CN103014795A - Bush plating solution for cylinder sleeve - Google Patents
Bush plating solution for cylinder sleeve Download PDFInfo
- Publication number
- CN103014795A CN103014795A CN2012104775698A CN201210477569A CN103014795A CN 103014795 A CN103014795 A CN 103014795A CN 2012104775698 A CN2012104775698 A CN 2012104775698A CN 201210477569 A CN201210477569 A CN 201210477569A CN 103014795 A CN103014795 A CN 103014795A
- Authority
- CN
- China
- Prior art keywords
- cylinder sleeve
- nickel
- brush plating
- plating liquid
- comprised
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007747 plating Methods 0.000 title claims abstract description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims description 25
- 230000004913 activation Effects 0.000 claims description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 6
- PYRZPBDTPRQYKG-UHFFFAOYSA-N cyclopentene-1-carboxylic acid Chemical compound OC(=O)C1=CCCC1 PYRZPBDTPRQYKG-UHFFFAOYSA-N 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- 150000002815 nickel Chemical class 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims description 3
- 239000001393 triammonium citrate Substances 0.000 claims description 3
- 235000011046 triammonium citrate Nutrition 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 229940038773 trisodium citrate Drugs 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 3
- 230000003213 activating effect Effects 0.000 abstract 3
- 239000012530 fluid Substances 0.000 abstract 3
- 238000002360 preparation method Methods 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
- Chemically Coating (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention discloses a bush plating solution for a cylinder sleeve. The bush plating solution consists of an electrocleaning solution, an activating fluid I, an activating fluid II, an activating fluid III, special nickel and rapid nickel. The bush plating solution disclosed by the invention is nontoxic and unharmful, convenient to prepare, free of special chemical reagents and convenient to operate.
Description
Technical field
The present invention relates to a kind of cylinder sleeve brush plating liquid.
Background technology
In the prior art, in order to make electrolytic coating smooth firmly, the prescription of electroplate liquid is often very complicated on the industrial production, prussiate commonly used was prepared electroplate liquid as complexing agent in the past, but because CN-has severe toxicity, Health cost to the electroplater is very large, and simultaneously, the sewage, waste gas that discharging contains CN-is serious environment pollution also.
Summary of the invention
The purpose of this invention is to provide a kind of nontoxic, prepare easily cylinder sleeve brush plating liquid.
The technical scheme that the present invention adopts for achieving the above object is: a kind of cylinder sleeve brush plating liquid is comprised of the clean liquid of electricity, No. two activation solutions, No. three activation solutions, special nickel and Fast Nickels.
The clean liquid of described electricity is comprised of anhydrous sodium carbonate 22g/l, tertiary sodium phosphate 50g/l and sodium-chlor 2.5g/l.
Described No. two activation solutions are comprised of sodium-chlor 150g/l and hydrochloric acid 42g/l.
Described No. three activation solutions are comprised of Trisodium Citrate 150g/l and citric acid 90g/l.
Adding hydrochloric acid 21ml/l after described special nickel is dissolved by nickelous chloride 15g/l, single nickel salt 396g/l, glacial acetic acid three ammonium 70g/l forms again.
Described Fast Nickel is comprised of single nickel salt 265g/l, Triammonium citrate 100g/l, glacial acetic acid three ammonium 30g/l, ammoniacal liquor 130-150ml/l and asccharin 0.5g/l.
The clean liquid pH value of described electricity is 0.5-0.8 greater than 11, No. two activation solution pH values, and No. three activation solution pH values are 3-5, and special nickel pH value is 0.3, and the Fast Nickel pH value is 7.2-7.5.
A kind of cylinder sleeve brush plating liquid of the present invention, nontoxic, preparation is convenient, and is without special chemical reagent, easy to operate.
Embodiment
Cylinder sleeve brush plating liquid of the present invention, by the clean liquid of electricity, No. two activation solutions, No. three activation solutions, special nickel and Fast Nickel form, the clean liquid pH value of electricity is greater than 11, for colourless, No. two activation solution pH values are 0.5-0.8, be light red, No. three activation solution pH values are 3-5, for light green, special nickel pH value is 0.3, the Fast Nickel pH value is 7.2-7.5, and the clean liquid of electricity is by anhydrous sodium carbonate 22g/l, tertiary sodium phosphate 50g/l and sodium-chlor 2.5g/l form, and No. two activation solution is comprised of sodium-chlor 150g/l and hydrochloric acid 42g/l, No. three activation solution is comprised of Trisodium Citrate 150g/l and citric acid 90g/l, special nickel is by nickelous chloride 15g/l, single nickel salt 396g/l, add hydrochloric acid 21ml/l after the glacial acetic acid three ammonium 70g/l dissolving again and form, Fast Nickel is by single nickel salt 265g/l, Triammonium citrate 100g/l, glacial acetic acid three ammonium 30g/l, ammoniacal liquor 130-150ml/l and asccharin 0.5g/l form, cylinder sleeve brush plating liquid of the present invention, nontoxic, preparation is convenient, and is without special chemical reagent, easy to operate.
Claims (7)
1. a cylinder sleeve brush plating liquid is characterized in that: be comprised of the clean liquid of electricity, No. two activation solutions, No. three activation solutions, special nickel and Fast Nickels.
2. a kind of cylinder sleeve brush plating liquid according to claim 1, it is characterized in that: the clean liquid of described electricity is comprised of anhydrous sodium carbonate 22g/l, tertiary sodium phosphate 50g/l and sodium-chlor 2.5g/l.
3. a kind of cylinder sleeve brush plating liquid according to claim 1, it is characterized in that: described No. two activation solutions are comprised of sodium-chlor 150g/l and hydrochloric acid 42g/l.
4. a kind of cylinder sleeve brush plating liquid according to claim 1, it is characterized in that: described No. three activation solutions are comprised of Trisodium Citrate 150g/l and citric acid 90g/l.
5. a kind of cylinder sleeve brush plating liquid according to claim 1 is characterized in that: add hydrochloric acid 21ml/l after described special nickel is dissolved by nickelous chloride 15g/l, single nickel salt 396g/l, glacial acetic acid three ammonium 70g/l again and form.
6. a kind of cylinder sleeve brush plating liquid according to claim 1, it is characterized in that: described Fast Nickel is comprised of single nickel salt 265g/l, Triammonium citrate 100g/l, glacial acetic acid three ammonium 30g/l, ammoniacal liquor 130-150ml/l and asccharin 0.5g/l.
7. a kind of cylinder sleeve brush plating liquid according to claim 1, it is characterized in that: the clean liquid pH of described electricity value is 0.5-0.8 greater than 11, No. two activation solution pH values, and No. three activation solution pH value is 3-5, and special nickel pH value is 0.3, and Fast Nickel pH value is 7.2-7.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210477569.8A CN103014795B (en) | 2012-11-22 | 2012-11-22 | Cylinder jacket brush plating liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210477569.8A CN103014795B (en) | 2012-11-22 | 2012-11-22 | Cylinder jacket brush plating liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103014795A true CN103014795A (en) | 2013-04-03 |
| CN103014795B CN103014795B (en) | 2016-05-25 |
Family
ID=47963894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210477569.8A Active CN103014795B (en) | 2012-11-22 | 2012-11-22 | Cylinder jacket brush plating liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103014795B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087989A (en) * | 2014-06-17 | 2014-10-08 | 宁国新博能电子有限公司 | Electrolytic treatment liquid used for nickel plating of copper wire |
| CN111041531A (en) * | 2019-11-28 | 2020-04-21 | 广东羚光新材料股份有限公司 | Capacitor nickel electroplating solution, electroplating method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4738756A (en) * | 1987-07-28 | 1988-04-19 | The Boeing Company | Method of brush chrome plating using tank chrome plating solutions |
| CN1986899A (en) * | 2006-11-29 | 2007-06-27 | 华南理工大学 | Brush electroplating process and apparatus for reinforcing large mold |
| CN101514468A (en) * | 2009-02-19 | 2009-08-26 | 中国人民解放军装甲兵工程学院 | Device and method for inner bore type component brush plating |
| CN101514467A (en) * | 2009-02-27 | 2009-08-26 | 西北工业大学 | Method for repairing generator shaft abrasion error fast |
-
2012
- 2012-11-22 CN CN201210477569.8A patent/CN103014795B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4738756A (en) * | 1987-07-28 | 1988-04-19 | The Boeing Company | Method of brush chrome plating using tank chrome plating solutions |
| CN1986899A (en) * | 2006-11-29 | 2007-06-27 | 华南理工大学 | Brush electroplating process and apparatus for reinforcing large mold |
| CN101514468A (en) * | 2009-02-19 | 2009-08-26 | 中国人民解放军装甲兵工程学院 | Device and method for inner bore type component brush plating |
| CN101514467A (en) * | 2009-02-27 | 2009-08-26 | 西北工业大学 | Method for repairing generator shaft abrasion error fast |
Non-Patent Citations (1)
| Title |
|---|
| 刘家浚等著: "《材料磨损原理及其耐磨性》", 30 November 1993 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087989A (en) * | 2014-06-17 | 2014-10-08 | 宁国新博能电子有限公司 | Electrolytic treatment liquid used for nickel plating of copper wire |
| CN111041531A (en) * | 2019-11-28 | 2020-04-21 | 广东羚光新材料股份有限公司 | Capacitor nickel electroplating solution, electroplating method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103014795B (en) | 2016-05-25 |
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Legal Events
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190107 Address after: No. 76 Iron and Steel Road, Dalian Economic and Technological Development Zone, Liaoning Province Patentee after: DALIAN HELLON KEBEN PISTON CO.,LTD. Address before: 116100 No. 128, Wuli Tai, Minhe Village, Jinzhou District, Dalian City, Liaoning Province Patentee before: DALIAN BINCHENG PISTON MANUFACTURING Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Cylinder liner brush plating solution Effective date of registration: 20220905 Granted publication date: 20160525 Pledgee: China Merchants Bank Co.,Ltd. Dalian Branch Pledgor: DALIAN HELLON KEBEN PISTON CO.,LTD. Registration number: Y2022210000139 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231221 Granted publication date: 20160525 Pledgee: China Merchants Bank Co.,Ltd. Dalian Branch Pledgor: DALIAN HELLON KEBEN PISTON CO.,LTD. Registration number: Y2022210000139 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Cylinder liner brush plating solution Effective date of registration: 20231225 Granted publication date: 20160525 Pledgee: China Merchants Bank Co.,Ltd. Dalian Branch Pledgor: DALIAN HELLON KEBEN PISTON CO.,LTD. Registration number: Y2023210000356 |