CN103044965A - Dispersed blue dye composition, dispersed blue dye, and preparation method and application thereof - Google Patents
Dispersed blue dye composition, dispersed blue dye, and preparation method and application thereof Download PDFInfo
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- CN103044965A CN103044965A CN2012105745007A CN201210574500A CN103044965A CN 103044965 A CN103044965 A CN 103044965A CN 2012105745007 A CN2012105745007 A CN 2012105745007A CN 201210574500 A CN201210574500 A CN 201210574500A CN 103044965 A CN103044965 A CN 103044965A
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Abstract
The invention relates to a dispersed blue dye composition, dispersed blue dye, and a preparation method and application thereof. Based on the total weight of the dispersed blue dye composition, the dispersed blue dye composition comprises 5 to 14 weight percent of component A shown as a formula (I), 50 to 80 weight percent of component B shown as a formula (II), 10 to 20 weight percent of component C shown as a formula (III), 5 to 14.5 weight percent of component D shown as a formula (IV) and 0 to 1.5 weight percent of component E shown as a formula (V). The dispersed blue dye consists of the dispersed blue dye composition and auxiliary materials, has high washing fastness and sublimation fastness and has low contamination property on polyester ammonia cotton and blended fabric thereof. R is Cl or Br, R2 is Cl or Br, and R3 is alkyl of C1-C2.
Description
Technical field
The present invention relates to a kind of disperse dye composition, dispersed blue dye and preparation method thereof, the invention still further relates to disperse dye composition and dispersed blue dye and be used for the dyeing of fabric and/or the purposes of stamp, with described disperse dye composition with dispersed blue dye dyes and/or stamp and the yarn fabric that obtains and the yarn fabric goods that use this yarn fabric to make.Described dispersed blue dye is applicable to dyeing and the stamp of polyster fibre, is particularly useful for washing dyeing and the stamp of the BLENDED FABRIC such as ammonia, polyester-cotton blend.
Background technology
Along with the fast development of washing the BLENDED FABRIC such as ammonia polyester-cotton blend, people are more and more higher to every application performance requirement of dyestuff, and every fastness excellence is the desired fundamental property of client.Then, the General Decentralized dyestuff is heavier to the staining of spandex, cotton, can't satisfy client's demand.Demand for EX-SF DISPERSE BLUE EX-SF 300 is very large in the market, traditional EX-SF DISPERSE BLUE EX-SF 300 WXF, EX-SF DISPERSE BLUE EX-SF 300 EX-SF are widely used, particularly because its washing fastness, sublimation fastness is good is promoted by the general trend of events, but EX-SF DISPERSE BLUE EX-SF 300 WXF, EX-SF DISPERSE BLUE EX-SF 300 EX-SF are only applicable to polyster fibre, washing on ammonia, the polyester fiber, the advantage of washing fastness is also not obvious.So for satisfying client's needs, work out the dyestuff of washing ammonia, polyester fiber dyeing washing fastness excellence very urgent.
Summary of the invention
The invention provides a kind of disperse dye composition of extra-high-speed washing fastness.This dye composite comprises component A, B component, component C, component D, component E, wherein,
Component A is following formula (I) compound,
B component is one or both of following formula (II) compound,
R wherein
1Be Cl or Br,
B is particularly
Component C is following formula (III) compound,
Component D is one or both of following formula (IV) compound,
R wherein
2Be Cl or Br.
D is particularly
Component E is one or both of lower formula V compound,
R wherein
3Be C
1~ C
2Alkyl,
E is particularly
And/or
In the disperse dye composition of the present invention, gross weight based on described disperse dye composition, the content of component A is 5 ~ 14 % by weight, the content of B component is 50 ~ 80 % by weight, the content of component C is 10 ~ 20 % by weight, the content of component D is 5 ~ 14.5 % by weight, and the content of component E is 0 ~ 1.5 % by weight; Preferably, the content of component A is 8.5 ~ 13.8 % by weight, and the content of B component is 55 ~ 68 % by weight, and the content of component C is 15 ~ 18 % by weight, and the content of component D is 8 ~ 12 % by weight, and the content of component E is 0.5 ~ 1.2 % by weight.
The present invention also provides a kind of dispersed blue dye, and it is comprised of disperse dye composition of the present invention and auxiliary material.
Disperse dye composition of the present invention generally needs during application to add auxiliary material, makes dispersed blue dye.Described auxiliary material comprises auxiliary agent and water etc.Auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite.Preferably include one of following or its any mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.Particularly, such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.Usually, auxiliary agent is 1.5 ~ 2.5:1 with the ratio of the weight of disperse dye composition.
Dispersed blue dye of the present invention can prepare with following methods: behind each wherein contained dye composition proportioning preparation dye composite in accordance with regulations, in the presence of auxiliary material, grind (corpusculed), and carry out as required drying, preferably carry out spraying drying; Perhaps each dye composition is ground respectively (corpusculed) in the presence of auxiliary material, then according to the rules ratio is mixed, and carries out drying as required, preferably carries out spraying drying.Above-mentioned dye composition all can adopt the commercially available prod.
Dispersed blue dye of the present invention can be aqueous, paste behind the corpusculed, can be powdery, particulate state after the spraying drying.
Dispersed blue dye of the present invention has than high washing fastness, is particularly useful for washing the BLENDED FABRIC such as ammonia, polyester-cotton blend, and is minimum to spandex, cotton contamination simultaneously.
Disperse dye composition of the present invention or dispersed blue dye are used for the dyeing of yarn fabric and/or the purposes of stamp.Described yarn fabric is BLENDED FABRIC, and described BLENDED FABRIC includes but not limited to polyster fibre, washs ammonia, polyester-cotton blend, is preferably and washs ammonia, polyester-cotton blend.
A kind of yarn fabric, it adopts according to disperse dye composition of the present invention or dispersed blue dye dyes and/or stamp obtains.
A kind of yarn fabric goods, it is made with yarn fabric of the present invention.Described textile fabrics includes but not limited to ready-made clothes and cap.
Embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
In an embodiment, after component A of the present invention, B component, component C, component D, component E add the water blending by certain proportioning and condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF) or sodium lignosulfonate (xylogen 85A, 83A), carry out grinding distribution with sand milling and make slurry, or further carry out spraying drying, make dye composite.
Below various compound be known dye composition, and can buy in market.Dispersant MF, dispersing agent NNO, dispersing agent CNF, xylogen 85A and xylogen 83A also are known auxiliary agent, and can buy in market.
Embodiment 1-8
According to the ratio shown in the table 1 component A-E, auxiliary agent are mixed with suitable quantity of water, grind, spraying drying makes composite disperse dye.
Table 1
Comparative Examples 1
Get 10g formula (1) compound, 25g formula (2-1), 25g(2-2) mixture of compound, 40g formula (3) compound mixes with the 200g Dispersant MF.
Comparative Examples 2
Get 6g formula (4) compound, 19g formula (5) compound, 75g formula (6) compound mixes with the 200g Dispersant MF.
With prepared dispersed dye among the embodiment 1-8, EX-SF DISPERSE BLUE EX-SF 300 EX-SF(Comparative Examples 1), EX-SF DISPERSE BLUE EX-SF 300 WXF(Comparative Examples 2) use 0.1 gram, wash ammonia textile fibres and 99.9 water with 10 grams, regulate dye bath pH to 4 ~ 5 with acetic acid, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, be cooled to 80 ℃ of taking-ups, carry out aftertreatment according to the GB/T2394-2006 standard, obtain blue textile materials, under 190 ℃ of temperature, carry out again 45 seconds heat treatments.According to accurate its washing fastness to vinegar ester, cotton, cotton synthetic fibre, terylene, acrylic fibers, wool of surveying of AATCC612A method 95 scales.
Table 2
| ? | The vinegar ester | Cotton | Cotton synthetic fibre | Terylene | Acrylic fibers | Wool |
| Embodiment 1 | 3 | 4 | 2-3 | 4 | 4-5 | 3-4 |
| Embodiment 2 | 3 | 4 | 2-3 | 4 | 4-5 | 3-4 |
| Embodiment 3 | 3 | 4-5 | 2-3 | 4-5 | 5 | 3-4 |
| Embodiment 4 | 3 | 4-5 | 2-3 | 4-5 | 5 | 3-4 |
| Embodiment 5 | 3 | 4-5 | 2-3 | 4-5 | 5 | 3-4 |
| Embodiment 6 | 3 | 4 | 2-3 | 4 | 4-5 | 3-4 |
| Embodiment 7 | 3 | 4-5 | 2-3 | 4-5 | 5 | 3-4 |
| Embodiment 8 | 3 | 4-5 | 2-3 | 4-5 | 5 | 3-4 |
| Comparative Examples 1 | 3 | 4-5 | 2-3 | 4 | 4-5 | 3 |
| Comparative Examples 2 | 2 | 4 | 2-3 | 4 | 4 | 3 |
With embodiment 1-8, prepared dispersed dye use 0.1 gram in the Comparative Examples 1, wash ammonia textile fibres and 99.9 water with 10 grams, regulate dye bath pH to 4 ~ 5 with acetic acid, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, be cooled to 80 ℃ of taking-ups, carry out aftertreatment according to the GB/T2394-2006 standard, obtain blue textile materials, under 190 ℃ of temperature, carry out again 45 seconds heat treatments.Adopt GB/T5718-1997 to measure its sublimation fastness (210 ℃, 30 seconds).
Table 3
| ? | Cotton is stained with | Wash and be stained with |
| Embodiment 1 | 4 | 3 |
| Embodiment 2 | 4 | 3 |
| Embodiment 3 | 4-5 | 3 |
| Embodiment 4 | 4-5 | 3 |
| Embodiment 5 | 4-5 | 3 |
| Embodiment 6 | 4 | 3 |
| Embodiment 7 | 4-5 | 3 |
| Embodiment 8 | 4-5 | 3 |
| Comparative Examples 1 | 3-4 | 2 |
Claims (10)
1. disperse dye composition, gross weight based on described disperse dye composition, comprise 5 ~ 14 % by weight formula (I) component A, 50 ~ 80 % by weight formula (II) B component, 10 ~ 20 % by weight formula (III) component C, 5 ~ 14.5 % by weight formula (IV) component D and 0 ~ 1.5 % by weight formula V component E
Component A is following formula (I) compound,
B component is one or both of following formula (II) compound,
R wherein
1Be Cl or Br,
Component C is following formula (III) compound,
Component D is one or both of following formula (IV) compound,
R wherein
2Be Cl or Br,
Component E is one or both of lower formula V compound,
R wherein
3Be C
1~ C
2Alkyl.
2. disperse dye composition according to claim 1, gross weight based on described disperse dye composition, comprise 8.5 ~ 13.8 % by weight formula (I) component A, 55 ~ 68 % by weight formula (II) B component, 15 ~ 18 % by weight formula (III) component C, 8 ~ 12 % by weight formula (IV) component D and 0.5 ~ 1.2 % by weight formula V component E.
3. dispersed blue dye, it is comprised of claim 1 or 2 described disperse dye compositions and auxiliary material.
4. dispersed blue dye according to claim 3, described auxiliary material comprises auxiliary agent and water.
5. dispersed blue dye according to claim 4, wherein auxiliary agent is 1.5 ~ 2.5:1 with the ratio of the weight of disperse dye composition.
6. the preparation method of each described dispersed blue dye of claim 3～5, comprise each wherein contained dye composition is mixed with disperse dye composition after, in the presence of auxiliary material, grind the optional drying of carrying out; Perhaps each dye composition is ground in the presence of auxiliary material respectively, then mix, the optional drying of carrying out.
7. each described dispersed blue dye of disperse dye composition according to claim 1 and 2 or claim 3～5 is used for the dyeing of fabric and/or the purposes of stamp.
8. purposes according to claim 7, wherein said fabric is BLENDED FABRIC, and described BLENDED FABRIC is preferably terylene, washs ammonia or polyester-cotton blend, and described fabric is more preferably washed ammonia or polyester-cotton blend.
9. yarn fabric, its adopt disperse dye composition according to claim 1 and 2 or according to claim 3 ~ 5 each described dispersed blue dye dye and/or stamp and obtaining.
10. yarn fabric goods, it is made with yarn fabric according to claim 9.
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| CN103044965B CN103044965B (en) | 2014-09-17 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073921A (en) * | 2012-12-30 | 2013-05-01 | 浙江龙盛集团股份有限公司 | Dispersed dark dye composition |
| CN104559322A (en) * | 2014-12-18 | 2015-04-29 | 浙江龙盛集团股份有限公司 | High-fastness disperse dark blue dye composition and dye product |
| CN107011695A (en) * | 2017-04-25 | 2017-08-04 | 江苏迪安化工有限公司 | A kind of Yellow disperse dye monomeric compound and its preparation method and application |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0300626B1 (en) * | 1987-07-22 | 1994-01-19 | Zeneca Limited | Disperse dye mixture |
| US5595575A (en) * | 1994-12-02 | 1997-01-21 | Dystar Japan Ltd. | Blue disperse dye mixture |
| CN101338081A (en) * | 2008-07-11 | 2009-01-07 | 浙江龙盛集团股份有限公司 | Dispersed deep blue dye composition |
| CN101955691A (en) * | 2010-08-26 | 2011-01-26 | 浙江龙盛集团股份有限公司 | Dispersed deep blue dye composition |
| CN101982510A (en) * | 2010-09-18 | 2011-03-02 | 浙江万丰化工有限公司 | Composite of dispersed dyes |
| CN102352125A (en) * | 2011-08-03 | 2012-02-15 | 浙江闰土股份有限公司 | Disperse black and blue dye composition |
| CN102746711A (en) * | 2012-07-10 | 2012-10-24 | 浙江昱泰染化科技有限公司 | Disperse dye composition, dye product and application thereof |
-
2012
- 2012-12-25 CN CN201210574500.7A patent/CN103044965B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0300626B1 (en) * | 1987-07-22 | 1994-01-19 | Zeneca Limited | Disperse dye mixture |
| US5595575A (en) * | 1994-12-02 | 1997-01-21 | Dystar Japan Ltd. | Blue disperse dye mixture |
| CN101338081A (en) * | 2008-07-11 | 2009-01-07 | 浙江龙盛集团股份有限公司 | Dispersed deep blue dye composition |
| CN101955691A (en) * | 2010-08-26 | 2011-01-26 | 浙江龙盛集团股份有限公司 | Dispersed deep blue dye composition |
| CN101982510A (en) * | 2010-09-18 | 2011-03-02 | 浙江万丰化工有限公司 | Composite of dispersed dyes |
| CN102352125A (en) * | 2011-08-03 | 2012-02-15 | 浙江闰土股份有限公司 | Disperse black and blue dye composition |
| CN102746711A (en) * | 2012-07-10 | 2012-10-24 | 浙江昱泰染化科技有限公司 | Disperse dye composition, dye product and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 何瑾馨: "《染料化学》", 31 January 2009, 中国纺织出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073921A (en) * | 2012-12-30 | 2013-05-01 | 浙江龙盛集团股份有限公司 | Dispersed dark dye composition |
| CN103073921B (en) * | 2012-12-30 | 2014-11-26 | 浙江龙盛集团股份有限公司 | Dispersed dark dye composition |
| CN104559322A (en) * | 2014-12-18 | 2015-04-29 | 浙江龙盛集团股份有限公司 | High-fastness disperse dark blue dye composition and dye product |
| CN107011695A (en) * | 2017-04-25 | 2017-08-04 | 江苏迪安化工有限公司 | A kind of Yellow disperse dye monomeric compound and its preparation method and application |
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| CN103044965B (en) | 2014-09-17 |
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