CN103059552A - Nano-particle modified polyurethane synthetic leather sizing agent - Google Patents
Nano-particle modified polyurethane synthetic leather sizing agent Download PDFInfo
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- CN103059552A CN103059552A CN201210530216XA CN201210530216A CN103059552A CN 103059552 A CN103059552 A CN 103059552A CN 201210530216X A CN201210530216X A CN 201210530216XA CN 201210530216 A CN201210530216 A CN 201210530216A CN 103059552 A CN103059552 A CN 103059552A
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Abstract
The invention discloses a nano-particle modified polyurethane synthetic leather sizing agent, which comprises the following components according to parts by weight: 15-30 parts of thermoplastic polyurethane, 62-83 parts of N,N-dimethylformamide, 1-2 parts of addition agent, 1-3 parts of color paste and 0.1-3 parts of nano-particles. The finished product of polyurethane synthetic leather made of the nano-particle modified polyurethane synthetic leather sizing agent manufactured by using the invention is good in abrasive resistance and water vapor permeability.
Description
Technical field
The present invention relates to the Synthetic Leather Material Field, specifically is a kind of nanometer particle-modified Synthetic Leather slurry.
Background technology
Synthetic Leather has soft, the nature of gloss, and soft, kishke feel is strong, and anti-deflection, the excellent characteristics such as anti-aging are the ideal substitutes of natural leather, are widely used in the industries such as clothes, shoemaking, case and bag, furniture; But Synthetic Leather in the market is too large with the natural leather gap aspect water vapour permeability, wear resistance, the poor Synthetic Leather goods of water vapour permeability can make us feeling sultry, clammy, for these shortcomings, mainly improve by the performance that changes the Synthetic Leather slurry at present, but the technique that changes in the market Synthetic Leather slurry water vapour permeability and wear resistance is complicated, cost is higher, and effect is also not too obvious.
Summary of the invention
Technical problem to be solved by this invention is to overcome the shortcoming of above prior art: the slurry that provide that a kind of cost is low, technique is simple, can effectively strengthen Synthetic Leather water vapour permeability and wear resistance.
Technical solution of the present invention is as follows:
A kind of nanometer particle-modified Synthetic Leather slurry, it is comprised of the component of following weight proportion: thermoplastic polyurethane 15-30 part, DMF 62-83 part, auxiliary agent 1-2 part, mill base 1-3 part, nanoparticle 0.1-3 part.
Described auxiliary agent is a kind of in commercially available aerosol-OT salt, the dimethyl silicone oil or their mixture.
Described nanoparticle is a kind of in commercially available nano silicon, polynite, the nano-cellulose.
Described polynite is a kind of in commercially available original montmorillonoid soil, amino acid modified montmorillonite, alkyl quaternary ammonium salts modified montmorillonoid and the silane coupler modified polynite.
Described alkyl quaternary ammonium salts modified montmorillonoid is octadecyl trimethyl ammonium chloride modified montmorillonoid or palmityl trimethyl ammonium chloride modified montmorillonoid.
A kind of preparation method of nanometer particle-modified Synthetic Leather slurry is as follows:
First commercially available DMF, auxiliary agent, mill base and nanoparticle are placed in the agitator and stirred 5-10 minute, and then add commercially available thermoplastic polyurethane, such as thermoplastic polyurethane SW-2020RH, continue stirring and got final product in 20-30 minute.
The invention has the beneficial effects as follows: the method Effective Raise of the present invention by directly in the Synthetic Leather slurry, adding nanoparticle wear resistance and the water vapour permeability of Synthetic Leather finished product, and have that cost is low, technique is simple, be beneficial to the advantage of suitability for industrialized production.
Embodiment
The below is described in further details the present invention with specific embodiment, but the present invention not only is confined to following specific embodiment.
Embodiment one
Take by weighing DMF 81.9g, dimethyl silicone oil 1g, stock white 1g, nano-cellulose 0.1g, thermoplastic polyurethane 16g;
First with N, dinethylformamide, dimethyl silicone oil, stock white and nano-cellulose place in the electric mixer and stirred 5 minutes, and then add thermoplastic polyurethane, continue to stir 20 minutes, the slurry that stirs evenly evenly coated to make on the separate-type paper be coated with membrane sample, will be coated with membrane sample and be placed on 50
oOven dry is 5 minutes in the air dry oven of C, the membrane sample that is coated with that takes out oven dry carries out wear resisting property and water vapour permeability test, with test data with do not add nanoparticle but the same sample test data of filming of other component concentrations compare, its result shows: that has added nanoparticle has been coated with membrane sample than the wear resisting property height that is coated with membrane sample that does not add nanoparticle 88.6%, and the water vapour permeability that is coated with membrane sample of not adding nanoparticle is 3.42 * 10
-14G.cm/cm
2.s.Pa, the water vapour permeability that is coated with membrane sample of interpolation nanoparticle is increased to 3.80 * 10
-12G.cm/cm
2It is .s.Pa, nanometer particle-modified that the good results are evident.
Embodiment two
Take by weighing DMF 80g, dimethyl silicone oil 1g, stock white 1g, nano-cellulose 0.1g, thermoplastic polyurethane 18g;
First with N, dinethylformamide, dimethyl silicone oil, stock white and nano-cellulose place in the electric mixer and stirred 5 minutes, and then add thermoplastic polyurethane, continue to stir 20 minutes, the slurry that stirs evenly evenly coated to make on the separate-type paper be coated with membrane sample, will be coated with membrane sample and be placed on 50
oOven dry is 5 minutes in the air dry oven of C, the membrane sample that is coated with that takes out oven dry carries out wear resisting property and water vapour permeability test, with test data with do not add nanoparticle but the same sample test data of filming of other component concentrations compare, its result shows: that has added nanoparticle has been coated with membrane sample than the wear resisting property height that is coated with membrane sample that does not add nanoparticle 76%, and the water vapour permeability that is coated with membrane sample of not adding nanoparticle is 2.6 * 10
-14G.cm/cm
2.s.Pa, the water vapour permeability that is coated with membrane sample of interpolation nanoparticle is increased to 8.3 * 10
-12G.cm/cm
2It is .s.Pa, nanometer particle-modified that the good results are evident.
Embodiment three
Take by weighing DMF 72g, dimethyl silicone oil 1g, stock white 1g, palmityl trimethyl ammonium chloride modified montmorillonoid 1g, thermoplastic polyurethane 25g;
First with N, dinethylformamide, dimethyl silicone oil, stock white and palmityl trimethyl ammonium chloride modified montmorillonoid place in the electric mixer and stirred 5 minutes, and then adding thermoplastic polyurethane, continue to stir 20 minutes, the slurry that stirs evenly evenly coated to make on the separate-type paper be coated with membrane sample, will be coated with membrane sample and be placed on 50
oOven dry is 5 minutes in the air dry oven of C, the membrane sample that is coated with that takes out oven dry carries out wear resisting property and water vapour permeability test, with test data with do not add nanoparticle but the same sample test data of filming of other component concentrations compare, its result shows: that has added nanoparticle has been coated with membrane sample than the wear resisting property height that is coated with membrane sample that does not add nanoparticle 96%, and the water vapour permeability that is coated with membrane sample of not adding nanoparticle is 1.27 * 10
-14G.cm/cm
2.s.Pa, the water vapour permeability that is coated with membrane sample of interpolation nanoparticle is increased to 8.10 * 10
-12G.cm/cm
2It is .s.Pa, nanometer particle-modified that the good results are evident.
Embodiment four
Take by weighing DMF 70g, dimethyl silicone oil 2g, stock white 2g, palmityl trimethyl ammonium chloride modified montmorillonoid 1g, thermoplastic polyurethane 25g;
First with N, dinethylformamide, dimethyl silicone oil, stock white and palmityl trimethyl ammonium chloride modified montmorillonoid place in the electric mixer and stirred 5 minutes, and then adding thermoplastic polyurethane, continue to stir 20 minutes, the slurry that stirs evenly evenly coated to make on the separate-type paper be coated with membrane sample, will be coated with membrane sample and be placed on 50
oOven dry is 5 minutes in the air dry oven of C, the membrane sample that is coated with that takes out oven dry carries out wear resisting property and water vapour permeability test, with test data with do not add nanoparticle but the same sample test data of filming of other component concentrations compare, its result shows: that has added nanoparticle has been coated with membrane sample than the wear resisting property height that is coated with membrane sample that does not add nanoparticle 95.6%, and the water vapour permeability that is coated with membrane sample of not adding nanoparticle is 1.12 * 10
-14G.cm/cm
2.s.Pa, the water vapour permeability that is coated with membrane sample of interpolation nanoparticle is increased to 8.29 * 10
-12G.cm/cm
2It is .s.Pa, nanometer particle-modified that the good results are evident.
Embodiment five
Take by weighing DMF 81g, dimethyl silicone oil 1g, stock white 1g, silane coupler modified polynite 1g, thermoplastic polyurethane 16g;
First with N, dinethylformamide, dimethyl silicone oil, stock white and silane coupler modified polynite place in the electric mixer and stirred 5 minutes, and then adding thermoplastic polyurethane, continue to stir 20 minutes, the slurry that stirs evenly evenly coated to make on the separate-type paper be coated with membrane sample, will be coated with membrane sample and be placed on 50
oOven dry is 5 minutes in the air dry oven of C, the membrane sample that is coated with that takes out oven dry carries out wear resisting property and water vapour permeability test, with test data with do not add nanoparticle but the same sample test data of filming of other component concentrations compare, its result shows: that has added nanoparticle has been coated with membrane sample than the wear resisting property height that is coated with membrane sample that does not add nanoparticle 74.4%, and the water vapour permeability that is coated with membrane sample of not adding nanoparticle is 3.35 * 10
-14G.cm/cm
2.s.Pa, the water vapour permeability that is coated with membrane sample of interpolation nanoparticle is increased to 9.20 * 10
-12G.cm/cm
2It is .s.Pa, nanometer particle-modified that the good results are evident.
Claims (5)
1. nanometer particle-modified Synthetic Leather slurry, it is characterized in that: it is comprised of the component of following weight proportion: thermoplastic polyurethane 15-30 part, DMF 62-83 part, auxiliary agent 1-2 part, mill base 1-3 part, nanoparticle 0.1-3 part.
2. nanometer particle-modified Synthetic Leather slurry according to claim 1 is characterized in that: described auxiliary agent is a kind of in aerosol-OT salt, the dimethyl silicone oil or their mixture.
3. nanometer particle-modified Synthetic Leather slurry according to claim 1 is characterized in that: described nanoparticle is a kind of in nano silicon, polynite, the nano-cellulose.
4. nanometer particle-modified Synthetic Leather slurry according to claim 3 is characterized in that: described polynite is a kind of in original montmorillonoid soil, amino acid modified montmorillonite, alkyl quaternary ammonium salts modified montmorillonoid and the silane coupler modified polynite.
5. nanometer particle-modified Synthetic Leather slurry according to claim 4, it is characterized in that: described alkyl quaternary ammonium salts modified montmorillonoid is octadecyl trimethyl ammonium chloride modified montmorillonoid or palmityl trimethyl ammonium chloride modified montmorillonoid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210530216.XA CN103059552B (en) | 2012-12-11 | 2012-12-11 | Nano-particle modified polyurethane synthetic leather sizing agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210530216.XA CN103059552B (en) | 2012-12-11 | 2012-12-11 | Nano-particle modified polyurethane synthetic leather sizing agent |
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| CN103059552A true CN103059552A (en) | 2013-04-24 |
| CN103059552B CN103059552B (en) | 2014-12-17 |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103821010A (en) * | 2014-02-20 | 2014-05-28 | 安安(中国)有限公司 | Staining method of immersion type pigment for staining of superfine fiber synthetic leather base cloth |
| CN103981729A (en) * | 2014-05-07 | 2014-08-13 | 安安(中国)有限公司 | Aqueous polyurethane making method used for superfine fiber synthetic leather production |
| CN104312090A (en) * | 2014-10-25 | 2015-01-28 | 合肥市安山涂层织物有限公司 | Anti-aging synthetic leather slurry and preparation method thereof |
| CN104312087A (en) * | 2014-10-25 | 2015-01-28 | 合肥市安山涂层织物有限公司 | Environment-friendly flame-retardant synthetic leather slurry and preparation method thereof |
| CN105133366A (en) * | 2015-07-17 | 2015-12-09 | 浙江锦尚合成革有限公司 | Environment-protective synthetic leather and preparation method thereof |
| CN105155293A (en) * | 2015-07-17 | 2015-12-16 | 浙江锦尚合成革有限公司 | Anti-microbial synthetic leather and preparation method thereof |
| CN105176053A (en) * | 2015-07-17 | 2015-12-23 | 浙江锦尚合成革有限公司 | Synthetic leather slurry and preparation method thereof |
| CN106633793A (en) * | 2016-11-08 | 2017-05-10 | 宁波锐克轮业科技有限公司 | Environment-friendly polyurethane material for roller outer ring and preparation method of environment-friendly polyurethane material |
| CN106988131A (en) * | 2017-05-28 | 2017-07-28 | 韦爱龄 | The preparation technology of synthetic leather with high-wear resistance |
| CN107130437A (en) * | 2017-05-28 | 2017-09-05 | 韦爱龄 | The preparation technology of high-wearing feature synthetic leather |
| CN107142739A (en) * | 2017-05-28 | 2017-09-08 | 韦爱龄 | The preparation technology of the durability of synthetic leather can be improved |
| CN107142744A (en) * | 2017-05-28 | 2017-09-08 | 韦爱龄 | The preparation technology of synthetic leather |
| CN109023977A (en) * | 2018-10-22 | 2018-12-18 | 江西泽晞新材料有限公司 | A kind of water-soluble polyurethane leather beth preparation method |
| CN109852036A (en) * | 2018-12-04 | 2019-06-07 | 广州市沃利司皮具有限公司 | Durable suitcase |
| CN110093789A (en) * | 2019-05-15 | 2019-08-06 | 安徽省思维新型建材有限公司 | A kind of improved silica/rare earth/Synthetic Leather adsorbing dust |
| CN110184827A (en) * | 2019-05-15 | 2019-08-30 | 安徽省思维新型建材有限公司 | A kind of preparation method of the environmental protection leather with adsorbing powder dust function |
| CN110938299A (en) * | 2019-11-20 | 2020-03-31 | 东莞市雄林新材料科技股份有限公司 | TPU composite material for chemical protective clothing and preparation method thereof |
| CN111138750A (en) * | 2019-12-27 | 2020-05-12 | 安踏（中国）有限公司 | Anti-slip wear-resistant composite material and preparation method thereof |
| CN111321606A (en) * | 2020-03-13 | 2020-06-23 | 李圣舜 | Synthetic leather and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407997A (en) * | 2008-11-14 | 2009-04-15 | 温州大学 | Nano pulp for producing nano synthetic leather base by wet method and wet method process thereof |
| CN102182073A (en) * | 2011-04-25 | 2011-09-14 | 安安(中国)有限公司 | Method for manufacturing synthetic leather for mildewproof and antibacterial sneakers |
-
2012
- 2012-12-11 CN CN201210530216.XA patent/CN103059552B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407997A (en) * | 2008-11-14 | 2009-04-15 | 温州大学 | Nano pulp for producing nano synthetic leather base by wet method and wet method process thereof |
| CN102182073A (en) * | 2011-04-25 | 2011-09-14 | 安安(中国)有限公司 | Method for manufacturing synthetic leather for mildewproof and antibacterial sneakers |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103821010B (en) * | 2014-02-20 | 2016-08-24 | 安安(中国)有限公司 | A kind of impregnated pigment coloring method for superfine fiber synthetic leather base cloth coloring |
| CN103821010A (en) * | 2014-02-20 | 2014-05-28 | 安安(中国)有限公司 | Staining method of immersion type pigment for staining of superfine fiber synthetic leather base cloth |
| CN103981729A (en) * | 2014-05-07 | 2014-08-13 | 安安(中国)有限公司 | Aqueous polyurethane making method used for superfine fiber synthetic leather production |
| CN103981729B (en) * | 2014-05-07 | 2016-01-20 | 安安(中国)有限公司 | A kind of aqueous polyurethane for superfine fiber chemical leather manufacture makes face method |
| CN104312090A (en) * | 2014-10-25 | 2015-01-28 | 合肥市安山涂层织物有限公司 | Anti-aging synthetic leather slurry and preparation method thereof |
| CN104312087A (en) * | 2014-10-25 | 2015-01-28 | 合肥市安山涂层织物有限公司 | Environment-friendly flame-retardant synthetic leather slurry and preparation method thereof |
| CN105176053B (en) * | 2015-07-17 | 2018-06-19 | 浙江锦尚合成革有限公司 | A kind of synthetic leather slurry and preparation method thereof |
| CN105133366A (en) * | 2015-07-17 | 2015-12-09 | 浙江锦尚合成革有限公司 | Environment-protective synthetic leather and preparation method thereof |
| CN105155293A (en) * | 2015-07-17 | 2015-12-16 | 浙江锦尚合成革有限公司 | Anti-microbial synthetic leather and preparation method thereof |
| CN105176053A (en) * | 2015-07-17 | 2015-12-23 | 浙江锦尚合成革有限公司 | Synthetic leather slurry and preparation method thereof |
| CN106633793A (en) * | 2016-11-08 | 2017-05-10 | 宁波锐克轮业科技有限公司 | Environment-friendly polyurethane material for roller outer ring and preparation method of environment-friendly polyurethane material |
| CN106988131A (en) * | 2017-05-28 | 2017-07-28 | 韦爱龄 | The preparation technology of synthetic leather with high-wear resistance |
| CN107142739A (en) * | 2017-05-28 | 2017-09-08 | 韦爱龄 | The preparation technology of the durability of synthetic leather can be improved |
| CN107142744A (en) * | 2017-05-28 | 2017-09-08 | 韦爱龄 | The preparation technology of synthetic leather |
| CN107130437A (en) * | 2017-05-28 | 2017-09-05 | 韦爱龄 | The preparation technology of high-wearing feature synthetic leather |
| CN109023977A (en) * | 2018-10-22 | 2018-12-18 | 江西泽晞新材料有限公司 | A kind of water-soluble polyurethane leather beth preparation method |
| CN109852036A (en) * | 2018-12-04 | 2019-06-07 | 广州市沃利司皮具有限公司 | Durable suitcase |
| CN110093789A (en) * | 2019-05-15 | 2019-08-06 | 安徽省思维新型建材有限公司 | A kind of improved silica/rare earth/Synthetic Leather adsorbing dust |
| CN110184827A (en) * | 2019-05-15 | 2019-08-30 | 安徽省思维新型建材有限公司 | A kind of preparation method of the environmental protection leather with adsorbing powder dust function |
| CN110938299A (en) * | 2019-11-20 | 2020-03-31 | 东莞市雄林新材料科技股份有限公司 | TPU composite material for chemical protective clothing and preparation method thereof |
| CN111138750A (en) * | 2019-12-27 | 2020-05-12 | 安踏（中国）有限公司 | Anti-slip wear-resistant composite material and preparation method thereof |
| CN111321606A (en) * | 2020-03-13 | 2020-06-23 | 李圣舜 | Synthetic leather and preparation method thereof |
| CN111321606B (en) * | 2020-03-13 | 2022-11-11 | 李圣舜 | Synthetic leather and preparation method thereof |
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