CN103058532B - Antiultraviolet composite fireproof glass - Google Patents

Antiultraviolet composite fireproof glass Download PDF

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Publication number
CN103058532B
CN103058532B CN201110321264.3A CN201110321264A CN103058532B CN 103058532 B CN103058532 B CN 103058532B CN 201110321264 A CN201110321264 A CN 201110321264A CN 103058532 B CN103058532 B CN 103058532B
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China
Prior art keywords
fireproofing
glass
composite fireproof
fireproof glass
glass substrate
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Expired - Fee Related
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CN201110321264.3A
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Chinese (zh)
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CN103058532A (en
Inventor
薛林
王正
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Zhejiang Fulongding Glass Technology Co., Ltd.
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ZHEJIANG FULONGDING GLASS TECHNOLOGY Co Ltd
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Priority to CN201110321264.3A priority Critical patent/CN103058532B/en
Publication of CN103058532A publication Critical patent/CN103058532A/en
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Abstract

The invention discloses one and effectively can intercept ultraviolet fire prevention composite structure glass, comprise two panels glass substrate, be filled with fireproofing in two panels glass substrate, fireproofing comprises first first junket 50%, dibutylester 15%, S-WAT 20%, zinc oxide (ZNO) 1.3%, magnesium hydroxide 3%, phthalic acid fourth Bian fat 0.2%, acrylamide 10%, ethanol 0.1%, ESCALOL 567 0.4% by weight percentage.The present invention adopts the fireproofing of this kind of formula, and effectively can intercept ultraviolet, fire performance is good, and under long-time using state, fireproofing is not easy foaming, and therefore light transmission is good.

Description

Antiultraviolet composite fireproof glass
[technical field]
The invention belongs to flame resistant glass Material Field, especially there is the composite fireproof glass of antiultraviolet effect.
[background technology]
Antiultraviolet composite fireproof glass is the structure at two sheet glass central filler fireproofings, and when by uviolizing, fireproofing specific proportions batching can effective ultraviolet-cutoff and light transmission is good; When fire occurs, fireproofing specific proportions batching will absorb the heat of flame transmission in large quantities by foaming and intumescing, and the heat stoping burning to produce is from counter-fire towards the transmission in the fiery face of the back of the body.In actual use, it is more weak that common composite fireproof glass penetrates obstructing capacity to ultraviolet, and under ultraviolet long-term irradiation, fire-resistant fluid can become oyster white and produce steam bubble, loses the transparent functional of glass, thus limits its range of application.And common pad pasting or coating against UV-radiation glass are also because of the restriction of working life, the occasion that particularly sunlight equitemperature is slightly high, its aging speed is constantly accelerated, and rete, coating go bad gradually, and effect weakens in time.
[summary of the invention]
The object of the invention is to the deficiency overcoming above-mentioned existence, provide a kind of stability high and can effectively intercept ultraviolet composite fireproof glass.
The object of the invention is to have come by following technical solution, antiultraviolet composite fireproof glass, comprises two panels glass substrate, is filled with fireproofing in two panels glass substrate, and fireproofing comprises following components by weight percentage:
First methyl esters 50%; Dibutylester 15%; S-WAT 20%;
Zinc oxide (ZnO) 1.3%; Magnesium hydroxide 3%; Phthalic acid fourth benzyl fat 0.2%;
Acrylamide 10%; Ethanol 0.1%; ESCALOL 567 0.4%.
Each component function illustrates:
1, ESCALOL 567
It contains the benzophenone of two vicinal hydroxyl groups, absorbs ultraviolet ability the strongest, has strong absorption effect to the UV-light that wavelength is 330-370nm.
2, phthalic acid fourth benzyl fat
Strengthen goods thermotolerance, photostabilization and winter hardiness.
3, zinc oxide
Absorb ultraviolet.
4, first methyl esters
Methyl methacrylate, molecular formula is C5H8O2, specific refractory power 1.4142.
5, dibutylester
Lubricant and tenderizer.
6, S-WAT
Bleaching reductive agent, sanitas, antichlor etc.
7, magnesium hydroxide
Carbonic acid gas in easy absorption air.
8, ethanol
Reduce freezing point of solution, play antifreeze effect; Due to the existence of tensio-active agent, by wetting infiltration, the effect of reach clean decontamination, enhancing the transparency.
The present invention adopts the fireproofing of this kind of formula, and effectively can intercept ultraviolet, fire performance is good, and under long-time using state, fireproofing is not easy foaming, and therefore light transmission is good.
[embodiment]
Detailed introduction is done to fireproofing component of the present invention and compound glass manufacturing process below:
Antiultraviolet composite fireproof glass, comprises two panels glass substrate, is filled with fireproofing in two panels glass substrate, and glass substrate can adopt toughened glass, and fireproofing comprises following components by weight percentage:
First methyl esters 50%; Dibutylester 15%; S-WAT 20%;
Zinc oxide (ZnO) 1.3%; Magnesium hydroxide 3%; Phthalic acid fourth benzyl fat 0.2%;
Acrylamide 10%; Ethanol 0.1%; ESCALOL 567 0.4%.
Each component function illustrates:
1, ESCALOL 567
It contains the benzophenone of two vicinal hydroxyl groups, absorbs ultraviolet ability the strongest, has strong absorption effect to the UV-light that wavelength is 330-370nm.
2, phthalic acid fourth benzyl fat
Strengthen goods thermotolerance, photostabilization and winter hardiness.
3, zinc oxide
Absorb ultraviolet.
4, first methyl esters
Methyl methacrylate, molecular formula is C5H8O2, specific refractory power 1.4142.
5, dibutylester
Lubricant and tenderizer.
6, S-WAT
Bleaching reductive agent, sanitas, antichlor etc.
7, magnesium hydroxide
Carbonic acid gas in easy absorption air.
8, ethanol
Reduce freezing point of solution, play antifreeze effect; Due to the existence of tensio-active agent, by wetting infiltration, the effect of reach clean decontamination, enhancing the transparency.
The present invention adopts the fireproofing of this kind of formula, and effectively can intercept ultraviolet, fire performance is good, and under long-time using state, fireproofing is not easy foaming, and therefore light transmission is good.
Below introduce the manufacturing operation code of compound glass:
1) size cutting glass plate on demand, scale error < 0.2mm.
2) glass fine-grinding four limit, and send into temperature tempering in the annealing furnace of 650-750 DEG C
3) wash away with softening water after coming out of the stove; Good perfusion face, first with dry cloth wiping, ensures clean clean.
4) use cloth to wipe with wipe dry after, then be stained with acetone wiping degreasing with clean cotton, can not there be greasy dirt or dirt settling in surface, for subsequent use.
5), on the glass after one piece wiping, joint strip is sticked along limit.After real, by angle injecting glue entrance being stayed the one end on the long limit of glass.
6) sealed strip is in stitching portion, is cut into 45 degree of docking, during joint close, adhesive tape is coated with some glue preventing from cementing leakages.
7) joint strip will develop, compacting.Do not allow artificial elongation or shortening, prevent shrink, wrinkling.
8) after glazing tape posts, with " dovetail clip ", glass surrounding is clipped, aligns, reserve injecting glue entrance and venting hole.The glue injection frame being placed in inclination gets final product injecting glue.The tank glue device made with pop can is inserted tank Jiao Kou, inserts tank glue device with screwdriver, slightly glass is strutted some gaps, facilitate the quick person who lives in exile of glue.
9) thick with every square of rice glue: the 1. ratio metering glue consumption of 0.38mm/0.45Kg, 2. 0.76mm/0.86Kg, 3. 1mm/1.14Kg, calculates the perfusion of glue consumption by physical size, extract tank glue device, checked whether bubble after injection.As found that there is bubble, using to knock or put in syringe derives bubble.
10) slowly universal stage is rotated to level attitude, glue is refluxed, be full of whole glass chamber completely, close gum-injecting port.
11), after laminated glass work in-process rationally put into still car, fixing situation is checked;
12) connect the rail joints of rotating disk and kettle, at the uniform velocity will enter still car and advance still internal fixtion;
13) autoclave operation work removes rail joints link, and translation interface platform closes still door;
14) turn on the power switch, setting Heating temperature 132 DEG C, preheating temperature 55 DEG C, exhaust temperature 55 DEG C, setting soaking time 30-60min, check whether vent valve is opened.
15) start swing to close the door, be rocked to travel switch place, start rotation and close the door, be threaded to travel switch place.
16) bat-handle switch on closed still door limit, starts autoclave.Open little intake valve, open little water pump, open air compressor machine, open intake valve.
17) air pressure reaches set(ting)value ± 12MPA, closes air compressor machine, closes master air suction valve.Temperature reaches 132 DEG C, and after carrying out heat-insulation pressure keeping, open cooling-water pump and make temperature in the kettle be down to 55 DEG C, autoclave out of service, vent valve opens exhaust automatically, turns off cooling-water pump.
18) when still internal gas pressure is drained, display with no pressure in operation cabinet still, opens bat-handle switch, swings and open the door, turn to open.
19) finished product shelves warehouse-in through inspection.

Claims (2)

1. an antiultraviolet composite fireproof glass, is characterized in that: the fireproofing being filled with special proportioning in two panels glass substrate, and fireproofing comprises following composition by weight percentage:
First methyl esters 50%; Dibutylester 15%; S-WAT 20%;
Zinc oxide (ZnO) 1.3%; Magnesium hydroxide 3%; Phthalic acid fourth benzyl fat 0.2%;
Acrylamide 10%; Ethanol 0.1%; ESCALOL 567 0.4%.
2. antiultraviolet composite fireproof glass according to claim 1 is characterized in that: based on fire prevention effect outer to have ultraviolet penetrate obstructing capacity, and not exposure time limitation.
CN201110321264.3A 2011-10-18 2011-10-18 Antiultraviolet composite fireproof glass Expired - Fee Related CN103058532B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110321264.3A CN103058532B (en) 2011-10-18 2011-10-18 Antiultraviolet composite fireproof glass

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Application Number Priority Date Filing Date Title
CN201110321264.3A CN103058532B (en) 2011-10-18 2011-10-18 Antiultraviolet composite fireproof glass

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CN103058532A CN103058532A (en) 2013-04-24
CN103058532B true CN103058532B (en) 2015-09-09

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232159A (en) * 2013-05-10 2013-08-07 苏州工业园区方圆金属制品有限公司 Multifunctional plate glass
CN106183243A (en) * 2016-07-27 2016-12-07 泉州市科茂利通智能科技有限公司 A kind of windshield
CN107640914A (en) * 2017-10-10 2018-01-30 浙江树人学院 The fire prevention perfusion and encapsulating method of a kind of filling type flame resistant glass
CN107915416A (en) * 2017-11-27 2018-04-17 信利光电股份有限公司 A kind of liquid filling method and its system
CN108490998A (en) * 2018-02-02 2018-09-04 信义玻璃工程(东莞)有限公司 A kind of control method of autoclave, system and terminal device
CN108483905A (en) * 2018-05-14 2018-09-04 江苏铁锚玻璃股份有限公司 A kind of vehicle glass and its manufacturing method
CN108585526A (en) * 2018-05-15 2018-09-28 江苏铁锚玻璃股份有限公司 A kind of aircraft glass and its manufacturing method
CN111635148B (en) * 2020-07-08 2024-07-23 广东平治防火材料有限公司 Fireproof laminated glass and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN88100180A (en) * 1988-01-20 1988-08-03 北京市有机玻璃制品厂 X-ray-preventing ultraviolet ray synthetic glass and method for making
CN1394741A (en) * 2002-07-10 2003-02-05 黄志清 Photochromic sandwich glass
CN1898175A (en) * 2003-12-26 2007-01-17 积水化学工业株式会社 Interlayer film for laminated glass, and laminated glass
CN201419535Y (en) * 2009-05-25 2010-03-10 席德水 Fireproof compound glass
JP2011168477A (en) * 2010-01-22 2011-09-01 Nippon Electric Glass Co Ltd Fireproof protective plate glass with antireflection film, fireproof protective laminated glass with the antireflection film, and specific fire prevention apparatus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN88100180A (en) * 1988-01-20 1988-08-03 北京市有机玻璃制品厂 X-ray-preventing ultraviolet ray synthetic glass and method for making
CN1394741A (en) * 2002-07-10 2003-02-05 黄志清 Photochromic sandwich glass
CN1898175A (en) * 2003-12-26 2007-01-17 积水化学工业株式会社 Interlayer film for laminated glass, and laminated glass
CN201419535Y (en) * 2009-05-25 2010-03-10 席德水 Fireproof compound glass
JP2011168477A (en) * 2010-01-22 2011-09-01 Nippon Electric Glass Co Ltd Fireproof protective plate glass with antireflection film, fireproof protective laminated glass with the antireflection film, and specific fire prevention apparatus

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
温变英.添加剂概论.《高分子材料与加工》.中国轻工业出版社,2011, *
王国建等.复合型防火玻璃防火层的类型和特点.《建筑防火材料》.中国石化出版社,2006, *

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Address before: Go Green Road Industrial Park, No. 199 Zhejiang fulongding Glass Technology Co., Ltd. Hangzhou City, Zhejiang province 310018 Hangzhou economic and Technological Development Zone

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