CN103059389A - Environment-friendly flame-retardant antistatic polyethylene pipeline - Google Patents
Environment-friendly flame-retardant antistatic polyethylene pipeline Download PDFInfo
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- CN103059389A CN103059389A CN2013100406237A CN201310040623A CN103059389A CN 103059389 A CN103059389 A CN 103059389A CN 2013100406237 A CN2013100406237 A CN 2013100406237A CN 201310040623 A CN201310040623 A CN 201310040623A CN 103059389 A CN103059389 A CN 103059389A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Abstract
The invention relates to an environment-friendly flame-retardant antistatic polyethylene pipeline which is prepared from high-density polyethylene resin, Mg(OH)2, 35-42 parts by weight of phenoxy polyphosphazene elastomer, nano calcium carbonate, nano carbon black, silane coupling agent KH-570, pentaerythritol stearamide, antioxidant 736 and antioxidant 168. The environment-friendly flame-retardant antistatic polyethylene pipeline provided by the invention has the advantages of high flame-retardant efficiency, small addition amount and favorable comprehensive mechanical properties, and generates no molten drops or harmful gas and less smoke in the combustion process.
Description
Technical field
The present invention relates to a kind of environment-protection flame-proof electrostatic resistance polyethylene pipe, relate in particular to a kind of environment-protection flame-proof electrostatic resistance polyethylene pipe for delivery of inflammable gases such as coal gas.
Background technology
Polyethylene pipe is one of modal pipeline, and it has low-temperature impact resistance, resistance to chemical attack, the advantage such as wear-resisting, all is used widely in feedwater, draining, heat supply, for combustion gas, agricultural irrigation, hydro project and various full scale plant.Polyethylene (Polyethylene, be called for short PE) refer to the polymkeric substance that formed by vinyl monomer radical polymerization, one of general-purpose plastics of output maximum, be a kind of light weight, nontoxic, have physical strength preferably, good electrical insulating property and a thermoplastics of resistance to chemical corrosion.And forming process is convenient, is widely used in the industries such as electric wire, chemical industry, food, packing, machinery, telecommunications, home decoration and civil construction, and its demand rises just year by year.The main degradation production of polyethylene has ethane, ethene, propane, propylene, butylene, amylene, 1-butylene, hexane etc., and the degraded product of its formation is relevant with the route that intermolecular chain shifts.Degradation process is being subject under the effect of oxygen, and degraded product mainly contains propionic aldehyde, amylene, Skellysolve A, butyraldehyde, valeral etc.The thermal destruction product that combustion processes is found mainly contains amylene, butyraldehyde, 1-hexene, normal hexane, benzene, valeral etc.Polyethylene is combustible polymers, oxygen index is 17 ~ 18%, combustion heat value belongs to the higher person in polymer materials, be 45.9 MJ/kg, the heat release rate of measuring with the taper calorimeter is also higher, polyethylene is vinyl monomer by the synthetic polymkeric substance of polyaddition reaction, only has carbon, two kinds of elements of hydrogen in molecular structure.Polyethylene is said between 50 ℃ about 335 greatly and is decomposed.Under oxygen free condition, thermostability is higher.In inert atmosphere, polyethylene is crosslinked 202 ℃ of lower generations, and molecular weight begins to descend in the time of 292 ℃, degraded occurs, but significant decomposition can not occur before 372 ℃.Poly thermal degradation reaction is in random scission and the molecule and the intermolecular transfer reaction, and high-temperature heating is degraded into low molecular weight substance, propagating flame very easily, initiation fire.Only because the fire losses that electric wire causes reaches more than 50 hundred million yuans every year, this just is restricted polyolefine application in a lot of fields in China.
Along with further developing of modern flame-retarded technology, increasing fire retardant appears in the flame retardant area, for the Security and development of society has been made huge contribution.People's fire retardant commonly used in polyolefine has two kinds now: a kind of is reactive flame retardant; Another kind is additive flame retardant.
Reactive flame retardant is to participate in polyreaction by the monomer that some is contained ignition-proof element, makes in the main chain of polymkeric substance or the side chain with ignition-proof element, plays fire-retardant effect.Reactive flame retardant mainly contains halo phenols, halo anhydrides, halogenated alcohols, halogen ester, halo ethers.Additive flame retardant refers to carry out with macromolecular material with the physical dispersion state fire retardant of blend performance fire retardation.Halogenated flame retardant is few with its addition, and flame retardant effect is significantly and commonly used, the 70-80 age in 20th century be experienced the development golden age.Although its consumption is gradually downward trend, its output and consumption are still in the world larger fire retardant kind at present.Halogenated flame retardant mainly contains chlorine-based flame retardant and bromide fire retardant two large classes.The kind that chlorine-based flame retardant is commonly used has that clorafin, chlorinatedpolyethylene, tetrachlorophthalic acid are joined, tetrachlorobisphenol A, hexachlorocyclopentadiene and derivative thereof etc.The flame retardant effect of chlorine-based flame retardant is not as good as bromide fire retardant, and this bond energy with the C-Cl key is larger than the bond energy of C-Br key, and it is relevant to be difficult for producing chlorine radicals.Thereby in halogenated flame retardant, bromide fire retardant is absolute main flow.Bromide fire retardant divides from molecular structure can be divided into four kinds of aromatic series, aliphatics, alicyclic and mixed types.From compound structure, it can be divided into bromo-diphenyl ether, tetrabromo-bisphenol class, bromo polyalcohols, bromophthalic acid acid anhydride class, and other various novel sea flame retardants, bromide fire retardant commonly used mainly contains decabromodiphenyl oxide (DBDPO), two (tetrabromo-phthalic two formyls) ethane etc.Yet, although halogenated flame retardant has preferably flame retardant effect, but emit a large amount of toxic gases during burning, produce a large amount of toxic smogs, human body there is larger harm, since the Dioxin problem that occurred in 1986, halogenated flame retardant especially bromide fire retardant is faced with huge environmental protection pressure.
Reactive flame retardant is because it makes the structural unit with anti-flaming function receive on the polymer by chemical bond-linking by polyreaction, therefore its flame retardant effect is lasting, and less on the physical and mechanical property impact of material, but because the problem of technology and price is greatly limited its promotion and application.Compare with reactive flame retardant, the right agent of additive flame is easy to use, cheap, thereby be the common method that realizes at present polyethylene anti-flaming, the additive flame retardant that is usually used in the polyethylene anti-flaming modification has halogenated flame retardant, halogen-free flame retardants and composite flame retardant system etc.
Halogen-free flame retardants mainly comprises following a few class:
(1) hydroxide hydrate
That obtain at present main application is Mg (OH)
2And Al (OH)
3Two kinds.Hydroxide hydrate because of its do not produce secondary pollution, Heat stability is good, good, nontoxic, non-volatile without burn into other fire retardant synergistic effect, do not produce toxic gas, low, the wide material sources of price, being described as nuisanceless fire retardant, is to integrate fire-retardant, press down cigarette, fill the fire retardant of three large functions.Yet, the large physical and mechanical properties that affects of inorganic combustion inhibitor addition, the magnesium hydroxide addition often needs to reach more than 50% and just can reach good flame retardant effect, and adds in a large number Mg (OH)
2And AI (OH)
3Polyethylene mechanical property and processing characteristics are obviously descended.
(2) phosphorus flame retardant
Phosphorus flame retardant is take red phosphorus as representative, and red phosphorus system is red to the red-purple powder, and because of its phosphorus element-containing only, so compare with other phosphorus compound, it is high that the flame retarding efficiency of red phosphorus is wanted.Its fire-retardant rank of HDPE that contains 8% red phosphorus just can reach UL-94 V-0 level.
Yet red phosphorus also exists with poor, the easy moisture absorption of the consistency of polyvinyl resin, the deficiency such as the color is too dark.
(3) expansibility flame-proof agent
The expansibility flame-proof agent is not single fire retardant kind, but the Halogen composite flame retardant system take phosphorus, nitrogen, carbon as main component, it is not halogen-containing, does not adopt Sb yet
2O
3Make synergist, self have synergy in its system.Because this based flame retardant can be expanded foamed when being heated, so be called the expansibility flame-proof agent.The plastics that contain expansibility flame-proof agent surface when burning can generate the carbonaceous foam, plays heat insulation, oxygen barrier, presses down cigarette, anti-melting the effect such as drip, and has good flame retardant properties, has again the advantages such as Halogen, low cigarette, low toxicity, anti-drippage and non-corrosiveness gas.
The expansibility flame-proof agent generally is comprised of three parts: acid source, charcoal source, source of the gas.Concrete three components are as follows: 1. acid source is called again dewatering agent, catalyzer or charing promotor.Be generally mineral acid or inorganic acid compound, can with the resin effect, promote the generation of carbide.Concrete kind has: phosphoric acid, sulfuric acid, boric acid, phosphoric acid money salt, phosphoric acid vinegar, phosphoric acid salt and polyphosphoric acid amine etc. are the most commonly used with polyphosphoric acid amine.2. the charcoal source is called again char-forming agent.Be mainly the more much higher light based compound of some carbon content or carbohydrate, such as resin itself, starch, tetramethylolmethane and dimer and tripolymer etc.3. source of the gas is called again whipping agent, can discharge rare gas element.For containing nitrogen compound, such as amine and phthalein amine, urea, trimerization pendant amine, Dyhard RU 100, polyphosphoric acid amine, cruel, the poly-resin etc. that takes of poly-ammonia are arranged specifically.Nitrogen compound also has promoter action to the formation of charring layer except playing foaming effect.Yet these fire retardants exist moisture absorption, combustion decomposition process to be difficult for obtaining closed pore charcoal layer and the not good defective of flame retardant effect.
Summary of the invention
The purpose of this invention is to provide a kind of environment-protection flame-proof electrostatic resistance polyethylene pipe, have good flame retardant properties and do not produce toxic gas on the basis that keeps the original performance of polyvinyl resin.
The technical scheme that adopts for achieving the above object of the present invention is:
A kind of environment-protection flame-proof electrostatic resistance polyethylene pipe is comprised of the raw material of following weight part meter:
High-density polyethylene resin 97 ~ 103 weight parts,
Mg (OH)
231～39 weight parts,
Phenoxy group polyphosphonitrile elastomerics 35～42 weight parts,
Nanometer grade calcium carbonate 37～40 weight parts,
Nano level carbon black 6 ~ 8 weight parts,
Silane coupling reagent KH-570 5 ~ 7 weight parts,
Tetramethylolmethane Stearyl Amine 1 ~ 1.3 weight part,
Oxidation inhibitor 736 0.8 ~ 1 weight part,
Irgasfos 168 0.6 ~ 0.9 weight part.
Its preparation method is as follows:
1) according to each component of said components proportion speed weighing, then fully dry;
2) irgasfos 168 of getting first oxidation inhibitor 736,0.2 ~ 0.3 weight part of tetramethylolmethane Stearyl Amine, 0.2 ~ 0.4 weight part of phenoxy group polyphosphonitrile elastomerics, 0.4 ~ 0.6 weight part of high-density polyethylene resin, 12 ~ 20 weight parts of 30～50 weight parts adds in the high-speed mixer and mixes, mixing time 2-3 minute, then 130 ℃～150 ℃ banburyings 15～20 minutes in Banbury mixer, take out the broken polyethylene master batch that obtains containing the phenoxy group polyphosphonitrile;
3) in proportion with step 2) the polyethylene master batch that contains the phenoxy group polyphosphonitrile that makes, add in the high-speed mixer and mix together with Mg (OH) 2, nanometer grade calcium carbonate, nano level carbon black, Silane coupling reagent KH-570 and remaining high-density polyethylene resin, tetramethylolmethane Stearyl Amine and oxidation inhibitor 736, irgasfos 168, mixing time 4-6 minute, discharging was for subsequent use;
4) material that step 3) is mixed in twin screw extruder under 145 ℃～165 ℃ conditions extruding pelletization;
5) the material drying after the step 4) granulation is processed after, extrude through forming machine at the polyvinyl piping materials production line again that------step of traction---cooling and shaping---cutting is made tubing to sizing.
Fire retardant, antistatic polyethylene pipe of the present invention road, add therein the nano level carbon black and improved its antistatic effect, add simultaneously phenoxy group polyphosphonitrile elastomerics and improve poly flame retardant properties, phenoxy group polyphosphonitrile elastomerics contains the phosphoric of high level, can generate the strong acid such as phosphoric acid, metaphosphoric acid under the high temperature, promote that organics dehydration becomes charcoal; Can generate nitrogen dilution and blocking oxygen under the nitrogen element high temperature; Phenyl ring then provides a large amount of charcoals, remedies the problem of polyethylene combustion decomposition process neat coal amout deficiency.Nano level Mg (OH)
2As synergist, utilize its function that presses down cigarette, cooling further to improve poly flame retardant properties.Nanometer grade calcium carbonate can the Effective Raise material mechanical property and flame retardant properties.Cooperation and synergy by above each component have played fabulous flame retardant effect.Through Mechanics Performance Testing and combustionproperty test, fire retardant, antistatic polyethylene pipe of the present invention road fire retardant efficient is high, and addition is little, and it is little that burning does not produce molten drop and the amount of being fuming, and do not produce obnoxious flavour, and comprehensive mechanical property is good in fire-retardant.
Description of drawings
Fig. 1 is the synoptic diagram of environment-protection flame-proof electrostatic resistance polyethylene pipe of the present invention.
Embodiment
Following examples describe the present invention in detail.Various raw material used in the present invention and items of equipment are conventional commercially available prod, all can buy directly by market to obtain.
Embodiment 1
Prepare as follows the environment-protection flame-proof electrostatic resistance polyethylene pipe
1) according to each component of the accurate weighing of following component proportion, then fully dry;
High-density polyethylene resin 97 weight parts,
Mg (OH)
239 weight parts,
Phenoxy group polyphosphonitrile elastomerics 35 weight parts,
Nanometer grade calcium carbonate 37 weight parts,
Nano level carbon black 6 weight parts,
Silane coupling reagent KH-570 5 weight parts,
Tetramethylolmethane Stearyl Amine 1 weight part,
Oxidation inhibitor 736 0.8 weight parts,
Irgasfos 168 0.6 weight part,
Its preparation method is as follows:
2) irgasfos 168 of getting first oxidation inhibitor 736,0.2 weight part of tetramethylolmethane Stearyl Amine, 0.2 weight part of phenoxy group polyphosphonitrile elastomerics, 0.4 weight part of high-density polyethylene resin, 12 weight parts of 30 weight parts adds in the GH-10A type high-speed mixer and mixes, mixing time 2 minutes, then 130 ℃ of banburyings 15 minutes in Banbury mixer, take out the broken polyethylene master batch that obtains containing the phenoxy group polyphosphonitrile;
3) in proportion with step 2) the polyethylene master batch that contains the phenoxy group polyphosphonitrile that makes, add in the GH-10A type high-speed mixer together with Mg (OH) 2, nanometer grade calcium carbonate, nano level carbon black, Silane coupling reagent KH-570 and remaining high-density polyethylene resin, tetramethylolmethane Stearyl Amine and oxidation inhibitor 736, irgasfos 168 and to mix, mixing time 4 minutes, discharging is for subsequent use;
4) material that step 3) is mixed carries out the melting mixing extruding pelletization by SHJ-36 type parallel double-screw mixing extruder, the temperature of melting mixing is as follows: 145 ℃ in the first district, 150 ℃ of Second Regions, 155 ℃ in the 3rd district, 160 ℃ in the 4th district, 165 ℃ in the 5th district, 155 ℃ in the 6th district, 150 ℃ of SECTOR-SEVENs, 145 ℃ of Section Eight, 145 ℃ of machine head port moulds; Screw speed is 300r/min; The feed screw rotating speed is 24r/min.
5) the material drying after the step 4) granulation is processed after, extrude through forming machine at the polyvinyl piping materials production line again that------step of traction---cooling and shaping---cutting is made tubing to sizing.This step is conventional polyvinyl piping materials production sequence, gives unnecessary details no longer in detail.
Product to embodiment 1 carries out mechanics and combustionproperty test, wherein adopt the CMT-6104 electronic universal tester by GB/T 1040-92 plastic tensile experimental technique test tensile strength and elongation at break, draw speed is 100mm/min, shock strength adopts XCS-200 impact specimen machine, presses GB/T 1040-93 and measures; HC-2 type oxygen index instrument is adopted in the limiting oxygen index(LOI) test, tests by the GB/T2406-93 standard test methods.
Through test, the flame retardant rating of the environment-protection flame-proof electrostatic resistance polyethylene pipe of embodiment 1 is the FV-0 level, and tensile strength is 26.3Mpa, and elongation at break is 630%, and notched Izod impact strength is 21 KJ/m
2
Embodiment 2
Prepare as follows the environment-protection flame-proof electrostatic resistance polyethylene pipe
1) according to each component of the accurate weighing of following component proportion, then fully dry;
High-density polyethylene resin 99 weight parts,
Mg (OH)
235 weight parts,
Phenoxy group polyphosphonitrile elastomerics 39 weight parts,
Nanometer grade calcium carbonate 38 weight parts,
Nano level carbon black 7 weight parts,
Silane coupling reagent KH-570 6 weight parts,
Tetramethylolmethane Stearyl Amine 1.2 weight parts,
Oxidation inhibitor 736 0.9 weight parts,
Irgasfos 168 0.8 weight part,
Its preparation method is as follows:
2) irgasfos 168 of getting first oxidation inhibitor 736,0.2 weight part of tetramethylolmethane Stearyl Amine, 0.3 weight part of phenoxy group polyphosphonitrile elastomerics, 0.5 weight part of high-density polyethylene resin, 17 weight parts of 40 weight parts adds in the GH-10A type high-speed mixer and mixes, mixing time 3 minutes, then 140 ℃ of banburyings 18 minutes in Banbury mixer, take out the broken polyethylene master batch that obtains containing the phenoxy group polyphosphonitrile;
3) in proportion with step 2) the polyethylene master batch that contains the phenoxy group polyphosphonitrile that makes, add in the GH-10A type high-speed mixer together with Mg (OH) 2, nanometer grade calcium carbonate, nano level carbon black, Silane coupling reagent KH-570 and remaining high-density polyethylene resin, tetramethylolmethane Stearyl Amine and oxidation inhibitor 736, irgasfos 168 and to mix, mixing time 5 minutes, discharging is for subsequent use;
4) material that step 3) is mixed carries out the melting mixing extruding pelletization by SHJ-36 type parallel double-screw mixing extruder, the temperature of melting mixing is as follows: 145 ℃ in the first district, 150 ℃ of Second Regions, 155 ℃ in the 3rd district, 160 ℃ in the 4th district, 165 ℃ in the 5th district, 155 ℃ in the 6th district, 150 ℃ of SECTOR-SEVENs, 145 ℃ of Section Eight, 145 ℃ of machine head port moulds; Screw speed is 300r/min; The feed screw rotating speed is 24r/min.
5) the material drying after the step 4) granulation is processed after, extrude through forming machine at the polyvinyl piping materials production line again that------step of traction---cooling and shaping---cutting is made tubing to sizing.
Product to present embodiment carries out mechanics and combustionproperty test, and testing method is the same
Through test, the flame retardant rating of the environment-protection flame-proof electrostatic resistance polyethylene pipe of present embodiment is the FV-0 level, and tensile strength is 27.1Mpa, and elongation at break is 643%, and notched Izod impact strength is 22 KJ/m
2
Embodiment 3
Prepare as follows the environment-protection flame-proof electrostatic resistance polyethylene pipe
1) according to each component of the accurate weighing of following component proportion, then fully dry;
High-density polyethylene resin 103 weight parts,
Mg (OH)
231 weight parts,
Phenoxy group polyphosphonitrile elastomerics 42 weight parts,
Nanometer grade calcium carbonate 40 weight parts,
Nano level carbon black 8 weight parts,
Silane coupling reagent KH-570 7 weight parts,
Tetramethylolmethane Stearyl Amine 1.3 weight parts,
Oxidation inhibitor 736 1 weight parts,
Irgasfos 168 0.9 weight part,
Its preparation method is as follows:
2) irgasfos 168 of getting first oxidation inhibitor 736,0.2 ~ 0.3 weight part of tetramethylolmethane Stearyl Amine, 0.4 weight part of phenoxy group polyphosphonitrile elastomerics, 0.6 weight part of high-density polyethylene resin, 20 weight parts of 50 weight parts adds in the GH-10A type high-speed mixer and mixes, mixing time 3 minutes, then 150 ℃ of banburyings 20 minutes in Banbury mixer, take out the broken polyethylene master batch that obtains containing the phenoxy group polyphosphonitrile;
3) in proportion with step 2) the polyethylene master batch that contains the phenoxy group polyphosphonitrile that makes, add in the GH-10A type high-speed mixer together with Mg (OH) 2, nanometer grade calcium carbonate, nano level carbon black, Silane coupling reagent KH-570 and remaining high-density polyethylene resin, tetramethylolmethane Stearyl Amine and oxidation inhibitor 736, irgasfos 168 and to mix, mixing time 6 minutes, discharging is for subsequent use;
4) material that step 3) is mixed carries out the melting mixing extruding pelletization by SHJ-36 type parallel double-screw mixing extruder, the temperature of melting mixing is as follows: 145 ℃ in the first district, 150 ℃ of Second Regions, 155 ℃ in the 3rd district, 160 ℃ in the 4th district, 165 ℃ in the 5th district, 155 ℃ in the 6th district, 150 ℃ of SECTOR-SEVENs, 145 ℃ of Section Eight, 145 ℃ of machine head port moulds; Screw speed is 300r/min; The feed screw rotating speed is 24r/min.
5) the material drying after the step 4) granulation is processed after, extrude through forming machine at the polyvinyl piping materials production line again that------step of traction---cooling and shaping---cutting is made tubing to sizing.
Product to present embodiment carries out mechanics and combustionproperty test, and testing method is the same
Through test, the flame retardant rating of the environment-protection flame-proof electrostatic resistance polyethylene pipe of present embodiment is the FV-0 level, and tensile strength is 27.7Mpa, and elongation at break is 639%, and notched Izod impact strength is 21 KJ/m
2
Ultimate principle of the present invention and principal character and advantage of the present invention have more than been described; the technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications; these changes and improvements all fall in the claimed scope of the invention, and the claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (3)
1. an environment-protection flame-proof electrostatic resistance polyethylene pipe is characterized in that, and is composed of the following components:
High-density polyethylene resin 97 ~ 103 weight parts,
Mg (OH)
231～39 weight parts,
Phenoxy group polyphosphonitrile elastomerics 35～42 weight parts,
Nanometer grade calcium carbonate 37～40 weight parts,
Nano level carbon black 6 ~ 8 weight parts,
Silane coupling reagent KH-570 5 ~ 7 weight parts,
Tetramethylolmethane Stearyl Amine 1 ~ 1.3 weight part,
Oxidation inhibitor 736 0.8 ~ 1 weight part,
Irgasfos 168 0.6 ~ 0.9 weight part.
2. environment-protection flame-proof electrostatic resistance polyethylene pipe according to claim 1 is characterized in that, the Mg in the described component (OH)
2Be nano level.
3. environment-protection flame-proof electrostatic resistance polyethylene pipe according to claim 1 and 2 is characterized in that, described device for cleaning pipeline is crossed following steps and made:
1) according to each component of said components proportion speed weighing, then fully dry;
2) irgasfos 168 of getting first oxidation inhibitor 736,0.2 ~ 0.3 weight part of tetramethylolmethane Stearyl Amine, 0.2 ~ 0.4 weight part of phenoxy group polyphosphonitrile elastomerics, 0.4 ~ 0.6 weight part of high-density polyethylene resin, 12 ~ 20 weight parts of 30～50 weight parts adds in the high-speed mixer and mixes, mixing time 2-3 minute, then 130 ℃～150 ℃ banburyings 15～20 minutes in Banbury mixer, take out the broken polyethylene master batch that obtains containing the phenoxy group polyphosphonitrile;
3) in proportion with step 2) the polyethylene master batch that contains the phenoxy group polyphosphonitrile that makes, add in the high-speed mixer and mix together with Mg (OH) 2, nanometer grade calcium carbonate, nano level carbon black, Silane coupling reagent KH-570 and remaining high-density polyethylene resin, tetramethylolmethane Stearyl Amine and oxidation inhibitor 736, irgasfos 168, mixing time 4-6 minute, discharging was for subsequent use;
4) material that step 3) is mixed in twin screw extruder under 145 ℃～165 ℃ conditions extruding pelletization;
5) the material drying after the step 4) granulation is processed after, extrude through forming machine at the polyvinyl piping materials production line again that------step of traction---cooling and shaping---cutting is made tubing to sizing.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103568240A (en) * | 2013-07-17 | 2014-02-12 | 扬州巨业耐磨复合材料有限责任公司 | Extruding and forming method of polyethylene pipe for water supply |
| CN105037900A (en) * | 2015-09-06 | 2015-11-11 | 杭州鑫璐实业有限公司 | Flame-retardant high-density polyethylene pipeline and preparation method thereof |
| CN109249606A (en) * | 2018-09-12 | 2019-01-22 | 东港市远东节水灌溉设备有限公司 | A kind of fire retardant, antistatic polyethylene pipe material and preparation method thereof |
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| JPH04154852A (en) * | 1990-10-19 | 1992-05-27 | Hitachi Cable Ltd | Flame retardant electrical insulating composition |
| CN102558841A (en) * | 2011-12-29 | 2012-07-11 | 上海金发科技发展有限公司 | Flame-retardant polyamide composite material and preparation method thereof |
| CN102850629A (en) * | 2012-09-18 | 2013-01-02 | 浙江新大塑料管件有限公司 | Mine polyethylene tube |
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| JPH04154852A (en) * | 1990-10-19 | 1992-05-27 | Hitachi Cable Ltd | Flame retardant electrical insulating composition |
| CN102558841A (en) * | 2011-12-29 | 2012-07-11 | 上海金发科技发展有限公司 | Flame-retardant polyamide composite material and preparation method thereof |
| CN102850629A (en) * | 2012-09-18 | 2013-01-02 | 浙江新大塑料管件有限公司 | Mine polyethylene tube |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103568240A (en) * | 2013-07-17 | 2014-02-12 | 扬州巨业耐磨复合材料有限责任公司 | Extruding and forming method of polyethylene pipe for water supply |
| CN103568240B (en) * | 2013-07-17 | 2016-01-20 | 扬州巨业耐磨复合材料有限责任公司 | A kind of polyethylene pipe workpiece for water supply extruding forming method |
| CN105037900A (en) * | 2015-09-06 | 2015-11-11 | 杭州鑫璐实业有限公司 | Flame-retardant high-density polyethylene pipeline and preparation method thereof |
| CN109249606A (en) * | 2018-09-12 | 2019-01-22 | 东港市远东节水灌溉设备有限公司 | A kind of fire retardant, antistatic polyethylene pipe material and preparation method thereof |
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