CN102964849A - Fish scale collagen protein/pulullan compound edible film and preparation method thereof - Google Patents
Fish scale collagen protein/pulullan compound edible film and preparation method thereof Download PDFInfo
- Publication number
- CN102964849A CN102964849A CN2012105654309A CN201210565430A CN102964849A CN 102964849 A CN102964849 A CN 102964849A CN 2012105654309 A CN2012105654309 A CN 2012105654309A CN 201210565430 A CN201210565430 A CN 201210565430A CN 102964849 A CN102964849 A CN 102964849A
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- CN
- China
- Prior art keywords
- fish scale
- scale collagen
- pulullan
- pulullan polysaccharide
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 102000008186 Collagen Human genes 0.000 title claims abstract description 46
- 108010035532 Collagen Proteins 0.000 title claims abstract description 46
- 150000001875 compounds Chemical class 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 241000251468 Actinopterygii Species 0.000 claims abstract description 41
- 229920001436 collagen Polymers 0.000 claims abstract description 40
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000012153 distilled water Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000004132 cross linking Methods 0.000 claims abstract description 4
- 150000004676 glycans Chemical class 0.000 claims description 28
- 229920001282 polysaccharide Polymers 0.000 claims description 28
- 239000005017 polysaccharide Substances 0.000 claims description 28
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 5
- 241001005836 Euchloe ausonia Species 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- -1 filtered while hot Substances 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 238000004153 renaturation Methods 0.000 claims description 3
- 238000007669 thermal treatment Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims 1
- 230000004888 barrier function Effects 0.000 abstract description 4
- 239000000243 solution Substances 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 1
- 239000012460 protein solution Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Meat, Egg Or Seafood Products (AREA)
- Peptides Or Proteins (AREA)
Abstract
The invention relates to a fish scale collagen protein/pulullan compound edible film which comprises the raw materials in parts by weight: 50 parts of crudely extracted fish scale collagen protein, 40-60 parts of pulullan and 10-20 parts of glycerol. A preparation method comprises the steps of: (1) adding the crudely extracted fish scale collagen protein in distilled water with a temperature of 50 DEG C for stirring and dissolving, and filtering; (2), adding the pulullan in distilled water with a temperature of 60 DEG C for stirring and dissolving; (3), mixing a crudely extracted fish scale collagen protein solution with a pulullan solution, adding the glycerol, fully stirring uniformly at a normal temperature, carrying out a crosslinking reaction in a water bath with a temperature of 60 DEG C for 1 hour; and (4), pouring the solution in a smooth plastic plate, and drying to form the film. The fish scale collagen protein/pulullan compound edible film has better flexibility, plasticity and gas barrier property.
Description
Technical field
The present invention relates to compound edible film of a kind of fish scale collagen/pulullan polysaccharide and preparation method thereof, belong to edible film blending and modifying field.
Background technology
A large amount of uses of society plastic packaging film have caused plastic garbage to spread unchecked, the serious harm ecotope.Pack the replacement conventional plastic with the edibility natural macromolecular material and pack, become one of development trend of packaging industry.The edible film performance of different polymkeric substance preparations is different, the characteristics advantage is difference to some extent, carry out different polymkeric substance composite, can be in conjunction with the advantage of various polymkeric substance, improve the performance of single polymers, thereby obtaining having the polymkeric substance compound system of multiple premium properties, and can reduce cost, therefore is a kind of important method that preparation has the edible film of premium properties with the many kinds of substance blending and modifying.
Summary of the invention
The purpose of this invention is to provide compound edible film of a kind of fish scale collagen/pulullan polysaccharide and preparation method thereof, this edible composite film has preferably snappiness, plasticity-and gas barrier property.
For realizing above purpose, the compound edible film of a kind of fish scale collagen/pulullan polysaccharide of the present invention, raw material consists of: slightly carry 50 parts of fish scale collagens, pulullan polysaccharide 40-60 part, glycerine 10-20 part.
The thick extracting method of fish scale collagen of the present invention is: with fresh fish scale flushing post-drying, then pulverize, getting 1 part of pearl white is dissolved in 20 parts of distilled water, mix, place 75 ℃ of waters bath with thermostatic control to heat 6h, add 10 parts of distilled water every 2h, then add 1% citric acid, filtered while hot, filtrate are put into rapidly cooling renaturation 30min in-20 ℃ of refrigerators, get and slightly carry fish scale collagen.
The preparation method of the compound edible film of scale collagen fish scale collagen/pulullan polysaccharide of the present invention is: (1) will slightly put forward stirring and dissolving in the distilled water that fish scale collagen joins 50 ℃, filter; (2) pulullan polysaccharide is joined stirring and dissolving in 60 ℃ the distilled water; (3) will slightly propose fish scale collagen solution, the mixing of pulullan polysaccharide solution, add glycerine, stir crosslinking reaction 1h in 60 ℃ of water-baths under the normal temperature; (4) with solution casting on smooth plastic plate, drying and forming-film at 120 ℃ of thermal treatment 20min, gets the compound edible film of scale collagen fish scale collagen/pulullan polysaccharide after film broken away from.
Beneficial effect of the present invention is, the fish scale macromole has spirane structure, makes it possess certain thermostability and fibrous texture closely, makes collagen protein present stronger toughness and intensity.The plasticity-of pulullan polysaccharide, viscosity are all stronger, and gas barrier property is good, and the gases such as oxygen, nitrogen, carbonic acid gas and fragrance almost can not pass through, and reduce the nutritive loss of food in the storage process.Fish scale collagen and pulullan polysaccharide are carried out compositely can obtaining the edible composite film that snappiness is good, plasticity-is strong, gas barrier property is good in suitable ratio.
Embodiment
Embodiment 1:
The compound edible film of a kind of fish scale collagen/pulullan polysaccharide, raw material consists of: slightly carry 50 parts of fish scale collagens, 40 parts of pulullan polysaccharides, 10 parts of glycerine.
Embodiment 2:
The compound edible film of a kind of fish scale collagen/pulullan polysaccharide, raw material consists of: slightly carry 50 parts of fish scale collagens, 50 parts of pulullan polysaccharides, 15 parts of glycerine.
Embodiment 3:
The compound edible film of a kind of fish scale collagen/pulullan polysaccharide, raw material consists of: slightly carry 50 parts of fish scale collagens, 60 parts of pulullan polysaccharides, 20 parts of glycerine.
Embodiment 4:
The thick extracting method of fish scale collagen is: with fresh fish scale flushing post-drying, then pulverize, getting 1 part of pearl white is dissolved in 20 parts of distilled water, mix, place 75 ℃ of waters bath with thermostatic control to heat 6h, add 10 parts of distilled water every 2h, then add 1% citric acid, filtered while hot, filtrate are put into rapidly cooling renaturation 30min in-20 ℃ of refrigerators, get and slightly carry fish scale collagen.
Embodiment 5:
The preparation method of the compound edible film of a kind of fish scale collagen/pulullan polysaccharide is: (1) will slightly put forward stirring and dissolving in the distilled water that fish scale collagen joins 50 ℃, filter; (2) pulullan polysaccharide is joined stirring and dissolving in 60 ℃ the distilled water; (3) will slightly propose fish scale collagen solution, the mixing of pulullan polysaccharide solution, add glycerine, stir crosslinking reaction 1h in 60 ℃ of water-baths under the normal temperature; (4) with solution casting on smooth plastic plate, drying and forming-film at 120 ℃ of thermal treatment 20min, gets the compound edible film of scale collagen fish scale collagen/pulullan polysaccharide after film broken away from.
Claims (3)
1.
A kind ofThe compound edible film of scale collagen fish scale collagen/pulullan polysaccharide, it is characterized in that: raw material consists of: slightly carry 50 parts of fish scale collagens, pulullan polysaccharide 40-60 part, glycerine 10-20 part.
2. the compound edible film of a kind of scale collagen fish scale collagen/pulullan polysaccharide as claimed in claim 1, it is characterized in that: the thick extracting method of fish scale collagen is for washing post-drying with fresh fish scale, then pulverize, getting 1 part of pearl white is dissolved in 20 parts of distilled water, mix, place 75 ℃ of waters bath with thermostatic control to heat 6h, add 10 parts of distilled water every 2h, then add 1% citric acid, filtered while hot, filtrate is put into rapidly cooling renaturation 30min in-20 ℃ of refrigerators, gets and slightly carries fish scale collagen.
3. the compound edible film of a kind of scale collagen fish scale collagen/pulullan polysaccharide as claimed in claim 1 or 2, it is characterized in that: the preparation method is:
(1) will slightly put forward stirring and dissolving in the distilled water that fish scale collagen joins 50 ℃, filter;
(2) pulullan polysaccharide is joined stirring and dissolving in 60 ℃ the distilled water;
(3) will slightly propose fish scale collagen solution, the mixing of pulullan polysaccharide solution, add glycerine, stir crosslinking reaction 1h in 60 ℃ of water-baths under the normal temperature;
On smooth plastic plate, drying and forming-film afterwards at 120 ℃ of thermal treatment 20min, gets the compound edible film of fish scale collagen/pulullan polysaccharide with the film disengaging with solution casting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210565430.9A CN102964849B (en) | 2012-12-24 | 2012-12-24 | A kind of fish scale collagen protein/pullulan composite edible membrane and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210565430.9A CN102964849B (en) | 2012-12-24 | 2012-12-24 | A kind of fish scale collagen protein/pullulan composite edible membrane and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102964849A true CN102964849A (en) | 2013-03-13 |
| CN102964849B CN102964849B (en) | 2015-10-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210565430.9A Active CN102964849B (en) | 2012-12-24 | 2012-12-24 | A kind of fish scale collagen protein/pullulan composite edible membrane and preparation method thereof |
Country Status (1)
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| CN (1) | CN102964849B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103030978A (en) * | 2012-12-24 | 2013-04-10 | 青岛佰众化工技术有限公司 | Fish scale collagen/ pullulan composite edible membrane and preparation method thereof |
| CN103613939A (en) * | 2013-12-10 | 2014-03-05 | 湖北工业大学 | Polysaccharide-protein composite membrane and preparation method thereof |
| CN106726629A (en) * | 2016-11-29 | 2017-05-31 | 涂方颖 | A kind of method for preparing the compound edible face pack paper of polysaccharide collagen |
| US11319566B2 (en) | 2017-04-14 | 2022-05-03 | Capsugel Belgium Nv | Process for making pullulan |
| US11576870B2 (en) | 2017-04-14 | 2023-02-14 | Capsugel Belgium Nv | Pullulan capsules |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6180150B1 (en) * | 1997-07-11 | 2001-01-30 | World-Pac International Ag | Process for packing foodstuffs with a film |
| WO2007149276A2 (en) * | 2006-06-16 | 2007-12-27 | Tate & Lyle Ingredients Americas, Inc. | Pullulan films and their use in edible packaging |
| CN103030978A (en) * | 2012-12-24 | 2013-04-10 | 青岛佰众化工技术有限公司 | Fish scale collagen/ pullulan composite edible membrane and preparation method thereof |
-
2012
- 2012-12-24 CN CN201210565430.9A patent/CN102964849B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6180150B1 (en) * | 1997-07-11 | 2001-01-30 | World-Pac International Ag | Process for packing foodstuffs with a film |
| WO2007149276A2 (en) * | 2006-06-16 | 2007-12-27 | Tate & Lyle Ingredients Americas, Inc. | Pullulan films and their use in edible packaging |
| CN103030978A (en) * | 2012-12-24 | 2013-04-10 | 青岛佰众化工技术有限公司 | Fish scale collagen/ pullulan composite edible membrane and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 梁志等: ""鱼鳞制备的可食用膜性能测定"", 《现代农业科技》 * |
| 高丹丹等: ""普鲁兰多糖-明胶可食用膜封合工艺的优化"", 《食品工业科技》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103030978A (en) * | 2012-12-24 | 2013-04-10 | 青岛佰众化工技术有限公司 | Fish scale collagen/ pullulan composite edible membrane and preparation method thereof |
| CN103030978B (en) * | 2012-12-24 | 2015-07-08 | 青岛文创科技有限公司 | Fish scale collagen/ pullulan composite edible membrane and preparation method thereof |
| CN103613939A (en) * | 2013-12-10 | 2014-03-05 | 湖北工业大学 | Polysaccharide-protein composite membrane and preparation method thereof |
| CN106726629A (en) * | 2016-11-29 | 2017-05-31 | 涂方颖 | A kind of method for preparing the compound edible face pack paper of polysaccharide collagen |
| US11319566B2 (en) | 2017-04-14 | 2022-05-03 | Capsugel Belgium Nv | Process for making pullulan |
| US11576870B2 (en) | 2017-04-14 | 2023-02-14 | Capsugel Belgium Nv | Pullulan capsules |
| US11878079B2 (en) | 2017-04-14 | 2024-01-23 | Capsugel Belgium Nv | Pullulan capsules |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102964849B (en) | 2015-10-21 |
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Owner name: QINGDAO WINCHANCE TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: QINGDAO HAIER SOFTWARE CO., LTD. Effective date: 20150820 |
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| C41 | Transfer of patent application or patent right or utility model | ||
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| CB03 | Change of inventor or designer information |
Inventor after: Su Jianli Inventor before: Yu Zhongqing Inventor before: Fu Rao |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: YU ZHONGQING FU RAO TO: SU JIANLI |
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Effective date of registration: 20150820 Address after: 266061 Shandong, Laoshan, Hongkong East Road, No. Pioneering Park, biological park, room 248, No. 239 Applicant after: Qingdao Wenchuang Science & Technology Co., Ltd. Address before: Laoshan District Green Road 266000 Shandong city of Qingdao province No. 19 22 11 floor Applicant before: Haiersoft Corporation |
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Effective date of registration: 20180927 Address after: 226100 No. 40 Zhonghua East Road, three Factory Street, Haimen City, Nantong, Jiangsu Patentee after: Nantong Mega new Mstar Technology Ltd Address before: 266061 Qingdao Hongkong Laoshan road 248, Pioneer Park, 239 Biological Park 239 Patentee before: Qingdao Wenchuang Science & Technology Co., Ltd. |
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