CN102993744A - Glass fiber reinforced nylon 66 composite with super toughness and preparation method thereof - Google Patents
Glass fiber reinforced nylon 66 composite with super toughness and preparation method thereof Download PDFInfo
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- CN102993744A CN102993744A CN201210480118XA CN201210480118A CN102993744A CN 102993744 A CN102993744 A CN 102993744A CN 201210480118X A CN201210480118X A CN 201210480118XA CN 201210480118 A CN201210480118 A CN 201210480118A CN 102993744 A CN102993744 A CN 102993744A
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Abstract
The invention discloses a glass fiber reinforced nylon 66 composite with super toughness and a preparation method thereof. The composite comprises the components of 35-84% of nylon 66 resin, 10-40% of chopped glass fiber, 5-15% of maleic anhydride grafted polyolefin, 0.1-1% of chain extender and 0.1-10% of other auxiliaries by weight percentage. By adding the chain extender, the fusion of the maleic anhydride grafted polyolefin and resin and glass fiber is improved. The toughness of material is improved and meanwhile, the reduction of rigidity of tensile strength and the like is lessened to achieve good balance of toughness and rigidity. The glass fiber reinforced nylon 66 composite with super toughness of the invention has a good toughness, high rigidity and good heat resistance.
Description
Technical field
The invention belongs to the polymer composite field, be specifically related to a kind of superhigh tenacity glass fiber reinforced nylon 66 matrix materials and preparation method thereof.
Background technology
The glass fibre reinforced nylon material has the superperformances such as high strength, high heat-resisting, highly anti-fatigue, low mould shrinkage, therefore is widely used in the fields such as automobile, machinery, household electrical appliances, aviation and military parts.
Yet the nylon material impact property that has added glass fibre can descend, and especially unnotched impact strength can descend a lot, in order to improve glass in the toughness of nylon material, common way is to add some toughner, such as maleic anhydride stem grafting polyolefin, or some nucleocapsid toughner.But it is limited that these common ways improve shock strengths, and can cause the tensile strength of glass fiber enhanced nylon and flexural strength along with the raising of toughner content descends a lot.
Summary of the invention
Technical problem to be solved by this invention is to overcome above shortcomings in the prior art, and a kind of superhigh tenacity glass fiber reinforced nylon 66 matrix materials and preparation method thereof are provided.
Its goal of the invention can be achieved by the following technical programs.
A kind of superhigh tenacity glass fiber reinforced nylon 66 matrix materials comprise the component of following weight percent:
More preferably:
A kind of superhigh tenacity glass fiber reinforced nylon 66 matrix materials comprise the component of following weight percent:
Further, a kind of superhigh tenacity glass fiber reinforced nylon 66 matrix materials comprise the component of following weight percent:
Nylon 66 relative viscosity in superhigh tenacity glass fiber reinforced nylon 66 matrix materials of the present invention is 2.0～3.5.
Short glass fiber in superhigh tenacity glass fiber reinforced nylon 66 matrix materials of the present invention is alkali free glass fibre, and its Fibre diameter is 5～15 μ m, and staple length is 2～10mm.
Maleic anhydride stem grafting polyolefin in superhigh tenacity glass fiber reinforced nylon 66 matrix materials of the present invention is maleic anhydride graft POE.
Chainextender in superhigh tenacity glass fiber reinforced nylon 66 matrix materials of the present invention is copolymer from ethylene and maleie anhydride.
Other auxiliary agents in superhigh tenacity glass fiber reinforced nylon 66 matrix materials of the present invention are one or more in silane coupling agent, lubricant, fire retardant, oxidation inhibitor and the color auxiliary agent.
Described silane coupling agent is a kind of in γ-aminopropyl triethoxysilane, γ-aminopropyl methyldiethoxysilane and g-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.
Described oxidation inhibitor is four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, N, one or both combinations in N '-hexa-methylene two (3,5-di-t-butyl-4-hydroxybenzene propionic acid amide) and tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) ester.
Superhigh tenacity glass fiber reinforced nylon 66 composite manufacture methods of the present invention, concrete steps are as follows:
1) takes by weighing various materials by above-mentioned component proportioning; 2) mixer mixing 3-5 minute, then the material that mixes except short glass fiber is added twin screw extruder, wherein short glass fiber adds from first exhaust ports; 3) extrusion temperature is set between 250～280 ℃, and engine speed is 20～50 hertz, cooling, and pelletizing, pellet is produced batten with injection molding machine of plastic.
The present invention improves the fusion of maleic anhydride stem grafting polyolefin and resin and glass fibre by adding the method for chainextender, when improving toughness of material, reduces the reduction of the rigidity such as tensile strength, reaches good rigidity-toughness balanced.Superhigh tenacity glass fiber reinforced nylon 66 composite material toughness of the present invention are good, and rigidity is high, and is heat-resisting good.
Embodiment
Further specify the present invention below by embodiment and Comparative Examples, do not violating under the aim of the present invention, the present invention should be not limited to the content that following experimental example is specifically expressed.
Embodiment and Comparative Examples raw materials are as follows:
The PA66 resin, FYR27D, the refreshing horse in Henan group;
Short glass fiber, ECS 301CL, the international matrix material in Chongqing company;
Maleic anhydride stem grafting polyolefin, maleic anhydride graft POE-JY086, Shanghai is poly-company for a long time;
Copolymer from ethylene and maleie anhydride, E60, Shanghai is bright abundant;
Silane coupling agent, KH-550, Nanjing dawn chemical industry company limited;
Oxidation inhibitor, 168 and 1010, Ciba fine chemicals.
In super mixer, said components (except short glass fiber) was at room temperature mixed 3 minutes, with TE-35 (L/D=36) the twin screw extruder production (short glass fiber adds from first venting port position) of Nanjing Ke Ya company production.The section particle that obtains after dry 3 hours, is used day HT1150B injection moulding machine sample preparation of sea, Ningbo in 100 ℃ convection oven.
Performance test
Shock strength and notched Izod impact strength are pressed ISO 179 and are carried out, and testing apparatus is German ZwickB5102.202 shock-testing machine; The tensile property test is pressed ISO 527 and is carried out, and testing apparatus is German Zwick Z010 electronic tensile machine, and draw speed is 50mm/min; The test of bending property is pressed ISO178 and is carried out, and testing apparatus is Zwick Z010 electronic tensile machine, and span is 64mm, and speed is 2mm/min; Heat-drawn wire is carried out by testing standard ISO 75, and testing apparatus is the dimension card heat-drawn wire tester of Italian CEAST company, load 1.8MPa, and heat-up rate is 120 ℃/hour.
Embodiment 1～5
Various raw-material weight percents are as shown in table 1 in the matrix material, and the temperature of twin screw extruder is respectively (from spout to extrusion die): 250 ℃, and 280 ℃, 260 ℃, 260 ℃, 270 ℃.Engine speed is 30 hertz.
Table 1 embodiment 1-5 prescription and material property table
Annotate: the numerical value of shock strength " constantly " expression shock strength is at 100kJ/m
2About.
Comparative Examples 1～5
Various raw-material weight percents are as shown in table 2 in the matrix material, and the temperature of twin screw extruder is respectively (from spout to extrusion die): 250 ℃, and 280 ℃, 260 ℃, 260 ℃, 270 ℃.Engine speed is 30 hertz.
Table 2 Comparative Examples 1-5 prescription and material property table
From the result of embodiment and Comparative Examples, the material property rigidity-toughness balanced that has added chainextender is fine, has increased substantially toughness, and rigidity descends seldom.When especially chainextender was the content of 0.4-1%, it is perfect that rigid-tough balance more is tending towards.
Claims (10)
1. superhigh tenacity glass fiber reinforced nylon 66 matrix materials is characterized in that: the component that comprises following weight percent:
2. a kind of superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 1 is characterized in that: the component that comprises following weight percent:
3. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 1 and 2, it is characterized in that: described Nylon 66 relative viscosity is 2.0～3.5.
4. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 1 and 2, it is characterized in that: described short glass fiber is alkali free glass fibre, and its Fibre diameter is 5～15 μ m, and staple length is 2～10mm.
5. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 1 and 2, it is characterized in that: described maleic anhydride stem grafting polyolefin is maleic anhydride graft POE.
6. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 1 and 2, it is characterized in that: described chainextender is copolymer from ethylene and maleie anhydride.
7. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 1 and 2, it is characterized in that: described other auxiliary agents are one or more in silane coupling agent, lubricant, fire retardant, oxidation inhibitor and the color auxiliary agent.
8. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 7, it is characterized in that: described silane coupling agent is a kind of in γ-aminopropyl triethoxysilane, γ-aminopropyl methyldiethoxysilane and g-(2,3-epoxy the third oxygen) propyl trimethoxy silicane.
9. superhigh tenacity glass fiber reinforced nylon 66 matrix materials according to claim 7, it is characterized in that: described oxidation inhibitor is four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, N, N '-hexa-methylene two (3,5-di-t-butyl-4-hydroxybenzene propionic acid amide) and one or both combinations in tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) ester.
10. method for preparing described superhigh tenacity glass fiber reinforced nylon 66 matrix materials of claim 1, it is characterized in that: concrete steps are as follows:
1) takes by weighing various materials by above-mentioned component proportioning;
2) mixer mixing 3-5 minute, then the material that mixes except short glass fiber is added twin screw extruder, wherein short glass fiber adds from first exhaust ports;
3) extrusion temperature is set between 250～280 ℃, and engine speed is 20～50 hertz, cooling, and pelletizing, pellet is produced batten with injection molding machine of plastic.
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| CN201210480118XA CN102993744A (en) | 2012-11-22 | 2012-11-22 | Glass fiber reinforced nylon 66 composite with super toughness and preparation method thereof |
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| CN201210480118XA CN102993744A (en) | 2012-11-22 | 2012-11-22 | Glass fiber reinforced nylon 66 composite with super toughness and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788643A (en) * | 2014-01-27 | 2014-05-14 | 上海日之升新技术发展有限公司 | High anti-explosion pressure glass fiber reinforced hydrolysis-resistant PA66 material and preparation method thereof |
| CN103937231A (en) * | 2014-03-12 | 2014-07-23 | 金发科技股份有限公司 | Glass fiber reinforced nylon compound used for extrusion molding, and preparation method and application thereof |
| CN105383424A (en) * | 2015-12-11 | 2016-03-09 | 广东东箭汽车用品制造有限公司 | Automobile bumper |
| CN106751783A (en) * | 2016-12-29 | 2017-05-31 | 上海普利特复合材料股份有限公司 | High visocity nylon 6 composite prepared by a kind of melting extrusion chain extending reaction and preparation method thereof |
| CN106751804A (en) * | 2016-12-29 | 2017-05-31 | 上海普利特复合材料股份有限公司 | A kind of high-performance composite materials as prepared by recovery waste carpet PA66 materials and preparation method thereof |
| CN110591345A (en) * | 2019-09-04 | 2019-12-20 | 上海日之升科技有限公司 | Aluminum-like thermal conductive composite material with linear expansion coefficient and preparation method thereof |
| CN111205636A (en) * | 2020-02-28 | 2020-05-29 | 金旸（厦门）新材料科技有限公司 | Polyamide material and preparation method and application thereof |
| CN113980459A (en) * | 2021-11-12 | 2022-01-28 | 安徽中鼎橡塑制品有限公司 | High-rigidity glass fiber reinforced nylon composite material and preparation method thereof |
| US20220243060A1 (en) * | 2019-10-24 | 2022-08-04 | Inv Nylon Chemicals Americas, Llc | Polyamide compositions and articles made therefrom |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788643B (en) * | 2014-01-27 | 2016-08-17 | 上海日之升新技术发展有限公司 | High antiknock Compressive Strength fiberglass reinforced hydrolysis PA66 material and preparation method thereof |
| CN103788643A (en) * | 2014-01-27 | 2014-05-14 | 上海日之升新技术发展有限公司 | High anti-explosion pressure glass fiber reinforced hydrolysis-resistant PA66 material and preparation method thereof |
| CN103937231A (en) * | 2014-03-12 | 2014-07-23 | 金发科技股份有限公司 | Glass fiber reinforced nylon compound used for extrusion molding, and preparation method and application thereof |
| CN105383424B (en) * | 2015-12-11 | 2019-05-24 | 广东东箭汽车科技股份有限公司 | A kind of bumper for automobile |
| CN105383424A (en) * | 2015-12-11 | 2016-03-09 | 广东东箭汽车用品制造有限公司 | Automobile bumper |
| CN106751783A (en) * | 2016-12-29 | 2017-05-31 | 上海普利特复合材料股份有限公司 | High visocity nylon 6 composite prepared by a kind of melting extrusion chain extending reaction and preparation method thereof |
| CN106751804A (en) * | 2016-12-29 | 2017-05-31 | 上海普利特复合材料股份有限公司 | A kind of high-performance composite materials as prepared by recovery waste carpet PA66 materials and preparation method thereof |
| CN106751804B (en) * | 2016-12-29 | 2019-11-19 | 上海普利特复合材料股份有限公司 | A kind of high-performance composite materials as prepared by recycling waste carpet PA66 material and preparation method thereof |
| CN110591345A (en) * | 2019-09-04 | 2019-12-20 | 上海日之升科技有限公司 | Aluminum-like thermal conductive composite material with linear expansion coefficient and preparation method thereof |
| US20220243060A1 (en) * | 2019-10-24 | 2022-08-04 | Inv Nylon Chemicals Americas, Llc | Polyamide compositions and articles made therefrom |
| US11787939B2 (en) * | 2019-10-24 | 2023-10-17 | Inv Nylon Polymers Americas, Llc | Polyamide compositions and articles made therefrom |
| CN111205636A (en) * | 2020-02-28 | 2020-05-29 | 金旸（厦门）新材料科技有限公司 | Polyamide material and preparation method and application thereof |
| CN111205636B (en) * | 2020-02-28 | 2021-11-19 | 金旸（厦门）新材料科技有限公司 | Polyamide material and preparation method and application thereof |
| CN113980459A (en) * | 2021-11-12 | 2022-01-28 | 安徽中鼎橡塑制品有限公司 | High-rigidity glass fiber reinforced nylon composite material and preparation method thereof |
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Application publication date: 20130327 |