CN103011417A - Method for efficiently treating ammonia nitrogen sewage at low temperature - Google Patents

Method for efficiently treating ammonia nitrogen sewage at low temperature Download PDF

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Publication number
CN103011417A
CN103011417A CN2012104918102A CN201210491810A CN103011417A CN 103011417 A CN103011417 A CN 103011417A CN 2012104918102 A CN2012104918102 A CN 2012104918102A CN 201210491810 A CN201210491810 A CN 201210491810A CN 103011417 A CN103011417 A CN 103011417A
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China
Prior art keywords
nitrobacteria
carrier
embedding
ammonia nitrogen
sewage
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Pending
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CN2012104918102A
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Chinese (zh)
Inventor
赵雪莲
李宗慧
孟胜
任彦强
屈佳玉
刘金泉
王凯
姜安平
王俊安
刘杰
孙丽波
牛微
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Sound Group Co Ltd
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Sound Group Co Ltd
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Priority to CN2012104918102A priority Critical patent/CN103011417A/en
Publication of CN103011417A publication Critical patent/CN103011417A/en
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  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention discloses a method for efficiently treating ammonia nitrogen sewage at a low temperature. The method comprises the steps of: firstly, embedding nitrobacteria microorganisms inside a high polymer material as a carrier to form a nitrobacteria embedding carrier; then, in a reaction container, adding the nitrobacteria embedding carrier, introducing ammonia nitrogen sewage, and activating the nitrobacteria embedding carrier; and finally, after the carrier is activated successfully, inoculating sludge, and introducing sewage to be treated for aeration biochemical treatment. The nitrobacteria embedding carrier has better physical mechanical properties and chemical stability, resists biodegradation and abrasion, contains a large quantity of component materials beneficial to the nitrobacteria growth and reproduction, activity holding and mass transfer diffusion, and has the advantages of higher low-temperature ammonia nitrogen treating efficiency, short process flows, simple device and good treatment effect; and the existing treatment process is combined with a special carrier, thus the low-temperature nitrogen removal effect is well realized.

Description

The efficient cryogenic ammonia nitrogen sewage processing method
Technical field
The present invention relates to a kind of ammonia-nitrogen sewage treatment technology, relate in particular to a kind of efficient cryogenic ammonia nitrogen sewage processing method.
Background technology
The municipal effluent denitrification process is used comparatively generally activated sludge process and biomembrance process at present, but the method exists problems: (1) nitrobacteria is autotrophic bacteria, growth and breeding is slow, in Sludge System, can't compete with heterotrophic organism, be difficult to keep higher cell concn, the sludge retention time that needs to keep long is obtained preferably denitrification effect; (2) nitrobacteria is subject to the external environment impact, and is very responsive to environmental impact especially toxic impact; (3) nitrobacteria is in temperature during less than 15 ℃, active decrease, nitrated speed also obviously descends, when temperature was lower than 5 ℃, the vital movement of nitrobacteria almost stopped, and is in dormant state, so winter each sewage work ammonia nitrogen at all can't be up to standard.
Along with raising and " 12 " realization of plan of state sewage emission standard, it is imperative that the mark transformation is proposed by the municipal sewage plant.Present sewage disposal technology can make organism and the suspended substance in the sewage realize qualified discharge, and does not have preferably treatment process for ammonia nitrogen.Therefore, high-efficiency ammonia nitrogen degradation technology will become each municipal sewage plant and put forward the successful key of mark transformation, even process also most important for other ammonia nitrogen in waste water.
In the prior art, the technique that adopts in the sewage disposal of big and medium-sized cities mainly contains: A/O, A 2/ O, SBR and deformation technique thereof (CASS, CAST etc.), oxidation ditch, wherein A/O and A 2O section in the/O technique has traditional activated sludge process, bio-contact oxidation, MBBR, MBR etc.These techniques can realize all that at normal temperatures effective removal of ammonia nitrogen is also up to standard, but can not guarantee at low temperatures the water quality reaching standard discharging, the treatment process that is applied at present the municipal sewage plant mostly can be realized the ammonia nitrogen qualified discharge under the condition more than 12 ℃, can't ensure but when temperature is lower than 12 ℃ even when lower that water outlet is fully up to standard.
Summary of the invention
The efficient cryogenic ammonia nitrogen sewage processing method that the purpose of this invention is to provide a kind of good realization low-temperature denitrification effect.
The objective of the invention is to be achieved through the following technical solutions:
Efficient cryogenic ammonia nitrogen sewage processing method of the present invention comprises step:
At first, the employing macromolecular material is carrier, and the nitrobacteria of section's embedding within it microorganism is to form nitrobacteria embedding carrier;
Then, in reaction vessel, add described nitrobacteria embedding carrier, pass into and contain ammonia-nitrogen sewage, described nitrobacteria embedding carrier is activated;
After carrier activated successfully, seed sludge passed into and wants to dispose of sewage, and carried out aeration biochemical and processed.
As seen from the above technical solution provided by the invention, the efficient cryogenic ammonia nitrogen sewage processing method that the embodiment of the invention provides, because the embedding nitrifying bacteria vector has good physical and mechanical property and chemical stability, the antibiont degraded, wear-resistant, the embedding nitrifying bacteria vector contains and is beneficial in a large number nitrobacteria growth, the component substances of breeding and maintenance activity and mass transfer diffusion, has higher low temperature ammonia nitrogen processing efficiency, technical process is short, device is simple, treatment effect is good, to have treatment process now and special carrier combines, well realize the low-temperature denitrification effect.
Embodiment
The below will be described in further detail the embodiment of the invention.
Efficient cryogenic ammonia nitrogen sewage processing method of the present invention, its better embodiment comprises step:
At first, the employing macromolecular material is carrier, and the nitrobacteria of section's embedding within it microorganism is to form nitrobacteria embedding carrier;
Then, in reaction vessel, add described nitrobacteria embedding carrier, pass into and contain ammonia-nitrogen sewage, described nitrobacteria embedding carrier is activated;
After carrier activated successfully, seed sludge passed into and wants to dispose of sewage, and carried out aeration biochemical and processed, and water outlet can be up to standard.
Described nitrobacteria microorganism is from the bacterium liquid or the nitrifying sludge that contain nitrobacteria.
In the described activation step, stable the reaching more than 75% of the ammonia nitrogen removal frank of the nitrobacteria embedding carrier after to be activated namely activates successfully.
For newly-built Sewage Plant, the activation of embedding carrier is carried out or proceed step by step simultaneously with sludge seeding; Directly will activate in the embedding carrier input aeration tank for the reorganization and expansion Sewage Plant.Activation needs to carry out under the suitable the bread worm condition of nitrobacteria.
Efficient cryogenic ammonia nitrogen sewage processing method of the present invention both had been applicable to the processing of city domestic sewage, various industrial sewages, also was applicable to the improvement of rivers and lakes environmental wastewater, also can be used for rural sewage treatment, had higher low temperature ammonia nitrogen processing efficiency.Technical process is short, device is simple, treatment effect is good, will have treatment process now and special carrier combines, and well realizes the low-temperature denitrification effect.
The present invention draws and keeps the technical characterstic of MBBR technique, overcomes the technical problem in the MBBR technique, and the ammonia nitrogen processing efficiency is high, and effluent quality is good, and economic performance is good.
Embedding nitrifying bacteria vector among the present invention has good physical and mechanical property and chemical stability, and the antibiont degraded is wear-resistant.Embedding nitrifying bacteria vector of the present invention contains the component substances that is beneficial in a large number nitrobacteria growth, breeding and maintenance activity and mass transfer diffusion, thereby has high ammonia nitrogen removal frank.Embedding nitrifying bacteria vector of the present invention, the fixation of microbe ability is strong, and the biological load amount is large, and section can form biological bacterium colony group within it, and the nitrobacteria amount is larger than general filler or carrier; Embedded immobilization is processed the loss that reduces nitrobacteria simultaneously, thereby improves the effect that it processes ammonia nitrogen; The nitrobacteria of being fixed still can keep good biological activity at low temperatures.
Embodiment 1:
(1) nitrobacteria embedding carrier preparation: macromolecular material and other materials and solidifyingization of component mixing that become to grade that contain a large amount of nitrobacterias are obtained embedding nitrifying bacteria vector material.During use, be cut into fritter, namely obtain nitrobacteria embedding carrier.
(2) nitrobacteria embedding carrier activation: in indoor reaction vessel, add above-mentioned embedding nitrifying bacteria vector, pass into the ammonia nitrogen water sample of artificial preparation continuously or intermittently or the first heavy sewage of Sewage Plant carries out the aeration activation treatment, treat that stable the reaching more than 75% of ammonia nitrogen removal frank of embedding carrier namely activates successfully.
(3) nitrobacteria embedding carrier sewage disposal: will activate good carrier and directly drop in the aeration tank of sewage work, and carry out aeration biochemical and process.
Embodiment 2:
(1) nitrobacteria embedding carrier preparation: macromolecular material and other materials and solidifyingization of component mixing that become to grade that contain a large amount of nitrobacterias are obtained embedding nitrifying bacteria vector material.During use, be cut into fritter, namely obtain nitrobacteria embedding carrier.
(2) nitrobacteria embedding carrier activation: add above-mentioned embedding nitrifying bacteria vector in the aeration tank, the sewage that passes into continuously Sewage Plant carries out the aeration activation treatment, treats that stable the reaching more than 75% of ammonia nitrogen removal frank of embedding carrier namely activates successfully.
(3) nitre bacterium embedding carrier sewage disposal: seed sludge after the embedding carrier activates successfully, carry out aeration biochemical and process.
Embodiment 3:
(1) nitrobacteria embedding carrier preparation: macromolecular material and other materials and solidifyingization of component mixing that become to grade that contain a large amount of nitrobacterias are obtained embedding nitrifying bacteria vector material.During use, be cut into fritter, namely obtain nitrobacteria embedding carrier.
(2) activation of nitrobacteria embedding carrier and sewage disposal: in the aeration tank, add above-mentioned embedding nitrifying bacteria vector, and seed sludge, the sewage that passes into continuously Sewage Plant carries out aeration activation treatment and biochemical treatment, regularly measure the ammonia nitrogen removal frank of embedding carrier, until stable reaching more than 75% namely activates successfully.
After the aeration biochemical of for some time is processed, stable effluent quality, the effluent quality after the processing is as follows: water temperature<12 ℃; COD Cr<50mg/L, clearance is more than 90%; BOD 5<10mg/L, clearance is more than 95%; SS<10mg/L, clearance is more than 95%; NH 4 +N<5mg/L, clearance is more than 95%.
The below is listed below application examples to further specify the present invention according to example:
Application examples:
Adopt the present invention to process city domestic sewage, 10~14 ℃ of temperature, the average 55mg/L of influent ammonia nitrogen, water outlet ammonia nitrogen<1.5mg/L, clearance reaches more than 97.3%.
The present invention compares with the sewage disposal technology of generally using at present both at home and abroad has following advantage:
Processing speed is fast, and treatment effect is good;
The present invention adopts the embedded immobilization technology that nitrobacteria is fixed in the carrier, can significantly improve the charge capacity of nitrobacteria, improves biodegradation rate and processing efficiency, and effluent quality is good.This technology can be used for processing city domestic sewage, various industrial sewage, and the dosage that all can adjust as required carrier reaches national grade one discharge standard;
Nitrobacteria is active high, and breeding is fast, strong adaptability, and (<10 ℃) still have higher biological activity and processing efficiency at low temperatures;
The special construction of this embedding carrier still can be bred by raised growth nitrobacteria when temperature is low, have stronger thermal adaptability and higher biological activity, thereby make it have high subzero treatment efficient;
Take up an area little, less investment, running cost is low;
The nitrobacteria embedding is fixed in the carrier, has reduced the loss of nitrobacteria biomass, prolongs the residence time of nitrobacteria in the pond, has improved the ammonia nitrogen processing efficiency, can reduce hydraulic detention time, reduces the pond and holds and take up an area, thereby reduce investment; On the other hand, the embedding carrier presents fluidized state under the aeration effect, so that carrier has improved the aeration dissolved oxygen efficiency to the cutting action of bubble, reduces running cost;
Suitable old sewage work technological transformation and dilatation.
The present invention is applied to existing sewage work and carries out dilatation and technological transformation, and especially the sewage work of land used deficiency has advantage, need not moving capital construction facility, can realize.Operational management is convenient, and equipment can stop and can turn, and does not affect treatment effect, but how long all equipment stop plug and play, and treatment effect recovers at once.
The above; only for the better embodiment of the present invention, but protection scope of the present invention is not limited to this, anyly is familiar with those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.

Claims (4)

1. an efficient cryogenic ammonia nitrogen sewage processing method is characterized in that, comprises step:
At first, the employing macromolecular material is carrier, and the nitrobacteria of section's embedding within it microorganism is to form nitrobacteria embedding carrier;
Then, in reaction vessel, add described nitrobacteria embedding carrier, pass into and contain ammonia-nitrogen sewage, described nitrobacteria embedding carrier is activated;
After carrier activated successfully, seed sludge passed into and wants to dispose of sewage, and carried out aeration biochemical and processed.
2. efficient cryogenic ammonia nitrogen sewage processing method according to claim 1 is characterized in that, described nitrobacteria microorganism is from the bacterium liquid or the nitrifying sludge that contain nitrobacteria.
3. efficient cryogenic ammonia nitrogen sewage processing method according to claim 1 is characterized in that, in the described activation step, stable the reaching more than 75% of the ammonia nitrogen removal frank of the nitrobacteria embedding carrier after to be activated namely activates successfully.
4. according to claim 1 to 3 each described efficient cryogenic ammonia nitrogen sewage processing methods, it is characterized in that for newly-built Sewage Plant, the activation of embedding carrier is carried out or proceed step by step simultaneously with sludge seeding; Directly will activate in the embedding carrier input aeration tank for the reorganization and expansion Sewage Plant.
CN2012104918102A 2012-11-27 2012-11-27 Method for efficiently treating ammonia nitrogen sewage at low temperature Pending CN103011417A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104445595A (en) * 2014-11-05 2015-03-25 上海城市水资源开发利用国家工程中心有限公司 Process for reducing discharge of ammonia nitrogen in low-temperature urban wastewater
CN104478084A (en) * 2014-12-08 2015-04-01 天津城建大学 Method for enhancing biological denitrification and denitrification of low-temperature sewage in winter
CN105396565A (en) * 2015-12-25 2016-03-16 常州大学 Preparation method of epoxy resin embedded nitrobacterium high-concentration ammonia nitrogen wastewater adsorbent

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
《上海环境科学》 20031231 谢冰等 "硝化细菌的固定化研究" 第19-23页 1-4 第22卷, 第1期 *
谢冰等: ""硝化细菌的固定化研究"", 《上海环境科学》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104445595A (en) * 2014-11-05 2015-03-25 上海城市水资源开发利用国家工程中心有限公司 Process for reducing discharge of ammonia nitrogen in low-temperature urban wastewater
CN104445595B (en) * 2014-11-05 2016-05-04 上海城市水资源开发利用国家工程中心有限公司 The process that a kind of low temperature Ammonia Nitrogen in Sewage reduces discharging
CN104478084A (en) * 2014-12-08 2015-04-01 天津城建大学 Method for enhancing biological denitrification and denitrification of low-temperature sewage in winter
CN104478084B (en) * 2014-12-08 2016-02-17 天津城建大学 A kind of method improving winter low temperature saprobia denitrification denitrogenation
CN105396565A (en) * 2015-12-25 2016-03-16 常州大学 Preparation method of epoxy resin embedded nitrobacterium high-concentration ammonia nitrogen wastewater adsorbent

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Application publication date: 20130403