CN102952378B - Modified nano-clay dinner plate material and processing method thereof - Google Patents
Modified nano-clay dinner plate material and processing method thereof Download PDFInfo
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- CN102952378B CN102952378B CN201210399762.4A CN201210399762A CN102952378B CN 102952378 B CN102952378 B CN 102952378B CN 201210399762 A CN201210399762 A CN 201210399762A CN 102952378 B CN102952378 B CN 102952378B
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Abstract
The invention discloses a modified nano-clay dinner plate material and a processing method thereof. The modified nano-clay dinner plate material comprises the following raw materials by weight parts: 68-72 parts of butylene phthalate, 14-16 parts of of ABS (Acrylonitrile Butadiene Styrene) high-glue powder, 8-12 parts of of polycaprolactone, 18-22 parts of imarcaptoacetate dioctyltin, 4-6 parts of modified nano-clay, 1-3 parts of vinyltriethoxysilane, 0.3-0.5 part of ethylene bis-stearamide, 0.03-0.05 part of fatty alcohol polyoxyethylene ether, 0.1-0.2 part of chlorinated paraffin, 13-15 parts of titanium dioxide, 3-5 parts of dibutyl phthalate, 0.05-0.08 part of ultraviolet screening agent, 0.4-0.6 part of azodicarbonamide and 0.8-1.2 pats of antioxidant DSTP. The modified nano-clay dinner plate material is reasonable in formula; and the modified nano-clay and the chlorinated paraffin are added in the raw materials, and the nano-clay is modified, so that the good performance of a high polymer material in the raw materials is improved, and the modified nano-clay dinner plate material is environment-friendly and practical.
Description
Technical field
The present invention relates to service plate preparing technical field, be specifically related to a kind of modified Nano potter's clay service plate material and working method thereof.
Background technology
Service plate goods are widely used in people's life, the traditional manufacturing technique of service plate goods generally comprises key steps such as drying material, colour mixture, foaming, tradition service plate foam process is divided into chemical foaming, physical blowing and mechanical foaming three types conventionally, in actual production, select applicable service plate foam process type according to service plate characteristic, for example EVA (ethene-vinyl acetate copolymer) is relatively applicable to adopting chemical foaming technology to foam, chemical foaming technology is to borrow mechanical stirring that service plate raw material is fully mixed, and then forms the process of foaming service plate through sizing; The service plate goods that this chemical foaming technology makes are to be formed through molding sizing by raw material liquefactent, are not easy to people and adjust according to actual needs color and the structure of service plate foaming product.
Traditional service plate material is owing to can not reaching environmental protection standard, and poisonous have a taste, and therefore use range is restricted, and in order to use in the larger scope in space, formula and complete processing all need to improve.
Summary of the invention
The object of the present invention is to provide a kind of modified Nano potter's clay service plate material and working method thereof.
The present invention adopts following technical scheme to achieve these goals:
Modified Nano potter's clay service plate material, the weight part of its constitutive material is:
Vinegar 8-12, white carbon black 18-22, modified Nano potter's clay 4-6, vinyltriethoxysilane 1-3, ethylene bis stearamide 0.3-0.5, fatty alcohol-polyoxyethylene ether 0.03-0.05, clorafin 0.1-0.2, titanium dioxide 13-15, phthalic acid dibutyl ester 3-5, anti ultraviolet agent 0.05-0.08, Cellmic C 121 0.4-0.6 and oxidation inhibitor DSTP 0.8-1.2 in benzene dicarboxylic acid butanediol ester 68-72, ABS high glue powder 14-16, poly-caproic acid.
Modified Nano potter's clay service plate material, the weight part of its constitutive material is: vinegar 10, white carbon black 20, modified Nano potter's clay 5, modified Nano powder 2, vinyltriethoxysilane 2, ethylene bis stearamide 0.4, fatty alcohol-polyoxyethylene ether 0.04, water soluble phenol resin 0.15, titanium dioxide 14, phthalic acid dibutyl ester 4, anti ultraviolet agent 0.07, Cellmic C 121 0.5 and oxidation inhibitor DSTP 1 in benzene dicarboxylic acid butanediol ester 70, ABS high glue powder 15, poly-caproic acid.
The working method of modified Nano potter's clay service plate material, comprises the following steps:
(1) take each raw material by the weight part of constitutive material, vinegar in benzene dicarboxylic acid butanediol ester, ABS high glue powder and poly-caproic acid is mixed at 85-90 DEG C of temperature and mixes 10-15 minute, obtain mixture;
(2) in the mixture of step (1), add remaining other constitutive material, heated and stirred, to 180-210 DEG C, causes grain to obtain.
Described modified Nano potter's clay preparation method will adopt potter's clay to mix with silane coupling agent, silane coupling agent consumption is the 3-5% of potter's clay, be heated to 50-60 DEG C and stir 20-30 minute, add again and potter's clay nano silicon in proportion, 1% nano-sized carbon, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
Beneficial effect of the present invention:
The present invention fills a prescription rationally, has increased modified Nano potter's clay and clorafin in raw material, by nanometer potter's clay modification, has improved the premium properties of the macromolecular material in starting material, environmental protection practicality.
Embodiment
Embodiment 1: modified Nano potter's clay service plate material, the weight part of its constitutive material is: vinegar 10, white carbon black 20, modified Nano potter's clay 5, modified Nano powder 2, vinyltriethoxysilane 2, ethylene bis stearamide 0.4, fatty alcohol-polyoxyethylene ether 0.04, water soluble phenol resin 0.15, titanium dioxide 14, phthalic acid dibutyl ester 4, anti ultraviolet agent 0.07, Cellmic C 121 0.5 and oxidation inhibitor DSTP 1 in benzene dicarboxylic acid butanediol ester 70, ABS high glue powder 15, poly-caproic acid.
The working method of modified Nano potter's clay service plate material, comprises the following steps:
(1) take each raw material by the weight part of constitutive material, vinegar in benzene dicarboxylic acid butanediol ester, ABS high glue powder and poly-caproic acid is mixed at 85-90 DEG C of temperature and mixes 10-15 minute, obtain mixture;
(2) in the mixture of step (1), add remaining other constitutive material, heated and stirred, to 180-210 DEG C, causes grain to obtain.
Modified Nano potter's clay preparation method will adopt potter's clay to mix with silane coupling agent, silane coupling agent consumption is the 3-5% of potter's clay, be heated to 50-60 DEG C and stir 20-30 minute, add again and potter's clay nano silicon in proportion, 1% nano-sized carbon, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
Be service plate material by material injection molding obtained above, its performance index are as follows:
The performance perameter of the service plate that the present embodiment is produced sees the following form.
| Project | Index | The present embodiment service plate |
| Density (g/cm) | ≤1.2 | 0.96 |
| Tensile strength (MPa) | ≥20.0 | 28.75 |
| Shock strength is (KJ/ ㎡) longitudinally | ≥7.0 | 9.43 |
| Shock strength is (KJ/ ㎡) laterally | ≥3.5 | 5.89 |
| Vicat softening point (DEG C) | ≥120℃ | 168 |
| Longitudinal size velocity of variation (%) | ＜60 | 45 |
Claims (2)
1. a modified Nano potter's clay service plate material, is characterized in that the weight part of its constitutive material is:
Benzene dicarboxylic acid butanediol ester 68-72, ABS high glue powder 14-16, polycaprolactone 8-12, white carbon black 18-22, modified Nano potter's clay 4-6, vinyltriethoxysilane 1-3, ethylene bis stearamide 0.3-0.5, fatty alcohol-polyoxyethylene ether 0.03-0.05, clorafin 0.1-0.2, titanium dioxide 13-15, phthalic acid dibutyl ester 3-5, anti ultraviolet agent 0.05-0.08, Cellmic C 121 0.4-0.6 and oxidation inhibitor DSTP 0.8-1.2; Described modified Nano potter's clay preparation method will adopt potter's clay to mix with silane coupling agent, silane coupling agent consumption is the 3-5% of potter's clay, be heated to 50-60 DEG C and stir 20-30 minute, add again and potter's clay nano silicon in proportion, 1% nano-sized carbon, high speed dispersion, ovendry power is broken into 300-350 order powder, obtains modified Nano potter's clay.
2. a working method for modified Nano potter's clay service plate material as claimed in claim 1, is characterized in that comprising the following steps:
(1) take each raw material by the weight part of constitutive material, benzene dicarboxylic acid butanediol ester, ABS high glue powder and polycaprolactone are mixed at 85-90 DEG C of temperature and mix 10-15 minute, obtain mixture;
(2) in the mixture of step (1), add remaining other constitutive material, heated and stirred, to 180-210 DEG C, causes grain to obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210399762.4A CN102952378B (en) | 2012-10-19 | 2012-10-19 | Modified nano-clay dinner plate material and processing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210399762.4A CN102952378B (en) | 2012-10-19 | 2012-10-19 | Modified nano-clay dinner plate material and processing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102952378A CN102952378A (en) | 2013-03-06 |
| CN102952378B true CN102952378B (en) | 2014-07-23 |
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| CN201210399762.4A Expired - Fee Related CN102952378B (en) | 2012-10-19 | 2012-10-19 | Modified nano-clay dinner plate material and processing method thereof |
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| CN102964694B (en) * | 2012-10-19 | 2015-11-25 | 芜湖太平洋塑胶有限公司 | It is a kind of that high strength is resistance to falls PP plastics service plate and manufacture craft thereof |
| CN111154238B (en) * | 2020-01-17 | 2021-12-28 | 杭州普信塑料包装有限公司 | Impact-resistant PET material and preparation method thereof |
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| CN100344688C (en) * | 2005-01-07 | 2007-10-24 | 四川大学 | High performance polymer composite material capable of forming inorganic nano-particle network and its preparation method |
| CN102040380A (en) * | 2009-10-24 | 2011-05-04 | 朱艳 | Inorganic polymer bamboo charcoal tableware |
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