CN103101274A - Laminated packaging material - Google Patents
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- CN103101274A CN103101274A CN2012105947653A CN201210594765A CN103101274A CN 103101274 A CN103101274 A CN 103101274A CN 2012105947653 A CN2012105947653 A CN 2012105947653A CN 201210594765 A CN201210594765 A CN 201210594765A CN 103101274 A CN103101274 A CN 103101274A
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Abstract
The invention provides a laminated packaging material. The laminated packaging material comprises an outermost thermoplastic material layer, a sandwich layer, an intermediate thermoplastic material layer, a barrier layer and an innermost thermoplastic material layer from outside to inside, wherein the outermost thermoplastic material layer is made of metalloscene-catalyst-polymerized linear low-density polyethylene (mLLDPE) and LDPE; for the metalloscene catalyst polymerized mLLDPE, the mean density is 0.88-0.925g/cm<3>, the melt flow index (190 DEG C and 2.16kg) is 5-20g/10min, the peak melting point is 85-130 DEG C and the expansion ratio is 1.2-1.8; and for the LDPE, the mean density is 0.90-0.925g/cm<3>, the melt flow index (190 DEG C and 2.16kg) is 5-20g/10min, the peak melting point is 85-110 DEG C and the expansion ratio is 1.2-1.8. Packaging containers with good sealing strength can be obtained by using the laminated packaging material, the percent of pass of the prepared packaging containers is high, and liquid food in the prepared packaging containers is long in quality guarantee period.
Description
Technical field
The present invention relates to a kind of laminate wrapping material, relate in particular to a kind of laminate wrapping material for packaging liquid food.
Background technology
at present, the disposable disposal type packing container that is used for liquid food, brick is arranged, square, triangle, cross section is hexagonal octahedral bodily form, the shapes such as pillow-like, usually the laminate wrapping material of making these packing containers comprises the thermoplastic outermost layer of lamination successively, sandwich layer, the thermoplastic intermediate layer, the barrier layer, adhesive phase and thermoplastic innermost layer, the low density polyethylene (LDPE) (LDPE) that adopts high-pressure process to produce/printer's ink layer/paper (fiber) base layer/LDPE/ aluminium foil AL/LDPE/LDPE is also arranged, LDPE/ printer's ink layer/paper base layer/LDPE/LDPE, printer's ink layer/LDPE/ paper base layer/LDPE/LDPE, laminate wrapping material as LDPE/ printer's ink layer/paper base layer/sandwich constructions such as LDPE/ aluminium/polyester (PET).The food liquid that these packing containers can be packed has fresh milk, yoghurt, fruit juice etc.
core material commonly used has paper, brown paper or hardboard etc., barrier material commonly used has aluminium foil, metal/inorganic oxide film, ethylene-vinyl alcohol copolymer (EVOH), nylon etc., thermoplastic outermost layer commonly used, the intermediate layer, the low density polyethylene (LDPE) (LDPE) that the useful high-pressure process of the material of innermost layer is produced, LLDPE (LLDPE), the thermoplastics such as ethyleneα-olefincopolymer (mLLDPE) by the metalloscene catalyst catalytic polymerization, adhesive commonly used has polyurethane binder, Polyester Polyurethane Adhesive, the polyether-polyurethane adhesive, acrylic adhesive, polyester binder, polyamide binder, the polyvinyl acetate ester adhesive, epoxy adhesive, rubber adhesive etc.
The effect of each layer of packaging material is: the thermoplastic outermost layer can stop effectively that extraneous moisture, pollution or other magazines enter in packaging material, and forming in the packing container process at laminate wrapping material is that laminate wrapping material forms tubulose with thermoplastic innermost layer longitudinal sealing; Sandwich layer can the supporting package container; Thermoplastic intermediate layer and barrier layer can prevent effectively that food liquid from entering into sandwich layer, and starvation, sunlight make not light leak, air tight of packing container simultaneously, particularly do not leak oxygen, guarantee that the food liquid taste does not run off; The thermoplastic innermost layer directly contacts with food liquid, prevents that food liquid is to the infiltration of other each layers of packaging material when guaranteeing the food liquid quality; Adhesive phase adds the adhesion strength between high containment and thermoplastic innermost layer.
Fig. 1 shows a kind of common method of making laminate wrapping material, machine guiding core layer coiled material 1 moves ahead by the pressure roller of punching press platform 2, process hole and the required impression of FOLD AND PACK material of the required use of packing container opening device, continue to guide the sandwich layer coiled material 11 of perforate forward, arrive laminating bench 5, extruder 3 squeezes out thermoplastic intermediate layer coiled material and guides it to and reaches laminating bench 5 herein, barrier layer coiled material 4 is directed to laminating bench 5 simultaneously, 5 pairs of three-layer coil materials of laminating bench carry out lamination, in its roll gap center core layer, thermoplastic intermediate layer and barrier layer are pressed together, and the thermoplastic intermediate layer is between sandwich layer and barrier layer, become thus laminate 111. guide layer pressing plates 111 and arrive next stage laminating bench 6, herein by coextruding and coat the opposite side with thermoplastic innermost layer 7 paint laminate 111 barrier layers, in the roll gap of laminating bench 6, laminate 111 and thermoplastic innermost layer 7 are pressed together, form thus the inboard laminated material 1111 that is coated with the thermoplastic innermost layer, afterwards by extrusion coated thermoplastic outermost layer in the i.e. outside coating of sandwich layer opposite side, so far obtain packing container laminate wrapping material used.Certainly, the outermost coating of thermoplastic might not be placed on final step to be carried out, and also can according to circumstances apply in suitable before step.
The packing container of the laminate wrapping material Production and Packaging food liquid that available said method is made.In order to prevent that packaged food liquid from suffering secondary pollution, the production process of whole packing container is all carried out under aseptic condition: first laminate wrapping material is shaped to cylindric, and form tube in the vertical sealing-in of side, then in the tube one horizontal sealing-in of end, form top or the bottom of packing container, fill afterwards required food liquid, at last with the horizontal sealing-in of residue end of tube, bottom or the top of making packing container.By cutting transverse packed zone, can form single independently packing container, and with these independently packing container deliver in final folding and shaped device and be converted into net shape, as brick type or other shapes.Laminate wrapping material longitudinal sealing, transverse sealing time in forming the packing container process can have influence on production efficiency, the qualification rate of intensity effect packing container of longitudinal sealing, transverse sealing and guaranteeing the quality the time of food liquid.
Chinese invention patent application prospectus CN1337914A discloses a kind of paper container package material, at least the constituting layer that comprises has the thermoplastic outermost layer, the papery base layer, barrier layer and thermoplastic innermost layer are also pressed the said sequence lamination with each constituting layer, be characterised in that: the thermoplastic innermost layer comprises the LLDPE with narrow molecular weight distribution at least, has following performance parameter: averag density 0.900-0.915, 88-103 ℃ of peak value fusing point, melt flow index 5-20, expansion ratio (SR) 1.4-1.6 and bed thickness 20-50 micron, the thermoplastic outermost layer also adopts the material identical with aforementioned innermost layer to make.these packaging material make and are easy to pouring package packing container and rapid heat-seal, obtain the more firm container of sealing more by force, this material can be used for realizing being independent of in-built food temperature excellent sealing and thereby keep the ability that in-built product never degenerates and guarantees the quality, but, this packaging material are in the extruding layer compression technology of manufacture process, serious necking phenomenon can occur in molten condition during from the die head film extrusion of extruder in the thermoplastic outermost layer, be that the extrusion die dual-side can shrink to the centre, the phenomenon of breach even appears in the edge thickness inequality, papery base layer both sides can not be capped or cladding thickness inhomogeneous, in order to prevent that flaw from appearring in the finished product packing material, three kinds of solutions are arranged usually, a kind of is to do the die head of extruder wider than the width on papery base layer and barrier layer, the defective part in extrusion die both sides is not covered on the papery base layer, cooling forming excises again in follow-up lamination operation, another kind be with the width on papery base layer and barrier layer do wider, after extruding lamination, the flaw part of excision packaging material both sides obtains qualified packaging material, moreover reduce the necking phenomenon infringement by increasing thermoplastic outermost layer thickness.These three kinds of solutions all need extruder die head than wide many of the width on papery base layer and barrier layer, need more heat heating and melting thermoplastic, cause energy waste, and also will excise the flaw part of packaging material both sides after lamination is completed, cause waste of raw materials.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of laminate wrapping material, when this material is made packing container, longitudinal sealing section can rapid heat-seal, obtain the good packing container of sealing intensity, and serious necking phenomenon can not occur when it extrudes lamination thermoplastic outermost layer in manufacture process, can not cause the serious energy and waste of raw materials.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is: a kind of laminate wrapping material, comprise from outside to inside thermoplastic outermost layer, sandwich layer, thermoplastic intermediate layer, barrier layer and thermoplastic innermost layer, wherein, described thermoplastic outermost layer comprises LLDPE (MLLDPE) and the low density polyethylene (LDPE) (LDPE) of metalloscene catalyst polymerization; The LLDPE of described metalloscene catalyst polymerization (mLLDPE) has following parameter: averag density be 0.88g/cm3～0.925g/cm3, melt flow index (190 ℃, 2.16kg) for 5g/10min～20g/10min, peak value fusing point be that 85 ℃～130 ℃, expansion ratio are 1.2～1.8; Described low density polyethylene (LDPE) (LDPE) has following parameter: averag density is 0.90g/cm
3～0.925g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～110 ℃, expansion ratio are 1.2～1.8.
In the present invention, melt flow index is measured according to 190 ℃, the condition determination of 2.16kg in GB/T3682-2000 melt flow index assay method.Expansion ratio be illustrated in GB/T3682-2000 melt flow index assay method under identical condition determination (namely 190 ℃, 2.16kg), the cross sectional dimensions ratio of the cross sectional dimensions of the extrudate of measured depanning and die orifice.The peak value fusing point is obtained by differential scanning calorimetry, if two or more peak value refers to first peak value.Low density polyethylene (LDPE) (LDPE) can be LLDPE (LLDPE), also can be non-linear low density polyethylene (LDPE), just can satisfy requirement of the present invention as long as have above-mentioned performance parameter.
As a kind of improvement of technique scheme, wherein, the LLDPE of described metalloscene catalyst polymerization (mLLDPE) has following parameter: averag density is 0.90g/cm
3～0.915g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 88 ℃～120 ℃, expansion ratio are 1.4～1.6.
As further improvement in the technical proposal, wherein, the averag density of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 0.905g/cm
3～0.910g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 93 ℃～103 ℃, expansion ratio are 1.4～1.6.
As further improvement in the technical proposal, wherein, described low density polyethylene (LDPE) (LDPE) has following parameter: averag density is 0.910g/cm
3～0.92g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～110 ℃, expansion ratio are 1.4～1.6.
As further improvement in the technical proposal, wherein, the averag density of described low density polyethylene (LDPE) (LDPE) is 0.915g/cm
3～0.920g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 93 ℃～103 ℃, expansion ratio are 1.4～1.6.
As further improvement in the technical proposal, wherein, the weight percentage (wt) of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 50%～80%, and the weight percentage (wt) of described low density polyethylene (LDPE) (LDPE) is 20%～50%.
As further improvement in the technical proposal, wherein, the weight percentage (wt) of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 60%～75%, and the weight percentage (wt) of described low density polyethylene (LDPE) (LDPE) is 25%～40%.
As further improvement in the technical proposal, wherein, the weight percentage (wt) of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 70%, and the weight percentage (wt) of described low density polyethylene (LDPE) (LDPE) is 30%.
the present invention compared with prior art, because the thermoplastic outermost layer of laminate wrapping material has adopted LLDPE (MLLDPE) and the low density polyethylene (LDPE) (LDPE) with the polymerization of particular characteristic parameter metalloscene catalyst, in the extruding layer compression technology of manufacture process, necking phenomenon during from the die head film extrusion of extruder has obtained largely reducing the thermoplastic outermost layer in molten condition, the energy and waste of raw materials phenomenon have largely inhibition, and when using laminate wrapping material of the present invention to make packing container, in process, longitudinal sealing section can rapid heat-seal, obtain the good packing container of sealing intensity, the packing container qualification rate of making is high, the time of guaranteeing the quality of food liquid is long.
Figure of description
Fig. 1 is a kind of schematic diagram of making the laminate wrapping material method.
Fig. 2 is the cross sectional representation of a kind of laminate wrapping material of the present invention.
The specific embodiment
As shown in Figure 2, a kind of laminate wrapping material of the present invention comprises thermoplastic outermost layer 21, sandwich layer 22, thermoplastic intermediate layer 23, barrier layer 24, adhesive phase 25 and thermoplastic innermost layer 26 from outside to inside successively.
Thermoplastic outermost layer 21 comprises LLDPE (MLLDPE) and the low density polyethylene (LDPE) (LDPE) of metalloscene catalyst polymerization, wherein, the LLDPE of metalloscene catalyst polymerization (mLLDPE) has following parameter: averag density is 0.88g/cm
3～0.925g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～130 ℃, expansion ratio are 1.2～1.8; Low density polyethylene (LDPE) (LDPE) has following parameter: averag density is 0.90g/cm
3～0.925g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～110 ℃, expansion ratio are 1.2～1.8, low density polyethylene (LDPE) (LDPE) can be LLDPE, can be also non-LLDPE.The weight percentage (wt) of the LLDPE of metalloscene catalyst polymerization (mLLDPE) is 50%～80%, and the weight percentage (wt) of low density polyethylene (LDPE) (LDPE) is 20%～50%.
Continue to guide the sandwich layer coiled material of impression perforate forward, arrive laminating bench, extruder squeezes out the low-density polyethylene film as thermoplastic intermediate layer 23 herein, aluminum foil coiled material as barrier layer 24 is directed to laminating bench simultaneously, it is compound that laminating bench carries out lamination to trilaminate material, be pressed together on its roll gap center core layer 22 medial surfaces, thermoplastic intermediate layer 23 and barrier layer 24, then, polyvinyl acetate ester adhesive extruding layer is being pressed onto formation adhesive phase 25 on barrier layer 24.
Then the LLDPE of blend metalloscene catalyst polymerization (mLLDPE) and low density polyethylene (LDPE) obtain blend, wherein, the LLDPE of metalloscene catalyst polymerization (mLLDPE) has following parameter: averag density be 0.910g/cm3, melt flow index (190 ℃, 2.16kg) for 13g/10min, peak value fusing point be that 124 ℃, expansion ratio are 1.5; Low density polyethylene (LDPE) (LDPE) has following parameter: averag density is 0.918g/cm
3, melt flow index (190 ℃, 2.16kg) is that 7g/10min, peak value fusing point are that 107 ℃, expansion ratio are 1.6, be pressed onto take bed thickness as the blend extruding layer of 22 microns on the adhesive phase 25 of this multilayer material and form thermoplastic innermost layer 26.
When the LLDPE (mLLDPE) of blend metalloscene catalyst polymerization and low density polyethylene (LDPE) obtain blend, can adopt the particle Direct Uniform with both materials to mix, also can adopt bi-material is mixed after again melting stir, carry out granulation again and obtain the blend particle, the mixture homogeneity of rear a kind of mode is a kind of better than front.
The laminate wrapping material that obtains in pouring in liquid food process, can reliably be completed packing container longitudinal sealing, transverse sealing fast on bottle placer, the packing container qualification rate of making is high, and the time of guaranteeing the quality of food liquid is long.
Table 1:
Claims (10)
1. laminate wrapping material, comprise from outside to inside thermoplastic outermost layer (21), sandwich layer (22), thermoplastic intermediate layer (23), barrier layer (24) and thermoplastic innermost layer (26), it is characterized in that: described thermoplastic outermost layer (21) comprises LLDPE (MLLDPE) and the low density polyethylene (LDPE) (LDPE) of metalloscene catalyst polymerization;
The LLDPE of described metalloscene catalyst polymerization (mLLDPE) has following parameter: averag density is 0.88g/cm
3～0.925g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～130 ℃, expansion ratio are 1.2～1.8;
Described low density polyethylene (LDPE) (LDPE) has following parameter: averag density is 0.90g/cm
3～0.925g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～110 ℃, expansion ratio are 1.2～1.8.
2. a kind of laminate wrapping material according to claim 1, it is characterized in that: the LLDPE of described metalloscene catalyst polymerization (mLLDPE) has following parameter: averag density is 0.90g/cm
3～0.915g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 88 ℃～120 ℃, expansion ratio are 1.4～1.6.
3. a kind of laminate wrapping material according to claim 1, it is characterized in that: the averag density of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 0.905g/cm
3～0.910g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 93 ℃～103 ℃, expansion ratio are 1.4～1.6.
4. a kind of laminate wrapping material according to claim 1, it is characterized in that: described low density polyethylene (LDPE) (LDPE) has following parameter: averag density is 0.910g/cm
3～0.92g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 85 ℃～110 ℃, expansion ratio are 1.4～1.6.
5. a kind of laminate wrapping material according to claim 4, it is characterized in that: the averag density of described low density polyethylene (LDPE) (LDPE) is 0.915g/cm
3～0.920g/cm
3, melt flow index (190 ℃, 2.16kg) is that 5g/10min～20g/10min, peak value fusing point are that 93 ℃～103 ℃, expansion ratio are 1.4～1.6.
6. a kind of laminate wrapping material according to claim 1, it is characterized in that: described low density polyethylene (LDPE) (LDPE) is LLDPE (LLDPE).
7. a kind of laminate wrapping material according to claim 1, it is characterized in that: described low density polyethylene (LDPE) (LDPE) is non-linear low density polyethylene (LDPE).
8. the described a kind of laminate wrapping material of any one according to claim 1 to 7, it is characterized in that: the weight percentage (wt) of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 50%～80%, and the weight percentage (wt) of described low density polyethylene (LDPE) (LDPE) is 20%～50%.
9. the described a kind of laminate wrapping material of any one according to claim 1 to 7, it is characterized in that: the weight percentage (wt) of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 60%～75%, and the weight percentage (wt) of described low density polyethylene (LDPE) (LDPE) is 25%～40%.
10. the described a kind of laminate wrapping material of any one according to claim 1 to 7, it is characterized in that: the weight percentage (wt) of the LLDPE of described metalloscene catalyst polymerization (mLLDPE) is 70%, and the weight percentage (wt) of described low density polyethylene (LDPE) (LDPE) is 30%.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510156782.2A CN104742439A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156921.1A CN104760384A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156922.6A CN104760393A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156917.5A CN104760380A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156918.XA CN104760392A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156793.0A CN104742473A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201210594765.3A CN103101274B (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
| CN201510156817.2A CN104760378A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
| CN201510156830.8A CN104760375A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594765.3A CN103101274B (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
Related Child Applications (8)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510156817.2A Division CN104760378A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
| CN201510156782.2A Division CN104742439A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156921.1A Division CN104760384A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156922.6A Division CN104760393A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156793.0A Division CN104742473A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156917.5A Division CN104760380A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156918.XA Division CN104760392A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156830.8A Division CN104760375A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103101274A true CN103101274A (en) | 2013-05-15 |
| CN103101274B CN103101274B (en) | 2015-04-08 |
Family
ID=48309630
Family Applications (9)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210594765.3A Ceased CN103101274B (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
| CN201510156817.2A Withdrawn CN104760378A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
| CN201510156918.XA Withdrawn CN104760392A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156922.6A Withdrawn CN104760393A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156782.2A Withdrawn CN104742439A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156793.0A Withdrawn CN104742473A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156917.5A Withdrawn CN104760380A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156921.1A Withdrawn CN104760384A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156830.8A Withdrawn CN104760375A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
Family Applications After (8)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510156817.2A Withdrawn CN104760378A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
| CN201510156918.XA Withdrawn CN104760392A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156922.6A Withdrawn CN104760393A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156782.2A Withdrawn CN104742439A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156793.0A Withdrawn CN104742473A (en) | 2012-12-31 | 2012-12-31 | Laminated package material |
| CN201510156917.5A Withdrawn CN104760380A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156921.1A Withdrawn CN104760384A (en) | 2012-12-31 | 2012-12-31 | Method for manufacturing laminated packaging material |
| CN201510156830.8A Withdrawn CN104760375A (en) | 2012-12-31 | 2012-12-31 | Laminated packaging material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3400136A1 (en) * | 2016-01-07 | 2018-11-14 | Essel Propack Limited | Laminate for vignette and tonal image printing |
| CN115491146B (en) * | 2022-02-21 | 2023-12-12 | 广东东立新材料科技股份有限公司 | Ultrahigh temperature-resistant plastic-suction forming protective film and preparation method thereof |
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| JPH07148895A (en) * | 1993-11-30 | 1995-06-13 | Dainippon Printing Co Ltd | Paper container |
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| US6974612B1 (en) * | 1999-01-27 | 2005-12-13 | Tetra Laval Holdings & Finance S.A. | Laminated packaging material for paper container |
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| SE522498C2 (en) * | 2002-05-07 | 2004-02-10 | Tetra Laval Holdings & Finance | Packaging laminate, method of manufacture thereof, and packaging container made of packaging laminate |
| CN101823355B (en) * | 2009-03-03 | 2013-09-25 | E.I.内穆尔杜邦公司 | Polymer laminated film and solar panel using laminated film |
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2012
- 2012-12-31 CN CN201210594765.3A patent/CN103101274B/en not_active Ceased
- 2012-12-31 CN CN201510156817.2A patent/CN104760378A/en not_active Withdrawn
- 2012-12-31 CN CN201510156918.XA patent/CN104760392A/en not_active Withdrawn
- 2012-12-31 CN CN201510156922.6A patent/CN104760393A/en not_active Withdrawn
- 2012-12-31 CN CN201510156782.2A patent/CN104742439A/en not_active Withdrawn
- 2012-12-31 CN CN201510156793.0A patent/CN104742473A/en not_active Withdrawn
- 2012-12-31 CN CN201510156917.5A patent/CN104760380A/en not_active Withdrawn
- 2012-12-31 CN CN201510156921.1A patent/CN104760384A/en not_active Withdrawn
- 2012-12-31 CN CN201510156830.8A patent/CN104760375A/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04234645A (en) * | 1990-12-20 | 1992-08-24 | Westvaco Corp | Paperboard container and manufacture thereof |
| JPH07148895A (en) * | 1993-11-30 | 1995-06-13 | Dainippon Printing Co Ltd | Paper container |
| JP2000167973A (en) * | 1998-12-08 | 2000-06-20 | Dainippon Printing Co Ltd | Transparent barrier film, and lamination material and package container employing the film |
| US6974612B1 (en) * | 1999-01-27 | 2005-12-13 | Tetra Laval Holdings & Finance S.A. | Laminated packaging material for paper container |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104742473A (en) | 2015-07-01 |
| CN104760392A (en) | 2015-07-08 |
| CN104760384A (en) | 2015-07-08 |
| CN103101274B (en) | 2015-04-08 |
| CN104760378A (en) | 2015-07-08 |
| CN104742439A (en) | 2015-07-01 |
| CN104760393A (en) | 2015-07-08 |
| CN104760375A (en) | 2015-07-08 |
| CN104760380A (en) | 2015-07-08 |
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Address after: 318025 Gaoqiao street, Huangyan District, Zhejiang, Taizhou Patentee after: Taizhou Zhuye Machinery Technology Co., Ltd. Address before: 318025 Gaoqiao street, Linhai City, Zhejiang Province, Huangyan Patentee before: Taizhou Zhuye Machinery Technology Co., Ltd. |
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Decision date of declaring invalidation: 20200326 Decision number of declaring invalidation: 43680 Granted publication date: 20150408 |