CN103100376B - Fiber natural polymeric adsorbent and application thereof - Google Patents
Fiber natural polymeric adsorbent and application thereof Download PDFInfo
- Publication number
- CN103100376B CN103100376B CN201310059836.4A CN201310059836A CN103100376B CN 103100376 B CN103100376 B CN 103100376B CN 201310059836 A CN201310059836 A CN 201310059836A CN 103100376 B CN103100376 B CN 103100376B
- Authority
- CN
- China
- Prior art keywords
- natural polymeric
- polymeric adsorbent
- adsorbent
- fiber natural
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003463 adsorbent Substances 0.000 title claims abstract description 67
- 239000000835 fiber Substances 0.000 title claims abstract description 42
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000012153 distilled water Substances 0.000 claims abstract description 28
- 239000002351 wastewater Substances 0.000 claims abstract description 28
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims abstract description 26
- 244000046052 Phaseolus vulgaris Species 0.000 claims abstract description 26
- 239000000126 substance Substances 0.000 claims abstract description 20
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 17
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 5
- 238000012545 processing Methods 0.000 claims abstract description 3
- 238000010521 absorption reaction Methods 0.000 claims description 16
- 150000004780 naphthols Chemical class 0.000 claims description 15
- 238000005406 washing Methods 0.000 claims description 11
- 238000001291 vacuum drying Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 150000003384 small molecules Chemical class 0.000 claims description 9
- 244000068988 Glycine max Species 0.000 claims description 7
- 235000010469 Glycine max Nutrition 0.000 claims description 7
- 235000013336 milk Nutrition 0.000 claims description 6
- 239000008267 milk Substances 0.000 claims description 6
- 210000004080 milk Anatomy 0.000 claims description 6
- 235000013527 bean curd Nutrition 0.000 claims description 3
- 239000010802 sludge Substances 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 12
- 229920002678 cellulose Polymers 0.000 abstract description 10
- 239000001913 cellulose Substances 0.000 abstract description 10
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 abstract description 8
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 8
- 229910001431 copper ion Inorganic materials 0.000 abstract description 8
- 239000000975 dye Substances 0.000 abstract description 8
- 229940107698 malachite green Drugs 0.000 abstract description 8
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 abstract description 8
- 229960000907 methylthioninium chloride Drugs 0.000 abstract description 8
- 238000001179 sorption measurement Methods 0.000 abstract description 8
- JUQPZRLQQYSMEQ-UHFFFAOYSA-N CI Basic red 9 Chemical compound [Cl-].C1=CC(N)=CC=C1C(C=1C=CC(N)=CC=1)=C1C=CC(=[NH2+])C=C1 JUQPZRLQQYSMEQ-UHFFFAOYSA-N 0.000 abstract description 7
- 229940052223 basic fuchsin Drugs 0.000 abstract description 7
- 229920005610 lignin Polymers 0.000 abstract description 7
- 229920005615 natural polymer Polymers 0.000 abstract description 7
- 238000012360 testing method Methods 0.000 abstract description 7
- 238000004065 wastewater treatment Methods 0.000 abstract description 5
- 102000003886 Glycoproteins Human genes 0.000 abstract description 4
- 108090000288 Glycoproteins Proteins 0.000 abstract description 4
- 150000002500 ions Chemical class 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 206010027439 Metal poisoning Diseases 0.000 abstract description 2
- 208000010501 heavy metal poisoning Diseases 0.000 abstract description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000729 antidote Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000002957 persistent organic pollutant Substances 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 238000004042 decolorization Methods 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 7
- 238000007654 immersion Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 6
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 6
- 230000010355 oscillation Effects 0.000 description 6
- 238000010298 pulverizing process Methods 0.000 description 6
- 238000000967 suction filtration Methods 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 235000018102 proteins Nutrition 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000001784 detoxification Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000010815 organic waste Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- ZHUXMBYIONRQQX-UHFFFAOYSA-N hydroxidodioxidocarbon(.) Chemical compound [O]C(O)=O ZHUXMBYIONRQQX-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- CJWQYWQDLBZGPD-UHFFFAOYSA-N isoflavone Natural products C1=C(OC)C(OC)=CC(OC)=C1C1=COC2=C(C=CC(C)(C)O3)C3=C(OC)C=C2C1=O CJWQYWQDLBZGPD-UHFFFAOYSA-N 0.000 description 1
- 150000002515 isoflavone derivatives Chemical class 0.000 description 1
- 235000008696 isoflavones Nutrition 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000014786 phosphorus Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310059836.4A CN103100376B (en) | 2013-02-26 | 2013-02-26 | Fiber natural polymeric adsorbent and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310059836.4A CN103100376B (en) | 2013-02-26 | 2013-02-26 | Fiber natural polymeric adsorbent and application thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103100376A CN103100376A (en) | 2013-05-15 |
CN103100376B true CN103100376B (en) | 2015-05-13 |
Family
ID=48308768
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310059836.4A Expired - Fee Related CN103100376B (en) | 2013-02-26 | 2013-02-26 | Fiber natural polymeric adsorbent and application thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103100376B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103447007A (en) * | 2013-07-26 | 2013-12-18 | 北京工业大学 | Modified bean dreg adsorbent and preparation method as well as application thereof |
US10668416B2 (en) | 2014-08-15 | 2020-06-02 | Strix (Usa), Inc. | Granular filtration media mixture and uses in water purification |
CN105170077B (en) * | 2015-09-30 | 2017-10-27 | 太仓碧奇新材料研发有限公司 | The preparation method of pinkish red chalk powder composite material in a kind of removal dyeing waste water |
CN105080514B (en) * | 2015-10-09 | 2017-04-12 | 吉首大学 | Preparation method of cellulose-base absorbent |
CN105174354B (en) * | 2015-10-12 | 2017-11-14 | 南阳师范学院 | A kind of method that Wastewater Dyes are removed using waste edible fungus gurry |
CN107497408B (en) * | 2017-10-16 | 2020-10-02 | 西南大学 | Preparation method and application of novel polycyclic aromatic hydrocarbon compound (PAHs) adsorbent |
CN107865443A (en) * | 2017-10-26 | 2018-04-03 | 吕燕强 | A kind of preparation method of gomuti palm powder |
CN109231348A (en) * | 2018-11-20 | 2019-01-18 | 兰州城市学院 | The application of Propiram mycelium pellet and its derivative in processing organic dye waste water |
CN115364816A (en) * | 2022-09-22 | 2022-11-22 | 河北科技大学 | Modified wormcast and preparation method and application thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4462789B2 (en) * | 2001-09-03 | 2010-05-12 | 独立行政法人森林総合研究所 | Heavy metal adsorbent and method for producing the same |
CN101239305A (en) * | 2008-03-06 | 2008-08-13 | 上海交通大学 | Method for preparing modified plant fibrous sale price biological adsorption agent |
CN101703921B (en) * | 2009-10-31 | 2012-01-11 | 华南理工大学 | Method for preparing adsorbent by modifying pineapple peel residues |
-
2013
- 2013-02-26 CN CN201310059836.4A patent/CN103100376B/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN103100376A (en) | 2013-05-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103100376B (en) | Fiber natural polymeric adsorbent and application thereof | |
CN103071463A (en) | Modified peanut shell Pb(II) adsorbent, and preparation method and application thereof | |
CN103212378B (en) | Preparation method and application of citric acid modified palm tree bark adsorbing agent | |
CN103071461B (en) | The preparation of xanthogenation loess adsorbent and application in the treatment of waste water | |
CN101934223B (en) | Preparation method for composite crosslinked adsorbent for waste water treatment | |
CN106984285A (en) | The method that amination modifying sorbing material is prepared by matrix of polymer fiber material | |
CN104226259A (en) | Threonine modified attapulgite adsorbent and application thereof | |
CN109317122A (en) | A kind of modified alkali lignin and preparation method thereof and application as heavy metal ion agent for capturing | |
CN106861642B (en) | A kind of preparation and application of the biomass-based hydrogel with high absorption capacity | |
CN105413648A (en) | Folium ginkgo adsorbing material and preparation method thereof | |
CN103464119A (en) | Preparation method and application of modified cysteine palm bark adsorbent | |
Saraei et al. | Removing acidic yellow dye from wastewater using Moringa peregrina | |
CN101601991A (en) | Remove biomass adsorbent and preparation, application and the renovation process of lead ion in the waste water | |
CN102908998B (en) | Preparation method of xanthate macro-pore dextrangel adsorbent | |
CN103933944A (en) | Preparation and application of gamma-(aminopropyl)triethoxysilane modified loofah sponge adsorbent | |
CN105381787A (en) | New environmentally friendly adsorbent material and preparation process thereof | |
CN111167417A (en) | Modified bagasse, preparation method thereof and application of modified bagasse as adsorbent | |
CN105561943B (en) | A kind of preparation method and application of magnetic rape stalk sorbing material | |
CN104689795A (en) | Adsorbing material using soybean protein to load konjac glucomannan and preparation method thereof | |
CN101912767A (en) | Method for preparing modified furfural residue heavy metal adsorbent | |
CN106076301A (en) | The preparation method of succinic anhydride modified pomelo peel oil absorption material | |
CN105642245A (en) | Preparation method of magnetic egg white/loofah sponge adsorbing material | |
CN105692845A (en) | Preparing technology for shaddock peel natural coagulants | |
CN103464118B (en) | A kind of preparations and applicatio of epoxychloropropane palm fibre modification palmitic acid bark adsorbent | |
Saraei et al. | Removal of acidic yellow dye of wastewater by Moringa Peregrina |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: GANSU PLANTS TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: NORTHWEST NORMAL UNIVERSITY Effective date: 20150122 |
|
C41 | Transfer of patent application or patent right or utility model | ||
C53 | Correction of patent for invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Wang Rongmin Inventor after: Li Huiru Inventor after: He Yufeng Inventor after: Huang Yijun Inventor after: Zhang Lijia Inventor after: Meng Yuwei Inventor before: Wang Rongmin Inventor before: Li Huiru Inventor before: He Yufeng Inventor before: Huang Yijun Inventor before: Zhang Lijia |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: WANG RONGMIN LI HUIRU HE YUFENG HUANG YIJUN ZHANG LIJIA TO: WANG RONGMIN LI HUIRU HE YUFENG HUANG YIJUN ZHANG LIJIA MENG YUWEI Free format text: CORRECT: ADDRESS; FROM: 730070 LANZHOU, GANSU PROVINCE TO: 730050 LANZHOU, GANSU PROVINCE |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20150122 Address after: Qilihe Xijin road 730050 Gansu city of Lanzhou province No. 1168 Applicant after: GANSU TIPTOP PLANT TECHNOLOGY CORP., LTD. Address before: 730070 Anning Road, Anning District, Gansu, Lanzhou, China, No. 967 Applicant before: Northwest Normal University |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150513 Termination date: 20180226 |