 8.966891E-05 -3.952323E-04 -3.764049E-02
NRadius 2.899772E+02 6.300046E+01 2.064580E+02
Coefficient M3 M2 M1
K 5.744686E-01 -3.325393E+02 -1.583030E-02
Y 0.000000E+00 0.000000E+00 0.000000E+00
X2 3.551408E-01 3.277030E-01 -2.811984E-02
Y2 2.123536E+00 1.609563E+00 -4.135835E-01
X2Y 2.013521E-01 -6.948142E-01 -3.866470E-02
Y3 -1.210907E-02 3.694447E-01 -1.853273E-02
X4 5.478320E-02 1.369729E-01 1.349339E-03
X2Y2 7.482002E-02 1.984843E-01 3.032808E-03
Y4 8.327949E-02 -1.227576E-01 -2.824781E-03
X4Y -2.048831E-03 -4.568931E-02 -4.300195E-04
X2Y3 -4.029059E-03 -1.713508E-02 -6.501645E-04
Y5 -1.415756E-02 6.185385E-03 3.144628E-03
X6 1.998416E-04 -1.834856E-02 6.906841E-05
X4Y2 -1.979383E-03 -3.309794E-02 5.274081E-05
X2Y4 -5.943296E-03 -5.169942E-02 -1.330272E-03
Y6 1.246118E-03 -1.603819E-01 -1.363317E-02
X6Y 1.584327E-04 7.876367E-03 -2.377257E-05
X4Y3 -3.187207E-04 -1.244804E-02 -2.251271E-04
X2Y5 -5.566691E-04 -5.746055E-02 -9.996573E-04
Y7 -1.399787E-03 -3.870909E-02 4.001012E-03
NRadius 8.132829E+01 7.472082E+01 1.311311E+02
Coefficient M6 M5 M4 M3 M2 M1 Image plane
Y-is eccentric -51.252 -99.408 123.654 215.631 528.818 512.855 0.000
X-rotates 0.323 7.067 -2.444 10.483 16.940 3.488 0.000
In y-direction, the most in a scanning direction, projection optics system 9 has covering in the imaging scale of 1:8, i.e. thing field 5 Mould mother matrix 7 is that the octuple of its picture in image field 10 is big in a scanning direction.In the x direction, i.e. it is being perpendicular to scanning direction On direction, projection optics system 9 has the imaging scale of 1:4.Therefore, projection optics system 9 has and reduces effect.Projection optics The image-side numerical aperture of system 9 is 0.5.The image-side numerical aperture of projection optics system 9 especially at least 0.4.Image field 10 has The size of 2mmx26mm, wherein 2mm is in a scanning direction, and 26mm is in the direction perpendicular to the scan direction.Especially, sweeping Retouching on direction, image field 10 also can be of different sizes.The size of image field 10 is at least 1mm x10mm.It is perpendicular to scanning direction, Image field 10 especially has the width more than 13mm.Especially, image field 10 is rectangle.Especially, projection optics system 9 has at least The image space scanning seam width of 13mm, especially greater than 13mm, especially at least 26mm.For field central point, projection optics system 9 There is thing side's main beam angle of 6 °.Especially, the thing side's main beam angle for field central point is at most 7 °.This projection optics System has the optics total length of 2000mm.
Thing field 5 in this embodiment has the size of 16mmx104mm.In this case, 16mm in a scanning direction, and 104mm is in the direction perpendicular to the scan direction.
Reticle 7 also adapts to different imaging scale on scanning direction and perpendicular direction.It has this The structure of sample, this structure in a scanning direction with there is on the direction vertical from the direction different minimum compact mechanisms.Special Not, the structure on reticle 7 in a scanning direction with can have on the direction vertical with the direction be respectively these The size of the integral multiple of little physical dimension.In a scanning direction with the minimum compact mechanism on the direction vertical with the direction Ratio is just inversely proportional with the ratio of imaging scale in those directions.Especially, in a scanning direction and with the party Minimum compact mechanism the most different at least 10% on vertical direction, especially at least 20%, especially at least 50%.
Reticle 7 has the width of at least 104mm on the direction vertical with scanning direction.Especially, reticle 7 There is length in a scanning direction that adapt to bigger minification.Especially, reticle 7 has width and the 264mm of 104mm Length.Especially, the length of reticle is more than 132mm.Its especially at least 140mm, especially at least 165mm, especially It is at least 198mm.
Figure 4 and 5 show and can be used for projecting another structure in exposure system 1, projection optics system 9.With join above Examine the corresponding assembly of the assembly described by Fig. 2 and 3 and there is identical reference number, and be no longer discussed in detail.
Reflecting mirror M3 does not have through hole in optics uses region.But, the mechanical realization of optional reflecting mirror M3 so that The light reflecting mirror perforate by the mirror body of the unibody construction of M3 of reflecting mirror M5 is propagated to from reflecting mirror M4.
Reflecting mirror M1, M3, M4 and M6 have recessed reflecting surface.Reflecting mirror M2 and M5 has convex reflecting surface.
In this embodiment, the light path between reflecting mirror M2 and M3 is intersected with the light path between reflecting mirror M4 and M5.
In this embodiment, in a scanning direction, relative to image field 10, reflecting mirror M5 is arranged in identical with thing field 5 On side.
With in following table, the optical design data of projection optics system 9 that will sum up successively according to Figure 4 and 5.Free shape The mathematical description on surface corresponds to those having been described above above with reference to the structure according to Fig. 2 and 3.About according to Figure 4 and 5 The structure of the table of structure also corresponds to the structure of the table about the structure according to Fig. 2 and 3.
Surface Radius Thickness Mode of operation
Image plane Infinitely great 689.272
M6 -731.552 -639.272 Reflection
M5 -241.671 1420.179 Reflection
M4 -1500.000 -580.907 Reflection
M3 1422.356 1010.728 Reflection
M2 661.083 -1110.728 Reflection
M1 1384.311 1210.728 Reflection
Object plane Infinitely great 0.000
Coefficient M6 M5 M4
K 0.000000E+00 0.000000E+00 0.000000E+00
Y 0.000000E+00 0.000000E+00 0.000000E+00
X2 1.697113E+00 4.496118E+00 1.030719E+01
Y2 1.683950E+00 4.083378E+00 1.147196E+01
X2Y 1.755515E-01 -3.170399E-01 -1.434807E+00
Y3 2.279761E-02 9.028788E-02 1.085004E+00
X4 5.443962E-02 4.335109E-02 2.308628E-01
X2Y2 1.503579E-01 8.531612E-02 7.598943E-01
Y4 5.203904E-02 6.130679E-02 2.980202E-01
X4Y 5.039890E-03 -1.771794E-02 -8.711086E-03
X2Y3 8.907227E-03 -1.404665E-02 8.302498E-04
Y5 5.015844E-03 8.045746E-03 4.101109E-02
NRadius 2.899772E+02 6.300046E+01 2.064580E+02
Coefficient M3 M2 M1
K 0.000000E+00 0.000000E+00 0.000000E+00
Y 0.000000E+00 0.000000E+00 0.000000E+00
X2 -4.645076E-01 -5.243755E-01 -3.303400E-01
Y2 -2.057326E-01 -2.274245E-02 -7.527525E-01
X2Y -3.583366E-02 1.523089E+00 -2.593623E-03
Y3 3.371920E-02 -2.167244E+00 -3.182409E-02
X4 9.534050E-05 7.127442E-02 -8.002659E-04
X2Y2 4.301563E-03 -3.064519E-01 -5.376311E-03
Y4 -9.145920E-04 7.458445E-01 -7.154305E-03
X4Y 9.453851E-05 1.770844E-01 -2.938545E-04
X2Y3 -2.757417E-04 2.079536E-01 2.101675E-03
Y5 4.683904E-05 -1.544216E-01 6.098608E-04
NRadius 8.132829E+01 7.472082E+01 1.311311E+02
Coefficient M6 M5 M4 M3 M2 M1 Image plane
Y-is eccentric 0.000 99.374 -121.476 -185.579 311.769 482.388 0.000
X-rotates -4.418 -8.837 -1.271 16.249 8.734 -1.361 0.000
Fig. 6 and 7 shows the other design of projection optics system 9, and it can be used for projecting in exposure system 1.With above The corresponding assembly of assembly having been described above with reference to Fig. 2 and 3 has identical reference number, and is no longer discussed in detail.
Projection optics system 9 according to Fig. 6 and 7 has six reflecting mirror M1 to M6 altogether, and it is in the light path from thing field 5 Direction on by the most numbered M1 to M6.Projection optics system 9 according to Fig. 6 and 7 has the optics total length of 1865mm.
Reflecting mirror M1, M4 and M6 have recessed reflecting surface.Reflecting mirror M5 has convex reflecting surface.Reflecting mirror M2 and M3 exists It is convex on one direction, and about being recessed on the orthogonal direction of the direction, that is it has at the central point of reflecting mirror The shape in saddle (saddle) face.
Additionally, in this embodiment, on the scanning direction about image field 10, the side identical with thing field 5 is arranged Reflecting mirror M5.
With in following table, the optical design data of projection optics system 9 that will illustrate successively according to Fig. 6 and 7.Free shape table The mathematical description in face corresponds to those having been described above above with reference to the structure according to Fig. 2 and 3.About the structure according to Fig. 6 and 7 The structure of the table made also corresponds to the structure of the table about the structure according to Fig. 2 and 3.
Surface Radius Thickness Mode of operation
Image plane Infinitely great 752.663
M6 -770.716 -702.663 Reflection
M5 -150.912 1382.613 Reflection
M4 -996.191 -579.950 Reflection
M3 -3722.693 805.250 Reflection
M2 -19143.068 -805.250 Reflection
M1 1526.626 1011.848 Reflection
Object plane Infinitely great 0.000
Coefficient M6 M5 M4
K 0.000000E+00 0.000000E+00 0.000000E+00
Y 0.000000E+00 0.000000E+00 0.000000E+00
X2 1.014388E+00 5.967807E+00 1.640439E+00
Y2 9.176806E-01 5.297172E+00 1.185698E+01
X2Y 2.666213E-02 -2.932506E-02 -5.795084E-01
Y3 1.276213E-02 -1.747940E-01 2.665088E-01
X4 3.194237E-02 1.741906E-01 4.142971E-02
X2Y2 5.891573E-02 4.136465E-01 -2.431409E-02
Y4 2.892148E-02 1.408837E-01 8.604418E-01
X4Y 5.053354E-04 8.947414E-03 1.339774E-03
X2Y3 3.013407E-03 4.414092E-02 -2.210148E-02
Y5 2.088577E-03 3.281648E-02 -1.242199E+00
NRadius 2.899772E+02 6.300046E+01 2.064580E+02
Coefficient M3 M2 M1
K 0.000000E+00 0.000000E+00 0.000000E+00
Y 0.000000E+00 0.000000E+00 0.000000E+00
X2 -3.018727E+00 -4.089101E-01 -1.333076E-01
Y2 2.571222E+00 3.746969E+00 8.408741E-01
X2Y -2.111739E-01 -1.877269E-01 3.355099E-02
Y3 -1.035192E-03 -1.810657E-01 -3.518765E-03
X4 -9.587021E-05 -1.882449E-03 2.861048E-03
X2Y2 -2.154549E-02 8.492037E-02 3.127905E-02
Y4 1.331548E-02 -4.386749E-01 7.200871E-03
X4Y 3.718201E-03 -6.344503E-03 -2.655046E-04
X2Y3 4.305507E-03 -1.265202E-01 -6.358900E-03
Y5 -5.587835E-03 -6.311675E-01 -1.276179E-02
NRadius 8.132829E+01 7.472082E+01 1.311311E+02
Coefficient M6 M5 M4 M3 M2 M1 Image plane
Y-is eccentric -11.861 78.940 -76.134 224.849 34.161 393.420 0.000
X-rotates -4.070 -6.401 -16.914 -20.375 -18.683 -9.044 0.000
Fig. 8 and 9 shows another structure of projection optics system 9, and it can be used for projecting in exposure system 1.With join above The corresponding assembly of assembly examining Fig. 2 and 3 and have been described above has identical reference number, and is no longer discussed in detail.
Projection optics system 9 according to Fig. 8 and 9 has eight reflecting mirror M1 to M8.Reflecting mirror M1 to M6 forms first Divide mirror system 26.Reflecting mirror M7 and M8 forms Part II mirror system 27.Reflecting mirror M8 optics use in region have for Irradiate the through hole 28 that light passes through.Reflecting mirror M1 to M7 has the reflecting surface of Guan Bi, that is does not has through hole in optics uses region. Therefore, a reflecting mirror in optics uses region with through hole 28 is just comprised according to the projection optics system 9 of Fig. 8 and 9. Significantly, it is possible to construct the projection optics system 9 with eight reflecting mirror M1 to M8, the most more than one reflecting mirror makes at optics With region has through hole.
Pupil face 24 is located in the light path between reflecting mirror M3 and M5.Pupil face 29 is between reflecting mirror M7 and M8.According to The projection optics system 9 of Fig. 8 and 9 also has two part mirror systems 26,27.Projection optics system 9 just produces a centre Picture, it is geometrically positioned in the via regions of reflecting mirror M8.
Reflecting mirror M1, M2, M6 and M8 have recessed reflecting surface.Reflecting mirror M7 has convex reflecting surface.
Projection optics system according to Fig. 8 and 9 has the image-side numerical aperture of 0.65.As example above, below, The optical design data of projection optics system 9 according to Fig. 8 and 9 are summed up in table.
Surface Radius Thickness Mode of operation
Image plane Infinitely great 845.498
M8 -876.024 -795.498 Reflection
M7 -180.463 1850.000 Reflection
M6 -1124.587 -954.502 Reflection
M5 -488.461 539.347 Reflection
M4 -385.935 -268.946 Reflection
M3 -899.608 563.864 Reflection
M2 -1862.135 -962.532 Reflection
M1 -5181.887 1182.769 Reflection
Object plane Infinitely great 0.000
Coefficient M8 M7 M6 M5
K 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
Y 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X2 3.488069E+00 1.173931E+01 2.308119E+01 1.973785E+01
Y2 2.635738E+00 1.010579E+01 9.438034E+00 5.768532E+00
X2Y -3.059528E-01 -2.733318E-01 -2.266607E+00 -2.615013E+00
Y3 4.818868E-03 6.423471E-01 4.511519E-01 3.223897E+00
X4 1.179868E-01 5.618198E-01 1.276169E+00 3.423570E-01
X2Y2 3.744431E-01 9.722072E-01 1.994073E+00 1.253707E+00
Y4 1.874806E-01 5.624878E-01 9.258956E-01 1.143661E+00
X4Y 4.142568E-03 7.747318E-03 -2.207925E-01 2.696457E-02
X2Y3 -2.457062E-02 2.657340E-02 -4.677376E-02 1.053608E-01
Y5 -1.021381E-02 -2.031996E-02 3.450492E-01 1.716687E+00
X6 1.995975E-02 5.531407E-02 1.199126E-01 1.472679E-02
X4Y2 4.538384E-02 1.603998E-01 2.637967E-01 4.745154E-02
X2Y4 5.093101E-02 1.653739E-01 3.269947E-01 4.959237E-01
Y6 1.573648E-02 6.733509E-02 -1.107783E-01 -1.594589E+00
X6Y -4.813461E-03 1.089425E-03 -8.010947E-02 -1.168696E-04
X4Y3 -6.317680E-03 -3.797390E-03 -4.398398E-03 1.681727E-02
X2Y5 -4.665516E-03 -6.378254E-03 1.634222E-02 -8.741752E-01
Y7 -1.452902E-03 1.323361E-03 -8.378471E-01 -2.083305E-01
X8 2.243101E-03 8.933777E-03 -9.452801E-03 8.039655E-04
X6Y2 1.043837E-02 3.095089E-02 9.332196E-02 5.834641E-03
X4Y4 1.610588E-02 4.686597E-02 1.032458E-01 -1.262475E-01
X2Y6 1.112924E-02 3.372176E-02 -1.634446E-01 -2.791598E-01
Y8 2.847098E-03 9.333073E-03 -6.596064E-01 3.828685E-01
X8Y 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X6Y3 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X4Y5 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X2Y7 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
Y9 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X10 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X8Y2 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X6Y4 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X4Y6 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X2Y8 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
Y10 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
NRadius 4.270420E+02 8.460702E+01 3.587547E+02 1.359154E+02
Coefficient M4 M3 M2 M1
K 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
Y 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X2 7.762408E+00 0.000000E+00 0.000000E+00 2.415351E+01
Y2 5.991623E+00 2.100665E+01 1.742497E+01 2.450758E+01
X2Y -9.407982E-01 -1.845560E+01 0.000000E+00 2.857360E+00
Y3 7.990315E-02 1.826735E+00 0.000000E+00 -8.203766E-01
X4 2.084759E-01 0.000000E+00 0.000000E+00 -1.195250E-01
X2Y2 2.343824E-01 0.000000E+00 0.000000E+00 9.400506E-02
Y4 6.849174E-02 0.000000E+00 0.000000E+00 1.027239E-01
X4Y -3.590847E-02 0.000000E+00 0.000000E+00 5.178501E-02
X2Y3 -1.676285E-02 0.000000E+00 0.000000E+00 5.698284E-02
Y5 1.244977E-03 0.000000E+00 0.000000E+00 2.110062E-01
X6 7.609826E-04 0.000000E+00 0.000000E+00 1.852743E-03
X4Y2 1.642005E-02 0.000000E+00 0.000000E+00 -5.347458E-02
X2Y4 6.253616E-03 0.000000E+00 0.000000E+00 -2.587706E-01
Y6 1.353703E-03 0.000000E+00 0.000000E+00 1.608009E-01
X6Y -2.568254E-03 0.000000E+00 0.000000E+00 5.587846E-04
X4Y3 -4.755388E-03 0.000000E+00 0.000000E+00 5.397733E-02
X2Y5 -6.793506E-04 0.000000E+00 0.000000E+00 -2.400347E-01
Y7 -1.374859E-05 0.000000E+00 0.000000E+00 2.641466E-01
X8 2.488086E-04 0.000000E+00 0.000000E+00 5.593305E-04
X6Y2 1.255585E-03 0.000000E+00 0.000000E+00 6.244473E-03
X4Y4 1.194473E-03 0.000000E+00 0.000000E+00 1.145315E-01
X2Y6 3.001214E-04 0.000000E+00 0.000000E+00 8.712058E-02
Y8 5.813757E-05 0.000000E+00 0.000000E+00 6.570255E-01
X8Y 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X6Y3 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X4Y5 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X2Y7 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
Y9 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X10 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X8Y2 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X6Y4 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X4Y6 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
X2Y8 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
Y10 0.000000E+00 0.000000E+00 0.000000E+00 0.000000E+00
NRadius 7.497396E+01 2.029987E+02 2.738127E+02 2.966746E+02
Coefficient M8 M7 M6 M5 M4
Y-is eccentric 0.000 -116.456 154.238 192.354 412.808
X-rotates 4.164 8.327 3.019 9.973 -2.768
Coefficient M3 M2 M1 Image plane
Y-is eccentric 554.416 783.491 867.803 0.000
X-rotates -2.829 8.552 0.503 0.000
Such as seen from the description of embodiment above, projection optics system 9 is configured such that it is put down two masters Face (principal plane) has intermediary image.
Such as seen from description the preceding embodiment, projection optics system 9, especially two part mirror systems 26, 27 imaging scale on two principal plane directions are respectively provided with identical symbol.Especially, both of which has positive sign.Cause This will not occur as upset.
In order to manufacture micro-structural or nano-structured assembly, projection exposure system 1 used as described below: first, it is provided that cover Mould mother matrix 7 and wafer 12.Then, by means of projection exposure system 1, by the light of the arrangement projects on reticle 7 to wafer 12 In photosensitive layer.Then pass through development photosensitive layer, and on wafer 12, produce micro structure and nanostructured, and therefore manufacture micro-knot Structure assembly, the such as semiconductor subassembly of high density integrated circuit having form.
During the exposure of the photosensitive layer on wafer 12, by means of wafer holders 13, displacement wafer in a scanning direction. In this case, especially, about reticle 7 displacement in a scanning direction by reticle keeper 8, synchronously Carry out the displacement of wafer.Projection optics system 9 imaging scale reduced in a scanning direction can be mended by higher scanning speed Repay.

Claims (14)

1. the imaging optical system (9) being used for projecting exposure system (1), it has:
-at least one be deformed into as projectoscope system (26,27), it is arranged in the reticle plane of described projection exposure system And in the physical space between wafer plane,
-wherein said at least one be deformed into as projectoscope system (26,27) there is symbol in the first direction and a second direction Identical imaging scale,
Wherein said at least one be deformed into as projectoscope system (26,27) include at least four reflecting mirror, described image optics The object-side numerical aperture (NAO) of system (9) is directional dependence.
Imaging optical system the most according to claim 1 (9), it is characterised in that described at least one be deformed into as projection Mirror system has at least two part mirror system (26,27), at least one shifting ground in described at least two part mirror system Imaging.
Imaging optical system the most according to claim 1 and 2 (9), it is characterised in that circular emergent pupil.
Imaging optical system the most according to claim 1 and 2 (9), it is characterised in that described at least four reflecting mirror is extremely Few one has free shape surface.
Imaging optical system the most according to claim 1 and 2 (9), it is characterised in that the first imaging ratio on first direction The second imaging scale in example and second direction, described second imaging scale is at least the half as much again of described first imaging scale Greatly.
Imaging optical system the most according to claim 1 and 2 (9), it is characterised in that
The image-side numerical aperture of-at least 0.4,
Thing side's main beam angle of-central point is less than 7 °, and
-image field (10), it has the width more than 13mm on the direction vertical with scanning direction.
7. an optical system, has
-according to the imaging optical system (9) according to any one of claim 1,2,4 to 6, and
-lamp optical system (4), its radiation (14) for autoradiolysis source (3) in the future is transmitted to thing field (5).
Optical system the most according to claim 7, wherein said lamp optical system (4) comprises:
-at least one pupil facet reflecting mirror (18),
-it is characterized in that, oval emergent pupil, the half shaft length of this emergent pupil differs at least 10% each other.
Optical system the most according to claim 8, it is characterised in that described pupil facet reflecting mirror (18) is oval, and And there is the half shaft length differing at least 10% each other.
10. projection exposure system (1), has
-optical system according to claim 9, and
-radiation source (3).
11. projection exposure systems (1) according to claim 10, having can the reticle of displacement in a scanning direction Keeper, to keep reticle (7), it is characterised in that imaging optical system (9) imaging scale in a scanning direction is less than Imaging scale direction on vertical with scanning direction.
12. 1 kinds of reticle (7), it is for according to the projection exposure system described in any one in claim 10 or 11, There is the width of at least 104mm and the length more than 132mm.
13. 1 kinds are used for the method manufacturing the assembly of micro-structural, and it has steps of:
-reticle (7) is provided and there is the wafer (12) of radiation-sensitive layer,
-by means of according to the projection exposure system (1) described in claim 10 or 11, by the arrangement projects on reticle (7) Radiation-sensitive layer to wafer (12).
14. assemblies manufactured by method according to claim 13.
CN201180044617.8A 2010-09-15 2011-09-13 Imaging optical system Active CN103109225B (en)

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US38307910P 2010-09-15 2010-09-15
DE102010040811.5 2010-09-15
DE102010040811A DE102010040811A1 (en) 2010-09-15 2010-09-15 Imaging optics
US61/383,079 2010-09-15
PCT/EP2011/065823 WO2012034995A2 (en) 2010-09-15 2011-09-13 Imaging optical system

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