CN103086547A - Dioctyl phthalate wastewater treatment method - Google Patents
Dioctyl phthalate wastewater treatment method Download PDFInfo
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- CN103086547A CN103086547A CN2013100635715A CN201310063571A CN103086547A CN 103086547 A CN103086547 A CN 103086547A CN 2013100635715 A CN2013100635715 A CN 2013100635715A CN 201310063571 A CN201310063571 A CN 201310063571A CN 103086547 A CN103086547 A CN 103086547A
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- dioctyl phthalate
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Abstract
The invention discloses a method for treating dioctyl phthalate by using active carbon and Fenton reagent. The method comprises the following steps of: (1) dissolving the dioctyl phthalate by solvent, then, diluting the solution to the needed concentration by using distilled water; (2) regulating the pH of the prepared dioctyl phthalate solution, adding a certain amount of active carbon in the prepared dioctyl phthalate solution, stirring for a while at controlled stirring speed; 180min later, filtering to get the filtrate; (3) adding a certain amount of Fe<2+> and a certain amount of H2O2 of which mass fraction is 30% into the filtrate; (4) 150min later, taking the supernatant liquid for analysis and detection. The method obtains better treatment effect under the combined effect of active carbon and oxidant, the biochemical treatment process is not needed, the technological process is simplified, the investment and the operating cost can be effectively lowered, and engineering implementation applicability is very high.
Description
Technical field
The invention belongs to water treatment field, relate to a kind of gac and the coupling of Fenton reagent and process the Process for Wastewater from Production of Dioctyl Phthalate method.
Background technology
Along with the development of process of industrialization, people are increasing to the demand of softening agent.Dioctyl phthalate (DOP) (DOP) is one of phthalate compound (PAEs), it is a kind of universal softening agent of present turnout and consumption maximum, be mainly used in the processing of the superpolymer such as processing, acetate resin, ABS resin and rubber of polyvinyl chloride fat, also can be used for making paint, dyestuff, dispersion agent etc.The dioctyl phthalate (DOP) organism of synthetic under field conditions (factors), the hydrolysis and photodissociation speed all very slow, although acute toxicity intensity is little, but easily enrichment in vivo, teratogenesis and mutagenesis are arranged, and are a kind of Endocrine Disruptors, have caused serious harm to the mankind.At present, process the method for dioctyl phthalate (DOP) mainly take biological degradation method as main, but bioremediation comes with some shortcomings, and wastes time and energy as the cultivation of bacterial strain, when high density, the degradation rate of bacterial strain can obviously descend.Gac is to utilize charcoal, various shell and fat coal etc. as raw material, by the physics and chemistry method to raw material carry out fragmentation, sieve, the series of processes processing and manufacturing such as activation, rinsing, oven dry and screening forms.Its specific surface area is larger, and micropore is flourishing, and physical strength is high, and rate of adsorption is very fast, can remove stink, and dissolved organic matter etc. are a kind of very good sorbent materials.Gac has been widely used in water treatment field, and effect is better, and cost is lower.Fenton reagent in high-level oxidation technology is by molysite (Fe
3+Or Fe
2+) and H
2O
2The reaction system that forms, it can produce the OH(oxidizing potential with strong oxidizing property is 2.8V), a lot of organic compound of energy oxidation can be directly even CO with the organic pollutant mineralising
2And H
2O, speed of response is fast, and this reaction just can be carried out at normal temperatures and pressures.
Publication number is that the patent documentation that CN102516081A, name are called " method and apparatus that purifies and reclaim DOP " discloses a kind of method and apparatus that purifies and reclaim DOP, its defective is: can only remove partial impurities by adding thermal purification DOP, also cause impact for the synthetic PVC black color paste of follow-up use DOP.Publication number is that the patent documentation that CN102219280A, name are called " the removal by radiation method of high density dimethyl phthalate " discloses a kind of method that adopts energetic ray to process dimethyl phthalate.Its defective is: although removal effect is better, somewhat expensive can not be promoted in Practical Project well.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned the deficiencies in the prior art, proposes a kind of method of more effective processing dioctyl phthalate (DOP).
The technical scheme that the technical problem that the present invention solves is taked is: (1) use the dissolution with solvents dioctyl phthalate (DOP), and then with distilled water diluting required concentration extremely; (2) regulate the pH of the dioctyl phthalate (DOP) solution of preparation, then add a certain amount of gac in the dioctyl phthalate (DOP) solution of preparation, control stirring velocity, stir the regular hour, then filter after waiting for 180min, obtain filtrate; (3) add a certain amount of Fe in the filtrate of gained
2+With a certain amount of massfraction be 30% H
2O
2(4) get supernatant liquid after reaction 150min, carry out analyzing and testing.
The present invention uses alcohol solvent dissolving dioctyl phthalate (DOP), and after distilled water diluting, the dioctyl phthalate (DOP) COD content of gained is 1185mg/L~2010 mg/L.
In above-mentioned steps (2), the pH that regulates the dioctyl phthalate (DOP) solution of preparation is 1~7, and the gac dosage is 1.0g~5.0g, and stirring velocity is 20 r/min~100r/min, and churning time is 20min.In step (3), Fe
2+Concentration is 0.4 g/L~1.4g/L, H
2O
2Concentration is 0.3 g/L~1.5g/L.
The present invention only under gac and oxidant combined effect, can obtain treatment effect preferably, has saved biochemical processing process, has simplified technical process, effectively reduces investment and running cost, has very strong engineering construction applicability.
Embodiment
A kind of Process for Wastewater from Production of Dioctyl Phthalate treatment process is characterized in that realizing by following steps: dissolve dioctyl phthalate (DOP) with alcohol solvent, and then be 1185mg/L with distilled water diluting to COD content; The pH that then regulates the dioctyl phthalate (DOP) solution of preparation is 1~7, and the gac of 1.0g~5.0g is added in the dioctyl phthalate (DOP) solution of preparation, and stirring velocity is 20 r/min~100r/min, and churning time is 20min.Filter after 180min, obtain filtrate; Fe in the filtrate of gained
2+Concentration be 0.4 g/L~1.4g/L, massfraction is 30%H
2O
2Concentration be 0.3 g/L~1.5g/L; Get supernatant liquid after 150min, carry out analyzing and testing.
Below provide 5 embodiment with further elaboration the present invention:
Embodiment 1
As follows for the treatment of each component condition of dioctyl phthalate (DOP):
The pH that uses sodium hydroxide or sulfuric acid to regulate waste water is 1, and the dosage of gac is 1g, and stirring velocity is 20 r/min, after stirring 20min, allows it adsorb, and filters after 180min, and then adding concentration in the filtrate is 0.4g/L Fe
2+With 0.3 g/L H
2O
2Carry out deep oxidation and process, oxidization time is 150min.Analyze after processing, dioctyl phthalate (DOP) COD clearance is 15.8%.
Embodiment 2
As follows for the treatment of each component condition of dioctyl phthalate (DOP):
The pH that uses sodium hydroxide or sulfuric acid to regulate waste water is 3, and the dosage of gac is 2g, and stirring velocity is 40 r/min, after stirring 20min, allows it adsorb, and filters after 180min, and then adding concentration in the filtrate is 0.8g/L Fe
2+With 0.6 g/L H
2O
2Carry out deep oxidation and process, oxidization time is 150min.Analyze after processing, dioctyl phthalate (DOP) COD clearance is 51.5%.
Embodiment 3
As follows for the treatment of each component condition of dioctyl phthalate (DOP):
The pH that uses sodium hydroxide or sulfuric acid to regulate waste water is 3, and the dosage of gac is 3g, and stirring velocity is 60 r/min, after stirring 20min, allows it adsorb, and filters after 180min, and then adding concentration in the filtrate is 1.0g/L Fe
2+With 0.9 g/L H
2O
2Carry out deep oxidation and process, oxidization time is 150min.Analyze after processing, dioctyl phthalate (DOP) COD clearance is 85.0%.
Embodiment 4
As follows for the treatment of each component condition of dioctyl phthalate (DOP):
The pH that uses sodium hydroxide or sulfuric acid to regulate waste water is 5, and the dosage of gac is 4g, and stirring velocity is 80 r/min, after stirring 20min, allows it adsorb, and filters after 180min, and then adding concentration in the filtrate is 1.2g/L Fe
2+With 1.2 g/L H
2O
2Carry out deep oxidation and process, oxidization time is 150min.Analyze after processing, dioctyl phthalate (DOP) COD clearance is 32.3%.
Embodiment 5
As follows for the treatment of each component condition of dioctyl phthalate (DOP):
The pH that uses sodium hydroxide or sulfuric acid to regulate waste water is 7, and the dosage of gac is 5g, and stirring velocity is 100 r/min, after stirring 20min, allows it adsorb, and filters after 180min, and then adding concentration in the filtrate is 1.4g/L Fe
2+With 1.5 g/L H
2O
2Carry out deep oxidation and process, oxidization time is 150min.Analyze after processing, dioctyl phthalate (DOP) COD clearance is 20.9%.
Claims (6)
1. dioctyl phthalate (DOP) treatment process is characterized in that realizing by following steps:
(1) use the dissolution with solvents dioctyl phthalate (DOP), and then with distilled water diluting to required concentration;
(2) regulate the pH of the dioctyl phthalate (DOP) solution of preparation, then add a certain amount of gac in the dioctyl phthalate (DOP) solution of preparation, control stirring velocity, stir the regular hour, then filter after waiting for 180min, obtain filtrate;
(3) add a certain amount of Fe in the filtrate of gained
2+With a certain amount of massfraction be 30% H
2O
2
(4) get supernatant liquid after reaction 150min, carry out analyzing and testing.
2. a kind of dioctyl phthalate (DOP) treatment process according to claim 1, is characterized in that, in described step (1), solvent is ethanol, and after distilled water diluting, the dioctyl phthalate (DOP) COD content of gained is 1185mg/L~2010 mg/L.
3. a kind of dioctyl phthalate (DOP) treatment process according to claim 1, is characterized in that, in described step (2), the pH that regulates the dioctyl phthalate (DOP) solution of preparation is 1~7.
4. a kind of dioctyl phthalate (DOP) treatment process according to claim 1, is characterized in that, in described step (2), the gac dosage is 1.0g~5.0g.
5. a kind of dioctyl phthalate (DOP) treatment process according to claim 1, is characterized in that, in described step (2), stirring velocity is 20 r/min~100r/min, and churning time is 20min.
According to claim 1 described in a kind of dioctyl phthalate (DOP) treatment process, it is characterized in that, in described step (3), Fe
2+Concentration is 0.4 g/L~1.4g/L, H
2O
2Concentration is 0.3 g/L~1.5g/L.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104326611A (en) * | 2014-10-24 | 2015-02-04 | 苏州富奇诺水治理设备有限公司 | Method for processing organic wastewater by electro-fenton |
CN104386867A (en) * | 2014-10-24 | 2015-03-04 | 苏州富奇诺水治理设备有限公司 | Method for removing cyanide through basic Fenton reaction by utilizing ultrasonic catalysis |
CN104386866A (en) * | 2014-10-24 | 2015-03-04 | 苏州富奇诺水治理设备有限公司 | Method for treating water through Fenton oxidation of activated molecular oxygen by utilizing ultrasonic catalysis |
CN104386868A (en) * | 2014-10-24 | 2015-03-04 | 苏州富奇诺水治理设备有限公司 | Method for treating waste water through Fenton oxidation by utilizing ultrasonic catalysis |
CN105731686A (en) * | 2016-02-26 | 2016-07-06 | 广州市市政工程设计研究总院 | Method for simultaneously removing dimethyl phthalate and nickel ions in industrial wastewater |
CN106219823A (en) * | 2016-08-31 | 2016-12-14 | 浙江奇彩环境科技股份有限公司 | A kind of processing method containing aminobenzoic acids waste water |
CN108614061A (en) * | 2018-07-02 | 2018-10-02 | 山东师范大学 | A method of plasticiser in removal absolute ethyl alcohol and hexamethylene |
CN109626683A (en) * | 2017-10-09 | 2019-04-16 | 中国石油化工股份有限公司 | The processing method of waste water in a kind of plasticizer DINCH esterification process technique |
Citations (2)
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EP0364159A2 (en) * | 1988-10-11 | 1990-04-18 | Morton International, Inc. | Microbiocidal compositions |
CN101186719A (en) * | 2007-12-04 | 2008-05-28 | 南京大学 | Composite function resin, preparation method thereof, and method for treating phthalate pollution of water body |
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2013
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Patent Citations (2)
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EP0364159A2 (en) * | 1988-10-11 | 1990-04-18 | Morton International, Inc. | Microbiocidal compositions |
CN101186719A (en) * | 2007-12-04 | 2008-05-28 | 南京大学 | Composite function resin, preparation method thereof, and method for treating phthalate pollution of water body |
Non-Patent Citations (1)
Title |
---|
孙大贵等: "活性炭-Fenton组合法去除水中PAEs的研究", 《环境科学》 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104326611A (en) * | 2014-10-24 | 2015-02-04 | 苏州富奇诺水治理设备有限公司 | Method for processing organic wastewater by electro-fenton |
CN104386867A (en) * | 2014-10-24 | 2015-03-04 | 苏州富奇诺水治理设备有限公司 | Method for removing cyanide through basic Fenton reaction by utilizing ultrasonic catalysis |
CN104386866A (en) * | 2014-10-24 | 2015-03-04 | 苏州富奇诺水治理设备有限公司 | Method for treating water through Fenton oxidation of activated molecular oxygen by utilizing ultrasonic catalysis |
CN104386868A (en) * | 2014-10-24 | 2015-03-04 | 苏州富奇诺水治理设备有限公司 | Method for treating waste water through Fenton oxidation by utilizing ultrasonic catalysis |
CN105731686A (en) * | 2016-02-26 | 2016-07-06 | 广州市市政工程设计研究总院 | Method for simultaneously removing dimethyl phthalate and nickel ions in industrial wastewater |
CN105731686B (en) * | 2016-02-26 | 2019-03-29 | 广州市市政工程设计研究总院有限公司 | Method that is a kind of while removing repefral and nickel ion in industrial wastewater |
CN106219823A (en) * | 2016-08-31 | 2016-12-14 | 浙江奇彩环境科技股份有限公司 | A kind of processing method containing aminobenzoic acids waste water |
CN109626683A (en) * | 2017-10-09 | 2019-04-16 | 中国石油化工股份有限公司 | The processing method of waste water in a kind of plasticizer DINCH esterification process technique |
CN108614061A (en) * | 2018-07-02 | 2018-10-02 | 山东师范大学 | A method of plasticiser in removal absolute ethyl alcohol and hexamethylene |
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Application publication date: 20130508 |