CN102978785A - Refractory fiber cloth - Google Patents
Refractory fiber cloth Download PDFInfo
- Publication number
- CN102978785A CN102978785A CN201210508693.6A CN201210508693A CN102978785A CN 102978785 A CN102978785 A CN 102978785A CN 201210508693 A CN201210508693 A CN 201210508693A CN 102978785 A CN102978785 A CN 102978785A
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- China
- Prior art keywords
- raw material
- fiber
- refractory
- cloth
- polymer
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- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
- Woven Fabrics (AREA)
Abstract
The invention relates to refractory fiber cloth and belongs to the field of composition fiber manufacturing. The invention provides the refractory fiber cloth; warp and weft of refractory fiber are interwoven to form the refractory fiber cloth; the weft is chosen from at least one of the refractory fiber and a fixed fiber; the refractory fiber takes MgSiO3, Sb2O3, SiO2, ZnO, TiO2 and Al2O3 as substrates, a polymer as a matrix, and is prepared by a melt spinning method. The fiber has the characteristics of high intensity, good fire resistance, high flexibility and the like, and can be widely applied to the fields of metallurgy, petroleum, chemical industry, machinery and the like.
Description
Technical field
The present invention relates to a kind of refractory fiber cloth, belong to composite fibre and make the field.
Background technology
Refractory fibre is with high temperature resistant, vibration resistance, to the greatest extent heat, sound absorption and the advantage such as lightweight, replaced brick structure and castable and become fire-resistant, insulation, heat insulation, sound insulation, fireproof preferred material, be used widely in industries such as metallurgy, oil, chemical industry, machinery, buildings.
Refractory fibre is divided into noncrystalline and docrystalline two large classes.The noncrystalline refractory fibre comprises aluminosilicate property, high-purity aluminosilicate property, contains chromium aluminosilicate property and high alumina fiber.The docrystalline refractory fibre comprises mullite fiber, alumina fibre and Zirconium oxide fibre.The serviceability temperature of general docrystalline refractory fibre is 1400 ℃ ~ 1600 ℃, and is along with industrial expansion, more and more higher to the requirement of refractory fibre refractory temperature and its intensity.
Summary of the invention
The purpose of this invention is to provide a kind of refractory fiber cloth, this cloth has the characteristics such as intensity height, fire resistance is good, pliability is good.
A kind of refractory fiber cloth, described cloth is interwoven by refractory fibre organizine and tram, and described tram is selected from least a in the fiber of refractory fibre and typing,
Described refractory fibre prepares as follows, and described method comprises raw material processing, slurrying, spinning and heat treated step, and in the step that described raw material is processed, described raw material is comprised of following component by mass percentage:
Described MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Average grain diameter all below 200nm;
Described typing fiber is at least a in polyurethane fiber, polyacrylonitrile fibre, the polyvinyl pyrrolidone fiber.
In the step that preferred described raw material is processed among the preparation method of refractory fibre of the present invention, described raw material is comprised of following component by mass percentage:
In the step that preferred described raw material is processed among the preparation method of refractory fibre of the present invention, described raw material is comprised of following component by mass percentage:
Preferred described MgSiO among the preparation method of refractory fibre of the present invention
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Average grain diameter be 80nm～120nm.
Preferred described slurrying step is among the preparation method of refractory fibre of the present invention: raw material is dissolved in the polymer solute, and the molecular weight of described polymer is 50000 ~ 200000.
Preferably stating polymer among the preparation method of refractory fibre of the present invention is polyvinyl pyrrolidone, PLA, polyacrylonitrile or poly(ethylene oxide).
The further preferred following technical proposals of the preparation method of refractory fibre of the present invention:
1. raw material is processed: get the raw materials ready in proportion, with MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Average grain diameter all the raw material below 200nm evenly mix;
2. slurrying: with step 1. the gained raw material be dissolved in the polymer solute, the molecular weight of described polymer is 50000 ~ 200000;
3. spinning: with step 2. the gained slurries place melt spinning device, be heated to 80 ℃ ~ 120 ℃ under the vacuum, the insulation 0.5 ~ 1h, carry out spinning with the speed of 100 ~ 200m/min subsequently, diameter is the precursor of 5 ~ 50 μ m;
4. heat treatment: with step 3. the gained precursor place high temperature furnace, under vacuum, with the speed of 5 ℃/min, be warming up to 1600 ℃ ~ 2000 ℃, process 6 ~ 48h.
The invention has the beneficial effects as follows: the invention provides a kind of refractory fiber cloth, the described cloth of this cloth is interwoven by refractory fibre organizine and tram, and described tram is selected from least a in the fiber of refractory fibre and typing, and described refractory fibre is with MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Be matrix, take polymer as matrix, adopt the melt spinning method preparation.This fiber has the characteristics such as intensity height, fire resistance is good, pliability is good, can be widely used in the fields such as metallurgy, oil, chemical industry, machinery, building.
The specific embodiment
Following non-limiting example can make the present invention of those of ordinary skill in the art's comprehend, but does not limit the present invention in any way.
Embodiment 1
1. raw material is processed: get the raw materials ready in proportion, with MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Raw material evenly mixes;
Described MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Average grain diameter be 80nm.2. slurrying: with step 1. the gained raw material be dissolved in the polyvinyl pyrrolidone solute, the molecular weight of described polyvinyl pyrrolidone is 100000;
3. spinning: with step 2. the gained slurries place melt spinning device, be heated to 120 ℃ under the vacuum, the insulation 0.5h, carry out spinning with the speed of 150m/min subsequently, diameter is the precursor of 50 μ m;
4. heat treatment: with step 3. the gained precursor place high temperature furnace, under vacuum, with the speed of 5 ℃/min, be warming up to 1850 ℃, process 12h.
The described cloth of this cloth is interwoven by refractory fibre organizine and tram, and described tram is refractory fibre and polyvinyl pyrrolidone fiberoptic fiber.
Claims (7)
1. refractory fiber cloth, it is characterized in that: described cloth is interwoven by refractory fibre organizine and tram, and described tram is selected from least a in refractory fibre and the typing fiber,
Described refractory fibre prepares as follows, and described method comprises raw material processing, slurrying, spinning and heat treated step, and in the step that described raw material is processed, described raw material is comprised of following component by mass percentage:
Described MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Average grain diameter all below 200nm;
Described typing fiber is at least a in polyurethane fiber, polyacrylonitrile fibre, the polyvinyl pyrrolidone fiber.
2. cloth according to claim 1 is characterized in that: in the step that described raw material is processed, described raw material is comprised of following component by mass percentage:
3. cloth according to claim 1 is characterized in that: in the step that described raw material is processed, described raw material is comprised of following component by mass percentage:
4. cloth according to claim 1 is characterized in that: described MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO2 and Al
2O
3Average grain diameter be 80nm～120nm.
5. cloth according to claim 1, it is characterized in that: described slurrying step is: raw material is dissolved in the polymer solute, and the molecular weight of described polymer is 50000 ~ 200000.
6. cloth according to claim 5, it is characterized in that: described polymer is polyvinyl pyrrolidone, PLA, polyacrylonitrile or poly(ethylene oxide).
7. cloth according to claim 1, it is characterized in that: described preparation method comprises following processing step:
1. raw material is processed: get the raw materials ready in proportion, with MgSiO
3, Sb
2O
3, SiO
2, ZnO, TiO
2And Al
2O
3Average grain diameter all the raw material below 200nm evenly mix;
2. slurrying: with step 1. the gained raw material be dissolved in the polymer solute, the molecular weight of described polymer is 50000 ~ 200000;
3. spinning: with step 2. the gained slurries place melt spinning device, be heated to 80 ℃～120 ℃ under the vacuum, the insulation 0.5～1h, carry out spinning with the speed of 100 ~ 200m/min subsequently, diameter is the precursor of 5 ~ 50 μ m;
4. heat treatment: with step 3. the gained precursor place high temperature furnace, under vacuum, with the speed of 5 ℃/min, be warming up to 1600 ℃ ~ 2000 ℃, process 6 ~ 48h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210508693.6A CN102978785A (en) | 2012-11-29 | 2012-11-29 | Refractory fiber cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210508693.6A CN102978785A (en) | 2012-11-29 | 2012-11-29 | Refractory fiber cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102978785A true CN102978785A (en) | 2013-03-20 |
Family
ID=47853115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210508693.6A Pending CN102978785A (en) | 2012-11-29 | 2012-11-29 | Refractory fiber cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102978785A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104480573A (en) * | 2014-12-23 | 2015-04-01 | 常熟市云燕化纤有限公司 | Fireproof and antibacterial fiber |
| CN106435835A (en) * | 2016-08-30 | 2017-02-22 | 江苏南山冶金机械制造有限公司 | Preparing method of refractory fiber used for high-temperature furnace roller |
-
2012
- 2012-11-29 CN CN201210508693.6A patent/CN102978785A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104480573A (en) * | 2014-12-23 | 2015-04-01 | 常熟市云燕化纤有限公司 | Fireproof and antibacterial fiber |
| CN106435835A (en) * | 2016-08-30 | 2017-02-22 | 江苏南山冶金机械制造有限公司 | Preparing method of refractory fiber used for high-temperature furnace roller |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130320 |