CN102993777A - Active black dye - Google Patents
Active black dye Download PDFInfo
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- CN102993777A CN102993777A CN2012102244891A CN201210224489A CN102993777A CN 102993777 A CN102993777 A CN 102993777A CN 2012102244891 A CN2012102244891 A CN 2012102244891A CN 201210224489 A CN201210224489 A CN 201210224489A CN 102993777 A CN102993777 A CN 102993777A
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Abstract
The invention discloses an active black dye. The active black dye comprises the following components in percentage by weight: 5-25% of active red dye compound as shown in formula I, 20-55% of active yellow dye compound as shown in formula II and 45-70% of active blue dye compound as shown in formula III, wherein X1, X2 and X3 are of Cl or F independently; and M1, M2 and M3 are of H or Na independently. The active black dye disclosed by the invention can significantly improve the deep dyeing property and the compatibility of the dye and has a better promoting property, the active black dye has the advantages of deeper dyeing depth, uniform dyeing and good promoting capability, dyeing can be performed at a low temperature, energy is saved and environmental pollution is further reduced.
Description
Technical field
The present invention relates to a kind of reactive black dye.
Background technology
Black and active dye is that the kind more, that output is larger is used in the reactive dyestuffs field, namely is one of kind of current output maximum such as C.I. reactive black 5 #.
C.I. reactive black 5
Considerable in the market is the reactive black kind that obtains to have some superiority in the mode of three primary colors blending.But exist such as pitch black degree not, can't reach depth requirements; Each component property difference is large, and the deficiency that compatibleness is not good etc. is a difficult problem that faces in the reactive dyestuffs field.
Summary of the invention
Technical problem to be solved by this invention is that to have overcome the pitch black degree that existing reactive black dye exists inadequate, can't reach depth requirements, each component property difference is large, the defective that compatibleness is not good, and a kind of new reactive black dye is provided, by its each component is redesigned, all introduce double-active group, greatly improved its dyeing behavior, such as remarkable depth and the compatibleness of having improved dyestuff, and have better enhancing, can satisfy current demand to reactive black dye.
Therefore, the present invention relates to a kind of reactive black dye, it comprises the component of following mass percent: suc as formula the active red dye compound 5 ~ 25% shown in the I, and suc as formula the reactive yellow dye compounds 20 ~ 55% shown in the II, and suc as formula the reactive blue dye compound 45 ~ 70% shown in the III.
Wherein, X
1, X
2And X
3Be Cl or F independently; M
1, M
2And M
3Be H or Na independently.Distinguishingly, in the situation that without acidifying, M in the above-mentioned general formula compound
1, M
2And M
3Be Na, namely above-mentioned general formula compound all exists with the form of sodium salt.
Therefore, above-mentioned general formula compound I can be I(1) or I(2);
Above-mentioned general formula compound II can be II(1) or II(2);
Above-mentioned general formula compound III can be III(1) or III(2);
The invention further relates to the preparation method of above-mentioned reactive black dye, the blending device that uses this area routine with said ratio suc as formula the active red dye compound shown in the I, suc as formula the reactive yellow dye compounds shown in the II, and suc as formula the reactive blue dye compound mixing shown in the III, get final product; The auxiliary agent that as required, can suitably add this area routine is with performances such as the intensity of adjusting reactive black dye and dissolvings.
The invention still further relates to the preparation method of another reactive black dye, after namely using the synthetic method of published reactive red (I) in this area, reactive yellow (II), these three kinds of compounds of Reactive blue (III) to obtain respectively corresponding solution, determine respectively concentration with spectrophotometer method, the liquid lower reactive black dye liquid that fully is mixed in proportion is according to the method acquisition solid state powder shape commercial dye of commercialization dyestuff conventional in this area.
Reactive black dye of the present invention can dye by the dyeing of this area routine (accompanying drawing 1).Better dyeing condition is as follows: dye dosage is 2%(owf), at 40 ℃ of dyeing 90 minutes, soda ash consumption 5g/L, amount of caustic soda 1g/L.
Without prejudice to the field on the basis of common sense, but above-mentioned each preferred feature arbitrary combination among the present invention namely gets the preferred embodiments of the invention.
Raw material described in the present invention or reagent except specifying, equal commercially available getting.
Positive progressive effect of the present invention is: reactive black dye of the present invention has significantly improved depth and the compatibleness of dyestuff, and has a better enhancing, this reactive black dye dye level is darker, even dyeing, lifting force is good, can dye at low temperatures, save the energy and reduced pollution to environment.
Description of drawings
Fig. 1 is reactive black dye dyeing sketch of the present invention.
Embodiment
The below further specifies the present invention with embodiment, but the present invention is not limited.
Used raw material or reagent is except specifying among the embodiment, all commercially available getting.
Embodiment 1
According to mass percent, the active red dye chemical compounds I (1) with 5%, 50% reactive yellow dye compounds II (1) and 45% reactive blue dye compound III (1) fully mix in mechanical blending device.
Embodiment 2
According to mass percent, the active red dye chemical compounds I (1) with 25%, 20% reactive yellow dye compounds II (1) and 55% reactive blue dye compound III (1) fully mix in mechanical blending device.
Embodiment 3
According to mass percent, the active red dye chemical compounds I (2) with 10%, 20% reactive yellow dye compounds II (2) and 70% reactive blue dye compound III (2) fully mix in mechanical blending device.
Embodiment 4
According to mass percent, the active red dye chemical compounds I (2) with 15%, 25% reactive yellow dye compounds II (2) and 60% reactive blue dye compound III (2) fully mix in mechanical blending device.
Embodiment 5
According to mass percent, be that the reactive blue dye compound III (1) that the active red dye chemical compounds I (1) of 17.8g/L, reactive yellow dye compounds II (1) that 2.10L concentration is 14.3g/L and 2.16L concentration are 23.1g/L stirs in the reactor of 10L with 1.12L concentration, adding 450g refined salt stirs saltouts, by filtration-oven dry-pulverizing-stdn, obtain reactive black dye.
Embodiment 6
According to mass percent, be that the reactive blue dye compound III (2) that the active red dye chemical compounds I (2) of 17.8g/L, reactive yellow dye compounds II (2) that 1.54L concentration is 16.2g/L and 5.22L concentration are 11.5g/L stirs in the reactor of 10L with 0.84L concentration, adding 528g refined salt stirs saltouts, by filtration-oven dry-pulverizing-stdn, obtain reactive black dye.
Embodiment 7
According to the technical process of accompanying drawing 1, the reactive black dye that embodiment 1 ~ 5 is obtained dyes to pure cotton knitting cloth, and carries out performance test relatively with reactive black 5 #, the results are shown in following table:
| Title | Dyeing temperature | Degree of fixation | Solubleness | Enhancing | Weighed intensities |
| Embodiment 1 dyestuff | 40℃ | 82% | 250g/L | 8 | 106 |
| Embodiment 2 dyestuffs | 40℃ | 79% | 250g/L | 8 | 108 |
| Embodiment 3 dyestuffs | 40℃ | 76% | 250g/L | 7 | 108 |
| Embodiment 4 dyestuffs | 40℃ | 81% | 250g/L | 7 | 112 |
| Embodiment 5 dyestuffs | 40℃ | 75% | 250g/L | 8 | 105 |
| Embodiment 6 dyestuffs | 40℃ | 76% | 250g/L | 7 | 108 |
| Reactive black 5 # | 60℃ | 65% | 200g/L | 4 | 100 |
Claims (2)
1. reactive black dye, it is characterized in that: it comprises the component of following mass percent: suc as formula the active red dye compound 5 ~ 25% shown in the I, suc as formula the reactive yellow dye compounds 20 ~ 55% shown in the II, and suc as formula the reactive blue dye compound 45 ~ 70% shown in the III;
Wherein, X
1, X
2And X
3Be Cl or F independently; M
1, M
2And M
3Be H or Na independently.
2. reactive black dye as claimed in claim 1, it is characterized in that: general formula compound I is I(1) or I(2);
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210224489.1A CN102993777B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110182835.X | 2011-06-30 | ||
| CN201110182835 | 2011-06-30 | ||
| CN201210224489.1A CN102993777B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
Publications (2)
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|---|---|
| CN102993777A true CN102993777A (en) | 2013-03-27 |
| CN102993777B CN102993777B (en) | 2014-05-07 |
Family
ID=47795317
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210224032.0A Active CN102977631B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
| CN201210224488.7A Active CN102964869B (en) | 2011-06-30 | 2012-06-29 | Preparation method of reactive black dye |
| CN201210224489.1A Active CN102993777B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
| CN201210223745.5A Active CN102964877B (en) | 2011-06-30 | 2012-06-29 | Preparation method of reactive black dye |
| CN201210224031.6A Active CN102993776B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210224032.0A Active CN102977631B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
| CN201210224488.7A Active CN102964869B (en) | 2011-06-30 | 2012-06-29 | Preparation method of reactive black dye |
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| CN201210223745.5A Active CN102964877B (en) | 2011-06-30 | 2012-06-29 | Preparation method of reactive black dye |
| CN201210224031.6A Active CN102993776B (en) | 2011-06-30 | 2012-06-29 | Active black dye |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440993A (en) * | 2018-05-14 | 2018-08-24 | 吴江桃源染料有限公司 | A kind of active red dye and its preparation method and application |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391684B (en) * | 2011-07-07 | 2016-03-02 | 天津德凯化工股份有限公司 | A kind of Yellow active dye contaminating nylon and preparation method thereof |
| CN103554976A (en) * | 2013-09-29 | 2014-02-05 | 天津德凯化工股份有限公司 | Red reactive dye and preparation method thereof |
| CN104098926B (en) * | 2014-06-04 | 2016-03-09 | 杭州吉华江东化工有限公司 | A kind of reactive dye mixture |
| CN106317956A (en) * | 2016-07-26 | 2017-01-11 | 萧县凯奇化工科技有限公司 | Green and environment-friendly yellow G dye and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06107962A (en) * | 1992-09-30 | 1994-04-19 | Sumitomo Chem Co Ltd | Anthraquinone-based reaction dye composition and method for dyeing or printing fiber material using the same |
| EP0664323A1 (en) * | 1993-12-24 | 1995-07-26 | Sumitomo Chemical Company, Limited | A reactive dye composition and a method for dyeing or printing of fiber materials using the same |
| CN1158926A (en) * | 1995-11-23 | 1997-09-10 | 希巴特殊化学控股公司 | Process for dichromatic or trichromatic dyeing or printing |
| EP1234858A2 (en) * | 2001-02-27 | 2002-08-28 | Everlight USA, Inc. | Mixtures of reactive dyes and their use |
| US6443997B1 (en) * | 1998-03-26 | 2002-09-03 | Korea Research Institute Of Chemical Technology | Reactive black dye compositions for cellulose fibers |
| CN1616756A (en) * | 2003-09-24 | 2005-05-18 | 德意志戴斯达纺织品及染料两合公司 | Process for mono-, di- and trichromie dyeing and printing of natural and synthetic polyamide material |
| CN1720299A (en) * | 2002-12-02 | 2006-01-11 | 西巴特殊化学品控股有限公司 | Reactive dyes, a process for their preparation and their use |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3975370A (en) * | 1971-05-13 | 1976-08-17 | The United States Of America As Represented By The Secretary Of Agriculture | Methylolated reaction product of a hydroxy carbamate and cellulose-dyeing dyestuff containing vinyl sulfone groups |
| JPH04370157A (en) * | 1991-06-19 | 1992-12-22 | Sumitomo Chem Co Ltd | Reactive dye composition and method for dyeing or printing fiber material or leather with the same |
| DE4332048A1 (en) * | 1993-09-21 | 1995-03-23 | Hoechst Ag | Mixtures of dyes with fiber-reactive groups and their use for dyeing fiber materials |
| DE4414320A1 (en) * | 1994-04-25 | 1995-10-26 | Hoechst Ag | Black dye mixtures of fiber-reactive azo dyes and their use for dyeing fiber material containing hydroxyl and / or carbonamide groups |
| DE4441960A1 (en) * | 1994-11-25 | 1996-05-30 | Basf Ag | Dye preparations |
| TW466263B (en) * | 1998-07-28 | 2001-12-01 | Dystar Textilfarben Gmbh & Amp | Fiber-reactive black dye mixtures and use thereof for dyeing hydroxy-and/or carboxamido-containing fiber material |
| US6126700A (en) * | 1999-01-20 | 2000-10-03 | Everlight Usa, Inc. | Black dye composition |
| CN1511885A (en) * | 2002-12-31 | 2004-07-14 | 大连理工大学化工学院 | Black compound active dye |
| CN100478402C (en) * | 2007-09-12 | 2009-04-15 | 浙江瑞华化工有限公司 | Active black dye |
| CN101775235B (en) * | 2009-12-21 | 2013-04-24 | 浙江龙盛集团股份有限公司 | Active black dye |
| CN102101845B (en) * | 2009-12-22 | 2012-09-26 | 上海安诺其纺织化工股份有限公司 | Reactive dye compound and preparation method thereof, and reactive dye product |
-
2012
- 2012-06-29 CN CN201210224032.0A patent/CN102977631B/en active Active
- 2012-06-29 CN CN201210224488.7A patent/CN102964869B/en active Active
- 2012-06-29 CN CN201210224489.1A patent/CN102993777B/en active Active
- 2012-06-29 CN CN201210223745.5A patent/CN102964877B/en active Active
- 2012-06-29 CN CN201210224031.6A patent/CN102993776B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06107962A (en) * | 1992-09-30 | 1994-04-19 | Sumitomo Chem Co Ltd | Anthraquinone-based reaction dye composition and method for dyeing or printing fiber material using the same |
| EP0664323A1 (en) * | 1993-12-24 | 1995-07-26 | Sumitomo Chemical Company, Limited | A reactive dye composition and a method for dyeing or printing of fiber materials using the same |
| CN1158926A (en) * | 1995-11-23 | 1997-09-10 | 希巴特殊化学控股公司 | Process for dichromatic or trichromatic dyeing or printing |
| US6443997B1 (en) * | 1998-03-26 | 2002-09-03 | Korea Research Institute Of Chemical Technology | Reactive black dye compositions for cellulose fibers |
| EP1234858A2 (en) * | 2001-02-27 | 2002-08-28 | Everlight USA, Inc. | Mixtures of reactive dyes and their use |
| CN1720299A (en) * | 2002-12-02 | 2006-01-11 | 西巴特殊化学品控股有限公司 | Reactive dyes, a process for their preparation and their use |
| CN1720299B (en) * | 2002-12-02 | 2010-07-28 | 西巴特殊化学品控股有限公司 | Reactive dyes, a process for their preparation and their use |
| CN1616756A (en) * | 2003-09-24 | 2005-05-18 | 德意志戴斯达纺织品及染料两合公司 | Process for mono-, di- and trichromie dyeing and printing of natural and synthetic polyamide material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440993A (en) * | 2018-05-14 | 2018-08-24 | 吴江桃源染料有限公司 | A kind of active red dye and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102964869B (en) | 2014-06-04 |
| CN102993776B (en) | 2014-05-07 |
| CN102964877B (en) | 2014-04-23 |
| CN102993777B (en) | 2014-05-07 |
| CN102964869A (en) | 2013-03-13 |
| CN102977631A (en) | 2013-03-20 |
| CN102977631B (en) | 2014-06-04 |
| CN102993776A (en) | 2013-03-27 |
| CN102964877A (en) | 2013-03-13 |
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Owner name: SHANGHAI ANOKY GROUP CO., LTD. Free format text: FORMER NAME: SHANGHAI ANOKY TEXTILE CHEMICALS CO., LTD. |
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Address after: Liantang Town Qingpu District Shanghai city 201717 Zhu Feng Road No. 6188 room 2622 Patentee after: SHANGHAI ANOKY GROUP CO., LTD. Address before: Liantang Town Qingpu District Shanghai city 201717 Zhu Feng Road No. 6188 room 2622 Patentee before: Shanghai ANOKY Textile Chemicals Co., Ltd. |
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Effective date of registration: 20171116 Address after: 224631 Jiangsu province Yancheng City county road six North Ring Chen Zhen Wei Patentee after: JIANGSU ANOKY CHEMICAL CO., LTD. Address before: Liantang Town Qingpu District Shanghai city 201717 Zhu Feng Road No. 6188 room 2622 Patentee before: SHANGHAI ANOKY GROUP CO., LTD. |
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Effective date of registration: 20190806 Address after: 201703 Shanghai city Qingpu District Songhua Road No. 881 Co-patentee after: Yantai Anoky Fine Chemical Co., Ltd. Patentee after: SHANGHAI ANOKY GROUP CO., LTD. Co-patentee after: SHANGHAI ANOKY DIGITAL TECHNOLOGY CO., LTD. Co-patentee after: Dongying Annuoqi Textile Material Co., Ltd. Co-patentee after: Shanghai Shangyu Digital Technology Co., Ltd. Co-patentee after: Yantai Shangyu Digital Technology Co., Ltd. Address before: 224631 North of Weiliu Road, Chenjiagang Town, Xiangshui County, Yancheng City, Jiangsu Province Patentee before: JIANGSU ANOKY CHEMICAL CO., LTD. |
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