CN102987663B - Silica gel ring and making method thereof - Google Patents

Silica gel ring and making method thereof Download PDF

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Publication number
CN102987663B
CN102987663B CN201210552694.0A CN201210552694A CN102987663B CN 102987663 B CN102987663 B CN 102987663B CN 201210552694 A CN201210552694 A CN 201210552694A CN 102987663 B CN102987663 B CN 102987663B
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Prior art keywords
silica gel
falope ring
ring
variable color
reversible heat
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CN201210552694.0A
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CN102987663A (en
Inventor
邹勇
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SHENZHEN LYA SILICONE RUBBER PRODUCTS CO Ltd
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SHENZHEN LYA SILICONE RUBBER PRODUCTS CO Ltd
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Abstract

The invention relates to a method for making a silica gel ring. The method comprises the following steps of: 100, carrying out die cutting on a silica gel slice to obtain more than one silicon gel strip; and 200, connecting the silicon gel strips end to end with adhesive, so that the silica gel ring is formed. The method provided by the invention has the advantages that production efficiency is improved and the silica gel ring is resistant to wear, tear and high temperature and flexible, non-toxic and tasteless, does not crack or deform, produces no side effect to human body, is environment-friendly, long in service life, beautiful and fashionable and convenient to carry and also can measure temperature of human body.

Description

Make method and the falope ring of falope ring
Technical field
The present invention relates to a kind of method and the falope ring that make falope ring.
Background technology
The silica gel ornament occurred the earliest is silica gel bracelet, within 2005, first silica gel bracelet appears at the U.S., and come into vogue rapidly in the short time, first item silica gel bracelet is yellow " L IV ESTRONG " silica gel bracelet, why people wear this silica gel bracelet, mainly wish that oneself is healthy, opposing cancer.Silica gel bracelet is used for various public place of entertainment, can as gift, souvenir, promotional items etc. are a kind of ornaments of burning hot fashion, existing silica gel bracelet adopts firm silicone rubber to form through hydraulic press compacting, need certain thickness silica gel piece to be placed on backing plate center during compacting, before start and after pressure testing, also need inspection mould whether to have rhegma, can only suppress a falope ring during each compacting, the method production efficiency that silica gel piece is produced in this compacting is low.
In the life of people, clinical thermometer is a kind of necessary daily necessities, and the operation material of clinical thermometer is mercury, and above its vacuole volumetric ratio, tubule is capacious many.When surveying body temperature, the mercury in vacuole, volumetric expansion of being heated, mercury can rise to certain position in pipe by neck portion, and when reaching thermal balance with body temperature, mercury is constant.After clinical thermometer leaves human body, outside air temperature is lower, cold volume contraction met by mercury, just disconnect at narrow bent neck portion, the part mercury risen up in pipe is moved back to return, still keep mercury with the height reached during human contact, need the top holding clinical thermometer firmly down suddenly to get rid of, just can make to have risen up into the mercury in pipe, come back in vacuole.If but the glass of clinical thermometer is broken, the mercury in clinical thermometer can bring infringement and contaminated environment to human body, and along with the progress of science and technology, people have invented again a variety of clinical thermometer, as electronic thermometer, infrared thermometer etc.Said temperature meter is all independently single product, needs to carry in addition and use.If there is a kind of falope ring product, it not only has the basic function of falope ring, also has the function measuring body temperature simultaneously, will be subject to the favor in market.
Summary of the invention
The object of the invention is for the problems referred to above, a kind of method of the making falope ring that can enhance productivity is provided to society.
Second object of the present invention is to provide a kind of falope ring can measuring the body temperature of people.
Technical scheme of the present invention is: invent a kind of method making falope ring, comprising:
100. silica gel pieces are die-cut to one or more silica gel strip;
200., with the headtotail of binding by described silica gel strip, form falope ring.
As improvement of the present invention, described silica gel piece comprises the component of following percentage by weight, and reversible heat-sensible variable color microcapsules 4-15%, surplus is silica gel.
As improvement of the present invention, the composition by weight of the chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules is:
Poly-3-octyl thiophene 0.5-4.8 part
Bisphenol-A 0.5-5 part
Tetradecyl alchohol 10-30 part
Oxine 0.8-3.2 part.
As improvement of the present invention, described binding is heat-fusible adhesive, Emulsion Adhesive, aqueous type adhesive or solvent liquid adhesive.
The present invention also provides a kind of falope ring, and described falope ring is the falope ring be made up of following method:
100. silica gel pieces are die-cut to one or more silica gel strip;
200., with the headtotail of binding by described silica gel strip, form falope ring.
As improvement of the present invention, described falope ring comprises the component of following percentage by weight, and described reversible heat-sensible variable color microcapsules 4-15%, surplus is silica gel.
As improvement of the present invention, described falope ring comprises the component of following percentage by weight, and described reversible heat-sensible variable color microcapsules 4-7%, surplus is silica gel.
As improvement of the present invention, the composition by weight of the chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules is:
Poly-3-octyl thiophene 0.5-4.8 part
Bisphenol-A 0.5-5 part
Tetradecyl alchohol 10-30 part
Oxine 0.8-3.2 part.
As improvement of the present invention, the composition by weight of the chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules is:
Poly-3-octyl thiophene 0.5-1.7 part
Bisphenol-A 05-1.9 part
Tetradecyl alchohol 10-15 part
Oxine 0.8-1.2 part.
As improvement of the present invention, the diameter of described falope ring is selected at 10mm to 150mm, and described falope ring is finger ring, bracelet or pin ring.
The present invention has and enhances productivity, and does not wear-resistantly ftracture, high temperature resistant, soft indeformable, nonpoisonous and tasteless, has no side effect to human body, environmental protection, long service life, and fashion attractive in appearance is easy to carry, can also measure the advantage of the body temperature of people.
Accompanying drawing explanation
Fig. 1 is the frame structure schematic diagram that the present invention makes the method for falope ring.
Fig. 2 is the perspective view of a kind of embodiment of falope ring of the present invention.
Wherein: 1. falope ring; 2. outer surface; 3. inner surface; 4. reversible heat-sensible variable color microcapsules.
Detailed description of the invention
Refer to Fig. 1, what Fig. 1 disclosed is a kind of method making falope ring, comprising:
100. silica gel pieces are die-cut to one or more silica gel strip;
200., with the headtotail of binding by described silica gel strip, form falope ring.
Described silica gel piece comprises the component of following percentage by weight, and reversible heat-sensible variable color microcapsules 4-15%, surplus is silica gel.
The composition of the chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules is:
Poly-3-octyl thiophene 0.5-4.8 part
Bisphenol-A 0.5-5 part
Tetradecyl alchohol 10-30 part
Oxine 0.8-3.2 part.
The weight average molecular weight of described poly-3-octyl thiophene is 80000 ~ 120000, described poly-3-octyl thiophene is the procrypsis agent of supply characteristic electron, and described bisphenol-A is the developer accepting characteristic electron, and described tetradecyl alchohol is solvent, described oxine is antioxidant, extends the physical life of falope ring.
Described binding is heat-fusible adhesive, Emulsion Adhesive, aqueous type adhesive or solvent liquid adhesive.
Described heat-fusible adhesive uses after making adhesive melts by heating, is a kind of solid binder, mainly comprises the thermoplastic resins etc. such as polystyrene, polyurethane, polyacrylate; Described Emulsion Adhesive is many is suspension in water, mainly comprises vinyl acetate resin, acrylic resin etc.; Described aqueous type adhesive uses water as the adhesive of solvent, mainly comprises ethene-acetate ethylene copolymer, ethene-acrylic copolymer etc.; Described solvent type adhesive is water insoluble and be dissolved in the adhesive of certain solvent, mainly comprises butadiene-styrene rubber, polyurethane, celluloid, polyvinyl acetate etc.
The method of described making falope ring improves the efficiency of producing described falope ring.
Refer to Fig. 2, what Fig. 2 disclosed is a kind of falope ring, comprises falope ring 1, outer surface 2, inner surface 3 and reversible heat-sensible variable color microcapsules 4, described falope ring 1 is by what formed the headtotail of described silica gel strip with described binding, and described silica gel strip die-cutting machine cuts at silica gel piece patrix.
The thickness of described silica gel strip two relative edges evenly, between head and tail be parallel to each other, the diameter of described falope ring 1 is selected at 10mm to 150mm, described falope ring 1 is finger ring, bracelet or pin ring, described outer surface 2 is provided with rough word or pattern, the color of described word or pattern is identical or different, and described inner surface 3 is smooth or rough planes.
The composition of described falope ring 1 and described silica gel piece, comprises described reversible heat-sensible variable color microcapsules 4 that percentage by weight is 4-15% and surplus is described silica gel.The optimum weight percentage of described reversible heat-sensible variable color microcapsules 4 is 4-7%.Chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules 4 forms by gathering 3-octyl thiophene, bisphenol-A, tetradecyl alchohol and oxine.The weight average molecular weight of described poly-3-octyl thiophene is 80000 ~ 120000, the component of described poly-3-octyl thiophene is 0.5-4.8 part, the component of described bisphenol-A is 0.5-5 part, and the component of described tetradecyl alchohol is 10-30 part, and the component of described oxine is 0.8-3.2 part; The best component of described poly-3-octyl thiophene is 0.5-1.7 part, and the best component of described bisphenol-A is 0.5-1.9 part, and the best component of described tetradecyl alchohol is 10-15 part, and the best component of described oxine is 0.8-1.2 part.
Embodiment 1
The percentage by weight of described reversible heat-sensible variable color microcapsules 4 is 4%, and surplus is silica gel.
Embodiment 2
The percentage by weight of described reversible heat-sensible variable color microcapsules 4 is 7%, and surplus is silica gel.
Embodiment 3
The percentage by weight of described reversible heat-sensible variable color microcapsules 4 is 11%, and surplus is silica gel.
Embodiment 4
The percentage by weight of described reversible heat-sensible variable color microcapsules 4 is 15%, and surplus is silica gel.
In above-mentioned four kinds of embodiments, described reversible heat-sensible variable color microcapsules 4 are made up of four kinds of chromophoric dyestuffs of component different in following embodiment.
Embodiment 5
The component of four kinds of chromophoric dyestuffs of described reversible heat-sensible variable color microcapsules 4 is respectively:
Poly-3-octyl thiophene 0.5 part
Bisphenol-A 0.5 part
Tetradecyl alchohol 10 parts
Oxine 0.8 part.
Embodiment 6
The component of four kinds of chromophoric dyestuffs of described reversible heat-sensible variable color microcapsules 4 is respectively:
Poly-3-octyl thiophene 1.7 parts
Bisphenol-A 1.9 parts
Tetradecyl alchohol 15 parts
Oxine 1.2 parts.
Embodiment 7
The component of four kinds of chromophoric dyestuffs of described reversible heat-sensible variable color microcapsules 4 is respectively:
Poly-3-octyl thiophene 2.5 parts
Bisphenol-A 2.7 parts
Tetradecyl alchohol 20 parts
Oxine 1.9 parts.
Embodiment 8
The component of four kinds of chromophoric dyestuffs of described reversible heat-sensible variable color microcapsules 4 is respectively:
Poly-3-octyl thiophene 3.6 parts
Bisphenol-A 3.8 parts
Tetradecyl alchohol 25 parts
Oxine 2.5 parts.
Embodiment 9
The component of four kinds of chromophoric dyestuffs of described reversible heat-sensible variable color microcapsules 4 is respectively:
Poly-3-octyl thiophene 4.8 parts
Bisphenol-A 5 parts
Tetradecyl alchohol 30 parts
Oxine 3.2 parts.
In implementing according to above-mentioned difference, described falope ring 1 is different with the percentage by weight shared by the described reversible heat-sensible variable color microcapsules in described silica gel piece, and the difference of the component shared by four kinds of chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules, its temperature and color change result are as table one.
Table one is temperature and the color change table of the different embodiments of falope ring
When described falope ring 1 be worn over that finger is upper, in wrist or on ankle time, if described falope ring 1 is faint yellow, prove that the body temperature of the people wearing described falope ring 1 is normal; If described falope ring 1 becomes redness from faint yellow, prove that the body temperature of the people wearing described falope ring 1 is higher, exceeded 38 DEG C, the people at this moment wearing described falope ring 1 needs hospital to diagnose; If described falope ring 1 is faint yellow, prove that the body temperature of the people wearing described falope ring 1 is on the low side, lower than 36 DEG C, the people at this moment wearing described falope ring 1 needs hospital to diagnose.
People are by observing the color change of described falope ring 1, can recognize that whether the body temperature of the people wearing described falope ring 1 is normal in time, particularly child wears described falope ring 1, when child is sick have a high fever or low fever time, the head of a family can recognize the health of child in time, and the very first time treats.Described falope ring 1 has and wear-resistantly not to ftracture, high temperature resistant, soft indeformable, nonpoisonous and tasteless, has no side effect to human body, environmental protection, long service life, fashion attractive in appearance, advantage easy to carry.

Claims (2)

1. make a method for falope ring, it is characterized in that, comprising:
100. silica gel pieces are die-cut to one or more silica gel strip;
200., with the headtotail of binding by described silica gel strip, form falope ring; Described silica gel piece comprises the component of following percentage by weight, reversible heat-sensible variable color microcapsules 4-15%, and surplus is silica gel; The composition by weight of the chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules is:
Poly-3-octyl thiophene 0.5-4.8 part
Bisphenol-A 0.5-5 part
Tetradecyl alchohol 10-30 part
Oxine 0.8-3.2 part.
2. the method making falope ring as claimed in claim 1, is characterized in that: described binding is heat-fusible adhesive, Emulsion Adhesive, aqueous type adhesive or solvent liquid adhesive.
3. a falope ring, is characterized in that, described falope ring is the falope ring be made up of following method:
100. silica gel pieces are die-cut to one or more silica gel strip;
200., with the headtotail of binding by described silica gel strip, form described falope ring; Described falope ring comprises the component of following percentage by weight, reversible heat-sensible variable color microcapsules 4-15%, and surplus is silica gel; The composition by weight of the chromophoric dyestuffs in described reversible heat-sensible variable color microcapsules is:
Poly-3-octyl thiophene 0.5-4.8 part
Bisphenol-A 0.5-5 part
Tetradecyl alchohol 10-30 part
Oxine 0.8-3.2 part.
4. falope ring as claimed in claim 3, it is characterized in that: the diameter of described falope ring is selected at 10mm to 150mm, described falope ring is finger ring, bracelet or pin ring.
CN201210552694.0A 2012-12-19 2012-12-19 Silica gel ring and making method thereof Active CN102987663B (en)

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Application Number Priority Date Filing Date Title
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CN102987663B true CN102987663B (en) 2015-01-28

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104490021A (en) * 2015-01-08 2015-04-08 深圳市博恩实业有限公司 Intelligent color changing bracelet
CN107242650A (en) * 2017-05-05 2017-10-13 韦小敏 Temperature sensitive discoloring ring and preparation method thereof
CN107162556A (en) * 2017-06-15 2017-09-15 东莞市五同电子材料有限公司 A kind of annular temperature-sensitive silica gel product

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1280920A (en) * 2000-08-10 2001-01-24 上海天臣新技术有限公司 Reversible thermosensitive display material and its preparing process
CN1547662A (en) * 2001-01-10 2004-11-17 �޵õ�������ά��˹���ظߵȽ������� Thermochromic polymers for rapid visual assessment of temperature
CN1666140A (en) * 2002-04-29 2005-09-07 通用电气公司 Polymeric substrate for display and light emitting devices
CN101502353A (en) * 2009-03-17 2009-08-12 翟皓月 Technique for producing imitation crystal bracelet with embedded decorative color painting
CN102187747A (en) * 2008-11-12 2011-09-14 柯达公司 Polymeric conductive donor and transfer method
CN102477290A (en) * 2010-11-30 2012-05-30 北京华纺高新技术有限公司 Thermo-sensitive discoloration material microcapsule and preparation method thereof
CN202397080U (en) * 2011-11-30 2012-08-29 吴倩 Multifunctional water cup

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1280920A (en) * 2000-08-10 2001-01-24 上海天臣新技术有限公司 Reversible thermosensitive display material and its preparing process
CN1547662A (en) * 2001-01-10 2004-11-17 �޵õ�������ά��˹���ظߵȽ������� Thermochromic polymers for rapid visual assessment of temperature
CN1666140A (en) * 2002-04-29 2005-09-07 通用电气公司 Polymeric substrate for display and light emitting devices
CN102187747A (en) * 2008-11-12 2011-09-14 柯达公司 Polymeric conductive donor and transfer method
CN101502353A (en) * 2009-03-17 2009-08-12 翟皓月 Technique for producing imitation crystal bracelet with embedded decorative color painting
CN102477290A (en) * 2010-11-30 2012-05-30 北京华纺高新技术有限公司 Thermo-sensitive discoloration material microcapsule and preparation method thereof
CN202397080U (en) * 2011-11-30 2012-08-29 吴倩 Multifunctional water cup

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Owner name: SHENZHEN LYA SILICONE RUBBER PRODUCTS CO., LTD.

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Address after: 518000 Guangdong city of Shenzhen province Baoan District Longhua Industrial Park building two new Bauer

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Applicant before: Zou Yong

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