CN1030066A - Red nitric acid method of wastewater treatment and device thereof - Google Patents

Red nitric acid method of wastewater treatment and device thereof Download PDF

Info

Publication number
CN1030066A
CN1030066A CN 87104406 CN87104406A CN1030066A CN 1030066 A CN1030066 A CN 1030066A CN 87104406 CN87104406 CN 87104406 CN 87104406 A CN87104406 A CN 87104406A CN 1030066 A CN1030066 A CN 1030066A
Authority
CN
China
Prior art keywords
wastewater treatment
nitric acid
box car
red nitric
cylinder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 87104406
Other languages
Chinese (zh)
Other versions
CN1023208C (en
Inventor
廖勇兵
叶碎彩
陈明阳
肖新跃
罗建熙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Research Inst No6 Ministry Of Nuclear Industry
Original Assignee
Research Inst No6 Ministry Of Nuclear Industry
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Research Inst No6 Ministry Of Nuclear Industry filed Critical Research Inst No6 Ministry Of Nuclear Industry
Priority to CN 87104406 priority Critical patent/CN1023208C/en
Publication of CN1030066A publication Critical patent/CN1030066A/en
Application granted granted Critical
Publication of CN1023208C publication Critical patent/CN1023208C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Abstract

This method adopts the cylinder neutralisation, and its technical process is mixing, neutralization, clarification, oppositely aeration, filtration.Described flow process mainly realizes by process units such as water pump, lift, sour water handler, settling pond, shower nozzle, strainers.Described process unit except that strainer, all is installed in the box car, and box car is dragged by tow tractor, forms a kind of self-propelled wastewater treatment equipment.Be mainly used in and handle oxygenant nitric acid-20S waste water,, also can be used for handling alkaline waste water as changing reagent.

Description

Red nitric acid method of wastewater treatment and device thereof
The present invention relates to a kind of acid waste water, particularly red nitric acid method of wastewater treatment and device thereof are mainly used in and handle guided missile oxygenant nitric acid-2OS waste water.
For the processing of guided missile oxygenant nitric acid-2OS waste water, generally all adopt two kinds of methods (" Industrial Wastewater Treatment handbook, 496~507 pages, nineteen eighty-three workman press) at present both at home and abroad: (1) clay treatment method.Here it is in the corner, the method for digging pit in the barren hill and burying; (2) sea disposal method.Here it is with waste water storage in encloses container, encloses container is invested among the deep-sea again.These two kinds of methods all can cause secondary pollution because of without any physics and chemical treatment, destroy the eubiosis, influence safety, and waste time and energy.For the processing of general acid waste water, generally adopt at present two kinds of methods (" Industrial Wastewater Treatment engineering ", 349~350 pages, nineteen eighty-three University Of Xiangtan's chemical industry based environment engineering teaching and research room): during (1) flow lifting type expands and filter tank; (2) during speed changing type expands and filter tank.In these two kinds of filter tanks, all be that Wingdale is fixed, waste water by its down on flow through, be easy to generate like this that filtrate hardens and latch up phenomenon, cause reaction not exclusively, water outlet is difficult to reach national industrial discharge water quality standard.
Task of the present invention provides a kind of easy to use and low self-propelled red nitric acid method of wastewater treatment and device thereof of processing cost, be mainly used in and handle guided missile oxygenant nitric acid-2OS waste water, handling waste strength is 100~1000 mg/litre (being pH=2.8~1.8), and the discharge water after disposable processing reaches the industrial discharge standard.
Task of the present invention is achieved by the following technical solution.
At first be in the Wingdale neutralisation, make the filtration neutralisation that generally adopts at present into the cylinder neutralisation.This method technical process is mixing, neutralization, clarification, oppositely aeration and filtration.The function of each operation and being characterized as:
Mix: the waste water of wastewater disposal basin extracts with pump, flows to loading hopper through throttling valve, flow agent, and Wingdale is directly mentioned loading hopper by lift.
Neutralization: waste water flows to cylinder through pipeline and neutralizes with after Wingdale mixes in loading hopper.
The clarification: waste water and Wingdale in cylinder and after, flow to settling pond by its tail end mounting flange and pipeline.
Reverse aeration: waste water is extracted out by pump after neutralization, clarification, and through the reverse aeration of shower nozzle, jet flow is to strainer.
Filter: the treating water behind the reverse aeration of shower nozzle, in strainer, filter, remove suspended substance and silt particle, use water outlet limpid.
Next is to utilize prior art, selects, development one cover process unit, make its with decide technical process and desired result adapts.This process unit mainly comprises intake pump, lift, sour water handler, settling pond, goes out water pump, shower nozzle, strainer etc.Described process unit except that strainer, all is installed in the box car, and this box car is dragged by tow tractor, forms a kind of self-propelled wastewater treatment equipment.
Accompanying drawing has been described one embodiment of the present of invention.
Fig. 1. red nitric acid sewage treatment technology process synoptic diagram;
Fig. 2. red nitric acid waste water treatment process device plot plan;
Fig. 3. the self-propelled red nitric acid treatment unit synoptic diagram that gives up;
Fig. 4. neutralization cylinder output terminal sectional view;
Fig. 5. neutralization cylinder input terminus sectional view;
Fig. 6. the box car rear view.
Embodiment 1. red nitric acid wastewater treatment equipments.
This device is made of established technology device, bracing or strutting arrangement and towing mechanism three parts.Process unit comprises intake pump (1), single bucket elevator (2), sour water handler (3), settling pond (4), goes out water pump (5), shower nozzle (6), strainer (7).Bracing or strutting arrangement is box car (12).Towing mechanism is automobile (13).
Intake pump in the process unit (1) is used to extract red nitric acid waste water, adopts acidproof volute pump; Single bucket elevator (2) is used to extract Wingdale, 3~4 kilograms of every bucket load-carryings; Sour water handler (3) is used for and red nitric acid waste water, and it comprises four parts: supervisory control desk (8) ⒅ rushes down protruding grind or sharpen glass), loading hopper (10), deceleration device (11).Supervisory control desk (8) control total system, comprise intake pump (1), lift (2), in and cylinder (9), go out water pump (5) and room light, fan etc., make its co-ordination.In order to work conveniently, supervisory control desk (8) structure is made up of three parts: top is dashboard, is thereafter electric control box simultaneously, and the bottom is the work box.Settling pond (4) is used for clarification and water, adopts the steel sheet manufacturing, about 1 meter of volume.Go out the primary water after water pump (5) is used to extract processing, adopt the cast iron volute pump.
In order to prevent that water outlet from leaking, in and cylinder (9) output terminal be provided with mounting flange (14) and tightness system (15); In order to dwindle sour water handler (3) axial dimension so that install on the car, should make loading hopper support (16) as far as possible near in and cylinder (9), the obliquity of input channel (17) is increasing as far as possible, so that the charging smoothness.
Above-mentioned process unit except that strainer (7) build in the car wastewater disposal basin nearby outside, all the other devices (1)~(6) are installed in box car (12) lining.Box car (12) is dragged by tow tractor (13), forms a kind of self-propelled wastewater treatment equipment.
Box car (12) is converted by the supporting trailer of automobile, mainly is to make former trailer into bicycle shed (25), and bicycle shed one side is two fan open type gates (18), (19), during horizontal positioned, the platform of can working uses, and is movable column between two, has made things convenient for the in-vehicle device installation; A fan wicket (20) is respectively established in front and rear portions and central position, back in the another side, and (21), (22), the below, back door is provided with drawer type ladder (23), during vehicle to run, can be collected in the below, back door, pulls out use, convenient work when handling waste water.On the base plate of trailer chassis (24), be covered with acid-resistant rubber sheet, to guarantee safety.Bicycle shed (25) is a metal construction, and wherein skeleton is the hollow profile that steel sheet is made, and the canopy cover is made by the rust-preventing aluminum alloy plate, has both improved intensity, has alleviated weight again.
Embodiment 2. red nitric acid method of wastewater treatment
Reach state-set standard in order to ensure discharge water, adopt the cylinder neutralisation.Mixed waste water and Wingdale be the neutralization while rotating in cylinder, and neutralization reaction is fully carried out.When utilize this method to concentration be 100~1000 mg/litre guided missile oxygenant nitric acid-when 2OS waste water was handled, its corresponding process parameters was: 2~1 meters of wastewater treatment capacity (being the intake pump flow) 3/ hour; In and 20~10 rev/mins of drum rotational speeds; CaCO in the Wingdale 3Content 〉=90%; To the open drive first time, in should making He in the cylinder 100~200 kilograms Wingdale is arranged; In operation process, also should add 3~4 kilograms of Wingdales per half an hour.Concrete parameter and treatment effect are as follows:
Above-mentioned self-propelled wastewater treatment equipment has following advantage and effect:
1) maneuverability, easy to use: because device is self-propelled, so a table apparatus can be processed the waste water in several places, the Fixed Point Operation of flow is particularly favourable.
2) reagent source is wide, and universal performance is good: the domestic overwhelming majority all has lime stone inside the province, is conducive to the popularization of this device, and changes reagent, also can be used for processing alkaline waste water. Its use department spreads all over chemical industry, pharmacy, weaving, metallurgy, mine, factory, R﹠D institution and proving ground.
3) got rid of secondary pollution: owing to adopt cylinder neutralization, sufficient reacting; Adopt reverse aeration, removed the CO that produces in the reaction2, adopt fine sand to filter, removed suspension and dregs thereof, so discharge water pH value is higher, and fluorine in wastewater compound content there is certain removal ability, discharge water is limpid, transparent, meets national industrial discharge water quality standard fully.
4) reduced processing cost: general acid water processing cost; domestic is 0.861 yuan/ton; the annual fate 365 days (" sewage-treatment plant survey data compilation " of processing; 478~524 pages; Circumstances Protection Science Inst. of Jinzhou City); this device then is 0.60 yuan/ton, and annual processing fate is 200 days.

Claims (6)

1, a kind of acid waste water, especially red nitric acid wastewater treatment method adopt the Wingdale neutralisation, and feature of the present invention is that technical process comprises following operation: mixing, neutralization, clarification, oppositely aeration, filtration, neutralization employing cylinder neutralisation.
2, red nitric acid method of wastewater treatment as claimed in claim 1 is characterized in that when waste strength was 100~1000 mg/litre, corresponding process parameters was: 2~1 meters of wastewater treatment capacity (intake pump flow) 3/ hour; In and 20~10 rev/mins of drum rotational speeds; CaCO in the Wingdale 3Content 〉=90%; To the open drive first time, in should making He in the cylinder 100~200 kilograms of Wingdales are arranged, in operation process, also should add 3~4 kilograms of Wingdales per half an hour.
3, the used device of a kind of red nitric acid method of wastewater treatment, it is characterized in that by process treatment device intake pump (1), lift (2), sour water handler (3), settling pond (4), go out water pump (5), shower nozzle (6), strainer (7), bracing or strutting arrangement box car (12), actuator tow tractor (13) are formed, described process treatment device is except that strainer (7), all be installed in box car (12) lining, box car (12) is dragged by tow tractor (13), forms a kind of self-propelled wastewater treatment equipment.
4, red nitric acid wastewater treatment equipment as claimed in claim 3 is characterized in that sour water PCC processor control console (8) top is dashboard, is thereafter electric control box, and the bottom is the work box; In the sour water handler and cylinder (9) output terminal be provided with mounting flange (14) and tightness system (15).
5, red nitric acid wastewater treatment equipment as claimed in claim 4 is characterized in that box car (12) mainly comprises gate (18), (19), wicket (20), (21), (22), drawer type ladder (23), chassis (24) and bicycle shed (25).
6, red nitric acid wastewater treatment equipment as claimed in claim 5 is characterized in that bicycle shed (25) is metal construction, and wherein skeleton is the hollow profile that steel sheet is made, and the canopy cover is made by the rust-preventing aluminum alloy plate.
CN 87104406 1987-06-26 1987-06-26 Process and equipments for treating waste liquor of red nitric acid Expired - Fee Related CN1023208C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 87104406 CN1023208C (en) 1987-06-26 1987-06-26 Process and equipments for treating waste liquor of red nitric acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 87104406 CN1023208C (en) 1987-06-26 1987-06-26 Process and equipments for treating waste liquor of red nitric acid

Publications (2)

Publication Number Publication Date
CN1030066A true CN1030066A (en) 1989-01-04
CN1023208C CN1023208C (en) 1993-12-22

Family

ID=4814861

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 87104406 Expired - Fee Related CN1023208C (en) 1987-06-26 1987-06-26 Process and equipments for treating waste liquor of red nitric acid

Country Status (1)

Country Link
CN (1) CN1023208C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040345A (en) * 2010-11-17 2011-05-04 宋洪义 Device for converting gypsum powder in waste water
CN106431506A (en) * 2016-09-13 2017-02-22 广沣金源(北京)科技有限公司 Nitrogen fertilizer containing amide nitrogen and nitrate nitrogen and method for treating concentrated nitric acid contained wastewater

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040345A (en) * 2010-11-17 2011-05-04 宋洪义 Device for converting gypsum powder in waste water
CN106431506A (en) * 2016-09-13 2017-02-22 广沣金源(北京)科技有限公司 Nitrogen fertilizer containing amide nitrogen and nitrate nitrogen and method for treating concentrated nitric acid contained wastewater

Also Published As

Publication number Publication date
CN1023208C (en) 1993-12-22

Similar Documents

Publication Publication Date Title
CN100390081C (en) Process method for waste water containing nitrobenzene and aniline
CN206915935U (en) Emulsifying liquid waste water processing system
CN102206011B (en) Coagulation-oxidation combined type method for processing sewage
CN105293822B (en) Coal chemical industry sewage disposal fundamental technology
CN208120937U (en) A kind of papermaking wastewater treatment system
CN1023208C (en) Process and equipments for treating waste liquor of red nitric acid
CN102145928B (en) Efficient flocculation method and device for sewage treatment
CN102276112A (en) Method for treating flotation wastewater of non-ferrous metal ores
CN219279683U (en) Strip mine coal mining wastewater treatment device
CN107758916A (en) A kind of modularization integrated technology process suitable for acid wastewater in mine processing
CN111940478A (en) Equipment for improving permeability of clay soil and efficiently leaching heavy metal pollutants
CN107555719A (en) Industrial sewage treatment system
CN206783436U (en) A kind of accelerator
CN105502736A (en) Metallurgical wastewater treatment system
CN206970432U (en) A kind of online abatement system of sludge
CN104773880A (en) Sewage treatment technology and equipment for well drilling
CN105293821B (en) General chemical industry sewage disposal fundamental technology
CN105293660B (en) Pulping and paper-making industry sewage handles fundamental technology
CN208087423U (en) Painting wastewater processing equipment
CN207943962U (en) A kind of coating wastewater processing unit
CN216798808U (en) A palirrhea type pipe chute settling tank for flotation reagent
CN216997854U (en) Reaction device for treating garbage leakage liquid
CN105417836B (en) Food and cultivation industry sewage disposal fundamental technology
CN212450975U (en) Phosphorus-containing wastewater treatment device
CN214781229U (en) Hydrogen peroxide catalytic oxidation sewage treatment equipment

Legal Events

Date Code Title Description
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C06 Publication
PB01 Publication
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee