CN103043299A - Packaging container - Google Patents

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CN103043299A
CN103043299A CN2012105931392A CN201210593139A CN103043299A CN 103043299 A CN103043299 A CN 103043299A CN 2012105931392 A CN2012105931392 A CN 2012105931392A CN 201210593139 A CN201210593139 A CN 201210593139A CN 103043299 A CN103043299 A CN 103043299A
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density polyethylene
low density
10min
ldpe
thermoplastic material
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CN103043299B (en
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吴壮
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Taizhou Zhuye Machinery Technology Co., Ltd.
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吴壮
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Priority to CN201510156959.9A priority Critical patent/CN104760337A/en
Priority to CN201210593139.2A priority patent/CN103043299B/en
Priority to CN201510156961.6A priority patent/CN104760360A/en
Priority to CN201510156968.8A priority patent/CN104760388A/en
Priority to CN201510156957.XA priority patent/CN104760359A/en
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Abstract

The invention provides a packaging container which comprises an outmost thermoplastic material layer, a core layer, an intermediate thermoplastic material layer, a blocking layer and an innermost thermoplastic material layer from outside to inside. The innermost thermoplastic material layer contains metalloscene catalyst polymerized linear low density polyethylene (MLLDPE) and low density polyethylene (LDPE), the MLLDPE has following parameters: average density of 0.88g/cm3-0.925g/cm3, melt flow index (190 DEG C, 2.16kg) of 5g/10min-20g/10min, peak melting point of 85 DEG C-130 DEG C, and expansion ratio of 1.2-1.8, and the LDPE has following parameters: average density of 0.90g/cm3-0.925g/cm3, melt flow index (190 DEG C, 2.16kg) of 5g/10min-20g/10min, peak melting point of 85 DEG C-110 DEG C, and expansion ratio of 1.2-1.8. A longitudinal sealing portion can realize quick thermal sealing during the process of manufacturing the packaging container, sealing intensity is high, and the manufactured packaging container is high in pass percentage and long in shelf life of liquid food.

Description

A kind of packing container
Technical field
The present invention relates to a kind of packing container, relate in particular to a kind of packing container for packaging liquid food.
Background technology
At present, the disposable disposal type packing container that is used for liquid food, brick is arranged, square, triangle, cross-sectional plane is hexagonal octahedral bodily form, the shapes such as pillow-like, usually the laminate wrapping material of making these packing containers comprises the successively thermoplastic material outermost layer of lamination, sandwich layer, the thermoplastic material interlayer, barrier layere, adhesive phase and thermoplastic material innermost layer also have the Low Density Polyethylene (LDPE) that adopts high-pressure process to produce/printer's ink layer/paper (fiber) base layer/LDPE/ aluminium foil AL/LDPE/LDPE, LDPE/ printer's ink layer/paper base layer/LDPE/LDPE, printer's ink layer/LDPE/ paper base layer/LDPE/LDPE, laminate wrapping material such as LDPE/ printer's ink layer/paper base layer/multiple-structures such as LDPE/ aluminium/polyester (PET).The food liquid that these packing containers can be packed has fresh milk, yoghurt, fruit juice etc.
Core material commonly used has paper, craft paper or carboard etc., barrier material commonly used has aluminium foil, metal/inorganic oxide film, ethylene-vinyl alcohol copolymer (EVOH), nylon etc., thermoplastic material outermost layer commonly used, interlayer, the Low Density Polyethylene (LDPE) that the useful high-pressure process of the material of innermost layer is produced, linear low density polyethylene (LLDPE), by the thermoplastic materials such as ethyleneα-olefincopolymer (mLLDPE) of metalloscene catalyst catalytic polymerization, adhesives commonly used has polyurethane binder, Polyester Polyurethane Adhesive, the polyether-polyurethane adhesives, acrylic adhesive, polyester binder, polyamide binder, the polyvinyl acetate ester adhesive, epoxy adhesive, rubber adhesive etc.
The effect of each layer of packing is: the thermoplastic material outermost layer can stop that extraneous moisture, pollution or other magazines enter in the packing by actv.; Sandwich layer can the supporting package container; Thermoplastic material interlayer and barrier layere can prevent effectively that food liquid from entering into sandwich layer, and starvation, sunlight make not light leak, air tight of packing container simultaneously, particularly do not leak oxygen, guarantee that the food liquid taste does not run off; The thermoplastic material innermost layer directly contacts with food liquid, prevents that food liquid is to the infiltration of other each layers of packing when guaranteeing the food liquid quality; Adhesive phase adds the bond strength between high containment and the thermoplastic material innermost layer.
Fig. 1 shows a kind of common method of making laminate wrapping material, machine guiding core layer coiled material 1 moves ahead by the pressure roller of punching press platform 2, process hole and the required impression of FOLD AND PACK material of the required usefulness of packing container opening device, continue to guide the sandwich layer coiled material 11 of perforate forward, arrive laminating bench 5, extruder 3 squeezes out thermoplastic material interlayer coiled material and guides it to and reaches laminating bench 5 herein, barrier layere coiled material 4 is directed to laminating bench 5 simultaneously, 5 pairs of three-layer coil materials of laminating bench carry out lamination, in its roll gap center core layer, thermoplastic material interlayer and barrier layere are pressed together, and the thermoplastic material interlayer is between sandwich layer and barrier layere, become thus ply wood 111. guide layer pressing plates 111 and arrive next stage laminating bench 6, herein by coextruding and coat the opposite side with thermoplastic material innermost layer 7 paint ply woodes 111 barrier layeres, in the roll gap of laminating bench 6, ply wood 111 and thermoplastic material innermost layer 7 are pressed together, form thus the inboard laminated material 1111 that is coated with the thermoplastic material innermost layer, by extrusion coated thermoplastic material outermost layer in the i.e. outside coating of sandwich layer opposite side, so far obtain the used laminate wrapping material of packing container afterwards.Certainly, the outermost coating of thermoplastic material might not be placed on final step to be carried out, and also can according to circumstances apply in suitable before step.
The packing container of the laminate wrapping material Production and Packaging food liquid that available said method is made.In order to prevent that packaged food liquid from suffering secondary pollution, the production process of whole packing container all carries out under aseptic condition: first laminate wrapping material is shaped to cylindric, and at the vertical sealing-in formation of side pipe, then in the horizontal sealing-in of pipe one end, form top or the bottom of packing container, fill afterwards required food liquid, at last the residue of pipe is held horizontal sealing-in, make bottom or the top of packing container.By cutting transverse packed zone, can form single independently packing container, and with these independently packing container deliver in the final folding and shaped device and be converted into net shape, such as brick type or other shapes.Laminate wrapping material longitudinal sealing, transverse sealing time in forming the packing container process can have influence on production efficiency, the qualification rate of intensity effect packing container of longitudinal sealing, transverse sealing and guaranteeing the quality the time of food liquid.
Chinese invention patent application prospectus CN1337914A discloses a kind of paper container package material, at least the constituting layer that comprises thermoplastic material outermost layer, papery base layer, barrier layere and thermoplastic material innermost layer are arranged and with each constituting layer by the said sequence lamination, be characterised in that: the thermoplastic material innermost layer comprises the linear low density polyethylene with narrow molecular weight distribution at least, has following performance perameter: average density 0.900-0.915,88-103 ℃ of peak value fusing point, melt flow index 5-20, expansion ratio (SR) 1.4-1.6 and bed thickness 20-50 micron.These packing are so that be easy to pouring package packing container and rapid heat-seal, obtain the container of more firm stronger sealing, this material can be used for realizing being independent of in-built food temperature excellent sealing and thereby keep the ability that in-built product never degenerates and guarantees the quality, but, this packing are in the extruding layer compression technology of manufacturing process, serious necking phenomenon can occur in molten condition during from the die head film extrusion of extruder in the thermoplastic material innermost layer, be that the extrusion die dual-side can shrink to the centre, edge thickness is uneven even the phenomenon of breach occurs, the barrier layere both sides can not be capped or cladding thickness inhomogeneous, in order to prevent that flaw from appearring in the finished product packing material, three kinds of terms of settlement are arranged usually, a kind of is to do the die head of extruder wider than the width of papery base layer and barrier layere, extrusion die both sides nonconformity part is not covered on the barrier layere, and cooling forming excises again in follow-up lamination operation; Another kind be with the width of papery base layer and barrier layere do wider, extrude lamination after, the flaw part of excision packing both sides obtains qualified packing; Moreover reduce necking phenomenon by increase thermoplastic material innermost layer thickness and damage.These three kinds of terms of settlement all need extruder die head than wide many of the width of papery base layer and barrier layere, need more heat heating and melting thermoplastic material, cause energy dissipation, and after lamination is finished, also will excise the flaw part of packing both sides, cause waste of raw materials.
Summary of the invention
Technical matters to be solved by this invention provides a kind of packing container, energy rapid heat-seal vertical and horizontal junction surface when making packing container, sealing intensity is good, and it is in the laminate wrapping material process of making packing container, serious necking phenomenon can not occur when extruding lamination thermoplastic material innermost layer, can not cause the serious energy and waste of raw materials.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is: a kind of packing container, comprise from outside to inside thermoplastic material outermost layer, sandwich layer, thermoplastic material interlayer, barrier layere and thermoplastic material innermost layer, wherein, described thermoplastic material innermost layer comprises linear low density polyethylene (MLLDPE) and the Low Density Polyethylene (LDPE) of metalloscene catalyst polymerization; The linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) has following parameter: average density be 0.88g/cm3~0.925g/cm3, melt flow index (190 ℃, 2.16kg) for 5g/10min~20g/10min, peak value fusing point be that 85 ℃~130 ℃, expansion ratio are 1.2~1.8; Described Low Density Polyethylene (LDPE) has following parameter: average density is 0.90g/cm 3~0.925g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~110 ℃, expansion ratio are 1.2~1.8.
Among the present invention, melt flow index is measured according to 190 ℃, the condition determination of 2.16kg in the GB/T3682-2000 melt flow index measuring method.Expansion ratio be illustrated in GB/T3682-2000 melt flow index measuring method under the identical condition determination (namely 190 ℃, 2.16kg), the cross sectional dimensions ratio of the cross sectional dimensions of the extrudate of measured depanning and die orifice.The peak value fusing point is obtained by differential scanning calorimetry, if two or more peak value refers to first peak value.Low Density Polyethylene (LDPE) can be linear low density polyethylene (LLDPE), also can be non-linear Low Density Polyethylene, just can satisfy requirement of the present invention as long as have above-mentioned performance perameter.
As a kind of improvement of technique scheme, wherein, the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) has following parameter: average density is 0.90g/cm 3~0.915g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 88 ℃~120 ℃, expansion ratio are 1.4~1.6.
As further improvement in the technical proposal, wherein, the average density of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 0.905g/cm 3~0.910g/cm 3,, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 93 ℃~103 ℃, expansion ratio are 1.4~1.6.
As further improvement in the technical proposal, wherein, described Low Density Polyethylene (LDPE) has following parameter: average density is 0.910g/cm 3~0.92g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~110 ℃, expansion ratio are 1.4~1.6.
As further improvement in the technical proposal, wherein, the average density of described Low Density Polyethylene (LDPE) is 0.915g/cm 3~0.920g/cm 3,, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 93 ℃~103 ℃, expansion ratio are 1.4~1.6.
As further improvement in the technical proposal, wherein, the weight percentage (wt) of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 50%~80%, and the weight percentage (wt) of described Low Density Polyethylene (LDPE) is 20%~50%.
As further improvement in the technical proposal, wherein, the weight percentage (wt) of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 60%~75%, and the weight percentage (wt) of described Low Density Polyethylene (LDPE) is 25%~40%.
As further improvement in the technical proposal, wherein, the weight percentage (wt) of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 70%, and the weight percentage (wt) of described Low Density Polyethylene (LDPE) is 30%.
The present invention compared with prior art, because the thermoplastic material innermost layer of packing container has adopted linear low density polyethylene (MLLDPE) and the Low Density Polyethylene (LDPE) with the polymerization of particular characteristic parameter metalloscene catalyst, in the extruding layer compression technology of the laminate wrapping material process of making packing container, the thermoplastic material innermost layer has obtained largely reducing in the necking phenomenon of molten condition during from the die head film extrusion of extruder, the energy and waste of raw materials phenomenon have largely inhibition, and energy rapid heat-seal vertical and horizontal junction surface when using laminate wrapping material to make packing container, sealing intensity is good.
Figure of description
Fig. 1 is a kind of scheme drawing of making the laminate wrapping material method.
Fig. 2 is the schematic perspective view of a kind of packing container of the present invention.
Fig. 3 is the sidewall cross sectional representation of a kind of packing container of the present invention.
The specific embodiment
As shown in Figures 2 and 3, a kind of packing container of the present invention comprises thermoplastic material outermost layer 21, sandwich layer 22, thermoplastic material interlayer 23, barrier layere 24, adhesive phase 25 and thermoplastic material innermost layer 26 from outside to inside successively.
Thermoplastic material innermost layer 26 comprises linear low density polyethylene (MLLDPE) and the Low Density Polyethylene (LDPE) of metalloscene catalyst polymerization, wherein, the linear low density polyethylene of metalloscene catalyst polymerization (mLLDPE) has following parameter: average density is 0.88g/cm 3~0.925g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~130 ℃, expansion ratio are 1.2~1.8; Low Density Polyethylene (LDPE) has following parameter: average density is 0.90g/cm 3~0.925g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~110 ℃, expansion ratio are 1.2~1.8, Low Density Polyethylene (LDPE) can be linear low density polyethylene, also can be non-linear low density polyethylene.The weight percentage (wt) of the linear low density polyethylene of metalloscene catalyst polymerization (mLLDPE) is 50%~80%, and the weight percentage (wt) of Low Density Polyethylene (LDPE) is 20%~50%.
Sandwich layer 22 is the coiled material of paper substrates, behind the lateral surface printed patterns, after indentation roller is suppressed crease line and is stamped out open hole, form thermoplastic material outermost layer 21 in the outside of sandwich layer 22 by the extruding layer compression technology with low-density polyethylene material, continue to guide the sandwich layer coiled material of impression perforate forward, arrive laminating bench, extruder squeezes out the low-density polyethylene film as thermoplastic material interlayer 23 herein, aluminum foil coiled material as barrier layere 24 is directed to laminating bench simultaneously, it is compound that laminating bench carries out lamination to trilaminate material, at its roll gap center core layer 22 medial surfaces, thermoplastic material interlayer 23 and barrier layere 24 are pressed together, then, polyvinyl acetate ester adhesive extruding layer is being pressed onto barrier layere 24 formation adhesive phases 25.
With above-mentioned conventional material with extrude the multilayer material that laminating method makes thermoplastic material outermost layer 21/ sandwich layer 22/ thermoplastic material interlayer 23/ aluminium foil layer 24/ adhesive phase 25, then linear low density polyethylene (mLLDPE) and the Low Density Polyethylene of distinguishing weight percentage (wt) the blend metalloscene catalyst polymerization in the according to the form below 1 obtain blend, respectively take bed thickness as 20,22,25,30 microns blend extruding layer is pressed onto and forms thermoplastic material innermost layer 26 on the adhesive phase 25 of this multilayer material, when this blend is extruded the formation film from the extruder die orifice, the film both sides do not form breach, edge thickness is substantially even, dual-side can shrink to the centre very little, these multilayer material both sides are capped even thickness, the laminate wrapping material that obtains is on bottle placer in the pouring in liquid food process, can finish the packing container longitudinal sealing by reliable fast speed, transverse sealing, the qualification rate of the packing container of making is high, and the time of guaranteeing the quality of food liquid is long.
When the linear low density polyethylene (mLLDPE) of blend metalloscene catalyst polymerization and Low Density Polyethylene obtain blend, can adopt the particle Direct Uniform with both materials to mix, also can adopt bi-material mixed after again melting stir, carry out granulation again and obtain the blend particle, the mixture homogeneity of rear a kind of mode is a kind of better than front.
Adhesive phase 25 and thermoplastic material innermost layer 26 can adopt two-layer co-extrusion mode to be laminated on the aluminium foil of barrier layere 24, can simplify technique like this, and adhesive phase 25 and thermoplastic material innermost layer 26 interlayer binding forces are good.
Table 1:
Figure BDA00002695686700051

Claims (10)

1. packing container, comprise from outside to inside thermoplastic material outermost layer, sandwich layer, thermoplastic material interlayer, barrier layere and thermoplastic material innermost layer, it is characterized in that: described thermoplastic material innermost layer comprises linear low density polyethylene (MLLDPE) and the Low Density Polyethylene (LDPE) of metalloscene catalyst polymerization;
The linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) has following parameter: average density is 0.88g/cm 3~0.925g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~130 ℃, expansion ratio are 1.2~1.8;
Described Low Density Polyethylene (LDPE) has following parameter: average density is 0.90g/cm 3~0.925g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~110 ℃, expansion ratio are 1.2~1.8.
2. a kind of packing container according to claim 1, it is characterized in that: the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) has following parameter: average density is 0.90g/cm 3~0.915g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 88 ℃~120 ℃, expansion ratio are 1.4~1.6.
3. a kind of packing container according to claim 1, it is characterized in that: the average density of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 0.905g/cm 3~0.910g/cm 3,, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 93 ℃~103 ℃, expansion ratio are 1.4~1.6.
4. a kind of packing container according to claim 1, it is characterized in that: described Low Density Polyethylene (LDPE) has following parameter: average density is 0.910g/cm 3~0.92g/cm 3, melt flow index (190 ℃, 2.16kg) is that 5g/10min~20g/10min, peak value fusing point are that 85 ℃~110 ℃, expansion ratio are 1.4~1.6.
5. a kind of packing container according to claim 1, it is characterized in that: the average density of described Low Density Polyethylene (LDPE) is 0.915g/cm 3~0.920g/cm 3, melt flow index (190 ℃, 2.16kg) be 5g/10min~20g/10min, peak value fusing point be 93 ℃~103 ℃,, expansion ratio is 1.4~1.6.
6. a kind of packing container according to claim 1, it is characterized in that: described Low Density Polyethylene (LDPE) is linear low density polyethylene (LLDPE).
7. a kind of packing container according to claim 1, it is characterized in that: described Low Density Polyethylene (LDPE) is non-linear Low Density Polyethylene.
8. each described a kind of packing container in 7 according to claim 1, it is characterized in that: the weight percentage (wt) of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 50%~80%, and the weight percentage (wt) of described Low Density Polyethylene (LDPE) is 20%~50%.
9. each described a kind of packing container in 7 according to claim 1, it is characterized in that: the weight percentage (wt) of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 60%~75%, and the weight percentage (wt) of described Low Density Polyethylene (LDPE) is 25%~40%.
10. each described a kind of packing container in 7 according to claim 1, it is characterized in that: the weight percentage (wt) of the linear low density polyethylene of described metalloscene catalyst polymerization (mLLDPE) is 70%, and the weight percentage (wt) of described Low Density Polyethylene (LDPE) is 30%.
CN201210593139.2A 2012-12-31 2012-12-31 Packaging container Ceased CN103043299B (en)

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CN201510156959.9A CN104760337A (en) 2012-12-31 2012-12-31 Packaging container
CN201210593139.2A CN103043299B (en) 2012-12-31 2012-12-31 Packaging container
CN201510156961.6A CN104760360A (en) 2012-12-31 2012-12-31 Packaging container
CN201510156968.8A CN104760388A (en) 2012-12-31 2012-12-31 Packaging container
CN201510156957.XA CN104760359A (en) 2012-12-31 2012-12-31 Packaging container

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CN201510156968.8A Division CN104760388A (en) 2012-12-31 2012-12-31 Packaging container
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104999757A (en) * 2015-08-04 2015-10-28 厉善君 Aseptic packaging material and aseptic packaging container for edible liquor
CN112644163A (en) * 2020-12-11 2021-04-13 重庆宏声印务有限责任公司 Ink fountain convenient to clean

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115257108A (en) * 2022-07-29 2022-11-01 康美包(苏州)有限公司 Barrier layer for packaging, sheet-like composite layer for packaging, and packaging container

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CN1337914A (en) * 1999-01-27 2002-02-27 泰特拉-勒维尔金融控股公司 Laminated packaging material for paper container
CN1652934A (en) * 2002-05-07 2005-08-10 利乐拉瓦尔集团及财务有限公司 Packaging laminate, method for its manufacturing and packaging container manufactured from the packaging laminate
CN1805848A (en) * 2003-06-18 2006-07-19 博里利斯公司 Food packaging
WO2006091310A1 (en) * 2005-02-21 2006-08-31 Exxonmobil Chemical Patents Inc. Multi-layer polyethylene films
WO2007032719A1 (en) * 2005-09-15 2007-03-22 Tetra Laval Holdings & Finance S.A. A sealing strip as well as a packaging container including such a strip
CN102001207A (en) * 2010-08-30 2011-04-06 天津精华石化有限公司 Novel FFS heavy packaging film

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Publication number Priority date Publication date Assignee Title
CN1337914A (en) * 1999-01-27 2002-02-27 泰特拉-勒维尔金融控股公司 Laminated packaging material for paper container
CN1652934A (en) * 2002-05-07 2005-08-10 利乐拉瓦尔集团及财务有限公司 Packaging laminate, method for its manufacturing and packaging container manufactured from the packaging laminate
CN1805848A (en) * 2003-06-18 2006-07-19 博里利斯公司 Food packaging
WO2006091310A1 (en) * 2005-02-21 2006-08-31 Exxonmobil Chemical Patents Inc. Multi-layer polyethylene films
WO2007032719A1 (en) * 2005-09-15 2007-03-22 Tetra Laval Holdings & Finance S.A. A sealing strip as well as a packaging container including such a strip
CN102001207A (en) * 2010-08-30 2011-04-06 天津精华石化有限公司 Novel FFS heavy packaging film

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104999757A (en) * 2015-08-04 2015-10-28 厉善君 Aseptic packaging material and aseptic packaging container for edible liquor
CN112644163A (en) * 2020-12-11 2021-04-13 重庆宏声印务有限责任公司 Ink fountain convenient to clean
CN112644163B (en) * 2020-12-11 2022-02-01 重庆宏声印务有限责任公司 Ink fountain convenient to clean

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CN104760388A (en) 2015-07-08
CN104760359A (en) 2015-07-08

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