CN102964081A - Composite animal and vegetable protein foaming agent - Google Patents
Composite animal and vegetable protein foaming agent Download PDFInfo
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- CN102964081A CN102964081A CN2012104160231A CN201210416023A CN102964081A CN 102964081 A CN102964081 A CN 102964081A CN 2012104160231 A CN2012104160231 A CN 2012104160231A CN 201210416023 A CN201210416023 A CN 201210416023A CN 102964081 A CN102964081 A CN 102964081A
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Abstract
The invention discloses a composite animal and vegetable protein foaming agent, comprising the following materials, by weight: 1-10 parts of trotter, 1-6 parts of a horn powder, 2-6 parts of soybean meal, 1-5 parts of distillers' grains, 1-5 parts of fatty alcohol polyoxyethylene ether sulfate sodium, 1- 5 parts of sodium dodecyl benzene sulfonate, 1-3 parts of tea saponin, 2-4 parts of sodium bisulfite, 2-4 parts of thiourea, 5-10 parts of urea, 3-4 parts of calcium hydroxide,1-3 parts of phospholipid, 2-3 parts of gelatin and 150-200 parts of water. The compound protein foaming agent prepared from vegetable protein in the invention has performance better than that of a single animal or vegetable protein foaming agent, so as to solve the problem of poor comprehensive performance of a single protein component foaming agent. The composite animal and vegetable protein foaming agent produced by the invention has excellent foaming capacity, foam stability and compatibility with concrete, effectively improves the performance of foam concrete, and provides technical support for preparation of a novel wall material.
Description
Technical field
The present invention relates to a kind of whipping agent, be specifically related to a kind of compound animal/vegetable protein whipping agent.
Background technology
Along with the raising of country to the energy-saving building materials requirement, foamed concrete is subject to paying close attention to more and more widely, and foamed concrete is " close hole " light building material that is contained a large amount of sealed porositys by the inside that cast sclerosis after the main raw material fusion such as cement, lime, flyash, sand and admixture evenly forms.Whipping agent is a key factor of producing foamed concrete, and its performance is directly determining the quality of foamed concrete.The foam that concrete foamer requires to produce wants tiny even, steady time is long, when joining concrete, do not produce on a large scale and break, behind concrete coagulation, can form uniform sealed porosity, just produced thus the cellular concrete product that meets national standard.
In the prior art, concrete foamer is from early stage changing to protein substance gradually as the foaming source take surfactant-based material, the states such as the U.S., Japan, Italy develop multiple efficient protein matter class whipping agent in succession, and demonstrate gradually the advantage of its high stability, obtained larger application.Compare with external maturation protein whipping agent, China's single component protein foaming agent exists problems. be in particular in that vegetable-protein sends out
Infusion foam expansion and froth stability are undesirable, and the animal protein foaming agent foam expansion is high and stability is strong, but industrial scale is limited and expensive, and solving the not high problem of single protein component whipping agent over-all properties has become task too impatient to wait.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of compound animal/vegetable protein whipping agent is provided, thereby solve the not high problem of single protein component whipping agent over-all properties.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of compound animal/vegetable protein whipping agent, raw material by following weight part is made: Unguis Sus domestica 1-10 part, horn powder 1-6 part, dregs of beans 2-6 part, vinasse 1-5 part, polyoxyethylenated alcohol sodium sulfate 1-5 part, Sodium dodecylbenzene sulfonate 1-5 part, tea saponin 1-3 part, sodium bisulfite 2-4 part, thiocarbamide 2-4 part, urea 5-10 part, calcium hydroxide 3-4 part, phosphatidase 11-3 part, gelatin 2-3 part, water 150-200 part.
A kind of preparation method of compound animal/vegetable protein whipping agent may further comprise the steps:
(1) presses formulation ratio with the water mixing of Unguis Sus domestica, sodium bisulfite, thiocarbamide, urea and 40-50%, regulate pH to 5-6, then at 70-80 ℃ of lower hydrolysis 5-6h, be transferred to rapidly after reaction finishes and be cooled to normal temperature in the water-bath, centrifugal, to filter, filtrate is the animal protein foaming agent mother liquor;
(2) press formulation ratio dregs of beans, vinasse, calcium hydroxide and remaining water are mixed, at 80-90 ℃ of lower hydrolysis 4-5h, be transferred to rapidly after reaction finishes and be cooled to normal temperature in the water-bath, centrifugal, to filter, filtrate is vegetable-protein whipping agent mother liquor;
(3) the above-mentioned animal protein foaming agent mother liquor that makes and vegetable-protein whipping agent mother liquor are mixed, add remaining raw material, heat to 40-50 ℃, stir, after raw material fully dissolves, be cooled to normal temperature and namely get compound animal/vegetable protein whipping agent.
Beneficial effect of the present invention:
The present invention utilizes the conjugated protein whipping agent of animal/vegetable protein preparation, and its performance is better than by single animal or plant protein foaming agent, thereby solves the not high problem of single protein component whipping agent over-all properties.The compound animal/vegetable protein whipping agent that the present invention produces have good foaming power, foamed stability and and the concrete consistency, properties that can Effective Raise foamed concrete is for the preparation of novel wall material provides technical support; The used raw material sources of the present invention are abundant, easy a large amount of the acquisition, and cheap, the feature of environmental protection good, easily realize large-scale industrialized production.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment
A kind of preparation method of compound animal/vegetable protein whipping agent may further comprise the steps:
(1) water of getting 8 parts of Unguis Sus domesticas, 3 parts of sodium bisulfites, 2 parts of thiocarbamides, 6 parts of urea and 120 parts mixes, and regulates pH to 5.5, then at 75 ℃ of lower hydrolysis 6h, be transferred to rapidly after reaction finishes and be cooled to normal temperature in the water-bath, centrifugal, to filter, filtrate is the animal protein foaming agent mother liquor;
(2) get 5 parts of dregs of beans, 3 parts of vinasses, 3 parts of calcium hydroxides and 80 parts of water and mix, at 90 ℃ of lower hydrolysis 4h, be transferred to rapidly after reaction finishes and be cooled to normal temperature in the water-bath, centrifugal, to filter, filtrate is vegetable-protein whipping agent mother liquor;
(3) the above-mentioned animal protein foaming agent mother liquor that makes and vegetable-protein whipping agent mother liquor are mixed, add 3 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of Sodium dodecylbenzene sulfonatees, 2 parts of tea saponins, 1.5 parts of phosphatide, 2 parts of gelatin, heat to 40-50 ℃, stir, after raw material fully dissolves, be cooled to normal temperature and namely get compound animal/vegetable protein whipping agent.
The compound animal/vegetable protein whipping agent that present embodiment makes has that the frostproof froth n. multiple is large, stability is high, the advantages such as foam uniform and smooth, and performance comparison such as the following table of common single protein ingredient whipping agent:
| Product category | Foam expansion/doubly | Steady bubble time/h | Foaming height/cm | Bleeding quantity/mL |
| Composite foamable agent of the present invention | 38 | 9.2 | 12.5 | 8 |
| Common single whipping agent | 27 | 6.8 | 10.2 | 15 |
The whipping agent that makes is added in the concrete to preparation foamed concrete:
Controlling the design density of newly mixing foamed concrete when the foamed concrete sample prepares is 1000kg/m
3, 425 silicate cement consumption 950kg, water reducer 4.5kg, flyash 260kg, water consumption 200kg stirs.The whipping agent that makes is stirred into uniform foam, and getting the foams accumulated amount is 0.8m
3, with slurry mixing and stirring, mould molding, after maintenance in 28 days, the concrete performance of test sees the following form.
Claims (2)
1. compound animal/vegetable protein whipping agent, it is characterized in that, raw material by following weight part is made: Unguis Sus domestica 1-10 part, horn powder 1-6 part, dregs of beans 2-6 part, vinasse 1-5 part, polyoxyethylenated alcohol sodium sulfate 1-5 part, Sodium dodecylbenzene sulfonate 1-5 part, tea saponin 1-3 part, sodium bisulfite 2-4 part, thiocarbamide 2-4 part, urea 5-10 part, calcium hydroxide 3-4 part, phosphatidase 11-3 part, gelatin 2-3 part, water 150-200 part.
2. the preparation method of a compound animal/vegetable protein whipping agent as claimed in claim 1 is characterized in that may further comprise the steps:
(1) presses formulation ratio with the water mixing of Unguis Sus domestica, sodium bisulfite, thiocarbamide, urea and 40-50%, regulate pH to 5-6, then at 70-80 ℃ of lower hydrolysis 5-6h, be transferred to rapidly after reaction finishes and be cooled to normal temperature in the water-bath, centrifugal, to filter, filtrate is the animal protein foaming agent mother liquor;
(2) press formulation ratio dregs of beans, vinasse, calcium hydroxide and remaining water are mixed, at 80-90 ℃ of lower hydrolysis 4-5h, be transferred to rapidly after reaction finishes and be cooled to normal temperature in the water-bath, centrifugal, to filter, filtrate is vegetable-protein whipping agent mother liquor;
(3) the above-mentioned animal protein foaming agent mother liquor that makes and vegetable-protein whipping agent mother liquor are mixed, add remaining raw material, heat to 40-50 ℃, stir, after raw material fully dissolves, be cooled to normal temperature and namely get compound animal/vegetable protein whipping agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210416023.1A CN102964081B (en) | 2012-10-26 | 2012-10-26 | Composite animal and vegetable protein foaming agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210416023.1A CN102964081B (en) | 2012-10-26 | 2012-10-26 | Composite animal and vegetable protein foaming agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102964081A true CN102964081A (en) | 2013-03-13 |
| CN102964081B CN102964081B (en) | 2014-07-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210416023.1A Expired - Fee Related CN102964081B (en) | 2012-10-26 | 2012-10-26 | Composite animal and vegetable protein foaming agent |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098343A (en) * | 2013-04-15 | 2014-10-15 | 北京华德创业环保设备有限公司 | Foaming agent for filling materials |
| CN104609784A (en) * | 2015-01-06 | 2015-05-13 | 无为县严桥双龙建材厂 | High-performance foam concrete |
| CN104761746A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | PVC material compound foaming agent |
| CN107549443A (en) * | 2017-10-25 | 2018-01-09 | 武汉轻工大学 | A kind of preparation method of compound protein foaming agent |
| CN108147733A (en) * | 2016-12-03 | 2018-06-12 | 化晨冰 | A kind of insulated standard and its processing technology |
| CN110015906A (en) * | 2018-01-08 | 2019-07-16 | 北新集团建材股份有限公司 | A kind of low density paper surface gypsum board and its preparation process |
| CN111233365A (en) * | 2020-03-13 | 2020-06-05 | 浙江同为建材有限公司 | Soybean meal-based foam concrete foaming agent and preparation method and application thereof |
| CN115073208A (en) * | 2022-07-04 | 2022-09-20 | 广东中地新材料科技有限公司 | Heat storage type ground heating backfill cushion layer and preparation method and application thereof |
| CN115772036A (en) * | 2022-12-20 | 2023-03-10 | 鞍山钢铁冶金炉材科技有限公司 | Crack-reducing magnesium tundish prefabricated part and preparation method and application thereof |
| CN115869578A (en) * | 2022-09-26 | 2023-03-31 | 中国矿业大学(北京) | Gel protein foam extinguishing agent for fire in oil tank and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329149A (en) * | 2011-07-12 | 2012-01-25 | 梁材 | Foaming agent for sound absorption foam concrete product and preparation method for foaming agent |
| CN102515827A (en) * | 2011-12-08 | 2012-06-27 | 天津市裕川环境科技有限公司 | Method for preparing light foam concrete by using compound protein foaming agent |
-
2012
- 2012-10-26 CN CN201210416023.1A patent/CN102964081B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329149A (en) * | 2011-07-12 | 2012-01-25 | 梁材 | Foaming agent for sound absorption foam concrete product and preparation method for foaming agent |
| CN102515827A (en) * | 2011-12-08 | 2012-06-27 | 天津市裕川环境科技有限公司 | Method for preparing light foam concrete by using compound protein foaming agent |
Non-Patent Citations (2)
| Title |
|---|
| 于水军等: "复合型动植物蛋白发泡剂的制备及其性能研究", 《河南理工大学学报（自然科学版）》 * |
| 寿崇琦等: "一种动物蛋白水泥发泡剂的研制及其复合应用", 《化学建材》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098343A (en) * | 2013-04-15 | 2014-10-15 | 北京华德创业环保设备有限公司 | Foaming agent for filling materials |
| CN104609784A (en) * | 2015-01-06 | 2015-05-13 | 无为县严桥双龙建材厂 | High-performance foam concrete |
| CN104761746A (en) * | 2015-03-19 | 2015-07-08 | 苏州市景荣科技有限公司 | PVC material compound foaming agent |
| CN108147733A (en) * | 2016-12-03 | 2018-06-12 | 化晨冰 | A kind of insulated standard and its processing technology |
| CN107549443A (en) * | 2017-10-25 | 2018-01-09 | 武汉轻工大学 | A kind of preparation method of compound protein foaming agent |
| CN110015906A (en) * | 2018-01-08 | 2019-07-16 | 北新集团建材股份有限公司 | A kind of low density paper surface gypsum board and its preparation process |
| CN110015906B (en) * | 2018-01-08 | 2021-03-23 | 北新集团建材股份有限公司 | Low-density paper-surface gypsum board and preparation process thereof |
| CN111233365A (en) * | 2020-03-13 | 2020-06-05 | 浙江同为建材有限公司 | Soybean meal-based foam concrete foaming agent and preparation method and application thereof |
| CN115073208A (en) * | 2022-07-04 | 2022-09-20 | 广东中地新材料科技有限公司 | Heat storage type ground heating backfill cushion layer and preparation method and application thereof |
| CN115869578A (en) * | 2022-09-26 | 2023-03-31 | 中国矿业大学(北京) | Gel protein foam extinguishing agent for fire in oil tank and preparation method thereof |
| CN115772036A (en) * | 2022-12-20 | 2023-03-10 | 鞍山钢铁冶金炉材科技有限公司 | Crack-reducing magnesium tundish prefabricated part and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102964081B (en) | 2014-07-09 |
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