CN102992559B - Method for comprehensively utilizing anaerobic digestion and carbonization of municipal sludge - Google Patents
Method for comprehensively utilizing anaerobic digestion and carbonization of municipal sludge Download PDFInfo
- Publication number
- CN102992559B CN102992559B CN2012105238873A CN201210523887A CN102992559B CN 102992559 B CN102992559 B CN 102992559B CN 2012105238873 A CN2012105238873 A CN 2012105238873A CN 201210523887 A CN201210523887 A CN 201210523887A CN 102992559 B CN102992559 B CN 102992559B
- Authority
- CN
- China
- Prior art keywords
- anaerobic digestion
- mud
- carbonization
- sludge
- temperature
- Prior art date
Links
- 230000029087 digestion Effects 0.000 title claims abstract description 59
- 239000010802 sludge Substances 0.000 title claims abstract description 38
- 238000003763 carbonization Methods 0.000 title claims abstract description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 48
- 238000002156 mixing Methods 0.000 claims abstract description 35
- 239000011901 water Substances 0.000 claims abstract description 34
- 239000007789 gases Substances 0.000 claims abstract description 24
- 230000003750 conditioning Effects 0.000 claims abstract description 21
- 239000007788 liquids Substances 0.000 claims abstract description 20
- 238000006243 chemical reactions Methods 0.000 claims abstract description 18
- 238000000926 separation method Methods 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 239000002023 wood Substances 0.000 claims abstract description 10
- 239000010893 paper wastes Substances 0.000 claims abstract description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 239000000203 mixtures Substances 0.000 claims abstract description 3
- 239000011499 joint compounds Substances 0.000 claims description 61
- 239000002893 slag Substances 0.000 claims description 37
- 238000010000 carbonizing Methods 0.000 claims description 31
- 238000000034 methods Methods 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound 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[C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 239000010410 layers Substances 0.000 claims description 12
- 239000003337 fertilizer Substances 0.000 claims description 11
- 238000002485 combustion reactions Methods 0.000 claims description 9
- 239000010865 sewage Substances 0.000 claims description 7
- 238000005255 carburizing Methods 0.000 claims description 6
- 239000003153 chemical reaction reagents Substances 0.000 claims description 6
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Abstract
Description
Technical field
The invention belongs to environment project and field of ecological agricultural, relate to processing and the disposal of municipal sludge, specifically a kind of method of urban mud anaerobic digestion and carbonization comprehensive utilization.
Background technology
In recent years, under national energy-saving reduction of discharging and pro-active fiscal policy effect, town sewage is processed and is developed rapidly, and the Urban Water environmental improvement obtains remarkable effect, along with improving constantly of China's town sewage processing rate, the urban wastewater treatment firm sludge yield also sharply increases.2009,1992 of the urban wastewater treatment firms put into operation in the whole nation, the amount of disposing of sewage 28,000,000,000 m 3, the mud of generation water ratio 80% is 2,005 ten thousand t approximately, and along with the increase of the level of urbanization and sewage load, sludge quantity will be broken through 3,000 ten thousand t very soon.According to incompletely statistics, current national urban wastewater treatment firm mud only has small portion to carry out treatment and disposal in various degree, and major part is not carried out normalized processing disposal.Mud contains the hazardous and noxious substances such as pathogenic agent, heavy metal and persistent organism, water ratio is very high, without effectively processing and dispose, very easily underground water, soil etc. is caused to secondary pollution, direct threatening environment safety and public health, the environmental benefit of sewage treatment facility is reduced greatly, affect the positively effect that national energy-saving reduces discharging strategy implementation.
The processing of domestic city mud at present mainly adopts landfill, anhydration and incineration, as modes such as agriculture fertilizer, processes and dispose; Landfill mud need to take a large amount of agricultural arable lands; The anhydration and incineration of mud, the ubiquity construction investment is large, and the problem that working cost is high is difficult to support economically.Compare above treatment process, adopt anaerobic digestion techniques not only can realize the minimizing of mud, innoxious, stabilization and resource utilization; Mud is after anaerobic digestion, and volume reduces 50% left and right, can realize minimizing; After mesophilic digestion, the unwanted bacteria in mud obtains a large amount of eliminations, can realize innoxious and stabilization; The biogas that anaerobic digestion produces can be for fuel and generating, and the energy consumption of compensation water factory, be industry energy conservation 30%, is one of at present the most feasible sludge treatment technique, can realize resource utilization and energy-saving.
But the current sludge anaerobic treatment process used, exist state of the art low, sludge treatment weak effect, the low series of problems that waits of biogas utilization rate.And the sludge anaerobic treatment process, except producing biogas, also can produce the natural pond slag; Slag disposing technique most of composting technology that adopts in existing natural pond prepares fertilizer, but this technique needs a large amount of land resources, and in developed regions, application is restricted.
Country's " " 12 " energy-conserving and environment-protective industrial development planning " environmental protection industry gordian technique & Mud technology emphasis is to process disposal technology for farmland, burning and production building material product etc. after anaerobic sludge digestion or aerobic fermentation, the anaerobism effect process of mud, in the requirement of " urban wastewater treatment firm & Mud and pollution prevention technique policy ", proposes the principle that China's & Mud should meet " safety and environmental protection, recycle, save energy and reduce the cost, suit measures to local conditions, safe reliable ".Wherein recycle and energy-saving and cost-reducing bring forward respectively energy and the encouragement of reclaiming in mud by anaerobic digestion techniques and utilize biogas heat energy, rubbish and the sludge incineration waste heat produced in the anaerobic sludge digestion process.Therefore, it is the most important thing of current & Mud that Anaerobic Digestion is disposed, and does not have at present a kind of method of comprehensive utilization of applicable sludge treatment.
Summary of the invention
The objective of the invention is urban mud anaerobic digestion and carbonizing treatment, produce biogas and prepare the mud carbide, realize minimizing, energy, the Fertilizer Transformed of mud, finally reach the urban mud anaerobic digestion of comprehensive utilization of resources of mud and the method for carbonization comprehensive utilization.
The method of described a kind of urban mud anaerobic digestion and carbonization comprehensive utilization, is characterized in that, the concrete steps of described technique are as follows successively:
(1) sludge conditioning: adopt physical method or chemical process or first adopt physical method to adopt again chemical process to be nursed one's health mud, making that moisture percentage in sewage sludge after conditioning is 90～92%, carbon-nitrogen ratio is 10～20, pH is 6.5～7.5;
(2) the complete mixing anaerobic digestion of mud: will be transported to complete mixing anaerobic digester by satisfactory mud after step (1) conditioning, the complete mixing anaerobic digester here adopts German Lipp anaerobic digestor (being called for short German sharp Pu tank), the temperature of controlling in complete mixing anaerobic digester is 35～37 ℃, and regulate and control the interior local temperature difference of complete mixing anaerobic digester at ± 0.5 ℃, then pass through pneumatic stirring, or intermittent type mechanical stirs, or carry out pneumatic stirring and intermittent type mechanical simultaneously and stir the mud made in tank and mix, after carrying out Anaerobic Digestion 15-20 days, produce anaerobic digestion solution and containing the biogas of methane 60～70%, by the existing dehydration of the process of the biogas containing methane 60～70% of producing, after desulfurization and carbonization treatment, collect in tank for sewage gas standby, in anaerobic digestion process: described pneumatic stirring is to adopt biogas return stirring mode, identical with existing methane-generating pit pneumatic stirring mode, first the biogas of the generation in tank is extracted out outside tank, by gas diffusion tube, from pot bottom, pour in tank after compression, produce stronger gas backstreaming, thereby reach the purpose that stirs feed liquid, it is the alr mode that adopts intermittent type mechanical whipping appts that rotating speed is 10～60r/min to carry out that described intermittent type mechanical stirs,
(3) Digestive system solid-liquid separation: adopt Cyclonic reactor to carry out solid-liquid separation to the anaerobic digestion solution produced in step (2), isolate the natural pond slag of water ratio 50～70%, natural pond liquid after separation is as the raw material of fertilizer, or qualified discharge or comprehensive utilization after the bio-oxidation pond art breading;
(4) natural pond slag carbonizing treatment: adopting wood chip or waste paper is that 1: 3～10 ratios directly are mixed to get the natural pond slag that water ratio is 20～30% with water ratio 50～70% natural pond slags that separate in step (3) according to mass ratio, the natural pond slag that is 20～30% by water ratio again is transported in High Temperature High Pressure internal heat type converter carbonizing plant, anaerobism or hypoxia response 10～20min, produce carbonization gas and sludge organism carbon, the carbonization gas wherein produced after the reaction directly is conveyed in the combustion chamber of High Temperature High Pressure internal heat type converter carbonizing plant to burn away provides heat for carburizing reagent; In reaction process: the temperature of reaction in High Temperature High Pressure internal heat type converter carbonizing plant is that 600～800 ℃, pressure are 15.0～16.0Mpa.
The conditioning of physics described in step (1) is to add wood chip or waste paper in mud, and make mud and wood chip or waste paper according to mass ratio 10～500: 1 ratio is mixed; Described chemical conditioning is to add several following materials of measuring arbitrarily in the mud through after physics conditioning: 10.0～100.0mg/L chitosan, 1.0～10.0mg/L polyacrylamide and 20.0～150.0mg/L calcium hydroxide make the pH of mud reach 6.5～7.5.
The complete mixing anaerobic digestion of the mud described in step (2), in the mixing anaerobic digester, carrying out fully, described complete mixing anaerobic digester tank body adopts three-decker to form, outer is that compound flaggy, middle layer are that thermal insulation layer, internal layer are the stainless steel clad plate layer, in the mixing anaerobic digester, Pneumatic mixing device, intermittent type mechanical whipping appts and constant temperature fuzzy regulation system are set fully, described Pneumatic mixing device, intermittent type mechanical whipping appts and constant temperature fuzzy regulation system all adopt existing technology and device.
Natural pond slag carbonizing treatment described in step (4) is carried out at High Temperature High Pressure internal heat type converter carbonizing plant, this carbonizing plant comprises inner converter, intermediate combustion chamber and outer hull, the natural pond slag is delivered in the burner hearth of inner converter, adopt the reaction of electrically heated Starting mode high temperature cabonization, Formed oxidizing gases and biological carbon product; The carbonization gas produced is ejected in combustion chamber and burns by spraying technique, for natural pond slag in converter carries out carburizing reagent, provides heat.
Biological carbon particle diameter 0.5～1.0mm, the water ratio of preparation are 5～10% in step (4), filling proportion is 0.50～0.55g/cm 3, contain N, P, K element.
Beneficial effect of the present invention: 1. the mud in the present invention, after physics or chemistry or physics and chemistry mixing conditioning, enters in complete mixing anaerobic retort and carries out anaerobic digestion; It is short that the complete mixing anaerobic retort of Germany Li Pu has the construction period, insulation and favorable anti-corrosion effect, the characteristics such as gas producing efficiency high (gas production rate can improve 5.0～15.0%); The biogas produced prepares Sweet natural gas after dehydration desulfurization and decarburization art breading, and the natural gas methane content of preparation, up to more than 98.0%, can be used for fuel, generating and vehicle mounted gas etc.;
2. the natural pond liquid part after carrying out anaerobic digestion in complete mixing anaerobic retort can be for the production of the raw material of fertilizer, and the liquid fertilizer of preparation can be used for agriculture machine plant husbandry, can be agricultural produce 20%; Qualified discharge or comprehensive utilization after some employing bio-oxidation pond art breading;
3. the natural pond slag after separating directly is prepared into sludge organism carbon through natural pond slag carbonizing plant, and sludge organism carbon can be used for agricultural fertilizer, material for water treatment and soil improvement material etc.
The anaerobic digestion of municipal sludge of the present invention and the comprehensive utilization of carbonizing treatment, can realize minimizing, energy, Fertilizer Transformed and the resource utilization of municipal sludge, biogas production efficiency is high, Ye He natural pond, the natural pond slag produced can well be processed or again utilize, adopt complete mixing anaerobic digestion techniques to carry out the sludge anaerobic processing, its gas production rate exceeds 5%～15% than general anaerobic digestion techniques; Adopt the internal heat type carbonizing apparatus to dispose the natural pond slag and prepare biological activated carbon, the processing unit floor space is little, and energy consumption is low; The bioactive carbon volume of producing is little, convenient transportation and storage; And be rich in N, P, K nutritive element, be widely used in the fields such as agricultural.
The accompanying drawing specification sheets
Fig. 1 is process flow sheet of the present invention
Embodiment
Below in conjunction with embodiment, the invention will be further described.In following examples, the device of main use has German sharp Pu tank, High Temperature High Pressure internal heat type converter carbonizing plant and Cyclonic reactor, the tank body of described Germany sharp Pu tank adopts three-decker, outer is that compound flaggy, middle layer are that thermal insulation layer, internal layer are the stainless steel clad plate layer, be provided with Pneumatic mixing device, intermittent type mechanical whipping appts and constant temperature fuzzy regulation system in Germany's sharp Pu tank, these devices all adopt existing technology; Described High Temperature High Pressure internal heat type converter carbonizing plant comprises inner converter, intermediate combustion chamber and outer hull, and adopts the reaction of electrically heated Starting mode high temperature cabonization; Described Cyclonic reactor adopts existing cyclone separator.
Embodiment mono-:
The concrete steps of a kind of method of urban mud anaerobic digestion and carbonization comprehensive utilization are as follows successively:
(1) sludge conditioning: first adopt ratio that physics conditioning is 300: 1 with wood chip according to mass ratio by mud to be mixed and stir evenly, then add respectively 50.0mg/L chitosan, 3.0mg/L polyacrylamide and 150.0mg/L calcium hydroxide, make that moisture percentage in sewage sludge after conditioning is 90%, carbon-nitrogen ratio is 15, pH is 6.8;
(2) the complete mixing anaerobic digestion of mud: will be transported in the tank of German sharp Pu by satisfactory mud after step (1) conditioning, the temperature of controlling in the tank of German sharp Pu by constant temperature fuzzy regulation system is 35 ℃, and adjust tank interior local temperature difference in German sharp Pu at ± 0.5 ℃, then by being arranged on the intermittent type mechanical whipping appts that in the tank of German sharp Pu, rotating speed is 10～60r/min, the mud in tank is stirred, the biogas that Anaerobic Digestion is carried out producing afterwards anaerobic digestion solution in 15 days and contained methane 60%, will be containing the biogas of 60% methane after biogas dehydration and biogas desulfurization processing, be stored in the biogas hold-up vessel, for generating, for plant area,
(3) Digestive system solid-liquid separation: will adopt Cyclonic reactor to carry out solid-liquid separation to the anaerobic digestion solution produced in step (2), and isolate the natural pond slag of water ratio 60%, the natural pond liquid after separation is as the raw material of fertilizer;
(4) natural pond slag carbonizing treatment: the water ratio 60% natural pond slag separated in employing wood chip and step (3) directly is mixed to get according to the ratio of 1: 4 the natural pond slag that water ratio is 20%, the natural pond slag that is 20% by water ratio again is transported in High Temperature High Pressure internal heat type converter carbonizing plant, anaerobism or hypoxia response 10min, produce carbonization gas and sludge organism carbon, the carbonization gas wherein produced after the reaction is directly sent in the combustion chamber of High Temperature High Pressure internal heat type converter carbonizing plant to burn away by pipeline provides heat for carburizing reagent; In reaction process: the temperature of reaction in High Temperature High Pressure internal heat type converter carbonizing plant is that 800 ℃, pressure are 16Mpa.
By sludge organism carbon granules footpath 0.5mm, the water ratio of implementing a generation be 8%, filling proportion is 0.55g/cm 3, can be used for water treatment filter material.
Embodiment bis-:
The concrete steps of a kind of method of urban mud anaerobic digestion and carbonization comprehensive utilization are as follows successively:
(1) sludge conditioning: add respectively 20mg/L chitosan and 150.0mg/L calcium hydroxide, make that moisture percentage in sewage sludge after conditioning is 91%, pH is 7.0, carbon-nitrogen ratio is 12.
(2) the complete mixing anaerobic digestion of mud: will be transported in the tank of German sharp Pu by satisfactory mud after step (1) conditioning, the temperature of controlling in the tank of German sharp Pu by constant temperature fuzzy regulation system is 36 ℃, and regulate and control the interior local temperature difference of German sharp Pu tank at ± 0.5 ℃, then by being arranged on Pneumatic mixing device in the tank of German sharp Pu, mud in tank is carried out to pneumatic stirring, Anaerobic Digestion produces anaerobic digestion solution in 20 days and contains the biogas of methane 65%, will be containing the biogas of 65% methane after biogas dehydration and biogas desulfurization processing, be stored in the biogas hold-up vessel, for generating, the residual heat recovery boiler is for the sludge pretreatment heating,
(3) Digestive system solid-liquid separation: will adopt Cyclonic reactor to carry out solid-liquid separation to the anaerobic digestion solution produced in step (2), and isolate the natural pond slag of water ratio 68%, the qualified discharge after the bio-oxidation pond art breading of the natural pond liquid after separation;
(4) natural pond slag carbonizing treatment: adopt waste paper directly to be mixed to get according to 1: 5 ratio the natural pond slag that water ratio is 25% with the water ratio 68% natural pond slag separated in step (3), the natural pond slag that is 25% by water ratio again is transported in High Temperature High Pressure internal heat type converter carbonizing plant, anaerobism or hypoxia response 15min, produce carbonization gas and sludge organism carbon, in reaction process: the temperature of reaction in High Temperature High Pressure internal heat type converter carbonizing plant is that 600 ℃, pressure are 15.0Mpa.
Sludge organism carbon granules footpath 0.80mm, the water ratio produced by embodiment bis-is 9.0%, filling proportion is 0.53g/cm 3, contain abundant N, P, K element, with the composite solid organic fertilizer for preparing of natural pond liquid.
Embodiment tri-:
The concrete steps of a kind of method of urban mud anaerobic digestion and carbonization comprehensive utilization are as follows successively:
(1) sludge conditioning: the ratio that the conditioning of employing physics is 200: 1 with wood chip according to mass ratio by mud is mixed to be stirred evenly, and the moisture percentage in sewage sludge after making to nurse one's health is 92%.
(2) the complete mixing anaerobic digestion of mud: will be transported in the tank of German sharp Pu by satisfactory mud after step (1) conditioning, the temperature of controlling in the tank of German sharp Pu by constant temperature fuzzy regulation system is 35.5 ℃, and regulate and control the interior local temperature difference of German sharp Pu tank at ± 0.5 ℃, then by being arranged on Pneumatic mixing device in the tank of German sharp Pu, mud in tank is carried out to the biogas stirring simultaneously with the intermittent type mechanical whipping appts and the intermittent type mechanical stirring makes the mud in tank carry out 20 days Anaerobic Digestion, produce anaerobic digestion solution and containing the biogas of methane 60%, to through biogas, dewater containing the biogas of 60% methane, after biogas desulfurization and biogas carbonization treatment, be stored in the biogas hold-up vessel, for vehicle mounted gas, in the Anaerobic Digestion process: described gas stirring is to adopt biogas return stirring mode, and it is the alr mode that adopts intermittent type mechanical whipping appts that rotating speed is 10～60r/min to carry out that intermittent type mechanical stirs,
(3) Digestive system solid-liquid separation: will adopt Cyclonic reactor to carry out solid-liquid separation to the anaerobic digestion solution produced in step (2), and isolate the natural pond slag of water ratio 55%, the natural pond liquid after separation is as the raw material of fertilizer;
(4) natural pond slag carbonizing treatment: adopt waste paper directly to be mixed to get according to 1: 3 ratio the natural pond slag that water ratio is 20% with the water ratio 55% natural pond slag separated in step (3), the natural pond slag that is 20% by water ratio again is transported in High Temperature High Pressure internal heat type converter carbonizing plant, anaerobism or hypoxia response 12min, produce carbonization gas and sludge organism carbon, the carbonization gas wherein produced after the reaction is directly sent in the combustion chamber of High Temperature High Pressure internal heat type converter carbonizing plant to burn away by pipeline provides heat for carburizing reagent; In reaction process: the temperature of reaction in High Temperature High Pressure internal heat type converter carbonizing plant is that 750 ℃, pressure are 15Mpa.
Sludge organism carbon granules footpath 1.0mm, the water ratio produced by embodiment tri-is 10%, filling proportion is 0.50g/cm 3, for material of construction.
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Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN105060669A (en) * | 2015-09-18 | 2015-11-18 | 成都乐维斯科技有限公司 | Sludge comprehensive utilization method by anaerobic fermentation-carbonization combination technique |
| CN105087026A (en) * | 2015-09-18 | 2015-11-25 | 成都乐维斯科技有限公司 | System for preparing carbonized gas through waste resources |
| CN105505996A (en) * | 2016-01-12 | 2016-04-20 | 中国科学院城市环境研究所 | Biogas residue thermal cracking solid product and application method thereof |
| CN106495834A (en) * | 2016-10-09 | 2017-03-15 | 洛阳茂生生物技术有限公司 | A kind of method that utilization sludge prepares fertilizer |
| CN106495835A (en) * | 2016-10-09 | 2017-03-15 | 洛阳茂生生物技术有限公司 | A kind of preparation method of Organic sludge manure |
| CN107487982A (en) * | 2017-09-22 | 2017-12-19 | 兴源环境科技股份有限公司 | A kind of feces of livestock and poultry desiccation conditioning medicament and desiccation dewatering process |
| CN110235742A (en) * | 2019-06-17 | 2019-09-17 | 上海大学 | A method of green plants matrix is prepared using sludge biogas residue |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101311245A (en) * | 2007-05-23 | 2008-11-26 | 钟正贤 | Coke oven |
| KR100973786B1 (en) * | 2009-10-06 | 2010-08-03 | 김재우 | Anaerobic digestion method of organic waste having high salinity |
| CN102531312A (en) * | 2012-01-12 | 2012-07-04 | 北京昊海天际科技有限公司 | Technology for treating sludge by using dry anaerobic fermentation and low-temperature carbonization |
| CN102603141A (en) * | 2012-03-19 | 2012-07-25 | 同济大学 | Method for improving methane yield through anaerobic fermentation of low organic matter sludge by pretreatment |
-
2012
- 2012-12-07 CN CN2012105238873A patent/CN102992559B/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101311245A (en) * | 2007-05-23 | 2008-11-26 | 钟正贤 | Coke oven |
| KR100973786B1 (en) * | 2009-10-06 | 2010-08-03 | 김재우 | Anaerobic digestion method of organic waste having high salinity |
| CN102531312A (en) * | 2012-01-12 | 2012-07-04 | 北京昊海天际科技有限公司 | Technology for treating sludge by using dry anaerobic fermentation and low-temperature carbonization |
| CN102603141A (en) * | 2012-03-19 | 2012-07-25 | 同济大学 | Method for improving methane yield through anaerobic fermentation of low organic matter sludge by pretreatment |
Non-Patent Citations (2)
| Title |
|---|
| 周富春.完全混合式有机固体废物厌氧消化过程研究.《中国优秀博士学位论文全文数据库》.2006,第43页最后1段，第45页第1、9-11，第46页第1段及倒数第3段，图3.2. |
| 完全混合式有机固体废物厌氧消化过程研究;周富春;《中国优秀博士学位论文全文数据库》;20060521;第43页最后1段，第45页第1、9-11，第46页第1段及倒数第3段，图3.2 * |
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