CN103086603A - Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic - Google Patents
Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic Download PDFInfo
- Publication number
- CN103086603A CN103086603A CN2012105754260A CN201210575426A CN103086603A CN 103086603 A CN103086603 A CN 103086603A CN 2012105754260 A CN2012105754260 A CN 2012105754260A CN 201210575426 A CN201210575426 A CN 201210575426A CN 103086603 A CN103086603 A CN 103086603A
- Authority
- CN
- China
- Prior art keywords
- zirconium
- look
- colored glass
- dental prosthesis
- colorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Glass Compositions (AREA)
Abstract
The invention relates to a ceramic for a dental prosthesis, and discloses a colored glass ceramic for manufacturing the dental prosthesis and a preparation method for the colored glass ceramic. By adopting the colored glass ceramic, under the condition that the requirements on mechanical property of a dental glass ceramic are met, 16 colors of a Vitapan Classical color board which is most frequently used in dentistry can be obtained. The colored glass ceramic for manufacturing the dental prosthesis is characterized by comprising the following components in percentage by mass: 98.5 to 99.85 percent of basic component and 0.15 to 1.5 percent of pigment component, wherein the basic component comprises the following components in percentage by mass: 56 to 59 percent of SiO2, 28 to 30 percent of Li2CO3, 3.7 to 4.0 percent of K2CO3, 2.7 to 3.0 percent of Al2O3, 2.3 to 2.4 percent of ZrO2, 1.5 to 1.6 percent of CeO2 and 2.5 to 3.0 percent of P2O5; and the pigment component comprises zirconium praseodymium yellow, zirconium iron pink or zirconium vanadium blue, or any combination thereof.
Description
Technical field
The present invention relates to dental prosthesis with ceramic, particularly a kind of colored glass pottery for making dental prosthesis and preparation method thereof.
Background technology
Stupalith is because of its good biological safety and aesthetic property, and is more and more extensive in the application in field, oral cavity, and become emphasis and the focus of Oral Repair area research.Dental porcelain mainly comprises: feldspathic china, glass-ceramic, alumina ceramics and zirconium oxide porcelain.
Feldspathic china is low brilliant ceramic material, and its crystalline component is few, structurally closer to glass.The dental case permeability made from this class pottery is high, have good aesthetic property, but its flexural strength is usually lower, can only be used as finishing material or be used for making inlay and veneer of anterior tooth.Interpolation white garnet, mica etc. can carry out this class material toughness reinforcing, but the raising of the intensity of the material after toughness reinforcing is limited, still is confined to make inlay, labial teeth leaf-comb and veneer.
Alumina-ceramic and zirconia ceramics are the highest dental porcelains of physical strength, but its optical property is relatively poor, pure aluminum oxide and zirconium oxide porcelain present opaque white, light transmission is little, the making of multiplex stratum basale in all kinds of dummies, dummy aesthetic property and the emulation made are relatively poor, are not suitable for the aesthetics reparation for labial teeth.
Glass-ceramic is crystalline phase and the equally distributed polycrystalline solids of glassy phase that is made by controlling crystallizing by host glass, and it has concentrated the characteristics of pottery and glass.Separate out crystalline phase by thermal treatment process, the strength of materials and toughness are improved; In addition, containing the glassy phase of certain content due to glass-ceramic, possess outstanding semi-transparent characteristic, can farthest reproduce color and luster and the light transmission features of natural teeth, is the aesthstic preferred material of repairing of labial teeth.Increasing glass-ceramic product by Application and Development in succession in the Oral Repair field.But, substrate porcelain (core porcelain) color category of Dental Glass Ceramics is less at present, color as IPS e.max substrate porcelain only has 3～5 kinds, and the color category of clinical dentistry color board commonly used is more than 16 kinds, therefore, there is the inconsistent problem of color with the dentistry color board in the dummy of making of the substrate porcelain of present commercial glass-ceramic, needs when usually making dye to it.
Summary of the invention
The object of the present invention is to provide a kind of colored glass pottery for making dental prosthesis and preparation method thereof, require in the situation that satisfy the Dental Glass Ceramics mechanical property, can obtain 16 kinds of colors of the most frequently used Vitapan Classical color board of dentistry.
To achieve these goals, the present invention is achieved by the following technical solutions.
Technical scheme one:
A kind of colored glass pottery for making dental prosthesis is characterized in that, comprises that mass percent is 98.5～99.85% basal component and 0.15～1.5% colorant component; The mass percent of described basal component: 56～59% SiO
2, 28～30% Li
2CO
3, 3.7～4.0% K
2CO
3, 2.7～3.0% Al
2O
3, 2.3～2.4% ZrO
2, 1.5～1.6% CeO
2, and 2.5～3.0% P
2O
5Described colorant component comprises zirconium praseodymium yellow, zirconium iron pink or zirconium vanadium blue, or their arbitrary combination.
In technique scheme, preferably, the mass percent of described colorant component is less than 1.0%.
Preferably, 16 kinds of colors of corresponding Vitapan Classical color board, mass percent such as the following table of zirconium praseodymium yellow, zirconium iron pink, three kinds of colorants of zirconium vanadium blue:
| Color notation | Zirconium praseodymium yellow (wt%) | Zirconium iron pink (wt%) | Zirconium vanadium blue (wt%) |
| A1 | 0.13～0.28 | 0.03～0.09 | 0.01～0.05 |
| A2 | 0.30～0.42 | 0.06～0.13 | 0.02～0.07 |
| A3 | 0.44～0.56 | 0.10～0.17 | 0.04～0.09 |
| A3.5 | 0.57～0.66 | 0.12～0.19 | 0.05～0.11 |
| A4 | 0.67～0.90 | 0.13～0.25 | 0.06～0.14 |
| B1 | 0.15～0.28 | 0.02～0.06 | 0.01～0.04 |
| B2 | 0.30～0.44 | 0.04～0.09 | 0.02～0.06 |
| B3 | 0.46～0.69 | 0.07～0.14 | 0.03～0.09 |
| B4 | 0.70～0.90 | 0.10～0.18 | 0.05～0.11 |
| C1 | 0.17～0.29 | 0.05～0.11 | 0.05～0.11 |
| C2 | 0.30～0.44 | 0.08～0.15 | 0.08～0.15 |
| C3 | 0.45～0.56 | 0.12～0.19 | 0.12～0.19 |
| C4 | 0.57～0.76 | 0.15～0.25 | 0.15～0.25 |
| D2 | 0.18～0.30 | 0.05～0.11 | 0.04～0.10 |
| D3 | 0.32～0.59 | 0.10～0.20 | 0.08～0.17 |
| D4 | 0.37～0.60 | 0.07～0.21 | 0.06～0.15 |
Preferably, A look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 4.5:1.2:0.7; Corresponding its A1 look, A2 look, A3 look, A3.5 look, A4 look, the mass percent of colorant component is respectively: A1,0.3%; A2,0.5%; A3,0.7%; A3.5,0.85%; A4,1.0%.
Preferably, B look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 5:1:0.6; Corresponding its B1 look, B2 look, B3 look, B4 look, the mass percent of colorant component is respectively: B1,0.3%; B2,0.5%; B3,0.75%; B4,1.0%.
Preferably, C look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 4:1.3:1.2; Corresponding its C1 look, C2 look, C3 look, C4 look, the mass percent of colorant component is respectively: C1,0.4%; C2,0.6%; C3,0.8%; C4,1.0%.
Preferably, D2 and D3 look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 4:1.4:1.1; Corresponding its D2 and D3 look, the mass percent of colorant component is respectively: D2,0.4%; D3,0.6%.
Preferably, D4 look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 5:1.1:1; Corresponding its D4 look, the mass percent of colorant component is 0.7%.
Technical scheme two:
The preparation method of above-mentioned colored glass pottery for making dental prosthesis is characterized in that, comprises the following steps:
Take basal component and colorant component according to mass percent.Basal component is poured in ball grinder, added dehydrated alcohol, wet ball grinding mixes post-drying, gets mixed powder; Mixed powder is poured in quartz crucible, then 1400～1500 ℃ of melting 1.5～2h will melt slurry and pour in deionized water again, and cold quenching obtains glass particle; Glass particle is placed in agate jar, ball milling, drying gets glass powder; Again colorant and glass powder are placed in agate jar, ball milling, mixing, drying gets the colored glass powder; At last, the colored glass powder is put into prefabricated flask cold isostatic compaction, the base substrate after moulding carries out the two-part crystallization and thermal treatment, gets final product.
In technique scheme, described two-part crystallization and thermal treatment is 700 ℃/5h and 900 ℃/5h.
The color matching method of the glass-ceramic for making dental prosthesis of the present invention can be prepared the glass-ceramic that possesses 16 kinds of colors of dentistry Vitapan Classical color board, and the total content of its colorant component zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue is less than 1.0wt%.Add the 1.0wt% colorant on phase composition, microtexture and 3 curved intensity of glass-ceramic without impact.The three-point bending strength of the glass-ceramic after painted is (310MPa), satisfies dental porcelain ISO required standard.In addition, the glass-ceramic after painted still can keep semipermeability preferably when obtaining high-mechanical property.
Description of drawings
Below in conjunction with accompanying drawing and concrete body embodiment, the present invention is described in further details.
Fig. 1 is not for adding colorant, adding the scanning electron microscope (SEM) photograph of the glass-ceramic of 1.0wt% monochrome and colour mixture colorant (zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue mass ratio are 10:3:3).
Fig. 2 is not for adding colorant, adding X-ray diffraction analysis (XRD) figure of the glass-ceramic of 1.0wt% monochrome and colour mixture colorant (zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue mass ratio are 10:3:3).
Fig. 3 be the colored glass pottery of embodiment 2 preparation and dentistry Vitapan Classical color board 16 looks than color chips figure.
Fig. 4 be the colored glass pottery of embodiment 3 preparation and dentistry Vitapan Classical color board 16 looks than color chips figure.
Fig. 5 be the colored glass pottery of embodiment 4 preparation and dentistry Vitapan Classical color board 16 looks than color chips figure.
Fig. 6 be the colored glass pottery of embodiment 5 preparation and dentistry Vitapan Classical color board 16 looks than color chips figure.
Embodiment
Embodiment 1
Take according to mass ratio: 58.0% SiO
2, 29.0% Li
2CO
3, 3.7% K
2CO
3, 2.8% Al
2O
3, 2.4% ZrO
2, 1.5% CeO
2, 2.6% P
2O
5Amount to 500g as batching standby.
With the SiO that takes
2, Li
2CO
3, K
2CO
3,, Al
2O
3, ZrO
2, CeO
2, P
2O
5Pour in ball grinder, add the 500ml dehydrated alcohol, wet ball grinding 8h puts into baking oven after mixing, and 80 ℃ of oven dry 24h get mixed powder.
Quartz crucible is placed in the resistance furnace preheating, and resistance furnace is poured mixed powder in the quartz crucible of preheating after being warming up to 1480 ℃ with 10 ℃/min speed, founds 2h at 1480 ℃, and the molten slurry after melting is poured into rapidly in deionized water, and cold quenching obtains glass particle.The glass particle that obtains is placed in agate jar, adds 500ml dehydrated alcohol ball milling 12h, drying is crossed 120 mesh sieves, gets minus mesh, gets glass powder.
Before three kinds of colorants of zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue use with 10% hydrochloric acid in 80 ℃ of pickling 30min, then use washed with de-ionized water in supersonic cleaning machine, until the pH value is 7.
Not add colorant, interpolation 1.0wt% monochrome and colour mixture colorant (zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue mass ratio are as 10:3:3) as grouping.Do not add the colorant group, take 3g glass powder.Add 1.0wt% colorant group, take 2.97g glass powder and 0.03g colorant.Each group glass powder and colorant are placed in respectively agate jar, ball milling 2h, mixing.Add the 3mL deionized water in colored glass powder after mixing, and the prefabricated flask of packing into (cylindrical die cavity, diameter 13mm), cold isostatic compaction under 250MPa pressure forms base substrate.Above-mentioned base substrate is carried out crystallization and thermal treatment, begin to be warming up to 700 ℃ from room temperature, 700 ℃ of insulations were warming up to 900 ℃ after 5 hours, were incubated 5 hours, 10 ℃/min of temperature rise rate.Base substrate furnace cooling after crystallization is completed, be prepared into corresponding glass-ceramic, in conjunction with Fig. 1 for not adding colorant, adding the scanning electron microscope (SEM) photograph of glass-ceramic of 1.0wt% monochrome and colour mixture colorant (zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue mass ratio are 10:3:3) and Fig. 2 for not adding colorant, adding X-ray diffraction analysis (XRD) figure of the glass-ceramic of 1.0wt% monochrome and colour mixture colorant (zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue mass ratio are 10:3:3), and it is carried out three-point bending strength and transparency (TP value) analysis, result such as following table.
| Three-point bending strength (MPa) | Transparency (TP value) | |
| Do not add colorant | 312±22 a | 21.0±0.4 a |
| Add 1.0wt% zirconium praseodymium yellow | 301±16 a | 29.7±0.6 b |
| Add the 1.0wt% zirconium iron pink | 306±27 a | 14.0±0.4 c |
| Add the 1.0wt% zirconium vanadium blue | 299±22 a | 13.0±0.3 d |
| Add the 1.0wt% colour mixture | 315±19 a | 15.7±0.7 e |
*Same letter is shown no difference of science of statistics between group (p＞0.05)
The colorant of interpolation 1.0wt% does not make significant difference to microtexture, phase composition and the three-point bending strength of the glass-ceramic for making dental prosthesis of the present invention.Prepared colored glass pottery still can keep semipermeability preferably in the situation that satisfy the Dental Glass Ceramics mechanical property and require.
Embodiment 2
Take according to mass percent: 58.0% SiO
2, 29.0% Li
2CO
3, 3.7% K
2CO
3, 2.8% Al
2O
3, 2.4% ZrO
2, 1.5% CeO
2, 2.6% P
2O
5Amount to 500g as batching standby.
With the SiO that takes
2, Li
2CO
3, K
2CO
3,, Al
2O
3, ZrO
2, CeO
2, P
2O
5Pour in ball grinder, add the 500ml dehydrated alcohol, wet ball grinding 8h puts into baking oven after mixing, and 80 ℃ of oven dry 24h get mixed powder.
Quartz crucible is placed in the resistance furnace preheating, and resistance furnace is poured mixed powder in the quartz crucible of preheating after being warming up to 1480 ℃ with 10 ℃/min speed, founds 2h at 1480 ℃, and the molten slurry after melting is poured into rapidly in deionized water, and cold quenching obtains glass particle.The glass particle that obtains is placed in agate jar, adds 500ml dehydrated alcohol ball milling 12h, drying is crossed 120 mesh sieves, gets minus mesh, gets glass powder.
Before three kinds of colorants of zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue use with 10% hydrochloric acid in 80 ℃ of pickling 30min, then use washed with de-ionized water in supersonic cleaning machine, until the pH value is 7.According to Vitapan Classical color board 16 look color formulas, take glass powder and colorant amounts to 2g, the concrete quality per distribution ratio of each colorant sees the following form:
| Color notation | Zirconium praseodymium yellow (wt%) | Zirconium iron pink (wt%) | Zirconium vanadium blue (wt%) | Glass powder (wt%) |
| A1 | 0.21 | 0.06 | 0.03 | 99.70 |
| A2 | 0.35 | 0.09 | 0.05 | 99.51 |
| A3 | 0.49 | 0.13 | 0.08 | 99.30 |
| A3.5 | 0.60 | 0.16 | 0.09 | 99.15 |
| A4 | 0.70 | 0.19 | 0.11 | 99.00 |
| B1 | 0.23 | 0.05 | 0.03 | 99.69 |
| B2 | 0.38 | 0.08 | 0.05 | 99.49 |
| B3 | 0.57 | 0.11 | 0.07 | 99.25 |
| B4 | 0.76 | 0.15 | 0.09 | 99.00 |
| C1 | 0.25 | 0.08 | 0.07 | 99.60 |
| C2 | 0.37 | 0.12 | 0.11 | 99.40 |
| C3 | 0.49 | 0.16 | 0.15 | 99.20 |
| C4 | 0.61 | 0.20 | 0.19 | 99.00 |
| D2 | 0.25 | 0.09 | 0.07 | 99.59 |
| D3 | 0.37 | 0.13 | 0.10 | 99.40 |
| D4 | 0.49 | 0.11 | 0.10 | 99.30 |
Each group glass powder and colorant are placed in respectively agate jar, ball milling 2h, mixing.Add the 2mL deionized water in colored glass powder after mixing, and the prefabricated flask of packing into (cylindrical die cavity, diameter 13mm), cold isostatic compaction under 250MPa pressure forms base substrate.Above-mentioned base substrate is carried out crystallization and thermal treatment, begin to be warming up to 700 ℃ from room temperature, 700 ℃ of insulations were warming up to 900 ℃ after 5 hours, were incubated 5 hours, 10 ℃/min of temperature rise rate.Base substrate furnace cooling after crystallization is completed is namely completed the preparation of the colored glass pottery that is applied to mutually to make dental prosthesis.
Glass-ceramic (as shown in Figure 3) after painted by above-mentioned preparation method has obtained the color close with dentistry Vitapan Classical color board, each porcelain piece with corresponding be 4.7 than the average color difference between color chips, less than the clinical threshold of accepting.
Embodiment 3
Take according to mass ratio: 58.0% SiO
2, 29.0% Li
2CO
3, 3.7% K
2CO
3, 2.8% Al
2O
3, 2.4% ZrO
2, 1.5% CeO
2, 2.6% P
2O
5Amount to 500g as batching standby.
With the SiO that takes
2, Li
2CO
3, K
2CO
3,, Al
2O
3, ZrO
2, CeO
2, P
2O
5Pour in ball grinder, add the 500ml dehydrated alcohol, wet ball grinding 8h puts into baking oven after mixing, and 80 ℃ of oven dry 24h get mixed powder.
Quartz crucible is placed in the resistance furnace preheating, and resistance furnace is poured mixed powder in the quartz crucible of preheating after being warming up to 1480 ℃ with 10 ℃/min speed, founds 2h at 1480 ℃, and the molten slurry after melting is poured into rapidly in deionized water, and cold quenching obtains glass particle.The glass particle that obtains is placed in agate jar, adds 500ml dehydrated alcohol ball milling 12h, drying is crossed 120 mesh sieves, gets minus mesh, gets glass powder.
Before three kinds of colorants of zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue use with 10% hydrochloric acid in 80 ℃ of pickling 30min, then use washed with de-ionized water in supersonic cleaning machine, until the pH value is 7.According to Vitapan Classical color board 16 look color formulas, take glass powder and colorant amounts to 2g, the concrete quality per distribution ratio of each colorant sees the following form:
| Color notation | Zirconium praseodymium yellow (wt%) | Zirconium iron pink (wt%) | Zirconium vanadium blue (wt%) | Glass powder (wt%) |
| A1 | 0.22 | 0.05 | 0.02 | 99.71 |
| A2 | 0.37 | 0.09 | 0.04 | 99.50 |
| A3 | 0.52 | 0.12 | 0.06 | 99.30 |
| A3.5 | 0.63 | 0.15 | 0.07 | 99.15 |
| A4 | 0.74 | 0.18 | 0.08 | 99.00 |
| B1 | 0.24 | 0.04 | 0.02 | 99.70 |
| B2 | 0.40 | 0.07 | 0.04 | 99.49 |
| B3 | 0.60 | 0.10 | 0.06 | 99.24 |
| B4 | 0.80 | 0.13 | 0.07 | 99.00 |
| C1 | 0.24 | 0.08 | 0.08 | 99.60 |
| C2 | 0.35 | 0.12 | 0.12 | 99.41 |
| C3 | 0.47 | 0.16 | 0.16 | 99.21 |
| C4 | 0.58 | 0.21 | 0.21 | 99.00 |
| D2 | 0.24 | 0.08 | 0.07 | 99.61 |
| D3 | 0.37 | 0.12 | 0.11 | 99.40 |
| D4 | 0.43 | 0.16 | 0.11 | 99.30 |
Each group glass powder and colorant are placed in respectively agate jar, ball milling 2h, mixing.Add the 2mL deionized water in colored glass powder after mixing, and the prefabricated flask of packing into (cylindrical die cavity, diameter 13mm), cold isostatic compaction under 250MPa pressure forms base substrate.Above-mentioned base substrate is carried out crystallization and thermal treatment, begin to be warming up to 700 ℃ from room temperature, 700 ℃ of insulations were warming up to 900 ℃ after 5 hours, were incubated 5 hours, 10 ℃/min of temperature rise rate.Base substrate furnace cooling after crystallization is completed is namely completed the preparation of the colored glass pottery that is applied to mutually to make dental prosthesis.
Glass-ceramic (as shown in Figure 4) after painted by above-mentioned preparation method has obtained the color close with dentistry VitapanClassical color board, each porcelain piece with corresponding be 5.3 than the average color difference between color chips, less than the clinical threshold of accepting.
Embodiment 4
Take according to mass ratio: 58.0% SiO
2, 29.0% Li
2CO
3, 3.7% K
2CO
3, 2.8% Al
2O
3, 2.4% ZrO
2, 1.5% CeO
2, 2.6% P
2O
5Amount to 500g as batching standby.
With the SiO that takes
2, Li
2CO
3, K
2CO
3,, Al
2O
3, ZrO
2, CeO
2, P
2O
5Pour in ball grinder, add the 500ml dehydrated alcohol, wet ball grinding 8h puts into baking oven after mixing, and 80 ℃ of oven dry 24h get mixed powder.
Quartz crucible is placed in the resistance furnace preheating, and resistance furnace is poured mixed powder in the quartz crucible of preheating after being warming up to 1480 ℃ with 10 ℃/min speed, founds 2h at 1480 ℃, and the molten slurry after melting is poured into rapidly in deionized water, and cold quenching obtains glass particle.The glass particle that obtains is placed in agate jar, adds 500ml dehydrated alcohol ball milling 12h, drying is crossed 120 mesh sieves, gets minus mesh, gets glass powder.
Before three kinds of colorants of zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue use with 10% hydrochloric acid in 80 ℃ of pickling 30min, then use washed with de-ionized water in supersonic cleaning machine, until the pH value is 7.According to Vitapan Classical color board 16 look color formulas, take glass powder and colorant amounts to 2g, the concrete quality per distribution ratio of each colorant sees the following form:
| Color notation | Zirconium praseodymium yellow (wt%) | Zirconium iron pink (wt%) | Zirconium vanadium blue (wt%) | Glass powder (wt%) |
| A1 | 0.23 | 0.05 | 0.02 | 99.70 |
| A2 | 0.39 | 0.08 | 0.04 | 99.49 |
| A3 | 0.54 | 0.11 | 0.05 | 99.30 |
| A3.5 | 0.66 | 0.13 | 0.06 | 99.15 |
| A4 | 0.77 | 0.16 | 0.07 | 99.00 |
| B1 | 0.25 | 0.04 | 0.02 | 99.69 |
| B2 | 0.41 | 0.06 | 0.03 | 99.50 |
| B3 | 0.61 | 0.09 | 0.05 | 99.25 |
| B4 | 0.81 | 0.12 | 0.06 | 99.01 |
| C1 | 0.25 | 0.08 | 0.08 | 99.59 |
| C2 | 0.37 | 0.12 | 0.12 | 99.39 |
| C3 | 0.50 | 0.15 | 0.15 | 99.20 |
| C4 | 0.62 | 0.19 | 0.19 | 99.00 |
| D2 | 0.25 | 0.08 | 0.07 | 99.60 |
| D3 | 0.38 | 0.12 | 0.10 | 99.40 |
| D4 | 0.44 | 0.15 | 0.11 | 99.30 |
Each group glass powder and colorant are placed in respectively agate jar, ball milling 2h, mixing.Add the 2mL deionized water in colored glass powder after mixing, and the prefabricated flask of packing into (cylindrical die cavity, diameter 13mm), cold isostatic compaction under 250MPa pressure forms base substrate.Above-mentioned base substrate is carried out crystallization and thermal treatment, begin to be warming up to 700 ℃ from room temperature, 700 ℃ of insulations were warming up to 900 ℃ after 5 hours, were incubated 5 hours, 10 ℃/min of temperature rise rate.Base substrate furnace cooling after crystallization is completed is namely completed the preparation of the colored glass pottery that is applied to mutually to make dental prosthesis.
Glass-ceramic (as shown in Figure 5) after painted by above-mentioned preparation method has obtained the color close with dentistry Vitapan Classical color board, each porcelain piece with corresponding be 6.2 than the average color difference between color chips, less than the clinical threshold of accepting.
Embodiment 5
Take according to mass ratio: 58.0% SiO
2, 29.0% Li
2CO
3, 3.7% K
2CO
3, 2.8% Al
2O
3, 2.4% ZrO
2, 1.5% CeO
2, 2.6% P
2O
5Amount to 500g as batching standby.
With the SiO that takes
2, Li
2CO
3, K
2CO
3,, Al
2O
3, ZrO
2, CeO
2, P
2O
5Pour in ball grinder, add the 500ml dehydrated alcohol, wet ball grinding 8h puts into baking oven after mixing, and 80 ℃ of oven dry 24h get mixed powder.
Quartz crucible is placed in the resistance furnace preheating, and resistance furnace is poured mixed powder in the quartz crucible of preheating after being warming up to 1480 ℃ with 10 ℃/min speed, founds 2h at 1480 ℃, and the molten slurry after melting is poured into rapidly in deionized water, and cold quenching obtains glass particle.The glass particle that obtains is placed in agate jar, adds 500ml dehydrated alcohol ball milling 12h, drying is crossed 120 mesh sieves, gets minus mesh, gets glass powder.
Before three kinds of colorants of zirconium praseodymium yellow, zirconium iron pink, zirconium vanadium blue use with 10% hydrochloric acid in 80 ℃ of pickling 30min, then use washed with de-ionized water in supersonic cleaning machine, until the pH value is 7.According to Vitapan Classical color board 16 look color formulas, take glass powder and colorant amounts to 2g, the concrete quality per distribution ratio of each colorant sees the following form:
| Color notation | Zirconium praseodymium yellow (wt%) | Zirconium iron pink (wt%) | Zirconium vanadium blue (wt%) | Glass powder (wt%) |
| A1 | 0.22 | 0.06 | 0.02 | 99.70 |
| A2 | 0.37 | 0.10 | 0.04 | 99.49 |
| A3 | 0.52 | 0.13 | 0.05 | 99.30 |
| A3.5 | 0.63 | 0.16 | 0.06 | 99.15 |
| A4 | 0.73 | 0.19 | 0.08 | 99.00 |
| B1 | 0.24 | 0.05 | 0.02 | 99.69 |
| B2 | 0.40 | 0.08 | 0.03 | 99.49 |
| B3 | 0.60 | 0.11 | 0.05 | 99.24 |
| B4 | 0.79 | 0.14 | 0.07 | 99.00 |
| C1 | 0.26 | 0.07 | 0.07 | 99.60 |
| C2 | 0.39 | 0.11 | 0.11 | 99.39 |
| C3 | 0.52 | 0.14 | 0.14 | 99.20 |
| C4 | 0.64 | 0.18 | 0.18 | 99.00 |
| D2 | 0.26 | 0.08 | 0.06 | 99.60 |
| D3 | 0.39 | 0.12 | 0.10 | 99.39 |
| D4 | 0.49 | 0.12 | 0.10 | 99.29 |
Each group glass powder and colorant are placed in respectively agate jar, ball milling 2h, mixing.Add the 2mL deionized water in colored glass powder after mixing, and the prefabricated flask of packing into (cylindrical die cavity, diameter 13mm), cold isostatic compaction under 250MPa pressure forms base substrate.Above-mentioned base substrate is carried out crystallization and thermal treatment, begin to be warming up to 700 ℃ from room temperature, 700 ℃ of insulations were warming up to 900 ℃ after 5 hours, were incubated 5 hours, 10 ℃/min of temperature rise rate.Base substrate furnace cooling after crystallization is completed is namely completed the preparation of the colored glass pottery that is applied to mutually to make dental prosthesis.
Two lithium silicate glass-ceramic (as shown in Figure 6) after painted by above-mentioned preparation method have obtained the color close with dentistry Vitapan Classical color board, each porcelain piece with corresponding be 6.6 than the average color difference between color chips, less than the clinical threshold of accepting.
Above content is in conjunction with concrete preferred implementation further description made for the present invention; can not assert that the specific embodiment of the present invention only limits to this; for the general technical staff of the technical field of the invention; without departing from the inventive concept of the premise; can also make some simple deduction or replace, all should be considered as belonging to the present invention and determine scope of patent protection by claims of submitting to.
Claims (10)
1. a colored glass pottery that be used for to make dental prosthesis, is characterized in that, comprises that mass percent is 98.5～99.85% basal component and 0.15～1.5% colorant component; The mass percent of described basal component: 56～59% SiO
2, 28～30% Li
2CO
3, 3.7～4.0% K
2CO
3, 2.7～3.0% Al
2O
3, 2.3～2.4% ZrO
2, 1.5～1.6% CeO
2, and 2.5～3.0% P
2O
5Described colorant component comprises zirconium praseodymium yellow, zirconium iron pink or zirconium vanadium blue, or their arbitrary combination.
2. the color matching method of the glass-ceramic for making dental prosthesis according to claim 1, is characterized in that, the mass percent of described colorant component is less than 1.0%.
3. the colored glass pottery for making dental prosthesis according to claim 1, is characterized in that, 16 kinds of colors of corresponding Vitapan Classical color board, and mass percent such as the following table of zirconium praseodymium yellow, zirconium iron pink, three kinds of colorants of zirconium vanadium blue:
4. the colored glass for making dental prosthesis according to claim 3 is ceramic, it is characterized in that, A look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 4.5:1.2:0.7; Corresponding its A1 look, A2 look, A3 look, A3.5 look, A4 look, the mass percent of colorant component is respectively: A1,0.3%; A2,0.5%; A3,0.7%; A3.5,0.85%; A4,1.0%.
5. the colored glass for making dental prosthesis according to claim 3 is ceramic, it is characterized in that, B look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 5:1:0.6; Corresponding its B1 look, B2 look, B3 look, B4 look, the mass percent of colorant component is respectively: B1,0.3%; B2,0.5%; B3,0.75%; B4,1.0%.
6. the colored glass for making dental prosthesis according to claim 3 is ceramic, it is characterized in that, C look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 4:1.3:1.2; Corresponding its C1 look, C2 look, C3 look, C4 look, the mass percent of colorant component is respectively: C1,0.4%; C2,0.6%; C3,0.8%; C4,1.0%.
7. the colored glass for making dental prosthesis according to claim 3 is ceramic, it is characterized in that, D2 and D3 look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 4:1.4:1.1; Corresponding its D2 and D3 look, the mass percent of colorant component is respectively: D2,0.4%; D3,0.6%.
8. the colored glass for making dental prosthesis according to claim 3 is ceramic, it is characterized in that, D4 look in 16 kinds of colors of corresponding Vitapan Classical color board, the mass ratio of the zirconium praseodymium yellow in its colorant component, zirconium iron pink, zirconium vanadium blue is 5:1.1:1; Corresponding its D4 look, the mass percent of colorant component is 0.7%.
9. the preparation method of the colored glass pottery for making dental prosthesis according to claim 1, is characterized in that, comprises the following steps:
Take basal component and colorant component according to mass percent.Basal component is poured in ball grinder, added dehydrated alcohol, wet ball grinding mixes post-drying, gets mixed powder; Mixed powder is poured in quartz crucible, then 1400～1500 ℃ of melting 1.5～2h will melt slurry and pour in deionized water again, and cold quenching obtains glass particle; Glass particle is placed in agate jar, ball milling, drying gets glass powder; Again colorant and glass powder are placed in agate jar, ball milling, mixing, drying gets the colored glass powder; At last, the colored glass powder is put into prefabricated flask cold isostatic compaction, the base substrate after moulding carries out the two-part crystallization and thermal treatment, gets final product.
10. the preparation method of the colored glass pottery for making dental prosthesis according to claim 9, is characterized in that, described two-part crystallization and thermal treatment is 700 ℃/5h and 900 ℃/5h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210575426.0A CN103086603B (en) | 2012-12-26 | 2012-12-26 | Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210575426.0A CN103086603B (en) | 2012-12-26 | 2012-12-26 | Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103086603A true CN103086603A (en) | 2013-05-08 |
| CN103086603B CN103086603B (en) | 2015-05-27 |
Family
ID=48199804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210575426.0A Expired - Fee Related CN103086603B (en) | 2012-12-26 | 2012-12-26 | Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103086603B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103951190A (en) * | 2014-04-29 | 2014-07-30 | 山东科技大学 | Frit-pigment compounded tooth microcrystalline glass with colour gradient change |
| CN108751721A (en) * | 2018-06-15 | 2018-11-06 | 中国人民解放军第四军医大学 | A kind of lithium bisilicate glass ceramics and its preparation method and application for dental zirconium oxide surface decorations porcelain |
| CN114477977A (en) * | 2022-01-25 | 2022-05-13 | 洛阳北苑新材料技术有限公司 | Dental ternary color-masking porcelain powder, preparation method and color matching method |
| CN117179931A (en) * | 2023-10-10 | 2023-12-08 | 昆明医科大学附属口腔医院 | Computer color matching method for 3D printing dental polyether-ether-ketone composite material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165143A (en) * | 1994-06-10 | 1996-06-25 | Corning Inc | Colored transparent glass ceramic and method for adjusting its color |
-
2012
- 2012-12-26 CN CN201210575426.0A patent/CN103086603B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165143A (en) * | 1994-06-10 | 1996-06-25 | Corning Inc | Colored transparent glass ceramic and method for adjusting its color |
Non-Patent Citations (2)
| Title |
|---|
| 王富等: ""牙科热压技术对新型玻璃陶瓷微观结构和化学稳定性的影响"", 《功能材料》 * |
| 高婧: ""齿科二硅酸锂玻璃陶瓷的应用基础研究"", 《中国博士学位论文全文数据库 医药卫生科技辑》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103951190A (en) * | 2014-04-29 | 2014-07-30 | 山东科技大学 | Frit-pigment compounded tooth microcrystalline glass with colour gradient change |
| CN108751721A (en) * | 2018-06-15 | 2018-11-06 | 中国人民解放军第四军医大学 | A kind of lithium bisilicate glass ceramics and its preparation method and application for dental zirconium oxide surface decorations porcelain |
| CN114477977A (en) * | 2022-01-25 | 2022-05-13 | 洛阳北苑新材料技术有限公司 | Dental ternary color-masking porcelain powder, preparation method and color matching method |
| CN117179931A (en) * | 2023-10-10 | 2023-12-08 | 昆明医科大学附属口腔医院 | Computer color matching method for 3D printing dental polyether-ether-ketone composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103086603B (en) | 2015-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6374808B2 (en) | Lithium silicate glass ceramic and glass containing ZrO2 component | |
| CN104108883B (en) | A kind of high intensity lithium bisilicate glass ceramics and preparation method thereof | |
| CN112694253B (en) | Starting glass, lithium silicate glass with core, preparation method and application thereof | |
| KR101628587B1 (en) | Lithium silicate glass ceramic and lithium silicate glass comprising a monovalent metal oxide | |
| WO2015056900A1 (en) | Lithium silicate glass or lithium silicate crystallized glass to be placed on upper end of zirconia, and preparation method therefor | |
| KR20150143403A (en) | Lithium silicate glass ceramics and lithium silicate glass containing caesium oxide | |
| CN112551894A (en) | Starting glass, lithium silicate glass with core, preparation method and application thereof | |
| JP5662914B2 (en) | Process for the preparation of dental restorations | |
| US8865606B2 (en) | Process for the preparation of dental restorations | |
| CN103043910A (en) | Glass ceramic for making dental prosthesis and preparation method thereof | |
| CN103086603B (en) | Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic | |
| CN108328932A (en) | A kind of gear division devitrified glass that Ce, Er, Tb, Y are co-doped with and its preparation and application | |
| CN113461336A (en) | Lithium silicate glass ceramic for dentistry, preparation method thereof and lithium silicate glass ceramic restoration | |
| CN103910489A (en) | Glass used as dental veneering porcelain, preparation method and application thereof | |
| CN103011602A (en) | Strengthening-toughening glass ceramic and preparation method thereof | |
| KR20180011898A (en) | Dental pocelain containing a lithium disilicate and method of manufacturing the same | |
| CN102153284A (en) | Novel method for preparing lithium-based casting ceramic block | |
| CN114477773A (en) | Pyrochlore phase-lithium disilicate glass ceramic, preparation method thereof and dental prosthesis | |
| CN1192983C (en) | Dental micro crystal glass and its preparation method and use | |
| AU2019441599B2 (en) | Pre-sintered ceramic block for dental restoration, preparation method therefor and use thereof | |
| CN114644459B (en) | Lithium silicate glass ceramic, preparation method thereof and obtained prosthesis | |
| CN114671615B (en) | Lithium silicate glass ceramic, preparation method thereof and obtained prosthesis | |
| CN115093119B (en) | Preparation method of lithium disilicate dental microcrystalline glass | |
| RU2790555C1 (en) | Ceramic block for tooth restoration, subjected to pre-sintering, its manufacturing method and its use | |
| CN104556706A (en) | Novel glass ceramic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150527 Termination date: 20171226 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |