CN103014910A - Sewing thread with high softening point, preparation method and application of same - Google Patents

Sewing thread with high softening point, preparation method and application of same Download PDF

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Publication number
CN103014910A
CN103014910A CN201210585671XA CN201210585671A CN103014910A CN 103014910 A CN103014910 A CN 103014910A CN 201210585671X A CN201210585671X A CN 201210585671XA CN 201210585671 A CN201210585671 A CN 201210585671A CN 103014910 A CN103014910 A CN 103014910A
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CN
China
Prior art keywords
sewing thread
high softening
point
antioxidant
sewing
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Pending
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CN201210585671XA
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Chinese (zh)
Inventor
傅峰
林腾飞
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ZHONGSHAN KECHENG CHEMICAL FIBRE CO Ltd
South China University of Technology SCUT
Original Assignee
ZHONGSHAN KECHENG CHEMICAL FIBRE CO Ltd
South China University of Technology SCUT
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Application filed by ZHONGSHAN KECHENG CHEMICAL FIBRE CO Ltd, South China University of Technology SCUT filed Critical ZHONGSHAN KECHENG CHEMICAL FIBRE CO Ltd
Priority to CN201210585671XA priority Critical patent/CN103014910A/en
Publication of CN103014910A publication Critical patent/CN103014910A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a sewing thread with a high softening point, wherein the sewing thread comprises polypropylene, poly(4-methyl-1-pentene), an antioxidant and a heat stabilizer. The invention relates to the technical field of fiber textile; and the prepared sewing thread with the high softening point is applicable to the field of textile sewing, has a high softening point property, satisfies various industrial sewing, particularly requirements on high-speed sewing, and effectively solves a recycling difficulty at the same time.

Description

A kind of sewing thread and method for making and application with high softening-point
Technical field
The present invention relates to the fibrous woven technical field, particularly a kind of sewing thread and method for making and application with high softening-point.
Background technology
Sewing thread refers in the formed product processes such as clothes, interior decoration, gas support fabric construction and geotextiles, the yarn that different parts is linked together by seam.Sewing thread is widely used in the fields such as industry, agricultural, medical treatment, science and techniques of defence as the main material in the joint technique.As the industrial sewing line that is applied in the industry, the realization of the good and bad abutment joint of its combination property is most important.Along with the rise of fabrics for industrial use, the kind of industrial sewing thread and consumption are also significantly improving, and the industrial sewing product is special because of its purposes, and the performance of sewing thread in the abutment joint technology has also proposed more harsh requirement.
Along with the innovation of textile technology, industry is to industrial sewing thread, particularly the demand of high speed sewing thread also more cumulative adding.After in case sewing velocity improves, repeatedly deflect and and cloth between high-speed friction can bring the larger heat of giving birth to sewing thread, poor heat resistance, the softening point of ordinary sewing line are low, be easy to just occur situation softening even broken string, so the ordinary sewing line can't be competent at the occasions such as at a high speed sewing.Just because of this, current sewing thread shows all the more the restriction of industry.
On the other hand, the kind of current sewing thread is generally terylene, so that all there are significant difference in polypropylene fibre goods and sewing thread in outward appearance, feel, washing, and incompatible on terylene and the polypropylene fibre physical property, prior art becomes a key difficult problem that restricts Polypropylene recovery field to the reclaiming again of Polypropylene of terylene thread sewing.Chinese polyster fibre sewing thread output was 540,000 tons in 2003, quite a few is wherein arranged is to engage for the sewing of Polypropylene, to the Polypropylene discarded object of terylene thread sewing be reclaimed again under the prior art condition, have to rely on a large amount of labours to separate by hand terylene thread and polypropylene fibre goods, could reclaim again the polypropylene fibre goods.Such recovery method is time-consuming, effort; And owing to very easily causing again the unnecessary waste of Polypropylene reclaimed materials and loss in the separation process, this also is that restricting current the key technology difficult problem that Polypropylene reclaims the field.
In sum, at present about the preparation method of sewing thread with high softening-point report is not arranged also.
Summary of the invention
Goal of the invention of the present invention be low for existing sewing thread softening point and with the inconsistent technical deficiency of polypropylene cloth, a kind of sewing thread and method for making and application with high softening-point is provided.
For achieving the above object, the technical solution used in the present invention is:
A kind of sewing thread with high softening-point is provided, and the component of this sewing thread is: polypropylene, poly-4-methyl 1-amylene, antioxidant and heat stabilizer.
Preferably, the parts by weight of each component are as follows:
Polypropylene 30 ~ 70;
Poly-4-methyl 1-amylene 30 ~ 70;
Antioxidant 0.1 ~ 2;
Heat stabilizer 0.1 ~ 3.
Preferably, described antioxidant comprises one or more in antioxidant 1010, irgasfos 168, antioxidant 7910, antioxidant 264, antioxidant BHT or the anti-oxidant DLTP.
Preferably, described heat stabilizer is one or more in zinc stearate, calcium stearate, dolomol or the barium stearate.
Further, provide a kind of method for making with sewing thread of high softening-point, may further comprise the steps:
(1) polypropylene, poly-4-methyl 1-amylene, antioxidant, heat stabilizer are mixed under 25 ~ 140 ℃;
(2) in the above-mentioned compound feeding twin-screw melt spinning machine, melt extrude, spinning moulding, namely obtain having the sewing thread of high softening-point.
Preferably, the heating-up temperature of described twin-screw melt spinning machine is 190 ~ 260 ℃, and melt pressure is 8 ~ 15MPa, and spinning speed is 200 ~ 500m/min, and drafting multiple is 3 ~ 6 times, and temperature of heat plate is 60 ~ 80 ℃, and hot plate temperature is 110 ~ 130 ℃.
Further, provide the application of sewing thread in the textile fabric field with high softening-point.
The present invention has following beneficial effect with respect to prior art:
The present invention adopts melt spinning method preparation to have the sewing thread of high softening-point, and raw material is easy to get, and preparation technology is simple and feasible, and the former that need not to acquire other can carry out industrialization to the present invention.The sewing thread with high softening-point of the present invention preparation sewing field that can be applicable to weave has the characteristic of high softening-point, is satisfied with various industrial sewings, particularly the at a high speed requirement of sewing.By the sewing thread with high softening-point of the present invention's preparation, its softening point can reach 120 ℃, and TENSILE STRENGTH reaches more than the 4.0g/d, is satisfied with various industrial sewings, particularly the at a high speed requirement of sewing.
Thereby the present invention adopts polypropylene/poly-4-methyl 1-amylene melt blending spinning to prepare a kind of sewing thread with high softening-point.Poly-4-methyl 1-amylene is a kind of new type polyolefin material, has the very outstanding characteristics such as optical property, mechanical performance, heat-resisting quantity and electric property.The fusing point of poly-4-methyl 1-amylene is up to 240 ℃, and Vicat softening point is 173 ℃, so that it can use being higher than under the serviceability temperature of PP.The sewing thread with high softening-point of spinning preparation not only has the characteristic of high softening-point with polypropylene/poly-4-methyl 1-amylene melt blending, and it has good compatible properties to polyolefin articles simultaneously, efficiently solves simultaneously a difficult problem that reclaims again.
The specific embodiment
Below in conjunction with the drawings and specific embodiments goal of the invention of the present invention is described in further detail, embodiment can not give unnecessary details one by one at this, but therefore embodiments of the present invention are not defined in following examples.Unless stated otherwise, material and the processing method of the present invention's employing are the art conventional material and processing method.
Embodiment 1
In mixer, add successively 3kg polypropylene, the poly-4-methyl 1-amylene of 2kg, 100g antioxidant 1010,50g zinc stearate, the mixer mixing velocity is 100rpm; Obtain compound.In above-mentioned compound feeding twin-screw melt spinning machine, melt extrude, spinning moulding, namely obtain having the sewing thread of high softening-point.Wherein, the heating-up temperature of twin-screw melt spinning machine is followed successively by 180 ℃, 200 ℃, 220 ℃, 240 ℃, 240 ℃, 200 ℃; Melt pressure 8 Mpa ~ 15Mpa, spinning speed 400m/min, 4 ~ 6 times of drafting multiples, 60 ℃ ~ 80 ℃ of temperature of heat plate, 110 ℃ ~ 130 ℃ of hot plate temperatures; Make the sewing thread with high softening-point.
In the present embodiment, thereby adopt polypropylene/poly-4-methyl 1-amylene melt blending spinning to prepare a kind of sewing thread with high softening-point.Poly-4-methyl 1-amylene is a kind of new type polyolefin material, has the very outstanding characteristics such as optical property, mechanical performance, heat-resisting quantity and electric property.The fusing point of poly-4-methyl 1-amylene is up to 240 ℃, and Vicat softening point is 173 ℃, so that it can use being higher than under the serviceability temperature of PP.The sewing thread with high softening-point of spinning preparation not only has the characteristic of high softening-point with polypropylene/poly-4-methyl 1-amylene melt blending, and it has good compatible properties to polyolefin articles simultaneously, efficiently solves simultaneously a difficult problem that reclaims again.
Embodiment 2
In mixer, add successively 2.5kg polypropylene, the poly-4-methyl 1-amylene of 2.5kg, 80g antioxidant 1010,20g zinc stearate, the mixer mixing velocity is 100rpm; Obtain compound.In above-mentioned compound feeding twin-screw melt spinning machine, melt extrude, spinning moulding, namely obtain having the sewing thread of high softening-point.The heating-up temperature of twin-screw melt spinning machine is followed successively by 180 ℃, 200 ℃, 230 ℃, 250 ℃, 250 ℃, 210 ℃, melt pressure 8 Mpa ~ 15MPa, spinning speed 300m/min, 3 ~ 4 times of drafting multiples, 60 ℃ ~ 80 ℃ of temperature of heat plate, 110 ℃ ~ 130 ℃ of hot plate temperatures; Make the sewing thread with high softening-point.
The performance of gained sewing thread is as shown in the table:
Project Fracture strength/(g/d) Softening temperature (℃)
Embodiment 1 4.7 128
Embodiment 2 4.2 140
In the present embodiment, thereby adopt polypropylene/poly-4-methyl 1-amylene melt blending spinning to prepare a kind of sewing thread with high softening-point.Poly-4-methyl 1-amylene is a kind of new type polyolefin material, has the very outstanding characteristics such as optical property, mechanical performance, heat-resisting quantity and electric property.The fusing point of poly-4-methyl 1-amylene is up to 240 ℃, and Vicat softening point is 173 ℃, so that it can use being higher than under the serviceability temperature of PP.The sewing thread with high softening-point of spinning preparation not only has the characteristic of high softening-point with polypropylene/poly-4-methyl 1-amylene melt blending, and it has good compatible properties to polyolefin articles simultaneously, efficiently solves simultaneously a difficult problem that reclaims again.
Above-described embodiment is preferred embodiment of the present invention only, is not to limit practical range of the present invention.Be that all equalizations of doing according to content of the present invention change and modification, all contained by claim of the present invention scope required for protection.

Claims (7)

1. sewing thread with high softening-point, it is characterized in that: the component of this sewing thread is: polypropylene, poly-4-methyl 1-amylene, antioxidant and heat stabilizer.
2. the sewing thread with high softening-point according to claim 1, it is characterized in that: the parts by weight of each component are as follows:
Polypropylene 30 ~ 70;
Poly-4-methyl 1-amylene 30 ~ 70;
Antioxidant 0.1 ~ 2;
Heat stabilizer 0.1 ~ 3.
3. the sewing thread with high softening-point according to claim 1 and 2, it is characterized in that: described antioxidant comprises one or more in antioxidant 1010, irgasfos 168, antioxidant 7910, antioxidant 264, antioxidant BHT or the anti-oxidant DLTP.
4. the sewing thread with high softening-point according to claim 1 and 2, it is characterized in that: described heat stabilizer is one or more in zinc stearate, calcium stearate, dolomol or the barium stearate.
5. one of according to claim 1 ~ 4 described method for making with sewing thread of high softening-point is characterized in that, may further comprise the steps:
(1) polypropylene, poly-4-methyl 1-amylene, antioxidant, heat stabilizer are mixed under 25 ~ 140 ℃;
(2) in the above-mentioned compound feeding twin-screw melt spinning machine, melt extrude, spinning moulding, namely obtain having the sewing thread of high softening-point.
6. the method for making with sewing thread of high softening-point according to claim 5, it is characterized in that: the heating-up temperature of described twin-screw melt spinning machine is 190 ~ 260 ℃, melt pressure is 8 ~ 15MPa, spinning speed is 200 ~ 500m/min, drafting multiple is 3 ~ 6 times, temperature of heat plate is 60 ~ 80 ℃, and hot plate temperature is 110 ~ 130 ℃.
7. one of according to claim 1 ~ 4 described application of sewing thread in the textile fabric field with high softening-point.
CN201210585671XA 2012-12-30 2012-12-30 Sewing thread with high softening point, preparation method and application of same Pending CN103014910A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104711695A (en) * 2013-12-13 2015-06-17 东丽纤维研究所(中国)有限公司 Fiber, and preparation method and use thereof
JP2015132039A (en) * 2013-12-10 2015-07-23 東レ株式会社 polymethylpentene fiber
CN105696140A (en) * 2016-01-26 2016-06-22 吴江市震宇缝制设备有限公司 High-strength composite sewing thread and preparing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4874399A (en) * 1988-01-25 1989-10-17 Minnesota Mining And Manufacturing Company Electret filter made of fibers containing polypropylene and poly(4-methyl-1-pentene)
US5041325A (en) * 1987-08-10 1991-08-20 Minnesota Mining And Manufacturing Company Microwave food package and grease absorbent pad therefor
CN1102223A (en) * 1993-09-18 1995-05-03 格尔德·埃伯特 Sewing thread, nonwoven fabric sewed with same and preparation of same
JP2002348726A (en) * 2001-05-25 2002-12-04 Hagihara Industries Inc Resin-reinforcing fiber and frp formed product using the same
CN101113540A (en) * 2007-08-31 2008-01-30 赵瑞元 Down wear penetration-proof sewing thread and method for manufacturing same
CN101903166A (en) * 2007-12-14 2010-12-01 3M创新有限公司 Fiber aggregate

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5041325A (en) * 1987-08-10 1991-08-20 Minnesota Mining And Manufacturing Company Microwave food package and grease absorbent pad therefor
US4874399A (en) * 1988-01-25 1989-10-17 Minnesota Mining And Manufacturing Company Electret filter made of fibers containing polypropylene and poly(4-methyl-1-pentene)
CN1102223A (en) * 1993-09-18 1995-05-03 格尔德·埃伯特 Sewing thread, nonwoven fabric sewed with same and preparation of same
JP2002348726A (en) * 2001-05-25 2002-12-04 Hagihara Industries Inc Resin-reinforcing fiber and frp formed product using the same
CN101113540A (en) * 2007-08-31 2008-01-30 赵瑞元 Down wear penetration-proof sewing thread and method for manufacturing same
CN101903166A (en) * 2007-12-14 2010-12-01 3M创新有限公司 Fiber aggregate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
林其棱,谭武红: "丙纶高强丝应用初探", 《合成纤维工业》, vol. 17, no. 04, 5 August 1994 (1994-08-05), pages 28 - 33 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015132039A (en) * 2013-12-10 2015-07-23 東レ株式会社 polymethylpentene fiber
CN104711695A (en) * 2013-12-13 2015-06-17 东丽纤维研究所(中国)有限公司 Fiber, and preparation method and use thereof
CN104711695B (en) * 2013-12-13 2018-03-16 东丽纤维研究所(中国)有限公司 A kind of fiber and its production and use
CN105696140A (en) * 2016-01-26 2016-06-22 吴江市震宇缝制设备有限公司 High-strength composite sewing thread and preparing method thereof

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Application publication date: 20130403