CN102998250A - Experiment device for axial loading high-temperature stress corrosion test of metal material - Google Patents
Experiment device for axial loading high-temperature stress corrosion test of metal material Download PDFInfo
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- CN102998250A CN102998250A CN2012104761036A CN201210476103A CN102998250A CN 102998250 A CN102998250 A CN 102998250A CN 2012104761036 A CN2012104761036 A CN 2012104761036A CN 201210476103 A CN201210476103 A CN 201210476103A CN 102998250 A CN102998250 A CN 102998250A
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Abstract
The invention discloses an experiment device for an axial loading high-temperature stress corrosion test of a metal material. The experiment device comprises a medium bottle, two rubber seal cones, two gaskets, an upper thread port cover, a lower thread port cover, a rubber seal plug, a U-shaped heating tube, a reflux condensing tube, a resistance wire, a temperature control system, a ceramic tube, binding posts with control switches, and wires, wherein the gaskets are arranged on the connections of the thread port covers and thread ports, a lower drip mouth is adopted as circular reflux condenser, and the opening part of the U-shaped heating tube penetrating through the inner part of the medium bottle is arranged outside the bottle. The experiment device has the advantages of completely avoiding the problems of leakage/leaking of a corrosive medium in the process of the axial loading high-temperature stress corrosion test, constantly maintaining the requirements of concentration and temperature of the medium, preventing the medium from spattering when replenishing volatilized water is replenished, preventing the test from being improperly stopped, ensuring the safety and accuracy of the test, increasing the test efficiency and being good in using effect.
Description
Technical field
The present invention relates to a kind of metallic material corrosion Test And Check Technology, particularly a kind of environmental device that axially loads the high temperature stress corrosion test for metal material.
Background technology
Metal material has the possibility that delayed fracture and fracture occur voluntarily under tension and specific media environment double action.The low stress corrosion brittle failure that it produces has unpredictable character, usually causes the generation of accident and the loss of lot of materials, uses to engineering and has brought great potential safety hazard and property loss.For this reason, the stress corrosion crack problem of metal material is the key areas of material antiseptic and safe and reliable Journal of Sex Research, and stress corrosion (cracking) test is the important foundation of stress corrosion research, its result's accuracy directly affect engineering reliably whether.
At present, the metal material stress corrosion (cracking) test of carrying out both at home and abroad, mainly be that metal material processing is become specific sample (such as tensile sample, C type sample, bend specimen etc.), place specific simulated environment medium (such as seawater, fluidizing chlorination magnesium solution, water vapour), and by charger sample imposed load (constant stress, constant strain and slow strain rate) is tested.Relevant standard mainly contains GB15970 series, ASTM G49 and YB5362.For charger, mainly purchase from the market at present the lasting machine of ready-made dead load or slow strain rate test machine; For environmental device, each unit carries out designed, designed according to the test objective of oneself.In the standard, design for environmental device has only provided rough schematic, do not further specify and how to design and to prevent the seepage of corrosive medium/leakages in (the general time of stress corrosion (cracking) test is all long) process, to keep the constant of medium temperature and concentration in test, and these are no matter security or accuracys that collateral security is tested are all extremely important.For normal temperature or the low temperature stress corrosion design with the media environment device, the problems referred to above also are easier to avoid, because 1. the problem of seepage can be carried out encapsulation process to sample and environmental device binding site by silicon rubber and solved; 2. when low temperature was tested, resistance wire working time interval was large, long service life, joined the higher temperature control system of a cover precision, just the requirement of energy warranty test temperature; 3. the water in the medium volatilizees slowlyer in low temperature environment, and the water that regularly replenishes volatilization in the media environment device is to initial metal line (generally once a day), just the concentration of control medium effectively.And for the design of the environmental device that is used for the high temperature stress corrosion test, particularly be used to up and down the axial loading stress corrosion of wearing with the design of environmental device, the problems referred to above make the testing crew headache always.This be because: the ⑴ leakage problems: silicon rubber or other glue sealing effectiveness in hot environment weaken, and seepage/leakage phenomenon often occurs, cause the testing equipment corrosion, and process of the test is also very dangerous.⑵ temperature constant problem: resistance wire only works long hours even continuous working (such as the stress corrosion (cracking) test of fluidizing chlorination magnesium), guarantee high-temperature medium temperature constant, therefore be easy to burn out, as can not in time changing or keep in repair, will cause testing non-normal termination; ⑶ constant concentration and the medium problem of splashing: the water in the medium volatilizees when high temperature comparatively fast, supplementing water in the medium automatically and continuously, and on the one hand wayward magnitude of recruitment and the balance of waving the method amount, it is constant that concentration is difficult to keep; Also be prone on the other hand water at low temperature and add the phenomenon that medium that high-temperature medium causes splashes, process of the test is very dangerous.
Summary of the invention
Technical matters to be solved by this invention provides a kind of environmental device that axially loads the high temperature stress corrosion test for metal material, can not only avoid high-temperature medium seepage/leakage problem fully, constant maintenance concentration of medium and can when replenishing volatilization water, not cause that medium splashes, and make things convenient for simultaneously the replacing and the maintenance that are burned resistance wire in the process of the test, guarantee exactly the medium temperature requirement, avoid the non-normal termination of testing.
For the purpose that realizes solving the problems of the technologies described above, the present invention has adopted following technical scheme:
A kind of environmental device that axially loads the high temperature stress corrosion test for metal material of the present invention comprises medium bottle, two rubber seal cones, two packing rings, upper screw thread lid, lower screw thread lid, rubber seal plug, U-shaped heating tube, reflux condensing tube, resistance wire, temperature control system; Temperature control system comprises controller, thermometer or thermopair;
The medium bottle has screw thread mouth, lower screw thread mouth, thermometer mouth, reflux condenser mouth and sample, upper and lower screw thread mouth symmetry be distributed in the medium bottle on the central authorities that go to the bottom, the both sides that are distributed in screw thread mouth of thermometer mouth and reflux condensation mode mouth of pipe symmetry; The upper screw thread mouth of medium bottle, lower screw thread mouth, thermometer mouth and reflux condenser mouth internal diameter are designed to taper, and the vertex of a cone is in bottle, and the cone end is at bottleneck; The upper screw thread mouth of medium bottle, lower screw thread mouth internal diameter are consistent with rubber seal cone external diameter shape, and external diameter is consistent with upper screw thread lid and lower screw thread lid screw thread; Thermometer mouth internal diameter is consistent with rubber seal plug external diameter shape; Reflux condensation mode mouth of pipe internal diameter is consistent with the reflux condensing tube external diameter and process through ground;
Sample passes the upper and lower screw thread mouth of medium bottle, two relatively symmetrical upper and lower screw thread mouths that are through on the sample and are fixed on the medium bottle of rubber seal cone microcephaly, place a packing ring two rubber seal cones successively, and upper and lower screw thread lid is screwed on the upper and lower screw thread mouth of medium bottle; In the process of tightening, because packing ring can tightly withstand the rubber seal cone, thereby guaranteed to cooperate closely between rubber seal cone and upper and lower screw thread mouth and sample and the rubber seal cone, prevent high temperature corrosion medium seepage/leakage leakage;
Thermometer passes rubber seal plug, inserts the thermometer mouth of medium bottle, and solution in the lower end contact medium bottle of thermometer is monitored and controlled medium temperature by controller; After connecting, reflux condensing tube and running water pipe be inserted on the reflux condensation mode mouth of pipe of medium bottle; The inside of medium bottle is furnished with U-shaped heating tube, and its uncovered position is in the bottle outside, and resistance wire is through U-shaped heating tube inside and two and is exposed at the bottle outside and is connected with power supply lead wire.Can make things convenient for like this to change at any time or keep in repair in the process of the test and burn out resistance wire.
For preventing that water under the reflux condenser condensation from being in the solution that droplet-like splashes into the medium bottle, cause splashing of high temperature corrosion medium, the structure of reflux condenser can for: condenser water jacket length is no less than 250mm; The lower drip of reflux condenser is circular, and ground length and condenser connector height are in full accord.Can guarantee that like this water that replenishes drops down in the dielectric wall along the bottle wall, prevent that the water that replenishes from being droplet-like, causes splashing of high temperature corrosion medium; Guarantee simultaneously condensation effect.
The environmental device that axially loads the high temperature stress corrosion test for metal material of the present invention, its preferred technology technical scheme is: medium bottle, U-shaped heating tube high temp glass system; Packing ring, upper screw thread lid, lower screw thread lid teflon system; Rubber seal cone and rubber seal plug fluororubber system.Can guarantee that like this environmental device is high temperature resistant, anticorrosion.
The environmental device that axially loads the high temperature stress corrosion test for metal material of the present invention, be the convenience that guarantees that environmental device uses, its improved technical scheme also can be: the electric wire that is connected with resistance wire links to each other with power supply by the binding post with gauge tap.Make things convenient for like this in the process of the test whether the replacing of resistance wire and maintenance or control medium are heated.
The environmental device that axially loads the high temperature stress corrosion test for metal material of the present invention, thermometer or thermopair selection principle are: boiling temperature medium thermometer, non-boiling temperature medium thermopair.
A kind of environmental device that axially loads the high temperature stress corrosion test for metal material, be the security that guarantees that better environmental device uses, prevent the resistance wire that exposes ignite other article or calcination operator, its further improved technical scheme also can be: expose ceramic pipe on heating tube external resistance silk braid.
These technical schemes also can make up mutually or combination, thereby reach better technique effect.
By adopting technique scheme, the present invention has following beneficial effect:
The invention that axially loads the environmental device of high temperature stress corrosion test for metal material of the present invention, not only avoided the seepage/leakage problem of corrosive medium in the axial loading high temperature stress corrosion test process fully, and constant concentration of medium, the temperature requirement of having kept causes when having prevented additional volatilization water that medium splashes.Avoid the non-normal termination of test, guaranteed security and the accuracy of test.
The technical scheme of solution high temperature corrosion medium seepage/leakage problem provided by the invention is is not only loaded and unloaded sample convenient, and owing to not using fluid sealant, has avoided waiting for the process of glue drying, has improved test efficiency.This scheme is axially being used in normal temperature stress corrosion and the corrosion fatigue test, and result of use is also better, and it also extends in the design of other homologous series environmental devices.
Technique effect not only is embodied in the convenience of security, accuracy and the operation of axial loading stress corrosion test itself, is also embodied in its partial design thinking applying in other isonomic environmental device designs.
Description of drawings
Fig. 1 is the structural representation of reflux condenser.
Fig. 2 is a kind of environmental device schematic diagram that axially loads the high temperature stress corrosion test for metal material of invention.
Among the figure, 1, the modified reflux condensing tube, 2, upper screw thread lid, 3, packing ring, 4, the rubber seal cone, 5, sample, 6, condenser connector, 7, U-shaped heating tube, 8, the medium bottle, 9 times screw thread lids, 10, lower screw thread mouth, 11, resistance wire, 12, the thermometer connector, 13, upper screw thread mouth, 14 rubber seal plugs; 15, thermometer or thermopair, 16, with the binding post of gauge tap, 17, electric wire, 18, ceramic pipe, 19, plug, 20, lower drip.
Embodiment
Below in conjunction with accompanying drawing this patent is further explained.But the protection domain of this patent is not limited to concrete embodiment.
As shown in Figure 2, a kind of installation procedure that axially loads the environmental device of high temperature stress corrosion test for metal material of the present invention is: sample 5 to be tested is by upper screw thread mouth 13, lower screw thread mouth 10 passes medium bottle 8, and the working position is inner in media slot, 2 rubber seal cone 4(circular specimens are with flexible rubber cone body, plate tensile sample is with flat logical rubber cone body) microcephaly is inserted in the sample holder position from the two ends interference of sample relatively respectively, adjust distance between 2 rubber seal cones, it can just be filled in upper, on the lower screw thread mouth, pass packing ring 3 from the upper end of sample successively, upper screw thread lid 2, tighten screw thread lid 2, packing ring 3 is passed in the bottom of sample, lower screw thread lid 9 is tightened lower screw thread lid 9.Sample two is separately fixed at the upper lower clamp of testing machine, the thermopair 15(of thermometer or temperature regulating device is boiling temperature medium thermometer wherein, non-boiling temperature medium is with the thermopair of temperature regulating device) interference pass rubber seal plug 14 and the medium that inserts in the medium bottles 8 by temperature regulating device connector 12 in, modified reflux condensing tube 1 is connected on the condenser connector 6.Resistance wire 11 end of U-shaped heating tube 7 from the assay flask penetrates, the other end passes, notice guaranteeing that resistance wire 11 is stretching at the crooked position silk of U-shaped pipe, reduce the thermal value of crooked position, put ceramic pipe 18 at the resistance wire 11 that exposes outside U-shaped heating tube, link to each other with the electric wire 17 of drawing on the binding post 16 with gauge tap, plug 19 is inserted in the supply sockets.
Embodiment 1: the stress corrosion (cracking) test of boiling temperature medium solution
Take the stress corrosion (cracking) test of corrugated stainless steel tubing fluidizing chlorination magnesium as example.Measure diameter (circular specimen) or the length and width (plate tensile sample) of sample working portion, sectional area and the institute of calculating the sample working portion add load; According to the magnesium chloride of the big or small weighing appropriate amount of medium bottle and put into the medium bottle; Signal and installation detailed description according to accompanying drawing 2 are installed in experiment environment apparatus and sample on the loading tester; Slowly add a small amount of high purity water from the condenser mouth, be advisable to flood magnesium chloride; Depress the binding post gauge tap on " ON " position, begin environmental device is heated; Viewing test temperature in the process, temperature surpass when temperature required, slowly add a small amount of high purity water from the condenser mouth, so repeatedly repeatedly, until the temperature of fluidizing chlorination magnesium reaches extremely temperature required; At this moment, sample is loaded into preset value, the on-test timing; In the process of the test, blow if resistance wire occurs, then depress the heated beam switch on " OFF " position, the resistance wire that more renews guarantees heating continuously of medium; Sample fracture or reach the test Preset Time, test stops, the record test period; Treat that medium temperature drops to approximately 70 ℃, take off condenser and thermometer, unload sample and environmental device from testing machine, with magnesium chloride solution in the tap water diluent media bottle and pour out, turn on up and down screw thread lid, take out sample from the medium bottle, scouring media bottle, rubber seal cone and rubber seal plug are waited for next test.
Embodiment 2: the stress corrosion (cracking) test of non-boiling temperature medium solution
Take 80 ℃ of low concentration NaOH of high-strength steel bolt stress corrosion (cracking) test as example.Compare with embodiment 1, difference is: ⑴ does not need the NaOH of weighing appropriate amount and puts into the medium bottle, but prepare the NaOH solution for later use of respective concentration before installing according to accompanying drawing 2; ⑵ when press accompanying drawing 2 installation, do not use 15 thermometers, but the thermopair of 15 temperature control systems; ⑶ after installed, what fall from condenser 12 was not high purity water, but the NaOH solution of the respective concentration for preparing.⑷ do not need repeatedly repeatedly slowly to add a small amount of high purity water until reach temperature required from the condenser mouth.Other process and embodiment 1 are same.
Attention: embodiment 1 is because the medium temperature of fluidizing chlorination magnesium stress corrosion is to guarantee by control medium concentration with the operation difference of embodiment 2, i.e. the different principle of the boiling temperature of variable concentrations medium; Simultaneously, the preparation of test(ing) medium need be adjusted gradually by observing medium temperature.
Claims (6)
1. a metal material axially loads the environmental device of high temperature stress corrosion test, it is characterized in that: comprise medium bottle, two rubber seal cones, two packing rings, upper screw thread lid, lower screw thread lid, rubber seal plug, U-shaped heating tube, reflux condensing tube, resistance wire, temperature control system; Temperature control system comprises controller, thermometer or thermopair;
The medium bottle has screw thread mouth, lower screw thread mouth, thermometer mouth, reflux condenser mouth and sample, upper and lower screw thread mouth symmetry be distributed in the medium bottle on the central authorities that go to the bottom, the both sides that are distributed in screw thread mouth of thermometer mouth and reflux condensation mode mouth of pipe symmetry; The upper screw thread mouth of medium bottle, lower screw thread mouth, thermometer mouth and reflux condenser mouth internal diameter are designed to taper, and the vertex of a cone is in bottle, and the cone end is at bottleneck; The upper screw thread mouth of medium bottle, lower screw thread mouth internal diameter are consistent with rubber seal cone external diameter shape, and external diameter is consistent with upper screw thread lid and lower screw thread lid screw thread; Thermometer mouth internal diameter is consistent with rubber seal plug external diameter shape; Reflux condensation mode mouth of pipe internal diameter is consistent with the reflux condensing tube external diameter and process through ground;
Sample passes the upper and lower screw thread mouth of medium bottle, two relatively symmetrical upper and lower screw thread mouths that are through on the sample and are fixed on the medium bottle of rubber seal cone microcephaly, place a packing ring two rubber seal cones successively, and upper and lower screw thread lid is screwed on the upper and lower screw thread mouth of medium bottle;
Thermometer passes rubber seal plug, inserts the thermometer mouth of medium bottle, and solution in the lower end contact medium bottle of thermometer is monitored and controlled medium temperature by controller; After connecting, reflux condensing tube and running water pipe be inserted on the reflux condensation mode mouth of pipe of medium bottle; The inside of medium bottle is furnished with U-shaped heating tube, and its uncovered position is in the bottle outside, and resistance wire is through U-shaped heating tube inside and two and is exposed at the bottle outside and is connected with power supply lead wire.
2. described metal material axially loads the environmental device of high temperature stress corrosion test according to claim 1, and it is characterized in that: the structure of described reflux condenser is: condenser water jacket length is no less than 250mm; The lower drip of reflux condenser is circular, and ground length and condenser connector height are in full accord.
3. described metal material axially loads the environmental device of high temperature stress corrosion test according to claim 2, it is characterized in that: described medium bottle, U-shaped heating tube high temp glass system; Packing ring, upper screw thread lid, lower screw thread lid teflon system; Rubber seal cone and rubber seal plug fluororubber system.
4. described metal material axially loads the environmental device of high temperature stress corrosion test according to claim 1, and it is characterized in that: the electric wire that is connected with resistance wire links to each other with power supply by the binding post with gauge tap.
5. described metal material axially loads the environmental device of high temperature stress corrosion test according to claim 1, and it is characterized in that: described thermometer or thermopair selection principle are: boiling temperature medium thermometer, non-boiling temperature medium thermopair.
6. described metal material axially loads the environmental device of high temperature stress corrosion test according to claim 1, it is characterized in that: expose ceramic pipe on heating tube external resistance silk braid.
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CN108519321B (en) * | 2016-06-16 | 2020-07-28 | 天津大学 | Method for testing by using welding joint force-corrosion coupling testing device |
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