CN102994055B - Method for preparing filtrate reducer hydrolyzed polyacrylonitrile for drilling fluid - Google Patents
Method for preparing filtrate reducer hydrolyzed polyacrylonitrile for drilling fluid Download PDFInfo
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- 239000012530 fluid Substances 0.000 title claims abstract description 34
- 229920002239 polyacrylonitrile Polymers 0.000 title claims abstract description 33
- 238000005553 drilling Methods 0.000 title abstract description 30
- 239000000706 filtrate Substances 0.000 title abstract description 11
- 238000000034 method Methods 0.000 title abstract description 11
- 239000003638 chemical reducing agent Substances 0.000 title abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 17
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 14
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- 241000219146 Gossypium Species 0.000 claims abstract description 11
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- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 8
- 229940106681 chloroacetic acid Drugs 0.000 claims abstract description 7
- 238000006266 etherification reaction Methods 0.000 claims abstract description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 21
- 239000000654 additive Substances 0.000 claims description 17
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- 238000005507 spraying Methods 0.000 claims description 2
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- 239000002994 raw material Substances 0.000 abstract description 8
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- 230000009467 reduction Effects 0.000 abstract description 2
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- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000012267 brine Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
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- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
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- 239000004215 Carbon black (E152) Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
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- 239000004584 polyacrylic acid Substances 0.000 description 2
- 235000007686 potassium Nutrition 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
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- 239000011777 magnesium Substances 0.000 description 1
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- -1 polypropylene ammonium salt Polymers 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
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Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a method for preparing filtrate reducer hydrolyzed polyacrylonitrile for drilling fluid. The filtrate reducer hydrolyzed polyacrylonitrile comprises the raw materials in parts by weight: 400-500 parts of refined cottons, 90-110 parts of caustic soda, 15-25 parts of chloroacetic acid and 400-500 parts of acrylic fibers, wherein the raw materials are subjected to alkalization, etherification and hydrolysis reaction to obtain the filtrate reducer hydrolyzed polyacrylonitrile treating agent for the drilling fluid. The filtrate reducer hydrolyzed polyacrylonitrile for drilling fluid prepared by the method is simple in preparation process, short in reaction time, low in production energy consumption and facilitates industrial production; the filtrate reducer hydrolyzed polyacrylonitrile is applied to the drilling fluid because of small addition amount, high salt resistance, high-temperature resistant performance and good filtrate reduction effect; and the filtrate reducer hydrolyzed polyacrylonitrile is applied to offshore drilling and saturated salt water, so that the performance is stable when the drilling operation is carried out, and the viscosity of the drilling fluid is not increased.
Description
Technical field
The present invention relates to a kind of preparation method of fluid loss additive for boring fluid, be specifically related to a kind of preparation method of fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt.
Background technology
In petroleum drilling operation, will there is diafiltration while flowing through pervious course in drilling fluid under pressure, cause drilling fluid liquid phase to infiltrate stratum, and this process is referred to as " dehydration ".If dehydration can not be well controlled, a large amount of dehydrations enters stratum and not only induces well unstability, and can produce infringement to hydrocarbon zone, and the effective ways that address this problem at present add fluid loss agent exactly in drilling fluid.
Fluid loss agent is again water retaining, and its function is the stability that ensures drilling mud performance, reduces the filter loss of drilling mud and the apparent viscosity of drilling fluid, and reduces harmful liquid leak-off to stratum, the Simultaneous Stabilization borehole wall, guarantee hole diameter rule.Fluid loss agent product can be divided into two large classes: particulate material and water-soluble polymer and organic materials.What use the earliest is particulate material as wilkinite, pitch, silicon ash, Pericarppium arachidis hypogaeae, latex etc., but practical application is now less.At present, most of fluid loss agent product in practical application is water-soluble modified natural polymer and synthetic macromolecular material, mainly contains the multi-component copolymer product of carboxymethyl cellulose class, treated starch, resol class, brown coal class, hydrolyzed polyacrylonitrile class and chemosynthesis.Wherein, hydrolyzed polyacrylonitrile class is because cost is low, processing simple, the effective favor that enjoys user of heat and salinity tolerance.
Along with the exhaustion of the increase to hydrocarbon resources requirement and Shallow Oil-Gas resource, exploration, exploitation to deep formation hydrocarbon resources are more and more paid attention to, and ultra deep well wellbore construction quantity increases year by year.But along with the increase of depth of stratum; formation temperature also can more be come also high; and in drilling process, often can meet with saliferous strata, this just requires filtrate reducer for drilling fluid must have the filtrate loss controllability under good heat-resisting property, anticalcium magnesium ion pollutant performance and high-density simultaneously.But existing hydrolyzed polyacrylonitrile series products, only has certain temperature resistance and falls filtration effect, and anti-salt and caving-preventing characteristic are unsatisfactory.In addition,, because the raw material of process water depolymerization vinyl cyanide product is generally waste and old weaving acrylic fibers, the character of raw material often changes, and has also affected to a certain extent the stability of product performance.Therefore, overcome the deficiency of hydrolyzed polyacrylonitrile series products performance, the hydrolyzed polyacrylonitrile class fluid loss agent that research is applicable to deep-well, high temperature resistance, anti-salt, anticalcium magnesium becomes the direction that additive for drilling fluid is researched and developed.
CN10275772A has announced anti-ultrahigh-temperature salt resistant filter loss reduction agent and preparation method thereof for a kind of drilling fluid, is made up of the raw material of following weight proportioning: 20 ~ 50 parts of acrylic fibres waste silks; 5 ~ 20 parts, AMPS polymkeric substance; 10 ~ 30 parts of polyacrylic acid potassiums; 5 ~ 20 parts of calcium polyacrylate (CPA)s; 1 ~ 10 part of polyacrylamide; 10 ~ 30 parts of HF-342; 10 ~ 40 parts of HY-508; 2 ~ 15 parts of linking agents; 500 ~ 1000 parts, water.Take water and acrylic fibres waste silk by described weight part ratio, added in the reactor of stirring, seal and be warming up to 230 ~ 250 DEG C, react 7 ~ 10 hours, be cooled to below 60 DEG C; In reactor, add the AMPS polymkeric substance, polyacrylic acid potassium, calcium polyacrylate (CPA), polyacrylamide, HF-342, HY-508 and the linking agent that take by described weight part ratio, seal and be warming up to 180 ~ 200 DEG C, stirring reaction 4 ~ 6 hours; Blowing, products therefrom drying gets product.This invention has the function of anti-240 DEG C of high temperature, antisaturation salt solution, seawater, compound salt solution, can effectively reduce drilling mud filter loss, not tackify.But the method material used is more, complicated process of preparation, complex steps.
CN101117573A discloses a kind of non-fluorescence collapse-proof fluid loss additive for oil exploration drilling fluid, is prepared and is obtained by coal gangue 500kg, useless eyeball synthetic fibre silk 270kg, caustic soda 100kg, formaldehyde 20kg, sub-sodium 30kg, sodium bisulfite 30kg, phenol 50kg, water 3000kg.This invention product cost that processes raw material is low, compared with similar products, can reduce drilling mud cost 30%; In drilling process, consumption is few, and the dosage in fresh water is 1%, dosage 3% in seawater, and performance is better than the performance of all valchovite series products.Its drawback is that caving-preventing characteristic and viscosity-reducing performance are general, and environmental-protecting performance is not good.
Summary of the invention
The technical issues that need to address of the present invention are to provide that a kind of preparation technology is simple, the preparation method of high temperature resistance, anti-salt, fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt that filtrate loss controllability is good.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is:
A preparation method for fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt, each material is counted by weight: 400 ~ 500 parts of purified cottons, 90 ~ 110 parts, caustic soda, 15 ~ 25 parts of Mono Chloro Acetic Acids, 400 ~ 500 parts of acrylic fibers; Comprise the steps:
A, alkalization, the purified cotton of getting proportional quantity adds in reactor, the caustic soda of corresponding proportional quantity is added water and is configured to the caustic soda soln of concentration 10 wt % ~ 50wt%, and added in described reactor, and reactor is warming up to alkalization temperature, and constant temperature stirs 2 ~ 3 hours;
B, etherificate, get Mono Chloro Acetic Acid by proportioning and add water and be configured to the chloroacetic acid solution of 5 wt% ~ 20 wt%, added in aforesaid reaction vessel, is warming up to etherification temperature, and constant temperature stirs 2 ~ 3 hours;
C, hydrolysis add the acrylic fibers of corresponding proportional quantity in aforesaid reaction vessel, are warming up to hydrolysis temperature, and isothermal reaction 6 ~ 8 hours, obtains fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt glue;
D, the dry pulvis of making of finally spraying.
Further improvement of the present invention is: the polymerization temperature of described alkalization, etherificate is 70 DEG C ~ 90 DEG C.
Further improvement of the present invention is: described hydrolysis temperature is 190 DEG C ~ 210 DEG C.
Owing to having adopted technique scheme, the technical progress that the present invention obtains is:
The prepared hydrolyzed polyacrylonitrile ammonium salt of the present invention, compared with conventional polyacrylonitrile ammonium salt series products, has more good anti-salt, high temperature resistance and falls filtration effect, falls filter loss and can reach 10ml/30min; Can in marine drilling and saturated brine drilling environment, use; And performance is more stable, do not increase drilling fluid viscosity; Add-on is less, only add 1% can be effective, and the hydrolyzed polyacrylonitrile ammonium salt of other types need add 3% just can be effective.
The present invention is taking purified cotton and acrylic fibers as raw material, first purified cotton and caustic soda are alkalized, and then with Mono Chloro Acetic Acid generation etherificate, make to introduce sodium carboxymethyl group on its cellulose molecular chain, obtain a kind of water-soluble cellulose derivative, and in backward this water-soluble cellulose derivative system, add acrylic fibers, make it that cohydrolysis reaction occur, different molecular chains is connected together to the fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt treatment agent obtaining.Water-soluble cellulose derivative has thickening, dispersion, film forming, coheres and the characteristics such as protective colloid; the present invention has utilized the above-mentioned advantage of water-soluble cellulose derivative; prepared hydrolysis polypropylene ammonium salt can not only make filter loss significantly decline; also do not affect the solubility of hydrolysate simultaneously; and preparation technology is simple, transformation efficiency is high, cost is low, without aftertreatment, without the three wastes, environmental protection.In addition, the present invention adopts raw material to be without fluorescent material, noiseless to geological logging.
Embodiment
Below in conjunction with embodiment, the present invention is described in further details:
Embodiment 1
Get 450kg purified cotton and add in reactor, the caustic soda of 100kg is added water and is configured to the caustic soda soln of 20wt%, and add in described reactor, reactor is warmed up to 80 DEG C, constant temperature stirs 3 hours; Then 20kg Mono Chloro Acetic Acid is added water and is configured to the chloroacetic acid solution of 10wt%, and it adds in aforesaid reaction vessel, reactor is warmed up to 80 DEG C, and constant temperature stirs 2 hours; Finally add 430kg acrylic fibers, and reactor is warmed up to 200 DEG C, isothermal reaction obtains fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt glue for 6 hours, the last spray-dried pulvis of making.
Embodiment 2
Get 400kg purified cotton and add in reactor, 110kg caustic soda is added to the caustic soda soln that is configured to 10wt%, and join in described reactor, reactor is warmed up to 70 DEG C, constant temperature stirs 2 hours; Then the Mono Chloro Acetic Acid of getting 15kg adds water and is configured to the chloroacetic acid solution of 5wt%, and is added in aforesaid reaction vessel, and reactor is warmed up to 90 DEG C, and constant temperature stirs 3 hours; Finally add 500kg acrylic fibers, and reactor is warmed up to 190 DEG C, isothermal reaction obtains fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt glue for 8 hours, the last spray-dried pulvis of making.
Embodiment 3
Get 500kg purified cotton and add in reactor, the caustic soda of 90kg is added water and is configured to the caustic soda soln of 50wt%, and join in described reactor, reactor is warmed up to 90 DEG C, constant temperature stirs 2.5 hours; Then 25kg Mono Chloro Acetic Acid the is added water chloroacetic acid solution of the 20wt% being configured to, is added in aforesaid reaction vessel, and reactor is warmed up to 70 DEG C, and constant temperature stirs 2.5 hours; Finally add 400kg acrylic fibers, and reactor is warmed up to 210 DEG C, react and within 7 hours, obtain fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt glue, the last spray-dried pulvis of making.
Embodiment 4
Get 480kg purified cotton and add in reactor, the caustic soda of 105kg is added water and is configured to the caustic soda soln of 30wt%, and join in described reactor, reactor is warmed up to 85 DEG C, constant temperature stirs 2.3 hours; Then 18kg Mono Chloro Acetic Acid the is added water chloroacetic acid solution of the 15wt% being configured to, is added in aforesaid reaction vessel, and reactor is warmed up to 75 DEG C, and constant temperature stirs 2.8 hours; Finally add 480kg acrylic fibers, and reactor is warmed up to 205 DEG C, react and within 7.5 hours, obtain fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt glue, the last spray-dried pulvis of making.
Embodiment 1,2,3 and 4 prepared fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salts are joined in fresh water-based slurry, and add-on is 0.23%, adds the indices of the fresh water-based slurry after hydrolyzed polyacrylonitrile ammonium salt in table one.
Table one adds the indices of the fresh water-based slurry of hydrolyzed polyacrylonitrile ammonium salt
Described fresh water-based slurry is: 350ml distilled water+1.0g sodium bicarbonate+8.0g drilling fluid secondary sodium soil+24.5g drilling fluid is with evaluating soil.
Embodiment 1,2,3 and 4 prepared fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salts are joined in brine mud, and add-on is 1.13%, adds the indices of the brine mud after hydrolyzed polyacrylonitrile ammonium salt in table two.
Table two adds the indices of the brine mud of hydrolyzed polyacrylonitrile ammonium salt
Described brine mud is: salt solution+1.0g sodium bicarbonate+40g drilling fluid test of 350ml4% is native with evaluating with secondary sodium soil+24.5g drilling fluid.
Claims (1)
1. a preparation method for fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt, is characterized in that each material counts by weight: 400 ~ 500 parts of purified cottons, 90 ~ 110 parts, caustic soda, 15 ~ 25 parts of Mono Chloro Acetic Acids, 400 ~ 500 parts of acrylic fibers; Comprise the steps:
A, alkalization, the purified cotton of getting proportional quantity adds in reactor, the caustic soda of corresponding proportional quantity is added water and is configured to the caustic soda soln of concentration 10wt % ~ 50wt%, and add in described reactor, and reactor is warming up to alkalization temperature, and constant temperature stirs 2 ~ 3 hours; Described alkalization temperature is 70 DEG C ~ 90 DEG C;
B, etherificate, get Mono Chloro Acetic Acid by proportioning and add water and be configured to the chloroacetic acid solution of 5wt% ~ 20wt%, added in aforesaid reaction vessel, is warming up to etherification temperature, and constant temperature stirs 2 ~ 3 hours; Described etherification temperature is 70 DEG C ~ 90 DEG C;
C, hydrolysis add the acrylic fibers of corresponding proportional quantity in aforesaid reaction vessel, are warming up to hydrolysis temperature, and isothermal reaction 6 ~ 8 hours, obtains fluid loss additive for boring fluid hydrolyzed polyacrylonitrile ammonium salt glue; Described hydrolysis temperature is 190 DEG C ~ 210 DEG C;
D, the dry pulvis of making of finally spraying.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210576906.9A CN102994055B (en) | 2012-12-27 | 2012-12-27 | Method for preparing filtrate reducer hydrolyzed polyacrylonitrile for drilling fluid |
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| CN201210576906.9A CN102994055B (en) | 2012-12-27 | 2012-12-27 | Method for preparing filtrate reducer hydrolyzed polyacrylonitrile for drilling fluid |
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| CN102994055B true CN102994055B (en) | 2014-07-30 |
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Families Citing this family (6)
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| CN103740342B (en) * | 2014-01-09 | 2017-11-17 | 濮阳市诚信钻采助剂有限公司 | High-temperature resisting and salt-resisting fluid loss additive and preparation method thereof |
| CN103923242B (en) * | 2014-04-19 | 2015-04-08 | 商南天和泥浆有限公司 | Hydrolyzed polyacrylonitrile ammonium salt production system |
| CN106398660B (en) * | 2016-08-31 | 2019-04-12 | 四川上之登新材料有限公司 | A kind of pressure-bearing loss-stopping agent for drilling fluid |
| CN106398669B (en) * | 2016-08-31 | 2018-09-25 | 四川上之登新材料有限公司 | Preparation method of pressure-bearing plugging agent for drilling fluid |
| CN108102015A (en) * | 2017-12-16 | 2018-06-01 | 保定市三拓化工产品有限公司 | A kind of drilling fluid anti-calcium and anti-salt fluid loss additive quaternary ammonium polymer and preparation method thereof |
| CN108559465A (en) * | 2018-05-30 | 2018-09-21 | 河北华运鸿业化工有限公司 | A kind of drilling fluid polyacrylonitrile salt resistant filter loss reduction agent lotion |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3634025A (en) * | 1969-11-20 | 1972-01-11 | Alfred Landry | Water sterilizer |
| CN101955757A (en) * | 2010-08-25 | 2011-01-26 | 石家庄华莱化工有限公司 | Hydrolyzed polyacrylonitrile-compound ammonium salt for drilling fluid |
| CN102352223A (en) * | 2011-07-22 | 2012-02-15 | 石家庄华莱鼎盛科技有限公司 | Hydrolyzed polyacrylonitrile-bipoly ammonium salt for drilling fluid |
-
2012
- 2012-12-27 CN CN201210576906.9A patent/CN102994055B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3634025A (en) * | 1969-11-20 | 1972-01-11 | Alfred Landry | Water sterilizer |
| CN101955757A (en) * | 2010-08-25 | 2011-01-26 | 石家庄华莱化工有限公司 | Hydrolyzed polyacrylonitrile-compound ammonium salt for drilling fluid |
| CN102352223A (en) * | 2011-07-22 | 2012-02-15 | 石家庄华莱鼎盛科技有限公司 | Hydrolyzed polyacrylonitrile-bipoly ammonium salt for drilling fluid |
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