CN102965178A - High-speed chain lubricating grease and preparation method thereof - Google Patents
High-speed chain lubricating grease and preparation method thereof Download PDFInfo
- Publication number
- CN102965178A CN102965178A CN2012104273545A CN201210427354A CN102965178A CN 102965178 A CN102965178 A CN 102965178A CN 2012104273545 A CN2012104273545 A CN 2012104273545A CN 201210427354 A CN201210427354 A CN 201210427354A CN 102965178 A CN102965178 A CN 102965178A
- Authority
- CN
- China
- Prior art keywords
- lubricating grease
- chain
- speed chain
- employing
- chain lubricating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004519 grease Substances 0.000 title claims abstract description 56
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000000314 lubricant Substances 0.000 claims abstract description 20
- 239000007787 solid Substances 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 239000002199 base oil Substances 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 4
- -1 fatty acid ester Chemical class 0.000 claims description 37
- 239000003921 oil Substances 0.000 claims description 28
- 238000002156 mixing Methods 0.000 claims description 18
- 239000000654 additive Substances 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 14
- 239000004200 microcrystalline wax Substances 0.000 claims description 13
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- 229920002367 Polyisobutene Polymers 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 8
- 150000003852 triazoles Chemical class 0.000 claims description 8
- 239000007866 anti-wear additive Substances 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 230000018044 dehydration Effects 0.000 claims description 7
- 238000006297 dehydration reaction Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 7
- 150000004867 thiadiazoles Chemical class 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 7
- RAADJDWNEAXLBL-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene Chemical compound C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 RAADJDWNEAXLBL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical class NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- BFZUFHPKKNHSAG-UHFFFAOYSA-N [N].[P].[S] Chemical compound [N].[P].[S] BFZUFHPKKNHSAG-UHFFFAOYSA-N 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 229940059574 pentaerithrityl Drugs 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 239000004264 Petrolatum Substances 0.000 claims description 3
- 159000000009 barium salts Chemical class 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 229940066842 petrolatum Drugs 0.000 claims description 3
- 235000019271 petrolatum Nutrition 0.000 claims description 3
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 claims description 3
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims description 2
- 229930185605 Bisphenol Natural products 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- WLNWTZUBIFONCN-UHFFFAOYSA-N [N].[S].OP(O)(O)=O Chemical compound [N].[S].OP(O)(O)=O WLNWTZUBIFONCN-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000004982 aromatic amines Chemical class 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 1
- 150000003014 phosphoric acid esters Chemical class 0.000 claims 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 239000013556 antirust agent Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 description 11
- 238000007654 immersion Methods 0.000 description 6
- 229920000193 polymethacrylate Polymers 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 102220154133 rs202027697 Human genes 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 239000005069 Extreme pressure additive Substances 0.000 description 3
- 231100001010 corrosive Toxicity 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000010835 comparative analysis Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- 229960005215 dichloroacetic acid Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- WJUMWVJBOZKPPU-UHFFFAOYSA-N 2,3-bis(6-methylheptyl)-N-phenylaniline Chemical compound C(CCCCC(C)C)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCC(C)C WJUMWVJBOZKPPU-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000000703 anti-shock Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- OSPSWZSRKYCQPF-UHFFFAOYSA-N dibutoxy(oxo)phosphanium Chemical compound CCCCO[P+](=O)OCCCC OSPSWZSRKYCQPF-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention provides a high-speed chain lubricating grease, comprising the following components by weight: 28.8-90.1% of base oil, 5-25% of thickening agent, 0.1-1.0% of antioxidant, 0.5-5% of anti-wear reagent at extreme pressure, 0.3-3% of an anti-rust agent, 0.02-0.2% of a metal passivating agent, 2-20% of a solid lubricant and 2-20% of a tackifier. The invention also provides a preparation method of the high-speed chain lubricating grease. The high-speed chain grease provided by the invention is suitable for high-speed motorcycle chain, automobile engine chain and industrial chain. The high-speed chain lubricating grease provided by the invention adopts compound of the anti-wear reagent at extreme pressure and the solid lubricant, has excellent rust resistance, high temperature resistance, antifriction performance, water resistance, antiwear performance at extreme pressure and long-term anti-wear effect maintenance, and can be used in chains of extremely harsh speed racing car (motorcycle and automobile engine); and the chain has elongation less than 2 mm, and service life reaching up to 10000 kilometers.
Description
Technical field
The present invention relates to a kind of chain grease composition and method of making the same, specifically a kind of high-speed chain lubricating grease and preparation method thereof.
Background technology
At present, the drag racing car chain greasisng adopts the common chain rust inhibiting lubricant of dip-coating, and it consists of base oil and the ceresine viscosifying agent of mineral type, and add rust-preventive agent, oxidation inhibitor is composite forms.When these chain rust inhibiting lubricants commonly used are used on the drag racing car chain, mainly have following shortcoming: 1), a large amount of scratches and mill spot, 2 appear in chain), chain is excessively elongated and come off 3), chain moment fracture, 4), service life of chain is short.
These problems occurring mainly is owing to following reason causes: 1) base oil of chain rust inhibiting lubricant employing is plain mineral oil; have the following disadvantages: a, viscosity index are low; high temperature viscosity is little; use is on the chain of high-speed cruising; because friction temperature raises, and can not form continuous oil film and protect chain.B, at high temperature, vaporization losses is large, and is easily oxidized rotten, makes himself lifetime.2) viscosifying agent that adopts of chain rust inhibiting lubricant is the viscosifying agent of the low drippage points such as paraffin or ceresine, and use is easy to thinning loss or is got rid of on high-temperature chain, thereby causes chain and gear ring metal to-metal contact.3) Basic oil Viscosity of chain rust inhibiting lubricant employing is low, makes its poor adhesion on chain, is easily got rid of simultaneously also easily by the rainwater washout by the centrifugal force of the chain of high-speed cruising.4) antifriction quality of chain rust inhibiting lubricant is poor, and frictional force is large in the chain operational process, causes the chain self-heating severe.5) abrasion resistant extreme-pressure of chain rust inhibiting lubricant is poor, and the chain rust inhibiting lubricant does not generally add extreme pressure additive, perhaps adds dosage seldom, uses on common chain, certain scratch and wearing and tearing appear and after, chain can also continue use.But use on high-speed chain, chain was namely excessively elongated in very short time, thereby caused chain releasing or fracture.6) the chain rust inhibiting lubricant is because each component of its compatibility is only lubricated for satisfying common motorcycle or bicycle chain, use is on the racing car chain of high-speed cruising, cause the chain replacement cycle short, must change for general more than 1000 kilometers, coming off just appears in have even hundreds of kilometer, cause the racing car use cost to rise, the poor while of comprehensive economy also will affect driver's achievement.
Summary of the invention
One object of the present invention aims to provide a kind of high-speed chain lubricating grease, this lubricating grease has splendid antifriction quality, abrasion resistant extreme-pressure, rust-preventing characteristic and high and low temperature, water resisting property, use comprises on motorcycle chain and the Automotive Engine Chain at drag racing car, when the racing car rotating speed reaches 5000 rev/mins, travel 10000 kilometers, the elongation degree satisfies the at present lubricating requirement of the harshest chain less than 2mm.
Another object of the present invention provides above-mentioned high-speed chain preparation of greases method.
First purpose of the present invention is achieved through the following technical solutions: a kind of high-speed chain lubricating grease, it is characterized in that, and comprise the component of following mass percent:
Aforesaid high-speed chain lubricating grease, the mixing of one or more in described base oil employing hydroisomerization 500SN, bright stock 150BS, poly ﹠ Alpha ,-olefin oil and the ester class oil base oil.Wherein, poly ﹠ Alpha ,-olefin oil is the polymer of decene oligomerisation, and ester class oil is one or more the mixing in sebacic acid Diisooctyl, hexanodioic acid Diisooctyl, TriMethylolPropane(TMP) fatty acid ester and the acid of tetramethylolmethane fat.The hydroisomerization 500SN that adopts, bright stock 150BS, its viscosity index is at 90-100, and saturated hydrocarbon content is greater than 98%, and sulphur content is less than 0.03%; Poly ﹠ Alpha ,-olefin oil can adopt PA040, the PA010 of Mobil company or PAO170, the PAO180R of Ineis company.The sebacic acid Diisooctyl that adopts and hexanodioic acid Diisooctyl, its kinematic viscosity of 40 ℃ is 8～20mm2/s, acid number is less than 0.1mgKOH/g, and its kinematic viscosity of 40 ℃ of trimethylolpropane fatty acid ester and pentaerythritol fatty ester is 15～68mm2/s, and acid number is less than 0.1mgKOH/g.The embodiment of the invention preferentially adopts II, III class base oil (being bright stock 150BS, hydroisomerization 500SN) to be main foundation oil, and its effect is that enough oil films are provided on the chain surface, lubricate.Adopt the synthesizing ester base oil to be auxiliary base oil, its effect is to reduce the frictional coefficient of friction surface and improve additive and viscosifying agent dissolving power in base oil.The selected base oil of the present invention is hydroisomerization mineral oil and synthetic oil, and himself anti-oxidative stability is good, and vaporization losses is low, can satisfy the long lifetime requirement of high-speed chain lubricating grease.
Aforesaid high-speed chain lubricating grease, described viscosifying agent are one or both the mixing in Microcrystalline Wax and the polyethylene wax.The molecular-weight average of polyethylene wax is 2000～5000, and fusing point is 90～95, and Microcrystalline Wax is 75～No. 90, and the effect of selected viscosifying agent is colloidal structure and the denseness grade that keeps lubricating grease, and conveniently heating is smeared and soaked fat.
Aforesaid high-speed chain lubricating grease, the mixing of one or both in described oxidation inhibitor employing phenol type or the arylamine type oxidation inhibitor.Described phenol type antioxidant adopts 2,6 ditertiary butyl p cresol (T501) or 4,4-methylene radical bis-phenol; Described amine type oxidation inhibitor adopts phenyl-a-naphthylamine (T531), alkyl diamine (T534) or di-iso-octyldiphenylamine.The anti-oxidative stability of its Main Function: a, raising high-speed chain lubricating grease is controlled at 0.1～1.0% scope with its consumption the work-ing life of b, prolongation chain, can satisfy the oxidation stability requirement of high-speed chain lubricating grease.
Aforesaid high-speed chain lubricating grease, the mixing of one or more in described extreme pressure anti-wear additives employing P contained compound, sulfur phosphorus compound, sulphur phosphorus-nitrogen compound and the boron-containing compound.Described P contained compound can adopt tritolyl phosphate (T306) or di-n-butyl phosphite (T304); Described sulfur phosphorus compound can adopt thiophosphatephosphorothioate (T311) or triphenyl-thiophosphate (T309); Described sulphur phosphorus-nitrogen compound can adopt thiophosphatephosphorothioate amine salt (T307) or sulphur phosphoric acid nitrogen containing derivative (T305); Described boron-containing compound can adopt oiliness potassium borate (T361) or metaborate.The effect of extreme pressure anti-wear additives is to improve the oilness of chain fat; reduce scratch and the wearing and tearing of chain and fluted disc; and the extreme pressure anti-wear additives that contains active sulphur, phosphorus or nitrogen compound can react with the metallic surface; generate low phosphatization, sulfuration or the metal nitride solid protective membrane of shearing resistance; two kinds of metal coverings are separated, thereby prevent wearing and tearing and the sintering of metal.Boron-containing compound is under the extreme pressure state, not with the metallic surface react with, do not come lubricate by generating chemical films, but generate elastic semisolid at friction surface, the film of " non-sacrifice " that clinging power is very strong, thus the ability of anti-shock loading and vibrational loading is provided.The consumption of extreme pressure anti-wear additives is controlled at the scope of 0.5%-5%, can satisfies the abrasion resistant extreme-pressure requirement of high-speed chain lubricating grease.
Aforesaid high-speed chain lubricating grease, the mixing of one or more in described rust-preventive agent employing sulfonate, carboxylic acid and the carboxylate salt.Described sulfonate adopts dinonyl naphthalene sulfonate barium (T705); Described carboxylic acid and carboxylate salt adopt dimeracid, dodecenylsuccinic acid (T746) or oxidized petrolatum barium salt (T743).Its role is to improve the rust-preventing characteristic of high-speed chain lubricating grease; its concrete manifestation is: the polar group in the rust-preventive agent molecule has very strong adsorptive power to the metallic surface; form closely unit molecule or polymolecular protective layer in the metallic surface, stop corrosive medium and the metallic contact such as oxygen, play rust inhibition.Rust-preventive agent also has solubilising, dispersion or deactivation to water and some corrosivess simultaneously, thereby eliminates the erosion of corrosive goods confrontation metal.Its consumption is controlled at 0.3～3% scope, can satisfies the rust-preventing characteristic requirement of high-speed chain lubricating grease.
Aforesaid high-speed chain lubricating grease, the mixing of one or both in described metal passivator employing 124 Triazole and derivative or the thiadiazoles derivative; Described 124 Triazole and derivative thereof adopt benzotriazole (T706) or 124 Triazole derivative (T551); Described thiadiazoles derivative adopts thiadiazoles derivative or 2,5-disulfide group-1,3, the 4-thiadiazoles derivative its role is to metal passivator and can generate chemical films in the metallic surface, prevents that metal or metal ion from entering in the oil, to weaken the catalysed oxidn that oil product is produced, prevent sulphur, organic acid to the corrosion of the metallic surfaces such as non-ferrous metal such as copper, silver, and can not follow extreme pressure anti-wear additives competitive adsorption metallic surface, also do not affect the extreme pressure anti-wear of oil product.The consumption of metal passivator is controlled in 0.02～0.2% the scope, namely satisfies it and suppress active sulphur, organic acid to the corrosion on non-ferrous metal surface.
Aforesaid high-speed chain lubricating grease, the mixing of one or both in described solid lubricant employing tetrafluoroethylene super-fine powder (PTFE) and the melamine cyanurate salt (MCA), solid lubricant can reduce frictional coefficient, reduce the temperature rise of chain, reduce the wearing and tearing of chain, its consumption is controlled in 2～20% scopes.
Aforesaid high-speed chain lubricating grease, the mixing of one or more in described tackifier employing polyester, polyisobutene, the ethylene propylene copolymerization thing; Described polyester adopts polymethacrylate VISCOPLEX8-450; Described polyisobutene adopts low molecular polyisobutylene PB1300 or PB2400; Described ethylene-propylene copolymer adopts ethylene propylene copolymer T612 or T614.It act as: 1) improve high-speed chain grease base plinth oil viscosity; 2) improve high-speed chain lubricating grease in the adhesive capacity of metallic surface; 3) improve the low temperature properties of high-speed chain lubricating grease.
Second purpose of the present invention realizes by following technical measures: a kind of high-speed chain preparation of greases method comprises the steps:
1) first base oil, viscosifying agent and tackifier are added in the reactor together, heated and stirred is warming up to 100 ± 5 ℃, and constant temperature stirred 30-60 minute, make the viscosifying agent fusing, be warming up to again 120 ± 5 ℃, be evacuated to-0.08MPa, keep the logically true empty dehydration of constant temperature 1.5-3 hour;
2) add successively solid additive and solid lubricant again, mix 10-30 minute, make the solid additive dissolving, add fluid additive again, mix 30-60 minute, discharging enters in the bucket; Described solid additive and fluid additive refer to oxidation inhibitor, extreme pressure anti-wear additives, rust-preventive agent and metal passivator.
3) naturally cool to 40 ± 10 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Its immersion oil method of high-speed chain lubricating grease of the present invention is: high-speed chain lubricating grease is heated to 120～140 ℃, new chain is put into oil soak about 5 seconds, take out and dry or dry and can be delivered for use.Every chain immersion oil amount is 4 ± 0.5 grams.
Road test
1, test chain and vehicle: test chain strip adoption Yangtse River in Chongqing chain company limited produces the TD160 chain, the racing car motor GP150CC (LX150CC-56) that the test vehicle adopts Chongqing Longxin general dynamic stock company to produce.
2, test method: 2 months time, 20000 kilometers of mileages, 80 ± 10 kilometers/hour of average speeds, 10 of number of units.Chain immersion oil kind and immersion oil amount: the immersion oil kind is high-speed chain lubricating grease of the present invention, and the immersion oil amount is 4 ± 0.5 gram/bars.
3, test-results: 1) the chain outward appearance is without wearing and tearing, non-cracking, non-corroding.2) chain amount of tension: average amount of elongation 1.8mm.3) chain is changed situation: 1 bogie chain occurs and come off 1 time, do not change all the other 9 the replacing situations that do not occur coming off.Wherein a chassis of chain releasing belongs to fluted disc damage institute and causes on inspection, behind the replacing fluted disc, again loads onto former chain and continues test.
Compared with prior art, the beneficial effect that has of the present invention:
1, high-speed chain lubricating grease provided by the invention is base oil by hydroisomerization mineral oil and the synthetic oil of deep refining, make with extra care and form with viscosifying agent, antioxidant, extreme pressure additive, rust-preventive agent, metal passivator, solid lubricant, tackifier, have outstanding high and low temperature, antifriction quality, abrasion resistant extreme-pressure, adhesivity, rust-preventing characteristic and water resisting property.
2, high-speed chain lubricating grease provided by the invention, through 80 ± 10 kilometers/hour of V-bars, 20,000 kilometers driving experiment, its result is: chain is without wearing and tearing, non-cracking, non-corroding phenomenon, chain amount of tension average out to 1.8mm.
3, high-speed chain lubricating grease provided by the invention adopts extreme pressure additive and solid lubricant composite, and adds the synthesizing ester oil that the reduction frictional coefficient is arranged and improve anti-oxidative stability and improve adhering tackifier.Make the chain of high-speed cruising can continue for a long time to obtain the antiwear and antifriction protection, and can resist impact load and vibrational loading, have obvious technical superiority and technological innovation.
4, high-speed chain lubricating grease provided by the invention uses on the drag racing car chain, and the chain replacement cycle can reach more than 10,000 kilometers, is more than 5 times of chain rust inhibiting lubricant service life of chain that use at present.Use is on common motorcycle, motor car engine and industrial chain, and the replacement cycle can reach more than 20,000 kilometers, is more than 3 times of chain rust inhibiting lubricant service life of chain that use at present.Therefore, reduce the use cost of chain, had preferably economy and marketable value.
Embodiment
Below in conjunction with specific embodiment, the technical scheme among the present invention is clearly and completely described, however the non-following examples that only are confined to of protection scope of the present invention.
Embodiment one
1) first with 577 kilograms of hydroisomerization 500SN, 50 kilograms of sebacic acid Diisooctyl (V40=8.52mm
2/ s), double centner polyisobutene PB1300 (tackifier), 20 kilograms of polymethacrylate 8-450 (tackifier), No. 85 Microcrystalline Waxes of double centner (viscosifying agent), 50 kilograms of polyethylene waxs (viscosifying agent) add in the reactor together, heated and stirred is warming up to 100 ℃, constant temperature stirred 45 minutes, make the fusing of Microcrystalline Wax and polyethylene wax, be warming up to again 120 ℃, be evacuated to-0.08MPA, keep the logically true empty dehydration of constant temperature 2 hours.
2) add successively 3 kilograms of phenyl-a-naphthylamine (T531), 2 kilogram 2,6-ditertbutylparacresol (T501), 1 kilogram of benzotriazole (T706), 20 kilograms of oiliness potassium borates (T361), 50 kilograms of tetrafluoroethylene super-fine powder, mix 20 minutes, make the solid additive fusing, add 20 kilograms of nonyl naphthalene barium sulfonates (T705), 7.5 kilograms of dimeracids, 10 kilograms of tritolyl phosphate tritolyl phosphate T306 again, mix 20 minutes, discharging enters in the bucket.
3) naturally cool to 40 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Embodiment two
1) with 300 kilograms of hydroisomerization 500SN, 225 kilograms of bright stock 150BS, 50 kilograms of trimethylolpropane fatty acid ester (V40=67.2mm
2/ s), 50 kilograms of polymethacrylate 8-450 (tackifier), double centner ethylene propylene copolymer finish (T612C) (tackifier), 160 kilograms of No. 80 Microcrystalline Waxes (viscosifying agent) add in the reactor together, heated and stirred is warming up to 95 ℃, constant temperature stirred 30 minutes, make the Microcrystalline Wax fusing, be warming up to again 115 ℃, be evacuated to-0.08MPa, keep the logically true empty dehydration of constant temperature 1.5 hours.
2) add successively 3 kilograms of phenyl-a-naphthylamine (T531), 2 kilogram 2,6-ditertbutylparacresol (T501), 20 kilograms of oiliness potassium borates (T361), 30 kilograms of melamine cyanurate salts, 20 kilograms of tetrafluoroethylene super-fine powder, mix 15 minutes, make the solid additive fusing, add again 0.5 kilogram of 124 Triazole derivative (T551), 30 kilograms of dinonyl naphthalene sulfonate bariums (T705), 10 kilograms of positive butyl esters of phosphorous acid (T304), mix 30 minutes, discharging enters in the bucket.
3) naturally cool to 30 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Embodiment three
1) first with 120 kilograms of hydroisomerization 500SN, 455 kilograms of bright stock 150BS, 50 kilograms of trimethylolpropane fatty acid ester (V40=19.4mm
2/ s), 20 kilograms of polymethacrylate 8-450 (tackifier), 60 kilograms of polyisobutene PB2400 (tackifier), 90 kilograms of No. 90 Microcrystalline Waxes (viscosifying agent), 60 kilograms of polyethylene waxs (viscosifying agent) add in the reactor together, heated and stirred is warming up to 105 ℃, constant temperature stirred 60 minutes, make the fusing of Microcrystalline Wax and polyethylene wax, be warming up to again 125 ℃, be evacuated to-0.08MPa, keep the logically true empty dehydration of constant temperature 3 hours.
2) add successively 5 kilograms of alkyl diphenylamines (T534), 30 kilograms of oiliness potassium borates (T361), 50 kilograms of melamine cyanurate salts, 30 kilograms of tetrafluoroethylene super-fine powder, mix 15 minutes, make the solid additive fusing, add again 0.5 kilogram of thiadiazoles derivative (T561), 5 kilograms of dodecenylsuccinic acids (T746), 20 kilograms of dinonyl naphthalene sulfonate bariums (705), 5 kilograms of triphenyl-thiophosphates (T309), mix 60 minutes, discharging enters in the bucket.
3) naturally cool to 50 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Embodiment four
1) first with 229 kilograms of hydroisomerization 500SN, 300 kilograms of bright stock 150BS, 50 kilograms of pentaerythritol fatty ester (V40=67.2mm
2/ s), 50 kilograms of polymethacrylate 8-450,80 kg ethylene propylene copolymers (T614) (tackifier), 80 kilograms of No. 85 Microcrystalline Waxes (viscosifying agent), 80 kilograms of polyethylene waxs (viscosifying agent) add in the reactor together, heated and stirred is warming up to 100 ℃, constant temperature stirred 60 minutes, make the fusing of Microcrystalline Wax and polyethylene wax, be warming up to again 120 ℃, be evacuated to-0.08MPa, keep the logically true empty dehydration of constant temperature 3 hours.
2) add successively 5 kilograms of phenyl-a-naphthylamine (T531), 1 kilogram of benzotriazole (T706), 30 kilograms of oiliness potassium borates (T361), 50 kilograms of melamine cyanurate salts, 30 kilograms of tetrafluoroethylene super-fine powder, restir mixed 15 minutes, make the solid additive fusing, add again 10 kilograms of tritolyl phosphates (T306), 20 kilograms of dinonyl naphthalene sulfonate bariums (T705), 5 kilograms of oxidized petrolatum barium salts (T743), mix 60 minutes, discharging enters in the bucket.
3) naturally cool to 40 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Embodiment five
1) first with 232 kilograms of poly ﹠ Alpha ,-olefin oils (PAO170), 350 kilograms of poly ﹠ Alpha ,-olefin oils (PAO180R), 50 kilograms of trimethylolpropane fatty acid ester (V40=19.4mm
2/ s), 50 kilograms of polymethacrylate 8-450 (tackifier), 55 kg ethylene propylene copolymer finishes (T612C) (tackifier), 78 kilograms of No. 85 Microcrystalline Waxes (viscosifying agent), 62 kilograms of polyethylene waxs (viscosifying agent) add in the reactor together, heated and stirred is warming up to 100 ℃, constant temperature stirred 50 minutes, make the fusing of Microcrystalline Wax and polyethylene wax, be warming up to again 120 ℃, be evacuated to-0.08MPa, keep the logically true empty dehydration of constant temperature 1.5 hours.
2) add successively 5 kilograms of phenyl-a-naphthylamine (T531), 2 kilogram 2,6-ditertbutylparacresol (T501), 1 kilogram of 124 Triazole derivative (T551), 30 kilograms of oiliness borates (T361), 50 kilograms of tetrafluoroethylene super-fine powder, mix 10 minutes, make the solid additive fusing, add again 20 kilograms of dinonyl naphthalene sulfonate bariums (T705), 5 kilograms of dodecenylsuccinic acids (T746), 50 kilograms of thiophosphatephosphorothioate amine salt (T307), mix 30 minutes, discharging enters in the bucket.
3) naturally cool to 40 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Following table is listed the embodiment of the invention one, three and the comparative analysis result of commercially available two kinds of chain rust preventing greases.By as seen from Table 1, high-speed chain lubricating grease of the present invention and the contrast of commercially available chain rust preventing grease, viscosity is large, dropping point is high, vaporization losses is little for high-speed chain lubricating grease high-temperature of the present invention (100 ℃), salt fog and humidity cabinet experimental period are long, it is little that anti-water drenches loss, and it is high that four ball cards are stung load, and wear scar diameter is little, the rotary oxygen bomb time is long, shows that high-speed chain lubricating grease of the present invention has outstanding rust-preventing characteristic, high warm nature, abrasion resistant extreme-pressure, water resisting property and long work-ing life.Be particularly suitable for using on the racing car chain of running at high speed and industrial chain.
Table 1 embodiment of the invention one, three and the comparative analysis result of commercially available two kinds of chain rust preventing greases
The above; be the specific embodiment of the present invention only, but protection scope of the present invention is not limited to this, anyly belongs to those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.
Claims (10)
1. high-speed chain lubricating grease is characterized in that: the component that comprises following mass percent:
2. high-speed chain lubricating grease as claimed in claim 1, it is characterized in that: the mixing of one or more in described base oil employing hydroisomerization 500SN, bright stock 150BS, poly ﹠ Alpha ,-olefin oil and the ester class oil base oil, wherein, poly ﹠ Alpha ,-olefin oil is the polymer of decene oligomerisation, and ester class oil is one or more the mixing in sebacic acid Diisooctyl, hexanodioic acid Diisooctyl, TriMethylolPropane(TMP) fatty acid ester and the acid of tetramethylolmethane fat.
3. high-speed chain lubricating grease as claimed in claim 1 is characterized in that: described viscosifying agent is one or both the mixing in Microcrystalline Wax and the polyethylene wax.
4. high-speed chain lubricating grease as claimed in claim 1 is characterized in that: the mixing of one or both in described oxidation inhibitor employing phenol type or the arylamine type oxidation inhibitor; The mixing of one or more in described extreme pressure anti-wear additives employing P contained compound, sulfur phosphorus compound, sulphur phosphorus-nitrogen compound and the boron-containing compound; The mixing of one or more in described rust-preventive agent employing sulfonate, carboxylic acid and the carboxylate salt; The mixing of one or both in described metal passivator employing 124 Triazole and derivative or the thiadiazoles derivative; The mixing of one or both in described solid lubricant employing tetrafluoroethylene super-fine powder (PTFE) and the melamine cyanurate salt (MCA); The mixing of one or more in described tackifier employing polyester, polyisobutene, the ethylene propylene copolymerization thing.
5. high-speed chain lubricating grease as claimed in claim 4 is characterized in that: described phenol type antioxidant employing 2,6 ditertiary butyl p cresol or 4,4-methylene radical bis-phenol; Described amine type oxidation inhibitor adopts phenyl-a-naphthylamine, alkyl diamine.
6. high-speed chain lubricating grease as claimed in claim 4 is characterized in that: described P contained compound employing phosphoric acid ester or phosphorous acid ester; Described sulfur phosphorus compound adopts thiophosphatephosphorothioate or triphenyl-thiophosphate; Described sulphur phosphorus-nitrogen compound adopts thiophosphatephosphorothioate amine salt or sulphur phosphoric acid nitrogen containing derivative; Described boron-containing compound adopts oiliness potassium borate or metaborate.
7. high-speed chain lubricating grease as claimed in claim 4 is characterized in that: described sulfonate employing dinonyl naphthalene sulfonate barium; Described carboxylic acid and carboxylate salt adopt dimeracid, dodecenylsuccinic acid or oxidized petrolatum barium salt.
8. high-speed chain lubricating grease as claimed in claim 4 is characterized in that: described 124 Triazole and derivative employing benzotriazole or 124 Triazole derivative; Described thiadiazoles derivative adopts thiadiazoles derivative or 2,5-disulfide group-1,3,4-thiadiazoles derivative.
9. high-speed chain lubricating grease as claimed in claim 4 is characterized in that: the poly-methylpropane acid esters of described polyester employing; Described polyisobutene adopts low molecular polyisobutylene.
10. one kind such as the described high-speed chain preparation of greases of arbitrary claim method in the claim 1～9, it is characterized in that comprising the steps:
1) first base oil, viscosifying agent and tackifier are added in the reactor together, heated and stirred is warming up to 100 ± 5 ℃, and constant temperature stirred 30-60 minute, make the viscosifying agent fusing, be warming up to again 120 ± 5 ℃, be evacuated to-0.08MPa, keep the logically true empty dehydration of constant temperature 1.5-3 hour;
2) add successively solid additive and solid lubricant again, mix 10-30 minute, make the solid additive dissolving, add fluid additive again, mix 30-60 minute, discharging enters in the bucket;
3) naturally cool to 40 ± 10 ℃, grind 3 times by three-roll grinder, namely get high-speed chain lubricating grease.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210427354.5A CN102965178B (en) | 2012-10-30 | 2012-10-30 | High-speed chain lubricating grease and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210427354.5A CN102965178B (en) | 2012-10-30 | 2012-10-30 | High-speed chain lubricating grease and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102965178A true CN102965178A (en) | 2013-03-13 |
| CN102965178B CN102965178B (en) | 2014-10-15 |
Family
ID=47795614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210427354.5A Active CN102965178B (en) | 2012-10-30 | 2012-10-30 | High-speed chain lubricating grease and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102965178B (en) |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103242942A (en) * | 2013-04-26 | 2013-08-14 | 武汉博达特种润滑技术有限公司 | Low-temperature worm and gear lubricating grease composition and preparation method thereof |
| CN103275789A (en) * | 2013-06-27 | 2013-09-04 | 苏州工业园区依利电子贸易有限公司 | Multifunctional lubricating oil |
| CN103333725A (en) * | 2013-07-25 | 2013-10-02 | 中国石油化工股份有限公司 | Lubricating oil composition for paint drying room and preparation method thereof |
| CN103343042A (en) * | 2013-07-26 | 2013-10-09 | 中国石油化工股份有限公司 | Water-based chain lubricant |
| CN103497813A (en) * | 2013-09-02 | 2014-01-08 | 安庆市中天石油化工有限公司 | Lubricating grease specially used in metallurgical industry continuous casting machine, and preparation method thereof |
| CN103540389A (en) * | 2013-10-17 | 2014-01-29 | 深圳市红叶杰科技有限公司 | Fluorine-containing high-temperature lubricating grease |
| CN104119993A (en) * | 2014-07-01 | 2014-10-29 | 上海亚杜润滑材料股份有限公司 | Mechanical lubricant |
| CN104342263A (en) * | 2014-09-28 | 2015-02-11 | 苏州长盛机电有限公司 | High-temperature chain lubricant and preparation method thereof |
| CN104531285A (en) * | 2014-11-12 | 2015-04-22 | 安徽荣达阀门有限公司 | Antirust grease applicable to bearing sealing and preparation method thereof |
| CN105018202A (en) * | 2015-06-30 | 2015-11-04 | 上海禾泰特种润滑科技股份有限公司 | Steel wire rope lubricant composition and preparation method thereof |
| CN105018192A (en) * | 2015-06-15 | 2015-11-04 | 赵兰 | Lubricating oil for drive chains of locomotives and method for preparing same |
| CN105038925A (en) * | 2015-06-30 | 2015-11-11 | 上海禾泰特种润滑科技股份有限公司 | Lubricant and preparation method thereof |
| CN105112126A (en) * | 2015-08-25 | 2015-12-02 | 苏州铱诺化学材料有限公司 | Chain anti-rust lubricating grease and preparation method thereof |
| CN106281583A (en) * | 2015-05-29 | 2017-01-04 | 克鲁勃润滑产品（上海）有限公司 | Lubricant and preparation method thereof |
| CN106753688A (en) * | 2016-12-30 | 2017-05-31 | 天津南开大学蓖麻工程科技有限公司 | Biodegradable chain oil special for electric chain saw |
| CN107474922A (en) * | 2017-08-24 | 2017-12-15 | 中国石油化工股份有限公司 | A kind of wiper motor electric contact lubricant composition and preparation method |
| CN107828467A (en) * | 2017-10-19 | 2018-03-23 | 中国石油化工股份有限公司 | A kind of composition and preparation method of petroleum casing pipe storing lubricating grease |
| CN108518487A (en) * | 2018-04-23 | 2018-09-11 | 芜湖市华邦流体科技有限公司 | A kind of high leakproofness butterfly valve |
| CN108531264A (en) * | 2017-03-02 | 2018-09-14 | 深圳市合诚润滑材料有限公司 | Lubricating grease and preparation method thereof for automobile gate glass lifter |
| CN108865339A (en) * | 2018-08-01 | 2018-11-23 | 清研高装润滑科技（天津）有限公司 | A kind of high-speed EMUs axle box bearing lubricant composition and preparation method thereof |
| CN109504503A (en) * | 2018-11-06 | 2019-03-22 | 苏州玖城润滑油有限公司 | A kind of chain grease and preparation method thereof |
| CN109504500A (en) * | 2018-12-14 | 2019-03-22 | 中国石油化工股份有限公司 | A kind of lubricant composition and preparation method thereof for engine bearing assembly |
| CN110257132A (en) * | 2019-05-22 | 2019-09-20 | 常熟理工学院 | A kind of wide warm wire-rope grease of elevator |
| CN112175702A (en) * | 2020-10-20 | 2021-01-05 | 武汉博达特种润滑技术有限公司 | Lubricating grease composition for reduction gearbox of micro motor and preparation method thereof |
| CN112251275A (en) * | 2020-10-15 | 2021-01-22 | 武汉博达特种润滑技术有限公司 | Lubricating grease composition for fireproof door speed reducer and preparation method thereof |
| CN112552985A (en) * | 2020-12-14 | 2021-03-26 | 武汉博达特种润滑技术有限公司 | Low-temperature rod-shaped valve rod sealing grease composition and preparation method thereof |
| CN112608781A (en) * | 2020-12-08 | 2021-04-06 | 武汉博达特种润滑技术有限公司 | Rod-shaped valve rod sealant composition and preparation method thereof |
| US11697136B2 (en) | 2019-08-13 | 2023-07-11 | BBLink, LLC | Automated link chain cleaning and lubricating system |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101240220A (en) * | 2008-03-12 | 2008-08-13 | 益田润石（北京）化工有限公司 | Densification type high temperature chain lubricating agent composition |
| US20090062160A1 (en) * | 2007-09-03 | 2009-03-05 | Tsubakimoto Chain Co. | Oilless chain and method of producing oilless chain |
| CN101896587A (en) * | 2007-12-12 | 2010-11-24 | 株式会社椿本链条 | Lubricant composition for chain and chain |
| CN102618371A (en) * | 2012-03-09 | 2012-08-01 | 河南省煤炭科学研究院有限公司 | Steel rope grease with high dropping point and preparation method of steel rope grease |
-
2012
- 2012-10-30 CN CN201210427354.5A patent/CN102965178B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090062160A1 (en) * | 2007-09-03 | 2009-03-05 | Tsubakimoto Chain Co. | Oilless chain and method of producing oilless chain |
| CN101896587A (en) * | 2007-12-12 | 2010-11-24 | 株式会社椿本链条 | Lubricant composition for chain and chain |
| CN101240220A (en) * | 2008-03-12 | 2008-08-13 | 益田润石（北京）化工有限公司 | Densification type high temperature chain lubricating agent composition |
| CN102618371A (en) * | 2012-03-09 | 2012-08-01 | 河南省煤炭科学研究院有限公司 | Steel rope grease with high dropping point and preparation method of steel rope grease |
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103242942B (en) * | 2013-04-26 | 2014-08-13 | 武汉博达特种润滑技术有限公司 | Low-temperature worm and gear lubricating grease composition and preparation method thereof |
| CN103242942A (en) * | 2013-04-26 | 2013-08-14 | 武汉博达特种润滑技术有限公司 | Low-temperature worm and gear lubricating grease composition and preparation method thereof |
| CN103275789A (en) * | 2013-06-27 | 2013-09-04 | 苏州工业园区依利电子贸易有限公司 | Multifunctional lubricating oil |
| CN103333725A (en) * | 2013-07-25 | 2013-10-02 | 中国石油化工股份有限公司 | Lubricating oil composition for paint drying room and preparation method thereof |
| CN103343042A (en) * | 2013-07-26 | 2013-10-09 | 中国石油化工股份有限公司 | Water-based chain lubricant |
| CN103343042B (en) * | 2013-07-26 | 2014-12-10 | 中国石油化工股份有限公司 | Water-based chain lubricant |
| CN103497813B (en) * | 2013-09-02 | 2015-08-19 | 安庆市中天石油化工有限公司 | A kind ofly be exclusively used in lubricating grease of metallurgy industry continuous caster and preparation method thereof |
| CN103497813A (en) * | 2013-09-02 | 2014-01-08 | 安庆市中天石油化工有限公司 | Lubricating grease specially used in metallurgical industry continuous casting machine, and preparation method thereof |
| CN103540389A (en) * | 2013-10-17 | 2014-01-29 | 深圳市红叶杰科技有限公司 | Fluorine-containing high-temperature lubricating grease |
| CN104119993A (en) * | 2014-07-01 | 2014-10-29 | 上海亚杜润滑材料股份有限公司 | Mechanical lubricant |
| CN104342263A (en) * | 2014-09-28 | 2015-02-11 | 苏州长盛机电有限公司 | High-temperature chain lubricant and preparation method thereof |
| CN104531285A (en) * | 2014-11-12 | 2015-04-22 | 安徽荣达阀门有限公司 | Antirust grease applicable to bearing sealing and preparation method thereof |
| CN106281583A (en) * | 2015-05-29 | 2017-01-04 | 克鲁勃润滑产品（上海）有限公司 | Lubricant and preparation method thereof |
| CN105018192A (en) * | 2015-06-15 | 2015-11-04 | 赵兰 | Lubricating oil for drive chains of locomotives and method for preparing same |
| CN105018202A (en) * | 2015-06-30 | 2015-11-04 | 上海禾泰特种润滑科技股份有限公司 | Steel wire rope lubricant composition and preparation method thereof |
| CN105038925A (en) * | 2015-06-30 | 2015-11-11 | 上海禾泰特种润滑科技股份有限公司 | Lubricant and preparation method thereof |
| CN105038925B (en) * | 2015-06-30 | 2018-03-02 | 上海禾泰特种润滑科技股份有限公司 | Lubricant and preparation method thereof |
| CN105018202B (en) * | 2015-06-30 | 2018-03-02 | 上海禾泰特种润滑科技股份有限公司 | Ripe lubricant composition and preparation method thereof |
| CN105112126A (en) * | 2015-08-25 | 2015-12-02 | 苏州铱诺化学材料有限公司 | Chain anti-rust lubricating grease and preparation method thereof |
| CN106753688A (en) * | 2016-12-30 | 2017-05-31 | 天津南开大学蓖麻工程科技有限公司 | Biodegradable chain oil special for electric chain saw |
| CN108531264A (en) * | 2017-03-02 | 2018-09-14 | 深圳市合诚润滑材料有限公司 | Lubricating grease and preparation method thereof for automobile gate glass lifter |
| CN107474922A (en) * | 2017-08-24 | 2017-12-15 | 中国石油化工股份有限公司 | A kind of wiper motor electric contact lubricant composition and preparation method |
| CN107828467B (en) * | 2017-10-19 | 2020-12-08 | 中国石油化工股份有限公司 | Composition for storing lubricating grease for petroleum casing and preparation method thereof |
| CN107828467A (en) * | 2017-10-19 | 2018-03-23 | 中国石油化工股份有限公司 | A kind of composition and preparation method of petroleum casing pipe storing lubricating grease |
| CN108518487A (en) * | 2018-04-23 | 2018-09-11 | 芜湖市华邦流体科技有限公司 | A kind of high leakproofness butterfly valve |
| CN108865339A (en) * | 2018-08-01 | 2018-11-23 | 清研高装润滑科技（天津）有限公司 | A kind of high-speed EMUs axle box bearing lubricant composition and preparation method thereof |
| CN108865339B (en) * | 2018-08-01 | 2021-08-20 | 清研高装润滑科技（天津）有限公司 | Lubricating grease composition for axle box bearing of high-speed motor train unit and preparation method thereof |
| CN109504503A (en) * | 2018-11-06 | 2019-03-22 | 苏州玖城润滑油有限公司 | A kind of chain grease and preparation method thereof |
| CN109504500A (en) * | 2018-12-14 | 2019-03-22 | 中国石油化工股份有限公司 | A kind of lubricant composition and preparation method thereof for engine bearing assembly |
| CN110257132A (en) * | 2019-05-22 | 2019-09-20 | 常熟理工学院 | A kind of wide warm wire-rope grease of elevator |
| US11697136B2 (en) | 2019-08-13 | 2023-07-11 | BBLink, LLC | Automated link chain cleaning and lubricating system |
| CN112251275A (en) * | 2020-10-15 | 2021-01-22 | 武汉博达特种润滑技术有限公司 | Lubricating grease composition for fireproof door speed reducer and preparation method thereof |
| CN112175702A (en) * | 2020-10-20 | 2021-01-05 | 武汉博达特种润滑技术有限公司 | Lubricating grease composition for reduction gearbox of micro motor and preparation method thereof |
| CN112608781A (en) * | 2020-12-08 | 2021-04-06 | 武汉博达特种润滑技术有限公司 | Rod-shaped valve rod sealant composition and preparation method thereof |
| CN112608781B (en) * | 2020-12-08 | 2022-07-19 | 武汉博达特种润滑技术有限公司 | Rod-shaped valve rod sealant composition and preparation method thereof |
| CN112552985A (en) * | 2020-12-14 | 2021-03-26 | 武汉博达特种润滑技术有限公司 | Low-temperature rod-shaped valve rod sealing grease composition and preparation method thereof |
| CN112552985B (en) * | 2020-12-14 | 2022-07-19 | 武汉博达特种润滑技术有限公司 | Low-temperature rod-shaped valve rod sealing grease composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102965178B (en) | 2014-10-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102965178B (en) | High-speed chain lubricating grease and preparation method thereof | |
| CN107312598B (en) | Low-temperature overweight load synthetic gear oil | |
| JP5646859B2 (en) | Lubricating oil composition for continuously variable transmission | |
| CN107312597B (en) | Triple composite film wear-resistant energy-saving engine oil | |
| CN101696366B (en) | Method for preparing lubricating grease with excellent anti-wear and wear-resistant performance | |
| CN106190435B (en) | Quarry tipper heavy-duty gear oil compound additive and its lubricant oil composite | |
| JP6035175B2 (en) | Lubricating oil composition | |
| CN101993763A (en) | Gear oil composition for automobile | |
| CN105001960A (en) | Opening type rotor engine bearing lubricating grease composition | |
| CN104342226A (en) | Use of trimethylolpropane oleate, trimethylolpropane oleate containing composition and use of trimethylolpropane oleate containing composition | |
| JP2016190918A (en) | Lubricant composition | |
| CN116083150B (en) | Gear oil composition of transmission system and application thereof | |
| JP5961097B2 (en) | Lubricating oil composition | |
| JP5025842B2 (en) | Gear oil composition | |
| CN103666657B (en) | Heavy-load vehicle hub bearing grease | |
| JP6444219B2 (en) | Lubricating oil composition for gear oil | |
| CN105062638A (en) | Environment-friendly ultralow-temperature bearing grease composition with low noise performance | |
| CN1718701A (en) | Composite high temperature areidofat | |
| CN105255569A (en) | Working liquid composition for hydraulic hybrid power device | |
| CN116064187A (en) | Vehicle gear oil with long oil change period | |
| KR101030355B1 (en) | Environment-friendly grease composite which a price competitiveness is superior | |
| KR102312591B1 (en) | Hybrid Lubricant Composition | |
| CN112011390B (en) | Steel wire rope oil composition special for arresting cable | |
| JP6382749B2 (en) | Lubricating oil composition for final reduction gear | |
| CN115637186A (en) | High-temperature-resistant and wear-resistant hydraulic oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: No. 1-702 Wenhao Free Business Port, 699 Xiongchu Street, Wuhan City, Hubei Province 430074 Patentee after: Boda Industrial Technology Wuhan Co.,Ltd. Country or region after: China Address before: No. 1-702 Wenhao Free Business Port, 699 Xiongchu Street, Wuhan City, Hubei Province 430074 Patentee before: WUHAN BODA SPECIAL LUBRICANT TECHNOLOGY CO.,LTD. Country or region before: China |