CN103031604A - Nonlinear optical crystal rubidium calcium fluorine carbonate - Google Patents
Nonlinear optical crystal rubidium calcium fluorine carbonate Download PDFInfo
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- CN103031604A CN103031604A CN2011103040647A CN201110304064A CN103031604A CN 103031604 A CN103031604 A CN 103031604A CN 2011103040647 A CN2011103040647 A CN 2011103040647A CN 201110304064 A CN201110304064 A CN 201110304064A CN 103031604 A CN103031604 A CN 103031604A
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Abstract
The present invention relates to a kind of novel nonlinear optical crystal fluorine calcium carbonate rubidium, chemical formula is Rb3Ca3 (CO3) 3F3 (abbreviation RCCF), belongs to hexagonal crystal system, space group is
Cell parameter is
α=β=90 °, γ=120 °, z=1, unit-cell volume are
Its Clock Multiplier Factor is 1.2 times of KH2PO4 (KDP). Its ultraviolet absorption edge is shorter than 200nm. It is sintered at high temperature using solid phase synthesis process and obtains RCCF compound. Molten-salt growth method is used in CO2 atmosphere, monocrystal can be gone out with successful growth by making fluxing agent with RbF-Rb2CO3 or RbF-CaF2. Rb3Ca3 (CO3) 3F3 has nonlinear optical effect, the nonlinear optics application that can be used widely in various non-linear optical fields, and will open up deep ultraviolet band.
Description
Technical field
The present invention relates to a kind of photoelectron functional materials and growth method and purposes, particularly relate to a kind of non-linear optical crystal material and its production and use, i.e. fluorine calcium carbonate rubidium, its chemical formula is Rb
3Ca
3(CO
3)
3F
3, be called for short RCCF.
Background technology
The non-linear optical effect of crystal refers to a kind of like this effect: when a branch of laser with certain polarization direction passes through a non-linear optic crystal (such as RCCF) by certain incident direction, the frequency of this light beam will change.
Crystal with non-linearity optical effect is called non-linear optic crystal.Utilize non-linear optic crystal to carry out the laser frequency conversion, widen the scope of optical maser wavelength, make applications of laser more extensive.Especially the crystal such as borate family non-linear optic crystal such as BBO, LBO, KBBF, SBBO, TBO, KABO, BABO receive much attention with its excellent optical property.Development in photo-optics, photoengraving, precision instrument processing and other fields more and more needs ultraviolet and deep ultraviolet laser coherent source, namely needs ultraviolet and the deep ultraviolet nonlinear optical crystal of excellent performance.
The basic structure primitive of KBBF is (BO
3)
3-Plane group, the ultraviolet absorption edge of this crystal have moderate degree of birefringence (Δ n=0.07) about 155nm, can realize very wide phase matched scope, are classic deep ultraviolet nonlinear optical crystals so far.But because KBBF is a kind of crystal of laminate structure, be connected by electrostatic attraction rather than by valence link between layers, the stratiform habit is serious, and is very slow in the z direction speed of growth, and the single crystal demixing phenomenon that grows is obvious, and crystal is difficult for growth.
The basic structure primitive of SBBO also is (BO
3)
3-The plane group, but it replaces fluorion with oxygen, and so that interconnect by oxo bridge between layers, in order to improve the stratiform habit of KBBF, it is substantially constant that the structure of every one deck then keeps.SBBO not only has larger macroscopical Clock Multiplier Factor, low ultraviolet absorption edge (165nm), and moderate degree of birefringence (Δ n=0.06), and thoroughly overcome the stratiform habit of crystal, solved the problem of crystal growth.On this basis, keep (BO
3)
3-The structural condition of group is substantially constant, replaces kation S r
2+With the Be atom, in succession developed a series of non-linear optic crystals such as TBO, KABO, BABO, they are referred to as the SBBO group crystal.They have overcome the stratiform habit of KBBF single crystal growing, but up to the present these crystal can't replace the KBBF monocrystalline, because the structural integrity of SBBO and TBO crystal is bad, the non-constant of optical homogeneity that its macro property shows also can't be applied in practical devices at present; The structural integrity of KABO and BABO crystal is fine, has preferably optical homogeneity, but because Al has replaced Be, their ABSORPTION EDGE red shift is difficult to the harmonic wave of deep ultraviolet to about the 180nm.
Because (CO
3)
2-With (BO
3)
3-Structure similar with ligancy, we think available (CO
3)
2-Replace (BO
3)
3-, then with the alkali and alkaline earth metal ions ion as positively charged ion, add fluorion and adjust interlayer structure, thereby obtain novel compound, the application of developing deep ultraviolet nonlinear optical crystal.Through solid phase synthesis, the crystal growth, single crystal structure determination has confirmed that this imagination is possible.
Summary of the invention
The object of the present invention is to provide a kind of fluorine calcium carbonate rubidium compound, its chemical formula is Rb
3Ca
3(CO
3)
3F
3
Another object of the present invention is to provide a kind of fluorine calcium carbonate rubidium compound preparation method.
Another object of the present invention is to provide a kind of fluorine calcium carbonate rubidium non-linear optic crystal, its chemical formula is Rb
3Ca
3(CO
3)
3F
3
A further object of the present invention is to provide a kind of growth method of fluorine calcium carbonate rubidium non-linear optic crystal.
A further object of the invention is to provide the purposes of fluorine calcium carbonate rubidium non-linear optic crystal.
Technical scheme of the present invention is as follows:
Fluorine calcium carbonate rubidium compound provided by the invention, its chemical formula is Rb
3Ca
3(CO
3)
3F
3
The preparation method of fluorine calcium carbonate rubidium compound provided by the invention, its step is as follows: the raw materials of compound that will contain Rb, Ca, C and F is Rb: Ca: C: F=1 in its mol ratio: behind the even mixed grinding of 1: 1: 1 ratio, pack in the platinum alloy crucible, after 300～400 ℃ of the slow intensifications, pre-burning 1～5 hour; Be cooled to room temperature, take out and grind; Then 500～600 ℃ of lower sintering 12～20 hours, be cooled to room temperature, take out and grind, obtain Powdered fluorine calcium carbonate rubidium compound of the present invention, it is carried out XRD detect that (Fig. 3 a), its molecular formula is Rb
3Ca
3(CO
3)
3F
3The described Rb of containing raw materials of compound is fluorochemical or the carbonate that contains rubidium, fluorochemical or carbonate that the described Ca of containing raw materials of compound is calcic, and the described C of containing raw materials of compound is Rb
2CO
3Or CaCO
3, the described F of containing raw materials of compound is RbF or CaF
2
Fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, its chemical formula is Rb
3Ca
3(CO
3)
3F
3, this crystal does not have symmetry centre, belongs to hexagonal system, and spacer is P
62m, unit cell parameters is
α=β=90 °, γ=120 °, z=1, unit-cell volume is
Crystalline structure such as Fig. 2.
The growth method of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, its step is as follows: at CO
2In the atmosphere, with RbF and Rb
2CO
3Be fluxing agent growth, RbF/Rb
2CO
3Mol ratio is 1/2～2/1, solute and solvent mol ratio are 1/4～1/2 during take Rb as benchmark, raw material is mixed according to the above ratio, heat up 700～800 ℃ and melt fully to raw material, behind the constant temperature 1～20 hour, be cooled to rapidly above 5～10 ℃ of temperature of saturation, then by every day 1～5 ℃ speed be cooled to 600 ℃, close stove; After sample was cooled to room temperature, water flush away fusing assistant namely obtained fluorine calcium carbonate rubidium non-linear optic crystal of the present invention, is of a size of 0.5 * 0.4 * 0.3mm.The raw materials of compound that adopts is to contain the fluorochemical of the fluorochemical of rubidium or carbonate, calcic or carbonate, Rb
2CO
3Or CaCO
3With RbF or CaF
2The lenticular fluorine calcium carbonate rubidium that obtains, grind into powder carries out XRD to it and detects result such as Fig. 3 b again.
The growth method of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, its step is as follows: at CO
2In the atmosphere, adopt RbF-CaF
2The fusing assistant system, RbF/CaF
2Mol ratio is 1/3～3/1, solute and solvent mol ratio are 1/4～1/2 during take Rb as benchmark, raw material is mixed according to the above ratio, heat up 700～800 ℃ and melt fully to raw material, behind the constant temperature 1～20 hour, be cooled to rapidly above 5～10 ℃ of temperature of saturation, the lower end that seed crystal is fixed on seed rod contacts the growth of beginning crystal with melt liquid level; The speed of rotation of seed rod is 10～20 rev/mins, is cooled to temperature of saturation, then presses 1～5 ℃/day speed slow cooling; Cooling is lifted from liquid level with crystal after finishing, and is down to room temperature with 10～30 ℃/hour speed, obtains fluorine calcium carbonate rubidium non-linear optic crystal of the present invention.The raw materials of compound that adopts is to contain the fluorochemical of the fluorochemical of rubidium or carbonate, calcic or carbonate, Rb
2CO
3Or CaCO
3With RbF or CaF
2The lenticular fluorine calcium carbonate rubidium that obtains is of a size of 10 * 6 * 8mm, and grind into powder carries out XRD to it and detects result such as Fig. 3 b again.
The purposes of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, this non-linear optic crystal fluorine calcium carbonate rubidium is used for the frequency transformation of laser device laser output.
The purposes of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, this crystal produces 2 frequencys multiplication for the laser beam that to wavelength is 1.064 μ m, 3 frequencys multiplication, 4 frequencys multiplication, the humorous glistening light of waves output of 5 frequencys multiplication.
The purposes of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, this crystal are lower than the humorous glistening light of waves output of 200nm for generation of wavelength.
The purposes of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, described non-linear optic crystal is for being used for the harmonic generator of ultraviolet region, optical parameter and amplifying device and fiber waveguide device.
The purposes of fluorine calcium carbonate rubidium non-linear optic crystal provided by the invention, described non-linear optic crystal are optical parameter and the amplifying device from infrared to the ultraviolet region.
It is Rb that effect of the present invention is to provide a kind of chemical formula
3Ca
3(CO
3)
3F
3Compound, non-linear optic crystal of this compound and its production and use.Use the powder frequency doubling testing method to measure Rb
3Ca
3(CO
3)
3F
3The phase matched ability, its powder SHG effect is KH for its Clock Multiplier Factor
2PO
4(KDP) 1.2 times.Its ultraviolet absorption edge is shorter than 200nm.Rb
3Ca
3(CO
3)
3F
3Crystal can be realized 2 frequencys multiplication of Nd:YAG (λ=1.064 μ m), and, can predict Rb
3Ca
3(CO
3)
3F
3Can be used in 3 frequencys multiplication, 4 frequencys multiplication of Nd:YAG, the harmonic generator of 5 frequencys multiplication, even for generation of the humorous glistening light of waves output shorter than 200nm.In addition, Rb
3Ca
3(CO
3)
3F
3The monocrystalline water white transparency, chemical stability is good.So can predict Rb
3Ca
3(CO
3)
3F
3To in various non-linear optical fields, obtain widespread use, and will open up the nonlinear optics application of deep ultraviolet wave band.
Description of drawings
Fig. 1 is Rb
3Ca
3(CO
3)
3F
3Crystal is as the canonical schema of frequency-doubling crystal application non-linear hour optical effect, and wherein 1 is laser apparatus, and the 2nd, incoming laser beam, the 3rd, through the Rb of crystal aftertreatment and optics processing
3Ca
3(CO
3)
3F
3Single crystal, the 4th, the outgoing laser beam that produces, the 5th, filter plate.
Fig. 2 is Rb
3Ca
3(CO
3)
3F
3The crystal unit cell structural representation.
Fig. 3 is Rb
3Ca
3(CO
3)
3F
3X ray diffraction collection of illustrative plates, wherein 3a is solid phase synthesis Rb
3Ca
3(CO
3)
3F
3The diffractogram of powdered sample, 3b are Rb
3Ca
3(CO
3)
3F
3The monocrystalline last diffractogram of pulverizing.
Embodiment
Adopt high temperature solid state reaction synthetic compound Rb
3Ca
3(CO
3)
3F
3
Raw materials used: CaCO
31.0000 gram (0.01mol)
RbF 1.0447 grams (0.01mol)
Its chemical equation is:
3CaCO
3+ 3RbF=Rb
3Ca
3(CO
3)
3F
3Concrete operation step is as follows: after in operation box above-mentioned raw materials being weighed up by above-mentioned dosage, put into that mortar mixes and carefully grind, then pack in the platinum alloy crucible of Φ 30 * 30mm, with spoon its compression is added a cover, put into retort furnace (retort furnace places stink cupboard, and the fume hood exhaust mouth is by the water tank exhaust), slowly be warming up to 400 ℃ and constant temperature pre-burning 3 hours, the beginning temperature rise rate must be slow, prevents and treats the variation that causes proportioning because of decomposition, and solid state reaction is fully carried out.Take out crucible after the cooling, this moment, sample was more loose.Then take out sample and again grind evenly in operation box, place crucible to compress again and add a cover, in 600 ℃ of lower sintering 20 hours, take out after the cooling in retort furnace, at this moment sample is formed one, sample is put into mortar smash grinding to pieces and namely get product.This product is carried out X-ray analysis, and (Fig. 3 a) and Rb for the gained spectrogram
3Ca
3(CO
3)
3F
3The monocrystalline last X ray picture (Fig. 3 b) of pulverizing is consistent.
Adopt high temperature solid state reaction synthetic compound Rb
3Ca
3(CO
3)
3F
3
Raw materials used: Rb
2CO
32.3094 gram (0.01mol)
CaCO
31.0000 gram (0.01mol)
CaF
20.7807 gram (0.01mol)
Its chemical equation is:
3Rb
2CO
3+3CaCO
3+3CaF
2＝2Rb
3Ca
3(CO
3)
3F
3
Concrete operation step is as follows: after in operation box above-mentioned raw materials being weighed up by above-mentioned dosage, put into that mortar mixes and carefully grind, then pack in the platinum alloy crucible of Φ 30 * 30mm, with spoon its compression is added a cover, put into retort furnace (retort furnace places stink cupboard, and the fume hood exhaust mouth is by the water tank exhaust), slowly be warming up to 400 ℃ and constant temperature pre-burning 3 hours, the beginning temperature rise rate must be slow, prevents and treats the variation that causes proportioning because of decomposition, and solid state reaction is fully carried out.Take out crucible after the cooling, this moment, sample was more loose.Then take out sample and again grind evenly in operation box, place crucible to compress again and add a cover, in 600 ℃ of lower sintering 20 hours, take out after the cooling in retort furnace, at this moment sample is formed one, sample is put into mortar smash grinding to pieces and namely get product.This product is carried out X-ray analysis, and (Fig. 3 a) and Rb for the gained spectrogram
3Ca
3(CO
3)
3F
3The monocrystalline last X ray picture (Fig. 3 b) of pulverizing is consistent.
Adopt molten-salt growth crystal Rb
3Ca
3(CO
3)
3F
3
Crystal growing apparatus is homemade ventilation Resistant heating stove, and temperature controlling instruments is 908PHK20 type automatic temperature control instrument able to programme.Select RbF-Rb
2CO
3Make fusing assistant, sporadic nucleation obtains crystal.
Raw materials used: CaCO
3Analytical pure AR 20.000 grams (0.2mol)
RbF analytical pure AR 26.118 grams (0.25mol)
Rb
2CO
3Analytical pure AR 46.188 grams (0.2mol)
Concrete operation step is as follows: after above-mentioned raw materials is weighed up by above-mentioned dosage, mix, then pack in the platinum alloy crucible of Φ 60 * 60mm, place in the self-control growth furnace, heat up 750 ℃ and melt fully to raw material, constant temperature was cooled to rapidly above 5～10 ℃ of temperature of saturation after 10 hours, then by every day 3 ℃ speed be cooled to 600 ℃, close stove.After the sample cooling, water flush away fusing assistant namely obtains transparent Rb
3Ca
3(CO
3)
3F
3Monocrystalline is of a size of 0.5 * 0.4 * 0.3mm.
Adopt molten-salt growth crystal Rb
3Ca
3(CO
3)
3F
3
Crystal growing apparatus is homemade ventilation Resistant heating stove, and temperature controlling instruments is 908PHK20 type automatic temperature control instrument able to programme.Select RbF-CaF
2Make fusing assistant, the crystal that example 3 is obtained carries out directional cutting and becomes designed seed crystal.
Raw materials used:
Concrete operation step is as follows: after above-mentioned raw materials is weighed up by above-mentioned dosage, mix, then pack in the platinum alloy crucible of Φ 60 * 60mm, place in the self-control growth furnace, heat up 750 ℃ and melt fully to raw material, constant temperature is after 10 hours, be cooled to rapidly above 5～10 ℃ of temperature of saturation, seed crystal is fixed on the lower end of seed rod, imports crucible from the aperture of furnace roof section, seed crystal contact with melt liquid level begin crystal and grow.The speed of rotation of seed rod is 15 rev/mins, is cooled to temperature of saturation, then presses 1 ℃/day speed slow cooling.Cooling is lifted from liquid level with crystal after finishing, and is down to room temperature with 20 ℃/hour speed, namely obtains the Rb of large-size
3Ca
3(CO
3)
3F
3Monocrystalline, it is of a size of 10 * 6 * 8mm.
The crystal that example 4 is obtained, the processing cutting, directed, polishing is placed on the position of 3 in the device shown in Figure 1, at room temperature, with transferring Q Nd:YAG laser to do the input light source, incident wavelength is 1064nm, observe obvious 532nm frequency doubling green light output, output intensity is about 1.2 times of equal conditions KDP.
Claims (10)
1. compound fluorine calcium carbonate rubidium, it is characterized in that: its chemical formula is Rb
3Ca
3(CO
3)
3F
3, belonging to hexagonal system, spacer is
Unit cell parameters is
α=β=90 °, γ=120 °, z=1, unit-cell volume is
2. the preparation method of the fluorine calcium carbonate rubidium compound of a claim 1 is characterized in that: the raw materials of compound that will contain Rb, Ca, F and C by the even mixed grinding of suitable proportion after, slowly heat up after 300～400 ℃ pre-burning 1～5 hour; Be cooled to room temperature, take out and grind; Then 500～600 ℃ of lower sintering 12～20 hours, be cooled to room temperature and can obtain fluorine calcium carbonate rubidium compound.
3. the non-linear optic crystal of the compound fluorine calcium carbonate rubidium of claim 1.
4. the growth method of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 3 is at CO
2Adopt molten-salt growth in the atmosphere, it is characterized in that: with RbF-Rb
2CO
3Be fluxing agent growth, RbF/Rb
2CO
3Mol ratio is 1/2～2/1, solute and solvent mol ratio are 1/4～1/2 during take Rb as benchmark, raw material is mixed according to the above ratio, heat up 700～800 ℃ and melt fully to raw material, behind the constant temperature 1～20 hour, be cooled to rapidly above 5～10 ℃ of temperature of saturation, then by every day 1～5 ℃ speed be cooled to 600 ℃, close stove; After sample was cooled to room temperature, water flush away fusing assistant namely obtained 0.5 * 0.4 * 0.3mm fluorine calcium carbonate rubidium non-linear optic crystal that is of a size of of the present invention.
5. the growth method of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 3 is at CO
2Adopt molten-salt growth in the atmosphere, it is characterized in that: adopt RbF-CaF
2The fusing assistant system, RbF/CaF
2Mol ratio is 1/3～3/1, solute and solvent mol ratio are 1/4～1/2 during take Rb as benchmark, raw material is mixed according to the above ratio, heat up 700～800 ℃ and melt fully to raw material, behind the constant temperature 1～20 hour, be cooled to rapidly above 5～10 ℃ of temperature of saturation, the lower end that seed crystal is fixed on seed rod contacts the growth of beginning crystal with melt liquid level; The speed of rotation of seed rod is 10～20 rev/mins, is cooled to temperature of saturation, then presses 1～5 ℃/day speed slow cooling; Cooling is lifted from liquid level with crystal after finishing, and is down to room temperature with 10～30 ℃/hour speed, obtains 10 * 6 * 8mm fluorine calcium carbonate rubidium non-linear optic crystal that is of a size of of the present invention.
6. the purposes of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 3 is characterized in that: the frequency transformation that this non-linear optic crystal is exported for laser device laser.
7. the purposes of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 6 is characterized in that: it is the humorous glistening light of waves output that the laser beam of 1.064 μ m produces 2 frequencys multiplication or 3 frequencys multiplication or 4 frequencys multiplication or 5 frequencys multiplication that this crystal is used for wavelength.
8. the purposes of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 6 is characterized in that: this crystal is lower than the humorous glistening light of waves output of 200nm for generation of wavelength.
9. the purposes of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 6 is characterized in that: described non-linear optic crystal is for being used for the harmonic generator of ultraviolet region, optical parameter and amplifying device and fiber waveguide device.
10. the purposes of a fluorine calcium carbonate rubidium non-linear optic crystal claimed in claim 6 is characterized in that: described non-linear optic crystal is optical parameter and amplifying device from infrared to the ultraviolet region.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103710749A (en) * | 2013-12-16 | 2014-04-09 | 中国科学院福建物质结构研究所 | Sodium calcium fluorocarbonate compound and nonlinear optical crystal thereof, and crystal growth method |
| CN115044976A (en) * | 2021-03-09 | 2022-09-13 | 中国科学院理化技术研究所 | Second-order nonlinear optical crystal and preparation method and application thereof |
| CN115710748A (en) * | 2021-08-23 | 2023-02-24 | 中国科学院福建物质结构研究所 | Zinc carbonate ammonia nonlinear optical crystal and preparation method and application thereof |
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| CN103710749A (en) * | 2013-12-16 | 2014-04-09 | 中国科学院福建物质结构研究所 | Sodium calcium fluorocarbonate compound and nonlinear optical crystal thereof, and crystal growth method |
| CN115044976A (en) * | 2021-03-09 | 2022-09-13 | 中国科学院理化技术研究所 | Second-order nonlinear optical crystal and preparation method and application thereof |
| CN115044976B (en) * | 2021-03-09 | 2024-04-12 | 中国科学院理化技术研究所 | Second-order nonlinear optical crystal and preparation method and application thereof |
| CN115710748A (en) * | 2021-08-23 | 2023-02-24 | 中国科学院福建物质结构研究所 | Zinc carbonate ammonia nonlinear optical crystal and preparation method and application thereof |
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Application publication date: 20130410 |