CN103060710A - Rustproof and heat-resistant cast stainless steel pipe - Google Patents
Rustproof and heat-resistant cast stainless steel pipe Download PDFInfo
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- CN103060710A CN103060710A CN2013100406190A CN201310040619A CN103060710A CN 103060710 A CN103060710 A CN 103060710A CN 2013100406190 A CN2013100406190 A CN 2013100406190A CN 201310040619 A CN201310040619 A CN 201310040619A CN 103060710 A CN103060710 A CN 103060710A
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Abstract
The invention relates to a rustproof and heat-resistant cast stainless steel pipe. A medium-frequency electric furnace is adopted for smelting, chemical components are strictly controlled, the design of austenite stainless steel components is improved against the deficiencies of the prior art, W, Nb, Mo and other high temperature-resistant alloy elements are added on the basis of C, Si, Mn, Cr, Ni, W, Nb and Mo, and the content of C is properly increased. An acid cleaning solution with a specific mixture ratio is finally used for cleaning. The stainless steel pipe disclosed by the invention can significantly improve the high temperature resistance of stainless steel on the premise of ensuring rigidity and strength, further adsorb a layer of passivation film on the surface of metal while removing oil stains, dirt and an oxide skin during preparation, and simplify the production procedure.
Description
Technical field
What the present invention relates to is a kind of Cast Stainless Steel material, particularly a kind of Cast Stainless Steel pipe with high heat resistance.
Background technology
304 stainless steels belong to a kind of of austenitic stainless steel as a kind of broad-spectrum steel.Austenitic stainless steel is the stainless steel that has austenite structure under the normal temperature.Cr is about 18% when containing in the steel, when Ni 8%-10%, C about 0.1%, have stable austenite structure.Because austenitic stainless steel contains higher chromium, can form fine and close oxide film, so have good solidity to corrosion.Nickel is stable austenite and the element that enlarges the austenite phase region, in order to obtain single austenite structure, minimum nickel content required when containing 0.1% carbon and 18% chromium in the steel is about 8%, this is the basal component of the most famous 18-8 Chromiumnickel Austenite Stainless Steel, in the austenitic stainless steel, along with the increase of nickel content, remaining ferrite can be eliminated fully, and significantly reduces.The tendency that forms mutually; Martensite transformation temperature reduces simultaneously, even λ-M phase transformation can not occur, but the increase of nickel content can reduce the solubleness of carbon in austenitic stainless steel, thereby the Carbide Precipitation tendency is strengthened.Austenitic chromium nickel stainless steel comprises the 18Cr-8Ni steel and increases on this basis Cr, Ni content and add the high Cr-Ni Series Steel that the elements such as Mo, Cu, Si, Nb, Ti grow up.Austenitic stainless steel is nonmagnetic and have high tenacity and plasticity, but intensity is lower, can not make it to strengthen by phase transformation, only can strengthen by cold working.If add S, Ca, Se, the elements such as Te then have good free-cutting machinability.This type of steel scale resistance acid medium corrosion is if contain the also corrosion of ability sulfuric acid, phosphoric acid and formic acid, acetic acid, urea etc. of the elements such as Mo, Cu.If the carbon content in this type of steel is lower than 0.03% or contain Ti, Ni, just can significantly improve its intergranular corrosion resistance performance.The austenitic stainless steel of high silicon has good solidity to corrosion to concentrated nitric acid.Austenitic stainless steel density has larger elongation and relative reduction in area a little more than carbon steel, and hardness is lower.Austenite stainless steel plate improves hardness by work hardening usually, and the Austenitic stainless steel is nonmagnetic, but its cold hardening will produce magnetic when generating martensitic transformation, and the available heat treatment process is eliminated this martensitic stucture and recovered that it is nonmagnetic.The Austenitic stainless steel is similar with other most metallic substance, and its tensile strength, yield strength and hardness improve along with the reduction of temperature; Plasticity then reduces along with temperature and reduces.It is comparatively uniform that its tensile strength increases in temperature 15～800C scope, the more important thing is: along with the reduction of temperature, its impact toughness reduces slowly, does not have brittle transition temperature, so stainless steel can keep enough plasticity and toughness when low temperature.
The Austenitic stainless steel is compared with carbon steel, has following characteristics:
(1) high resistivity is about 5 times of carbon steel;
(2) large linear expansivity, larger 40% than carbon steel, and along with the rising of temperature, the numerical value of linear expansivity also correspondingly improves;
(3) low thermal conductivity is about 1/3 of carbon steel.
Based on These characteristics, there is series of problems in austenitic stainless steel in the tubulation welding process, as follows:
(1) coarse grained austenite stainless steel hot conductance is low, adopts the traditional electrical arc-welding to cause easily weld seam and nearly seam district coarse grains, affects property of welded joint;
(2) thermal stresses austenitic stainless steel thermal conductivity approximately only has half of carbon steel, and linear expansivity is much bigger, so postwelding can produce very large internal stress in joint;
(3) viscosity of pore liquid metal and surface tension are larger, easily produce pore; The weld metal wettability is poor, and the weld seam both sides easily produce undercut;
(4) crystallization and freezing of thermal crack austenitic steel is interval large, and crystallization time is long, and the austenite crystallization direction is strong,
So impurity segregation is more serious, easily produce thermal crack.
In addition, to usually can using acid pickling step in the preparation process of cast member, and the just complete cold-reduced sheet of pickling, its metal is in a quite active state, is easy to get rusty with the reaction such as airborne moisture, oxygen, carbonic acid gas.
Summary of the invention
The invention provides a kind of antirust heat-resistant cast stainless steel tube, can under the prerequisite that guarantees rigidity and intensity, significantly improve the effect of stainless steel resistance to elevated temperatures, in pickling, product is carried out antirust processing simultaneously, simplify production sequence.
A kind of antirust heat-resistant cast stainless steel tube is characterized in that described stainless steel tube comprises steel pipe body and rustproof layer, and the weight percent of the concrete chemical composition of described steel pipe body is,
C：0.11～0.19%，
Si：0.20～0.90%，
Mn：1.3~1.8%，
Cr：17.1～18.9%，
Ni：8.5～10.8%，
W: 1.6～2.4%,
Nb: 1.0～1.9%,
Mo: 2.1～2.9%,
S：≤0.03%，
P：≤0.035%，
Surplus is Fe and inevitable micro impurity element;
The weight percent of the concrete chemical composition of described rustproof layer is,
JFC permeate agent 9%;
Emulsifier op-10 10%;
Ammonium molybdate 7.5%;
DTPA 6.5%；
Citric acid 2%;
Oxalic acid 10%;
Sodium phosphate 10%;
Hydrochloric acid 2%;
Water 43%.
The preparation method of antirust heat-resistant cast stainless steel tube of the present invention is as follows:
1) dispose antirust Acidwash solution, dispose raw material according to following component and weight percent:
JFC permeate agent 10%;
Emulsifier op-10 10%;
Ammonium molybdate 7%;
EDTA 6%；
Citric acid 2%;
Oxalic acid 10%;
Sodium phosphate 10%;
Hydrochloric acid 2%;
Water 43%.
After all reinforced complete, restir 20 minutes ~ 30 minutes;
2) raw material is prepared: require and the smelting gross weight according to following composition, be equipped with C, Si, Mn, Cr, Ni, W, Nb, Mo material and the carburelant of approrpiate wts; Make the chemical composition content of product be,
C：0.11～0.19%，
Si：0.20～0.90%，
Mn：1.3~1.8%，
Cr：17.1～18.9%，
Ni：8.5～10.8%，
W: 1.6～2.4%,
Nb: 1.0～1.9%,
Mo: 2.1～2.9%,
S：≤0.03%，
P：≤0.035%，
Surplus is Fe and inevitable micro impurity element;
3) analyze check and correction before the charging, and carry out the scrubbing rust and process; Adopt medium-frequency induction furnace, dystectic W, Nb, Mo material are put into first crucible bottom, add successively technically pure iron, ferrochrome, sheet nickel, manganese metal, silicon metal again, and cover upper deslagging agent, plugged progressively increases power and smelts;
4) chemical ingredients qualified after, and molten steel temperature takes off cobbings when reaching 1650 ℃, adds silicocalcium and carries out last deoxidation, when molten steel temperature reaches 1660-1680 ℃, adds a small amount of carburelant and prepares to come out of the stove;
5) adopt the horizontal centrifuge casting, 1620 ℃-1650 ℃ of teeming temperatures, rotating speed 450-1550 rev/min, form cast tube at pouring speed 15-140kg/ second;
6) the cast tube surfaces externally and internally is carried out the emery wheel reconditioning, eliminate surface imperfection; Carry out water-cooled 1050-1080 ℃ of insulation after 30 minutes; Then cast tube is placed in the pickle solution that step 1) makes and soaks 90-120 minute, temperature remains on 50-60 ℃, cleans, and after the scale removal reaction meets the requirements of degree, takes out at last and dries after rushing dry cleaning.
The present invention adopts middle frequency furnace to carry out melting, and strictly control chemical ingredients, for the deficiencies in the prior art, improve the austenitic stainless steel Composition Design, on the basis of C, Si, Mn, Cr, Ni, W, Nb, Mo, add the high temperature alloy elements such as W, Nb, Mo, and suitably improve C content, these high temperature alloy elements and C form the alloy carbide of small and dispersed, and these carbide have the hardness height, be the characteristics that disperse distributes after solidifying.Owing to improved prescription and manufacturing process, the final acquisition has following characteristics in the product: the alloy carbide in the stainless steel at high temperature plays significant pinning effect to crystal boundary, can reduce simultaneously the solute velocity of diffusion of grain boundaries, thereby obviously improve the austenitic stainless steel grain-boundary strength, reach the remarkable effect of improving hot strength and high-temperature oxidation resistance.In addition, because the high temperature alloy element that adds is carbide, than the preferential formation carbide of Cr, thereby stops or avoid Cr and C formation carbide, guarantee that grain boundaries does not cause intergranular corrosion because of poor Cr.Therefore, can under the prerequisite that guarantees rigidity and intensity, significantly improve the effect of stainless steel resistance to elevated temperatures.
Antirust heat-resistant cast stainless steel tube of the present invention, its resistance toheat is good, and product mechanical property obtained above and oxidation weight gain are detected, and mechanical property test method obtains the yield strength index for carry out 900 ℃ of drawing by high temperature experiments according to GB/T4338-2006; The oxidation weight gain detection method be alloy behind 900 ℃ of high temperature oxidation 200h, together with oxide skin, adopt the balance test sample gross weight of weighing, with the difference of original sample divided by long-pending (unit surface) oxidation weight gain that is of specimen surface; At last detection obtains 900 ℃ of high-temperature behaviors and is: yield strength is greater than 50MPa; The 200h oxidation weight gain is less than 12mg/cm
2And in the preparation, can when oil stain, dirt and oxide skin are removed, at metallic surface absorption one deck passive film, simplify production sequence.
Embodiment
Following examples describe the present invention in detail.Various raw material used in the present invention and items of equipment are conventional commercially available prod, all can buy directly by market to obtain.
Embodiment 1:
1) dispose antirust Acidwash solution, dispose raw material according to following component and weight percent:
JFC permeate agent 10%;
Emulsifier op-10 10%;
Ammonium molybdate 7%;
EDTA 6%；
Citric acid 2%;
Oxalic acid 10%;
Sodium phosphate 10%;
Hydrochloric acid 2%;
Water 43%.
After all reinforced complete, restir 20 minutes ~ 30 minutes;
2) raw material is prepared: require and the smelting gross weight according to following composition, be equipped with C, Si, Mn, Cr, Ni, W, Nb, Mo material and the carburelant of approrpiate wts; Make the stainless chemical composition content of product be,
C:0.11%, Si:0.20%, Mn:1.3%, Cr:17.1%, Ni:8.5%, W:1.6%, Nb:1.0%, Mo:2.1%, S :≤0.03%, P :≤0.035%, surplus is Fe and inevitable micro impurity element;
3) analyze check and correction before the charging, and carry out the scrubbing rust and process; Adopt medium-frequency induction furnace, dystectic W, Nb, Mo material are put into first crucible bottom, add successively technically pure iron, ferrochrome, sheet nickel, manganese metal, silicon metal again, and cover upper deslagging agent, plugged progressively increases power and smelts;
4) chemical ingredients qualified after, and molten steel temperature takes off cobbings when reaching 1650 ℃, adds silicocalcium and carries out last deoxidation, when molten steel temperature reaches 1660-1680 ℃, adds a small amount of carburelant and prepares to come out of the stove;
5) adopt the horizontal centrifuge casting, 1620 ℃-1650 ℃ of teeming temperatures, pouring speed 15kg/ second, 450 rev/mins of rotating speeds form cast tube;
6) the cast tube surfaces externally and internally is carried out the emery wheel reconditioning, eliminate surface imperfection; Carry out water-cooled 1050-1080 ℃ of insulation after 30 minutes; Then cast tube is placed in the pickle solution that step 1) makes and soaks 90 minutes, temperature remains on 50 ℃, cleans, and after the scale removal reaction meets the requirements of degree, takes out at last and dries after rushing dry cleaning.
This embodiment product detection obtains 900 ℃ of high-temperature behaviors and is: yield strength is greater than 50MPa; The 200h oxidation weight gain is less than 12mg/cm
2
Embodiment 2
1) dispose antirust Acidwash solution, dispose raw material according to following component and weight percent:
JFC permeate agent 10%;
Emulsifier op-10 10%;
Ammonium molybdate 7%;
EDTA 6%；
Citric acid 2%;
Oxalic acid 10%;
Sodium phosphate 10%;
Hydrochloric acid 2%;
Water 43%.
After all reinforced complete, restir 20 minutes ~ 30 minutes;
2) raw material is prepared: require and the smelting gross weight according to following composition, be equipped with C, Si, Mn, Cr, Ni, W, Nb, Mo material and the carburelant of approrpiate wts; Make the stainless chemical composition content of product be,
C:0.13%, Si:0.65%, Mn:1.5%, Cr:17.9%, Ni:9.7%, W:1.9%, Nb:1.6%, Mo:2.6%, S :≤0.03%, P :≤0.035%, surplus is Fe and inevitable micro impurity element;
3) analyze check and correction before the charging, and carry out the scrubbing rust and process; Adopt medium-frequency induction furnace, dystectic W, Nb, Mo material are put into first crucible bottom, add successively technically pure iron, ferrochrome, sheet nickel, manganese metal, silicon metal again, and cover upper deslagging agent, plugged progressively increases power and smelts;
4) chemical ingredients qualified after, and molten steel temperature takes off cobbings when reaching 1650 ℃, adds silicocalcium and carries out last deoxidation, when molten steel temperature reaches 1660-1680 ℃, adds a small amount of carburelant and prepares to come out of the stove;
5) adopt the horizontal centrifuge casting, 1620 ℃-1650 ℃ of teeming temperatures, pouring speed 95kg/ second, 850 rev/mins of rotating speeds form cast tube;
6) the cast tube surfaces externally and internally is carried out the emery wheel reconditioning, eliminate surface imperfection; Carry out water-cooled 1050-1080 ℃ of insulation after 30 minutes; Then cast tube is placed in the pickle solution that step 1) makes and soaks 100 minutes, temperature remains on 60 ℃, cleans, and after the scale removal reaction meets the requirements of degree, takes out at last and dries after rushing dry cleaning.
This embodiment product detection obtains 900 ℃ of high-temperature behaviors and is: yield strength is greater than 53MPa; The 200h oxidation weight gain is less than 10.3mg/cm
2
Embodiment 3:
1) dispose antirust Acidwash solution, dispose raw material according to following component and weight percent:
JFC permeate agent 10%;
Emulsifier op-10 10%;
Ammonium molybdate 7%;
EDTA 6%；
Citric acid 2%;
Oxalic acid 10%;
Sodium phosphate 10%;
Hydrochloric acid 2%;
Water 43%.
After all reinforced complete, restir 20 minutes ~ 30 minutes;
2) raw material is prepared: require and the smelting gross weight according to following composition, be equipped with C, Si, Mn, Cr, Ni, W, Nb, Mo material and the carburelant of approrpiate wts; Make the stainless chemical composition content of product be,
C:0.19%, Si:0.90%, Mn:1.8%, Cr:18.9%, Ni:10.8%, W:2.4%, Nb:1.9%, Mo:2.9%, S :≤0.03%, P :≤0.035%, surplus is Fe and inevitable micro impurity element;
3) analyze check and correction before the charging, and carry out the scrubbing rust and process; Adopt medium-frequency induction furnace, dystectic W, Nb, Mo material are put into first crucible bottom, add successively technically pure iron, ferrochrome, sheet nickel, manganese metal, silicon metal again, and cover upper deslagging agent, plugged progressively increases power and smelts;
4) chemical ingredients qualified after, and molten steel temperature takes off cobbings when reaching 1650 ℃, adds silicocalcium and carries out last deoxidation, when molten steel temperature reaches 1660-1680 ℃, adds a small amount of carburelant and prepares to come out of the stove;
5) adopt the horizontal centrifuge casting, 1620 ℃-1650 ℃ of teeming temperatures, pouring speed 140kg/ second, 1550 rev/mins of rotating speeds form cast tube;
6) the cast tube surfaces externally and internally is carried out the emery wheel reconditioning, eliminate surface imperfection; Carry out water-cooled 1050-1080 ℃ of insulation after 30 minutes; Then cast tube is placed in the pickle solution that step 1) makes and soaks 120 minutes, temperature remains on 50-60 ℃, cleans, and after the scale removal reaction meets the requirements of degree, takes out at last and dries after rushing dry cleaning.
This embodiment product detection obtains 900 ℃ of high-temperature behaviors and is: yield strength is greater than 58MPa; The 200h oxidation weight gain is less than 9.7mg/cm
2
Foregoing description only proposes as the enforceable technical scheme of the present invention, not as the Single restriction condition to its technical scheme itself.
Claims (1)
1. an antirust heat-resistant cast stainless steel tube is characterized in that described stainless steel tube comprises steel pipe body and rustproof layer,
The weight percent of the concrete chemical composition of described steel pipe body is,
C：0.11～0.19%，
Si：0.20～0.90%，
Mn：1.3~1.8%，
Cr：17.1～18.9%，
Ni：8.5～10.8%，
W: 1.6～2.4%,
Nb: 1.0～1.9%,
Mo: 2.1～2.9%,
S：≤0.03%，
P：≤0.035%，
Surplus is Fe and inevitable micro impurity element;
The weight percent of the concrete chemical composition of described rustproof layer is,
JFC permeate agent 9%;
Emulsifier op-10 10%;
Ammonium molybdate 7.5%;
DTPA 6.5%；
Citric acid 2%;
Oxalic acid 10%;
Sodium phosphate 10%;
Hydrochloric acid 2%;
Water 43%.
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| CN2013100406190A CN103060710A (en) | 2013-02-03 | 2013-02-03 | Rustproof and heat-resistant cast stainless steel pipe |
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Cited By (3)
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| CN106854743A (en) * | 2016-12-29 | 2017-06-16 | 天津市必拓制钢有限公司 | A kind of acidation treatment method before steel pipe is zinc-plated |
| CN111684107A (en) * | 2018-03-02 | 2020-09-18 | 株式会社德山 | Stainless steel member and method for manufacturing same |
| CN115044839A (en) * | 2022-08-12 | 2022-09-13 | 浦项(张家港)不锈钢股份有限公司 | Stainless steel band with high-temperature oxidation resistant surface, manufacturing method and application |
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| CN102615106A (en) * | 2012-04-05 | 2012-08-01 | 常熟市轧辊厂限公司 | Boron-contained centrifugal composite high-speed steel roller and manufacturing method thereof |
| CN102877006A (en) * | 2012-10-15 | 2013-01-16 | 常州大学 | High heat-resistant casting austenitic stainless steel and method for preparing same |
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| CN101168840A (en) * | 2007-11-28 | 2008-04-30 | 东北大学 | Phosphor molybdenum heteropolyacid inactivating treatment liquid used for heat zinc coating plate |
| CN101469392A (en) * | 2007-12-29 | 2009-07-01 | 张朝龙 | High wear resistance alloy for slitting roller and manufacturing method thereof |
| CN101225500A (en) * | 2008-01-30 | 2008-07-23 | 中国科学院金属研究所 | High-molybdenum high-vanadium microsegregation cast high speed steel for rolls |
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| CN111684107A (en) * | 2018-03-02 | 2020-09-18 | 株式会社德山 | Stainless steel member and method for manufacturing same |
| CN115044839A (en) * | 2022-08-12 | 2022-09-13 | 浦项(张家港)不锈钢股份有限公司 | Stainless steel band with high-temperature oxidation resistant surface, manufacturing method and application |
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Application publication date: 20130424 |