CN103044897A - Halogen-free flame-retardant anti-drip thermoplastic polyurethane (TPU) material - Google Patents
Halogen-free flame-retardant anti-drip thermoplastic polyurethane (TPU) material Download PDFInfo
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- CN103044897A CN103044897A CN2012105548333A CN201210554833A CN103044897A CN 103044897 A CN103044897 A CN 103044897A CN 2012105548333 A CN2012105548333 A CN 2012105548333A CN 201210554833 A CN201210554833 A CN 201210554833A CN 103044897 A CN103044897 A CN 103044897A
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- tpu
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- halogen
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- free flameproof
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- 239000000463 material Substances 0.000 title claims abstract description 35
- 239000003063 flame retardant Substances 0.000 title claims abstract description 17
- 229920002803 thermoplastic polyurethane Polymers 0.000 title abstract description 33
- 239000004433 Thermoplastic polyurethane Substances 0.000 title abstract description 32
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 abstract description 3
- 239000003292 glue Substances 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 238000007790 scraping Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010051246 Photodermatosis Diseases 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000907903 Shorea Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005049 combustion synthesis Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a halogen-free flame-retardant anti-drip thermoplastic polyurethane (TPU) material. The halogen-free flame-retardant anti-drip TPU material is prepared from the following components in part by weight: 20 to 60 parts of TPU, 11 to 23 parts of SEBS, 18 to 25 parts of flame retardant, 5 to 25 parts of white oil, 1.3 to 2 parts of anti-drip agent and others. The halogen-free flame-retardant anti-drip TPU material solves the problems that the material without the anti-drip function is easy to separate out, the surface is susceptible to scraping white, scaling and glue removal, the processing difficulty is high and the surface is seedy and not smooth, swinging and adhesion occurs, and has low price.
Description
Technical field
The present invention relates to a kind of cable material production technical field, specifically relate to the anti-drip TPU material of halogen-free flameproof that a kind of electric wire and cable jacket is used.
Background technology
Since 08 year, just felt the halogen-free flameproof agitation that countries in the world are blown afloat the responsive a little people of electric wire field work, nowadays drill fiercer and fiercer.TPU provides tear-resistant, wear-resisting and crooked feature.High-and low-temperature resistance is the key of cable performance especially.In addition, chemicals-resistant, hydrolysis and Resistance to microbes, and easily process easy dyeing, so high-grade cable is used for protecting coating material and the purposes of the complicated cable of design also increasingly extensive such as control cables and power cable with TPU.Several years before 08 year all is that Halogen material rather than Halogen add fire retardant material.
It is as follows that TPU is different from the excellent properties of other thermoplastic elastomers: wear resistance is strong, tear strength is strong, bending property is outstanding, tensile strength and elongation at break high, low temperature resistant-35～50 ℃ and resistance to elevated temperatures are low with 150 ℃, long-term compression deformation rate, oil resistant, lubricating oil and the hydrocarbon solvent of aliphatics, oxygen and ozone are had the resistivity anti-aging property.But present TPU material does not possess anti-drip function, and price high, easily separate out, the surface easily scrape white, scaling fall glue, large, the surperficial seediness of difficulty of processing numb not smooth, wave or bonding.
TPU has the plurality of advantages such as low-temperature performance of good elasticity, physical strength, oil resistant, ozone resistance, excellence, but its shortcoming is quite a few, mainly comprises: ageing resistance is poor, poor fire, wet skin friction coefficient are low, easily skid, poor processability, cost are higher.Self does not have flame retardant properties TPU, and during combustion synthesis in air, flame is very violent and with strong black smoke, and has serious drip phenomenon.
Summary of the invention
The present invention has overcome the deficiencies in the prior art, and a kind of bittern-free flame-proof material is provided, so that the TPU material has anti-drip function, and anti-drip function is difficult for separating out.
Consider the problems referred to above of prior art, according to an aspect disclosed by the invention, the present invention by the following technical solutions:
A kind of halogen-free flameproof is prevented drip TPU material, comprising:
TPU-20 is to 60 parts;
SEBS-11 is to 23 parts;
Fire retardant-18 is to 25 parts;
White oil-5 is to 25 parts;
Anti-dripping agent-1.3 is to 2 parts;
Weighting agent.
In order to realize better the present invention, further technical scheme is:
In one embodiment of the invention, the shore hardness of described TPU is 80～90A.
In one embodiment of the invention, described weighting agent is talcum powder, rises to fill in prescription and does usefulness.
In one embodiment of the invention, described fire retardant is fire retardant 400A, and is not halogen-containing.
The present invention can also be:
In one embodiment of the invention, the content of described weighting agent is 2.5 to 7.5 parts.
Compared with prior art, one of beneficial effect of the present invention is:
Halogen-free flameproof TPU material in the technical scheme of the present invention has the performance of anti-drip function and halogen-free flameproof.Particularly, by add anti-dripping agent and an amount of proportioning thereof in material prescription, carbon-forming performance is excellent in combustion processes, can prevent that material from dripping because of fusing when high-temp combustion.Simultaneously, all material is all not halogen-containing, therefore has the performance of anti-drip function and halogen-free flameproof.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail, but embodiments of the present invention are not limited to this.
Embodiment 1
A kind of halogen-free flameproof is prevented drip TPU material, mixes by following weight proportion:
TPU-20 is to 60 parts;
SEBS-11 is to 23 parts;
Fire retardant-18 is to 25 parts;
White oil-5 is to 25 parts;
Anti-dripping agent-1.3 is to 2 parts;
Weighting agent.
Embodiment 2
A kind of halogen-free flameproof is prevented drip TPU material, and is as follows by weight ratio:
TPU—60﹪
SEBS—11﹪
Fire retardant-20 ﹪
White oil-5 ﹪
Anti-dripping agent-1.5 ﹪
Weighting agent-2.5 ﹪
Above each composition is blended on the twin screw extruder of φ 70, and mixing granulation obtains the anti-drip TPU material of high-temp resisting high-humidity resisting halogen-free flameproof under 140 ~ 200 ℃ of temperature ranges.
The fundamental characteristics TPU of the anti-drip TPU material of halogen-free flameproof is the material that contains the NH-COD-group in the molecule, the dibasic alcohol of long-chain and isocyanate prepolymer composition have consisted of soft section, the dibasic alcohol of short key and isocyanate prepolymer composition have consisted of hard section, the a lot of characteristics of TPU depend on the kind of long chain diol, its hardness is done ratio with hard section and is regulated, its photoaging can add photostabilizer and be improved, and depends on that also isocyanic ester is aromatic series or aliphatics simultaneously.
Above-mentioned TPU is the abbreviation of Thermoplastic Urethane, and Chinese is Polyurethane Thermoplastic Elastomer.SEBS is take polystyrene as end segment, the ethylene-butene copolymer that obtains take the polyhutadiene hydrogenation as in the middle of the linearity three embedding multipolymers of elastomeric block.SEBS does not contain unsaturated double-bond, therefore has satisfactory stability and ageing resistance.
Embodiment 3
A kind of halogen-free flameproof is prevented drip TPU material, mixes by following weight proportion:
TPU—50﹪
SEBS—15﹪
Fire retardant-18 ﹪
White oil-12.7 ﹪
Anti-dripping agent-1.3 ﹪
Weighting agent-3 ﹪
Embodiment 4
A kind of halogen-free flameproof is prevented drip TPU material, mixes by following weight proportion:
TPU—35﹪
SEBS—20﹪
Fire retardant-22 ﹪
White oil-18 ﹪
Anti-dripping agent-1.7 ﹪
Weighting agent-3.3 ﹪
Embodiment 5
A kind of halogen-free flameproof is prevented drip TPU material, mixes by following weight proportion:
TPU—30﹪
SEBS—20﹪
Fire retardant 400A-20 ﹪
White oil-21 ﹪
Anti-dripping agent-1.5 ﹪
Weighting agent-7.5 ﹪
Embodiment 6
A kind of halogen-free flameproof is prevented drip TPU material, mixes by following weight proportion:
TPU-25﹪
SEBS-22﹪
Fire retardant 400A-25 ﹪
White oil-20 ﹪
Anti-dripping agent-2 ﹪
Weighting agent-6 ﹪
Embodiment 7
A kind of halogen-free flameproof is prevented drip TPU material, mixes by following weight proportion:
TPU—20﹪
SEBS—23﹪
Fire retardant 400A-25 ﹪
White oil-25 ﹪
Anti-dripping agent-2 ﹪
Weighting agent-5 ﹪
The flame retardant performance judgement criteria that adopts is UL1581VW-1, and line-transect is No. 18 single-core lines, and wherein brass wire diameter is at 1.00 ~ 1.3mm, and thickness of insulating layer is: 0.8mm.
Hot and humid experiment: black print and line-transect at 85 ℃, were placed 96 hours in the circular chamber of relative humidity 95%.Require to observe without saltouing, physical strength and elongation at break velocity of variation are less than 25%, and line-transect passes through UL1581VW-1.
The immersion weathering test: 70 ℃, 168h requires the surface without bubble, and physical strength and fracture draw the elongation velocity of variation less than 25.
Embodiment 2-6: other become component and working method with embodiment 1.
Subordinate list: material and electrical property contrast.
| Sequence number | Hardness, shoreA | Tensile strength MPa | Elongation at break % | VW-1 |
| Embodiment 1 | 85 | 40 | 650 | By |
| Embodiment 2 | 84 | 38 | 630 | By |
| Embodiment 3 | 82 | 36 | 620 | By |
| Embodiment 4 | 83 | 35 | 600 | By |
| Embodiment 5 | 85 | 34 | 590 | By |
| Embodiment 6 | 84 | 32 | 590 | By |
Above embodiment can be that the shore hardness of described TPU is 80～90A.Described weighting agent is talcum powder, rises to fill in prescription and does usefulness, and described fire retardant is fire retardant 400A, and is not halogen-containing.
Each embodiment adopts the mode of going forward one by one to describe in this specification sheets, and what each embodiment stressed is and the difference of other embodiment that identical similar part cross-references gets final product between each embodiment.
" embodiment " who speaks of in this manual, " another embodiment ", " embodiment ", etc., refer to specific features, structure or the characteristics described in conjunction with this embodiment and be included among at least one embodiment that the application's generality describes.A plurality of local appearance statement of the same race is not necessarily to refer to same embodiment in specification sheets.Furthermore, when describing a specific features, structure or characteristics in conjunction with arbitrary embodiment, what advocate is to realize that in conjunction with other embodiment this feature, structure or characteristics also fall within the scope of the invention.
Although invention has been described with reference to a plurality of explanatory embodiment of the present invention here, but, should be appreciated that, those skilled in the art can design a lot of other modification and embodiments, and these are revised and embodiment will drop within the disclosed principle scope and spirit of the application.More particularly, in the scope of and claim open in the application, can carry out multiple modification and improvement to building block and/or the layout of subject combination layout.Except modification that building block and/or layout are carried out with improving, to those skilled in the art, other purposes also will be obvious.
Claims (5)
1. the anti-drip TPU material of halogen-free flameproof is characterized in that, and is as follows by weight ratio:
TPU-20 is to 60 parts;
SEBS-11 is to 23 parts;
Fire retardant-18 is to 25 parts;
White oil-5 is to 25 parts;
Anti-dripping agent-1.3 is to 2 parts;
Weighting agent.
2. the anti-drip TPU material of halogen-free flameproof according to claim 1 is characterized in that, the shore hardness of described TPU is 90A.
3. the anti-drip TPU material of halogen-free flameproof according to claim 1 is characterized in that, described weighting agent is talcum powder.
4. the anti-drip TPU material of halogen-free flameproof according to claim 1 is characterized in that, described fire retardant is fire retardant 400A.
5. the anti-drip TPU material of halogen-free flameproof according to claim 3 is characterized in that, the content of described its weighting agent is 2.5 to 7.5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105548333A CN103044897A (en) | 2012-12-20 | 2012-12-20 | Halogen-free flame-retardant anti-drip thermoplastic polyurethane (TPU) material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105548333A CN103044897A (en) | 2012-12-20 | 2012-12-20 | Halogen-free flame-retardant anti-drip thermoplastic polyurethane (TPU) material |
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| Publication Number | Publication Date |
|---|---|
| CN103044897A true CN103044897A (en) | 2013-04-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105548333A Pending CN103044897A (en) | 2012-12-20 | 2012-12-20 | Halogen-free flame-retardant anti-drip thermoplastic polyurethane (TPU) material |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212155A (en) * | 2014-09-15 | 2014-12-17 | 江苏华宏实业集团有限公司 | Preparation method of halogen-free flame-retardant thermoplastic polyurethane |
| CN104212156A (en) * | 2014-09-15 | 2014-12-17 | 江苏华宏实业集团有限公司 | Halogen-free flame-retardant thermoplastic polyurethane |
| CN104231590A (en) * | 2014-06-12 | 2014-12-24 | 东莞市德诚塑化科技有限公司 | Conductive thermoplastic polyurethane composite material and preparation method thereof |
| CN107177195A (en) * | 2017-07-26 | 2017-09-19 | 深圳市普特美橡塑原料有限公司 | A kind of fire-retardant TPU materials for charging pile cable |
| CN113930042A (en) * | 2020-06-29 | 2022-01-14 | 中国石油化工股份有限公司 | SEBS/TPU alloy material and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110011616A1 (en) * | 2008-02-08 | 2011-01-20 | Union Carbide Chemicals & Plastics Technology Llc | Flame-retardant polyolefin/thermoplastic polyurethane composition |
| TW201144417A (en) * | 2010-05-24 | 2011-12-16 | Dow Global Technologies Llc | Halogen-free, flame retardant composition comprising crosslinked silane-g-EVA |
| CN102816427A (en) * | 2012-09-06 | 2012-12-12 | 北京化工大学 | High-flame-retardance high-heat-resistance halogen-free flame-retardant thermoplastic polyurethane elastomer cable material and preparation method thereof |
-
2012
- 2012-12-20 CN CN2012105548333A patent/CN103044897A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110011616A1 (en) * | 2008-02-08 | 2011-01-20 | Union Carbide Chemicals & Plastics Technology Llc | Flame-retardant polyolefin/thermoplastic polyurethane composition |
| TW201144417A (en) * | 2010-05-24 | 2011-12-16 | Dow Global Technologies Llc | Halogen-free, flame retardant composition comprising crosslinked silane-g-EVA |
| CN102816427A (en) * | 2012-09-06 | 2012-12-12 | 北京化工大学 | High-flame-retardance high-heat-resistance halogen-free flame-retardant thermoplastic polyurethane elastomer cable material and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231590A (en) * | 2014-06-12 | 2014-12-24 | 东莞市德诚塑化科技有限公司 | Conductive thermoplastic polyurethane composite material and preparation method thereof |
| CN104212155A (en) * | 2014-09-15 | 2014-12-17 | 江苏华宏实业集团有限公司 | Preparation method of halogen-free flame-retardant thermoplastic polyurethane |
| CN104212156A (en) * | 2014-09-15 | 2014-12-17 | 江苏华宏实业集团有限公司 | Halogen-free flame-retardant thermoplastic polyurethane |
| CN107177195A (en) * | 2017-07-26 | 2017-09-19 | 深圳市普特美橡塑原料有限公司 | A kind of fire-retardant TPU materials for charging pile cable |
| CN113930042A (en) * | 2020-06-29 | 2022-01-14 | 中国石油化工股份有限公司 | SEBS/TPU alloy material and application thereof |
| CN113930042B (en) * | 2020-06-29 | 2024-04-12 | 中国石油化工股份有限公司 | SEBS/TPU alloy material and application thereof |
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Application publication date: 20130417 |